• Title/Summary/Keyword: Physical decomposition

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The Study on the Synthesis of Triazole Derivatives as Energetic Plasticizer (트리아졸 계열의 에너지 가소제 합성 연구)

  • Lee, Woonghee;Kim, Minjun;Park, Youngchul
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.2
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    • pp.31-38
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    • 2016
  • Most of propellants that is used widely in the world release toxic gases such as methane gas and carbon dioxide during combustion which are noxious to the environment. This study established a synthetic process of a high nitrogen containing derivative of triazole, 4,5-bis(azidomethyl)-methyl-1,2,3-triazole (DAMTR), which can be applied as energetic plasticizer to environmental concerns. Also, the compound was characterized by NMR, IR spectroscopy, and physical properties such as glass transition temperature, melting point, decomposition temperature, density, impact sensitivity, viscosity and volatility were measured. In addition, the heats of formation (${\Delta}H_f$) and detonation properties (pressure and velocity) of DAMTR were calculated using Gaussian 09 and EXPLO5 programs.

Study on Surface Chemical Structure and Mechanical Properties of EPDM Rubber with Microwave Irradiation Time

  • Eom, SeoBin;Lee, Sun Young;Park, Sung Han;Lee, Seung Goo
    • Elastomers and Composites
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    • v.53 no.3
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    • pp.124-130
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    • 2018
  • Recently, microwaves have been used for desulfurization because they can selectively dissociate C-S and S-S bonds present in vulcanized rubber. In this study, we investigated the changes in structural and physical properties of EPDM (Ethylene propylene diene monomer) rubber by irradiating it with microwaves for different durations. The surface chemical composition of the irradiated EPDM rubber was analyzed by FT-IR, XPS, and EDS analyses. It was confirmed by XPS that C-S and S-S S2p peak heights greatly decreased when microwave irradiation was performed for more than 5 min. In the EPDM sample irradiated with microwaves for 10 min, the number of S-O bonds significantly increased owing to oxidation. As the microwave irradiation time was increased, SEM images showed cracks and voids on the EPDM surface. The 20% decomposition temperature of the EPDM rubber sample was investigated by TGA, and it was found to be about $435.23^{\circ}C$ for the EPDM rubber irradiated for 10 min. The crosslinking density of the EPDM rubber was determined by measuring the degree of swelling, and the highest value was observed for the E5 sample irradiated for 5 min. The degree of swelling of the E10 sample irradiated for 10 min was lower than that of the E5 sample. These results indicate that when irradiated with microwaves for more than a certain time, desulfurization occurs and the side chain of the EPDM rubber dissociates and forms additional crosslinking bonds.

On the Use of Standing Oblique Detonation Waves in a Shcramjet Combustor

  • Fusina, Giovanni;Sislian, Jean P.;Schwientek, Alexander O.;Parent, Bernard
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.671-686
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    • 2004
  • The shock-induced combustion ramjet (shcramjet) is a hypersonic airbreathing propulsion concept which over-comes the drawbacks of the long, massive combustors present in the scramjet by using a standing oblique detonation wave (a coupled shock-combustion front) as a means of nearly instantaneous heat addition. A novel shcramjet combustor design that makes use of wedge-shaped flameholders to avoid detonation wave-wall interactions is proposed and analyzed with computational fluid dynamics (CFD) simulations in this study. The laminar, two-dimensional Navier-Stokes equations coupled with a non-equilibrium hydrogen-air combustion model based on chemical kinetics are used to represent the physical system. The equations are solved with the WARP (window-allocatable resolver for propulsion) CFD code (see: Parent, B. and Sislian, J. P., “The Use of Domain Decomposition in Accelerating the Convergence of Quasihyperbolic Systems”, J. of Comp. Physics, Vol. 179, No. 1,2002, pages 140-169). The solver was validated with experimental results found in the literature. A series of steady-state numerical simulations was conducted using WARP and it was deter-mined by means of thrust potential calculations that this combustor design is a viable one for shcramjet propulsion: assuming a shcramjet flight Mach number of twelve at an altitude of 36,000 m, the geometrical dimensions used for the combustor give rise to an operational range for combustor inlet Mach numbers between six and eight. Different shcramjet flight Mach numbers would require different combustor dimensions and hence a variable geometry system in or-der to be viable.

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Real Time AOA Estimation Using Neural Network combined with Array Antennas (어레이 안테나와 결합된 신경망모델에 의한 실시간 도래방향 추정 알고리즘에 관한 연구)

  • 정중식;임정빈;안영섭
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2003.05a
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    • pp.87-91
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    • 2003
  • It has well known that MUSIC and ESPRIT algorithms estimate angle of arrival(AOA) with high resolution by eigenvalue decomposition of the covariance matrix which were obtained from the array antennas. However, the disadvantage of MUSIC and ESPRIT is that they are computationally ineffective, and then they are difficult to implement in real time. The other problem of MUSIC and ESRPIT is to require calibrated antennas with uniform features, and are sensitive to the manufacturing facult and other physical uncertainties. To overcome these disadvantages, several method using neural model have been study. For multiple signals, those require huge training data prior to AOA estimation. This paper proposes the algorithm for AOA estimation by interconnected hopfield neural model. Computer simulations show the validity of the proposed algorithm. The proposed method does not require huge training procedure and only assigns interconnected coefficients to the neural network prior to AOA estimation.

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Real Time AOA Estimation Using Analog Neural Network Model (아날로그 신경망 모델을 이용한 실시간 도래방향 추정 알고리즘의 개발)

  • Jeong, Jung-Sik
    • Journal of Navigation and Port Research
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    • v.27 no.4
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    • pp.465-469
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    • 2003
  • It has well known that MUSIC and ESPRIT algorithms estimate angle of arrival(AOA) with high resolution by eigenvalue decomposition of the covariance matrix which were obtained from the array antennas, However, the disadvantage of MUSIC and ESPRIT is that they are computationally ineffective, and then they are difficult to implement in real time. the other problem of MUSIC and ESPRIT is to require calibrated antennas with uniform features, and are sensitive ti the manufacturing fault and other physical uncertainties. To overcome these disadvantages, several method using neural model have been study. For multiple signals, those methods require huge training data prior to AOA estimation. This paper proposes the algorithm for AOA estimation by interconnected Hopfield neural model. Computer simulations show the validity of the proposed algorithm. It follows that the proposed method yields better AOA estimates than MUSIC. Moreover, out method does not require huge training procedure and only assigns interconnected coefficients to the neural network prior to AOA estimation.

Structural health monitoring of a cable-stayed bridge using wireless smart sensor technology: data analyses

  • Cho, Soojin;Jo, Hongki;Jang, Shinae;Park, Jongwoong;Jung, Hyung-Jo;Yun, Chung-Bang;Spencer, Billie F. Jr.;Seo, Ju-Won
    • Smart Structures and Systems
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    • v.6 no.5_6
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    • pp.461-480
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    • 2010
  • This paper analyses the data collected from the $2^{nd}$ Jindo Bridge, a cable-stayed bridge in Korea that is a structural health monitoring (SHM) international test bed for advanced wireless smart sensors network (WSSN) technology. The SHM system consists of a total of 70 wireless smart sensor nodes deployed underneath of the deck, on the pylons, and on the cables to capture the vibration of the bridge excited by traffic and environmental loadings. Analysis of the data is performed in both the time and frequency domains. Modal properties of the bridge are identified using the frequency domain decomposition and the stochastic subspace identification methods based on the output-only measurements, and the results are compared with those obtained from a detailed finite element model. Tension forces for the 10 instrumented stay cables are also estimated from the ambient acceleration data and compared both with those from the initial design and with those obtained during two previous regular inspections. The results of the data analyses demonstrate that the WSSN-based SHM system performs effectively for this cable-stayed bridge, giving direct access to the physical status of the bridge.

Decomposition of Health Inequality in High School Students (고등학생의 건강 불균등 요인별 분해)

  • Ahn, Byung-Chul;Joung, Hyo-Jee
    • Journal of the Korean Society of School Health
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    • v.20 no.1
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    • pp.63-75
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    • 2007
  • Purpose: With economic development and prolonged longevity, the level of health and health disparities have became growing concerns for individual and society as well. Since youth's health status are influenced by households' socioeconomic status and associated with heath status in later stage of life, assessing health inequality in the youth is a significant step toward lessening health disparity and promoting health. We measured health inequality in high school students and decomposed it into health factors. Methods: The subjects included 3,787 high school students of 12th graders from the Korea Education and Employment Panel (KEEP) in 2004. True health status was assumed as a latent variable and estimated by ordered logistic regression model. The predicted health was used as a measure of individual health after rPSraling to [0,1] interval. Total health inequality was then measured by Gini coefficient and was decomposed into health factors. Results: Health inequality in high school students was observed. Of total health inequality, 44% was explained by biological factors such as body mass index (BMI) (32.5%) and gender (13.5%). Behavioral factors such as smoking, drinking, physical activity, hours in bed and hours of computer ussge added to 11.7%. Household income and work experiences explained 5.6% and 8.8%, respectively. School satisfaction explained 14.6%. Other school related factors such as self-assessed achievement and experience of being bullied accounted for 15.5%. Conclusion: Among the health factors, biological factor was the most important contributor in health disparity. Other factors such as health behaviors, socioeconomic factors, school satisfaction and school related factors exhibited somewhat similar magnitude. For policy purposes, it is recommended to look into modifiable factors depending BM, gender and school surroundings.

An Experiment Study on Electric Vehicle Fire and Fire Response Procedures (전기차 화재 실험 및 대응방안에 관한 연구)

  • Ki-Hun Nam;Jun-Sik Lee
    • Journal of the Korean Society of Industry Convergence
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    • v.27 no.1
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    • pp.63-70
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    • 2024
  • Lithium-ion batteries (LIB) are widely used in various sectors, such as transportation (e.g., electric vehicles (EV)) and energy (e.g., energy storage facilities) due to their high energy density, broad operating temperature (-20 ℃ ~ 60 ℃), and high capacities. LIBs are powerful but fragile on external factors, including pressure, physical damage, overheating, and overcharging, that cause thermal runaway causing fires and explosions. During a LIB fire, a large amount of oxygen is generated from the decomposition of ionogenic materials. A water fire extinguisher that helps with cooling and suffocating must be essentially required at the same time. In fact, however, it is difficult to suppress LIB fires in the case of EVs because a LIB is installed with a battery pack housing that interrupts direct extinguishing by water. Thus, this study aims to investigate effective fire extinguishing measurements for LIB fires by using an EV. Relevant documents, including research articles and reports, were reviewed to identify effective ways of LIBs fire extinguishing. A real-scale fire experiment generating thermal runaway was carried out to figure out the combustion characteristics of EVs. This study revealed that the most effective fire extinguishing measurements for LIB fires are applying fire blankets and water tanks. However, there is still a lack of adequate regulation and guidelines for LIB fire extinguishment. Taking this into account, developing functional fire extinguishment measurements and available regulatory instruments is an urgent issue to secure the safety of firefighters and citizens.

Preparation of TiO2Powder by Hydrothemal Precipitation Method and their Photocatalytic Properties (수열합성법에 의한 TiO2 분말 제조와 광촉매 특성)

  • Kim, Seok-Hyeon;Jeong, Sang-Gu;Na, Seok-En;Kim, Si-Young;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.51 no.2
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    • pp.195-202
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    • 2013
  • $TiO_2$ powders were prepared from titanium (IV) sulfate ($Ti(SO_4)_2$) solution using ammonia solution at low reaction temperature ($80{\sim}100^{\circ}C$) and atmospheric pressure by hydrothermal precipitation method without calcination. The effect of reaction conditions, such as reaction temperature, initial concentration of titanium (IV) sulfate ($Ti(SO_4)_2$) solution, pH of mixture solution and the physical properties of the prepared $TiO_2$, such as crystallite structure, crystallite size were investigated. The photocatalytic activity of prepared $TiO_2$ was tested by the photolysis of brilliant blue FCF (BB-FCF) under the UV and the analysis of UV-VIS diffuse reflectance spectroscopy (DRS). The physical properties of prepared $TiO_2$ were examined by X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence spectrometer (PL), particle size distribution measurements. The crystallite size and crystallinity of prepared $TiO_2$ increased with increasing titanium (IV) sulfate ($Ti(SO_4)_2$) concentration, but photocatalytic activity decreased. The crystallite size decreased with increasing pH of mixture solution, but photocatalytic activity increased. The crystallinity and photocatalytic activity increased with increasing reaction temperature. The results showed that anatase type $TiO_2$ could be prepared by hydrothermal precipitation method using titanium (IV) sulfate ($Ti(SO_4)_2$) solution and ammonia solution at low reaction temperature and atmospheric pressure without calcination.

Analysis of Free Fatty Acid Formation and Oxidative Rancidity for Deep Flying Oil Produced by Traditional and Modified Fryers (전통식과 개량식 튀김기에 대한 튀김기름의 유리지방산 생성 및 산패도 측정 비교)

  • Choi, Il-Sook;Choi, Soo-Keun;Lee, Young-Soon
    • Culinary science and hospitality research
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    • v.17 no.4
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    • pp.316-325
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    • 2011
  • The property of deep frying oil is one of die important factors in fried food quality. The purpose of this study is to identify die quality of deep frying oil in continuous usages for 4 days by two types of fryers: traditional and modified fryers. After frying polk cutlets, die flying oil was kept not only for several physical analyses such as color, viscosity, and water content but also for quality analyses of flying oil such as free fatty acid, double bond changes and oxidative rancidity formation. The fried oil by a traditional flyer was significantly increased in die physical values of color and viscosity than that by a modified fryer. In die acid value, the fried oil by a traditional fryer was significantly increased in free fatty acid than that by a modified fryer while die iodine value was significantly decreased in die fried oil by a traditional fryer when compared to control oil and fried oil by a modified fryer. In die peroxide value as an indicator of primary oxidation products, die fried oil by both fryers was significantly increased till die second day but decreased in die value after die third day because of unstable hydroperoxides' decomposition. In die p-anicidine value as an indicator of secondary oxidation products, die fried oil in a traditional fryer was significantly increased in die value than that in a modified fry.

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