• Title/Summary/Keyword: Physical dependence

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Dielectric and Electrical Characteristics of Lead-Free Complex Electronic Material: Ba0.8Ca0.2(Ti0.8Zr0.1Ce0.1)O3

  • Sahu, Manisha;Hajra, Sugato;Choudhary, Ram Naresh Prasad
    • Korean Journal of Materials Research
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    • v.29 no.8
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    • pp.469-476
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    • 2019
  • A lead-free bulk ceramic having a chemical formula $Ba_{0.8}Ca_{0.2}(Ti_{0.8}Zr_{0.1}Ce_{0.1})O_3$ (further termed as BCTZCO) is synthesized using mixed oxide route. The structural, dielectric, impedance, and conductivity properties, as well as the modulus of the synthesized sample are discussed in the present work. Analysis of X-ray diffraction data obtained at room temperature reveals the existence of some impurity phases. The natural surface morphology shows close packing of grains with few voids. Attempts have been made to study the (a) effect of microstructures containing grains, grain boundaries, and electrodes on impedance and capacitive characteristics, (b) relationship between properties and crystal structure, and (c) nature of the relaxation mechanism of the prepared samples. The relationship between the structure and physical properties is established. The frequency and temperature dependence of the dielectric properties reveal that this complex system has a high dielectric constant and low tangent loss. An analysis of impedance and related parameters illuminates the contributions of grains. The activation energy is determined for only the high temperature region in the temperature dependent AC conductivity graph. Deviation from the Debye behavior is seen in the Nyquist plot at different temperatures. The relaxation mechanism and the electrical transport properties in the sample are investigated with the help of various spectroscopic (i.e., dielectric, modulus, and impedance) techniques. This lead free sample will serve as a base for device engineering.

Magnetic properties and magnetocaloric effect of Sr-doped Pr0.7Ca0.3MnO3 compounds

  • Yen, Pham Duc Huyen;Dung, Nguyen Thi;Thanh, Tran Dang;Yu, Seong-Cho
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1280-1288
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    • 2018
  • In this work, we pointed out that Sr substitution for Ca leads to modify the magnetic and magnetocaloric properties of $Pr_{0.7}Ca_{0.3-x}Sr_xMnO_3$ compounds. Analyzing temperature dependence of magnetization, M(T), proves that the Curie temperature ($T_C$) increased with increasing Sr content (x); $T_C$ value is found to be 130-260 K for x = 0.0-0.3, respectively. Using the phenomenological model and M(T,H) data measured at several applied magnetic field, the magnetocaloric effect of $Pr_{0.7}Ca_{0.3-x}Sr_xMnO_3$ compounds has been investigated through their temperature and magnetic field dependences of magnetic entropy change ${\Delta}S_m$(T,H) and the change of the specific heat change ${\Delta}C_P$(T,H). Under an applied magnetic field change of 10 kOe, the maximum value of $-{\Delta}S_m$ is found to be about $3J/kg{\cdot}K$, and the maximum and minimum values of ${\Delta}C_P$(T) calculated to be about ${\pm}60J/kg{\cdot}K$ for x = 0.3 sample. Additionally, the critical behaviors of $Pr_{0.7}Ca_{0.3-x}Sr_xMnO_3$ compounds around their $T_C$ have been also analyzed. Results suggested a coexistence of the ferromagnetic short- and long-range interactions in samples. Moreover, Sr-doping favors establishing the short-range interactions.

Rotation Speed Dependence of ZnO Coating Layer on SnSe powders by Rotary Atomic Layer Deposition Reactor (회전형 원자층 증착기의 회전 속도에 따른 SnSe 분말 상 ZnO 박막 증착)

  • Jung, Myeong Jun;Yun, Ye Jun;Byun, Jongmin;Choi, Byung Joon
    • Journal of Powder Materials
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    • v.28 no.3
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    • pp.239-245
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    • 2021
  • The SnSe single crystal shows an outstanding figure of merit (ZT) of 2.6 at 973 K; thus, it is considered to be a promising thermoelectric material. However, the mass production of SnSe single crystals is difficult, and their mechanical properties are poor. Alternatively, we can use polycrystalline SnSe powder, which has better mechanical properties. In this study, surface modification by atomic layer deposition (ALD) is chosen to increase the ZT value of SnSe polycrystalline powder. SnSe powder is ground by a ball mill. An ALD coating process using a rotary-type reactor is adopted. ZnO thin films are grown by 100 ALD cycles using diethylzinc and H2O as precursors at 100℃. ALD is performed at rotation speeds of 30, 40, 50, and 60 rpm to examine the effects of rotation speed on the thin film characteristics. The physical and chemical properties of ALD-coated SnSe powders are characterized by scanning and tunneling electron microscopy combined with energy-dispersive spectroscopy. The results reveal that a smooth oxygen-rich ZnO layer is grown on SnSe at a rotation speed of 30 rpm. This result can be applied for the uniform coating of a ZnO layer on various powder materials.

How Supernovae Ejecta Is Transported In A Galaxy: DependenceOn Hydrodynamic Schemes In Numerical Simulations

  • Shin, Eun-jin;Kim, Ji-hoon
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.48.4-48.4
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    • 2019
  • We studied the metal-distribution of isolated Milky-way mass galaxy using various hydrodynamic solvers and investigated the difference of the result between AMR and SPH codes. In particle-based codes, physical quantities like mass or metallicity defined in each particle are conserved unless being injected explicitly by the effect of the supernova, whereas in the Eulerian codes the diffusion is simply accomplished by hydro-equation. Therefore, without including explicit physics of diffusion on the SPH- codes, the metal mixing in the galaxy or CGM only can be accomplished by the direct motion of the particles, however, the standard-SPH codes depress the instability of the turbulent fluid mixing. In this work, we simulated under common initial conditions, common gas-physics like cooling-heating models, and star-formation feedback using ENZO(AMR) GIZMO and GADGET-2 codes. We additionally included a metal-diffusion algorithm on the SPH-codes, which follows the subgrid-turbulent mixing model investigated by Shen et al. (2010) and compared the effect of the metal-outflow on the halo region of the galaxy in different hydro-solvers. We also found that for the implementation of the diffusion scheme in the SPH-codes, the existence of a sufficient number of the gas-particles, which is the carrier of the metals, is necessary. So we tested a new initial condition for proper implementation of the diffusion scheme on the SPH simulations. By comparing the metal-contamination of the circumgalactic medium with different hydrodynamics models, we quantify the diffusion strength of AMR codes using diffusion parameterization of the SPH codes and also suggest the calibration solutions in the different behavior of codes in metal-outflow.

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Pilot Study - Development of Sit-To-Stand and Stand-To-Sit Muscle-Assisted Wearable Robot Algorithms in Elderly Patients with Hip Angle and Angular Velocity (Pilot Study - 고관절 각도 및 각속도 기반 기립(Sit-To-Stand) 및 착석(Stand-To-Sit) 근력 지원 웨어러블 로봇 알고리즘 개발)

  • Yonghyun Lee;Jintak Choi;Dongbin Shin;Yeonghoon Ji;Hyeyeon Jang;Changsoo Han;Yeonjoon Lee
    • The Journal of Korea Robotics Society
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    • v.18 no.4
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    • pp.385-391
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    • 2023
  • In the elderly population, sarcopenia occurs due to physical aging, leading to movement restrictions and loss of function. This results in dependence on daily activities and limitations in participation, ultimately decreasing the overall quality of life. In this study, we propose an algorithm designed to enable patients with sarcopenia to perform sit-to-stand and stand-to-sit movements seamlessly in their daily lives. The algorithm incorporates a wearable robot for muscle support and includes algorithms for standing and seated muscle strength support. To validate the algorithm's performance, EMG sensors were attached to the Rectus Femoris and Biceps Femoris muscles. The participants underwent two scenarios: one without wearing the device and one with the device providing muscle strength support, performing sit-to-stand and stand-to-sit motions for one minute in each case. The results showed a 16% increase in the EMG peak value of the Rectus Femoris muscle during standing motion (p=0.009). On the right side, there was a roughly 20% decrease (p=0.018) during standing and a 21% decrease (p=0.014) during sitting motion. In the future, we aim to gather additional data to further refine the algorithm. Our goal is to develop an optimal muscle strength support algorithm based on this data, making it applicable for real-life use by patients with sarcopenia.

Applying Axiomatic Design to Design Evaluation of a Deep-Sea Manganese Nodule Miner (공리적 설계를 적용한 심해저 망간단괴 집광시스템의 설계평가)

  • Choi, Jong-Su;Hong, Sup;Kim, Hyung-Woo;Yeu, Tae-Kyung;Lee, Tae-Hee
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.13 no.3
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    • pp.246-251
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    • 2008
  • The conceptual design evaluation of Deep-Sea Manganese Nodule Miner(DSNM) based on Axiomatic Design was preformed. Functional Requirements(FRs) in functional domain and Design Parameters(DPs) in physical domain were embodied for the given concept design of DSNM. Interactions between FRs and DPs were sequentially analyzed from the first level hierarchy to the lower level hierarchy. The interactions were expressed as design matrices which showed the dependence or independence between FRs and DPs. The results showed that the design of DSNM was not a coupled one, but a decoupled. Finally, it was conceptually verified that DSNM was a good design satisfying the independence axiom of the Axiomatic Design.

Method of Generating Information Signals in the System Industrial Internet of Things

  • Aleksandr Serkov;Nina Kuchuk;Bogdan Lazurenko;Alla Horiuskina
    • International Journal of Computer Science & Network Security
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    • v.24 no.4
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    • pp.206-210
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    • 2024
  • Industrial facilities that use modern IT technologies require the ensured reliability and security of information in automated enterprise management. Concurrently, so as to ensure a high quality of communication, it is necessary to expand the bandwidth of communication channels, which are limited by the physical parameters of the radio frequency spectrum. In order to overcome this contradiction, we propose the application of technology fundamental to ultra-wideband signals, in which the ratio between the bandwidth and its central part is greater than "one". For this reason, the information signal is emitted without a carrier frequency - simultaneously within the entire frequency band - provided that the signal level is lower than the noise level. For the transmission of information content, the method of positional-time coding is used, in which each information bit is encoded by hundreds of ultrashort pulses that arrive within a certain sequence. Mathematical models of signals and values observed in wireless communication systems with autocorrelation reception of modulated ultra-wideband signals are furthermore recommended. These assist in identifying features of the dependence of the error probability on the normalized signal-to-noise ratio and the signal base. Comparative analysis has shown that the best noise immunity of the systems considered in this paper is the communication system, which uses the time separation of the reference and information signals. During the first half of the bit interval, the switch closes the output of the transmitter directly to the generator of the ultra-wideband signal - forming a reference signal. In the middle of the bit interval, the switch alternates the output to one of two possible positions depending on the encoding signal - "zero" or "one", forming the information part of the ultra-wideband signal. It should also be noted that systems with autocorrelation reception and separate transmission of reference and information signals, provide a high level of structural signal secrecy. Furthermore, they provide the reliable transmission of digital information, especially in interference conditions.

Magnetic and Electric Transport Properties of MnTe Thin Film Grown by Molecular Beam Epitaxy (분자선 증착법에 의해 성장한 MnTe 박막의 자기적 및 전기수송 특성)

  • Kim, Woo-Chul;Bae, Sung-Whan;Kim, Sam-Jin;Kim, Chul-Sung;Kim, Kwang-Joo;Yoon, Jung-Bum;Jung, Myung-Hwa
    • Journal of the Korean Magnetics Society
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    • v.17 no.2
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    • pp.81-85
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    • 2007
  • MnTe layers of high crystalline quality were successfully grown on Si(100) : B and Si(111) substrates by molecular beam epitaxy (MBE). Under tellurium-rich condition and the substrate temperature around $400^{\circ}C$, a layer thickness of $700{\AA}$ could be easily obtained with the growth rate of $1.1 {\AA}/s$. We investigated the structural, magnetic and transport properties of MnTe layers by using x-ray diffraction (XRD), superconducting quantum interference device (SQUID) magnetometry, and physical properties measurement system (PPMS). Characterization of MnTe layers on Si(100) : B and Si(111) substrates by XRD revealed a hexagonal structure of polycrystals with lattice parameters, ${\alpha}=4.143{\pm}0.001{\AA}\;and\;c=6.707{\pm}0.001{\AA}$. Investigation of magnetic and transport properties of MnTe films showed anomalies unlike antiferromagnetic powder MnTe. The temperature dependence of the magnetization data taken in zero-field-tooling (ZFC) and field-cooling (FC) conditions indicates three magnetic transitions at around 21, 49, and 210 K as well as the great irreversibility between ZFC and FC magnetization in the films. These anomalies are attributable to a magnetic-elastic coupling in the films. Magnetization measurements indicate ferromagnetic behaviour with hysteresis loops at 5 and 300 K for MnTe polycrystalline film. The coercivity ($H_c$) values at 5 and 300 K are 55 and 44 Oe, respectively. In electro-transport measurements, the temperature dependence of resistivity revealed a noticeable semiconducting behaviours and showed conduction via Mott variable range hopping at low temperatures.

Staticposture stability evaluation of female elderly using stability evaluation device (균형능력 평가 장치를 이용한 여성노인의 정적자세안정성 평가)

  • Kim, Tae-Hyung;Yi, Jae-Hoon;Oh, Seong-Geun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.12
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    • pp.5518-5524
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    • 2011
  • The purpose of this study is to investigate the change of balance ability on aging by measuring balance ability of elderly females whose age is over 65. The subjects are ten elderly women (the mean age: 71.9) able to walk without assistants, the assistant equipments and drug dependence and ten young healthy women (the mean age: 23.2). We measured stability index (ST), Fourier index (F), weight distribution (WD), weight distribution index (WDI), synchronization index (SI) and fall index (FI) by using Tetrax (Tetra-ataxiometric Posturography). In result, STs and Fs at the low frequency region (F1) represented the significant difference between two groups at all postures with PO (pillow with eye open) exception (p<.01). Fs at the other frequency regions (F2~F8) represented the significant difference between two groups (p<.05). WDI of the elderly women represented the higher values than the young women at all postures but there are the significant difference at PO and PC (pillow with eye closed) only. These results may be due to age-related ability decline of somatesthesia, vestibular organ, central nervous system.

Dependence of physical properties of artificial lightweight aggregates upon a flux and a bloating agent addition (인공경량골재 특성의 발포제 및 융제 첨가 의존성)

  • Kang, Seung-Gu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.1
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    • pp.48-53
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    • 2009
  • The effect of bloating and fluxing agent on the microstructure and physical properties were studied in manufacturing the artificial lightweight aggregates of bulk density below] using clay and stone sludge. In case of the aggregates added only with bloating agent, the bulk density and water absorption were $0.5{\sim}1.0$ and $41{\sim}110%$ respectively but the microstucture was not uniform with a rough appearance. For the aggregates added with a fluxing agent and one bloating agent, a part of shell was lost due to explosion of specimen caused by over-bloating during a sintering. The mixed addition of bloating agents with vacuum oil, carbon and ${Fe_2}{O_3}$ made the microstructure homogeneous by generating an uniform black core and shell structure. The aggregates added with mixed agents and sintered at $1200^{\circ}C$ showed the bulk density 67 % lower and water absorption 48 times higher than those of the specimen with no additives. ]n this study, the artificial lightweight aggregates showing the bulk density of $0.5{\sim}1.0$ and water absorption of $50{\sim}125%$ could be fabricated to apply to various fields.