• Title/Summary/Keyword: Physical decomposition

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Deterioration Mechanism Interpretation and Surface Contaminant Analysis of the Five-Storied Stone Pagoda in Tapriri, Uiseong (의성 탑리리 오층석탑의 표면오염물 분석 및 손상메커니즘 해석)

  • Lee, Mi Hye;Chun, Yu Gun;Lee, Myeong Seong
    • Economic and Environmental Geology
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    • v.46 no.5
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    • pp.445-453
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    • 2013
  • The Uiseong Tapriri Five-Storied Stone Pagoda (National Treasure No. 77) is typical stone cultural heritage in Unified Silla Dynasty, Korea. The pagoda has been occurred black, brown discoloration and microcrack, exfoliation, granularity decomposition with white discoloration because of continuous weathering. As the results of analysis for the contaminants, chemical weatherings are generated that black contaminant by manganese oxide, brown contaminant by iron oxide, white contaminants by gypsum and taranakite. And physical weatherings, such as microcrack, exfoliation, are occurred by salt(gypsum) crystallization. Therefore, these need to remove the contaminants according to the conservation treatment manual, and regular monitoring using P-XRF to preserve long-term the Five-Storied Stone Pagoda at Tapri-ri, Uiseong.

Characterization of Shelf Life Extension Packaging Material for Food and Fresh Cut Agricultural Product: A Review (식품, 신선편이 농산물용 저장기간 연장 포장 소재 특성 및 평가)

  • Rhee, Jin-Kyu;Yu, Ji Ye;Kim, Mi-Kyung;You, Young-Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.22 no.3
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    • pp.119-125
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    • 2016
  • Fresh-cut agricultural products provide convenience to consumers. However, quality changes or microbial growth can easily occur due to physical changes such as cutting and peeling etc. during processing. Therefore, efforts have been made to develop a functional packaging for extension of shelf life of fresh-cut agricultural products, food etc., and researches on prolongation of storage period have been actively developed. The shelf life is extended by antimicrobial, far infrared rays, air permeability, anti-fogging, weak current, ethylene gas adsorption or decomposition, gas composition changes such as MA (Modified Atmosphere) or CA (Controlled Atmosphere). The method of extending the shelf life by various complex factors. This paper based on the published literature to extend the shelf life of fresh-cut agricultural products, food etc., The paper has summarized the storage period extension packing method, packaging material for shelf life extension and comprehensive evaluation method.

Preparation of Different Fe Containing TiO2 Photocatalysts and Comparison of Their Photocatalytic Activity

  • Meng, Ze-Da;Zhang, Kan;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.20 no.4
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    • pp.228-234
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    • 2010
  • In this paper, Fe-$TiO_2$ and Fe-fullerene/$TiO_2$ composite photocatalysts were prepared with titanium (IV) n-butoxide (TNB) by a sol-gel method. $TiO_2$, Fe-$TiO_2$ and Fe-fullerene/$TiO_2$ were characterized by scanning electron microscopy (SEM), Transmission electron microscope (TEM), specific surface area (BET), X-ray diffraction analysis (XRD) and energy dispersive X-ray spectroscopy (EDX). The photocatalytic activities were evaluated by the photocatalytic oxidation of methylene blue (MB) solution. XRD patterns of the composites showed that the photocatalyst composite contained a typical single and clear anatase phase. The surface properties shown by SEM presented a characterization of the texture on Fe-fullerene/$TiO_2$ composites and showed a homogenous composition in the particles for the titanium sources used. The EDX spectra for the elemental identification showed the presence of O, C and Ti elements. Moreover, peaks of the Fe element were observed in the Fe-$TiO_2$ and Fe-fullerene/$TiO_2$ composites. The degradation of MB solution by UV-light irradiation in the presence of photocatalyst compounds was investigated in complete darkness. The degradation of MB concentration in aqueous solution occurred via three kinds of physical phenomena: quantum efficiency of the fullerene; organo-metallic reaction of the Fe compound; and decomposition of $TiO_2$. The degradation rate of the methylene blue solution increased when using Fe-fullerene/$TiO_2$ compounds.

Adaptive Cross-Layer Resource Optimization in Heterogeneous Wireless Networks with Multi-Homing User Equipments

  • Wu, Weihua;Yang, Qinghai;Li, Bingbing;Kwak, Kyung Sup
    • Journal of Communications and Networks
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    • v.18 no.5
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    • pp.784-795
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    • 2016
  • In this paper, we investigate the resource allocation problem in time-varying heterogeneous wireless networks (HetNet) with multi-homing user equipments (UE). The stochastic optimization model is employed to maximize the network utility, which is defined as the difference between the HetNet's throughput and the total energy consumption cost. In harmony with the hierarchical architecture of HetNet, the problem of stochastic optimization of resource allocation is decomposed into two subproblems by the Lyapunov optimization theory, associated with the flow control in transport layer and the power allocation in physical (PHY) layer, respectively. For avoiding the signaling overhead, outdated dynamic information, and scalability issues, the distributed resource allocation method is developed for solving the two subproblems based on the primal-dual decomposition theory. After that, the adaptive resource allocation algorithm is developed to accommodate the timevarying wireless network only according to the current network state information, i.e. the queue state information (QSI) at radio access networks (RAN) and the channel state information (CSI) of RANs-UE links. The tradeoff between network utility and delay is derived, where the increase of delay is approximately linear in V and the increase of network utility is at the speed of 1/V with a control parameter V. Extensive simulations are presented to show the effectiveness of our proposed scheme.

Infection Mechanism of Pathogenic Exduate by Soil-Borne Fungal Pathogens : A Review

  • Lim, You-Jin;Kim, Hye-Jin;Song, Jin-A;Chung, Doug-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.4
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    • pp.622-627
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    • 2012
  • The processes to determine the composition, dynamics, and activity of infection mechanisms by the rhizosphere microflora have attracted the interest of scientists from multiple disciplines although considerable progress of the infection pathways and plant-pathogen interactions by soil borne fungal pathogens have been made. Soilborne pathogens are confined within a three-dimensional matrix of mineral soil particles, pores, organic matter in various stages of decomposition and a biological component. Among the physical and chemical properties of soils soil texture and matric water potential may be the two most important factors that determine spread exudates by soil borne fungal pathogens, based on the size of the soil pores. Pathogenic invasion of plant roots involves complex molecular mechanisms which occur in the diffuse interface between the root and the soil created by root exudates. The initial infection by soilborne pathogens can be caused by enzymes which breakdown cell wall layers to penetrate the plant cell wall for the fungus. However, the fate and mobility of the exudates are less well understood. Therefore, it needs to develop methods to control disease caused by enzymes produced by the soilborne pathogens by verifying many other possible pathways and mechanisms of infection processes occurring in soils.

Functional Polythiophene Bearing Hydroxyethyl Groups and Their Derivatives

  • Kim Hyun-Chul;Kim Jong-Seong;Baek Sung-Sik;Ree Moon-Hor
    • Macromolecular Research
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    • v.14 no.2
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    • pp.173-178
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    • 2006
  • Poly(3-(2-hydroxyethyl)thiophene) (P3HET) was synthesized using oxidative coupling polymerization that involved the protecting and deprotecting of hydroxyl groups but not the chlorine substitution or oxidative decomposition of the hydroxyl groups. The resulting P3HET exhibited good solubility in aprotic solvents, in contrast to the insoluble polymer product synthesized directly from the monomer, 3-(2-hydroxyethyl)thiophene (3HET). P3HET had low conductivity due to the strong hydrogen bonding of its hydroxyl groups. The ester-functionalized poly(3-(2-acetoxyethyl)thiophene) and poly(3-(4-pentylbenzoateethyl)thiophene) were also prepared with reasonably high molecular weights in order to examine how this functionalization modified the physical and chemical properties of P3HET. These polymers exhibited better solubility in common solvents and higher conductivity than P3HET. All these polymers exhibited bathochromic shifts of their film state absorption maxima with respect to those found in the UV-visible spectra of their solution phases. The extent of the bathochromic shift was found to vary with the lengths of the side chains of the ester-functionalized polymers.

Prediction of Nitrogen Loading from Forest Stands in Eutrophication of Lake (호소 부영양화에 있어서 산림임반으로부터 질소부하 평가를 위한 조사)

  • Chung, Doug-Young;Lee, Young-Han;Lee, Jin-Ho;Park, Mi-Suk
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.4
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    • pp.430-437
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    • 2010
  • The continuous release of nutrient sources into natural water resource can be a continuing problem in eutrophication, as well as severe reductions in water quality. However, any desirable measure is not developed yet even though so many researches and efforts have been done to solve this problem. Forest as one of troublesome nonpoint sources may contributes most to nutrient loading, but the loading of N and P from forest in order to grasp the eutrophication potential of nonpoint sources has not been evaluated. The nutrient sources from the organic litter accumulated on the surface of forest soils can be a critical factor in continuity of eutrophication of a lake. The decomposition rate of litter can be estimated to predict release of N and P from the forest stand. The loss rate of nitrogen is complicated but depends in part upon the physical matrix of the element. Therefore, long-term nutrient budget and flux estimates at stand would be useful tools in calculating potential nutrient fluxes into the watercourses in a sustainable way. The present investigation can give insight to the actual situation of the eutrophication potentials of forest as the practical nonpoint sources.

Dynamics and Control Methods of Cyanotoxins in Aquatic Ecosystem

  • Park, Ho-Dong;Han, Jisun;Jeon, Bong-seok
    • Korean Journal of Ecology and Environment
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    • v.49 no.2
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    • pp.67-79
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    • 2016
  • Cyanotoxins in aquatic ecosystems have been investigated by many researchers worldwide. Cyanotoxins can be classified according to toxicity as neurotoxins (anatoxin-a, anatoxin-a(s), saxitoxins) or hepatotoxins (microcystins, nodularin, cylindrospermopsin). Microcystins are generally present within cyanobacterial cells and are released by damage to the cell membrane. Cyanotoxins have been reported to cause adverse effects and to accumulate in aquatic organisms in lakes, rivers and oceans. Possible pathways of microcystins in Lake Suwa, Japan, have been investigated from five perspectives: production, adsorption, physiochemical decomposition, bioaccumulation and biodegradation. In this study, temporal variability in microcystins in Lake Suwa were investigated over 25 years (1991~2015). In nature, microcystins are removed by biodegradation of microorganisms and/or feeding of predators. However, during water treatment, the use of copper sulfate to remove algal cells causes extraction of a mess of microcystins. Cyanotoxins are removed by physical, chemical and biological methods, and the reduction of nutrients inflow is a basic method to prevent cyanobacterial bloom formation. However, this method is not effective for eutrophic lakes because nutrients are already present. The presence of a cyanotoxins can be a potential threat and therefore must be considered during water treatment. A complete understanding of the mechanism of cyanotoxins degradation in the ecosystem requires more intensive study, including a quantitative enumeration of cyanotoxin degrading microbes. This should be done in conjunction with an investigation of the microbial ecological mechanism of cyanobacteria degradation.

Research on the phenomenon of sick house syndrome and how to remove harmful gases (새집증후군 현상 및 유해가스 제거방안 연구)

  • Choe, Yoowha
    • The Journal of the Convergence on Culture Technology
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    • v.6 no.3
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    • pp.449-456
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    • 2020
  • When you move to a new home, or when you change the wallpaper or flooring of your home, office, etc., you can enjoy the joy of opening your new home with the sick house syndrome, such as the stinging smell and stinging eyes that may appear after the interior work. It is only a moment. Volatile organic compounds from building materials, adhesives, wallpaper, and paints used in new buildings or new furniture cause residents' health and discomfort in indoor life. These volatile organic compounds include benzene, toluene, acetone, and styrene, as well as the representative formaldehyde, and these substances are slowly released over a long period of time, causing acute or chronic diseases to residents. As a method for removing organic volatile substances, physical methods using adsorption, chemical methods for converting volatile substances to other substances, or a mixture of the two are mainly used. In this paper, a sustained release chlorine dioxide gel pack obtained by a method for controlling the reaction rate of a reactant and the release of a product is mixed with a zeolite adsorbent having an optimized hole diameter to adsorb and decompose and remove formaldehyde suspended in the air. I would suggest an effective method.

Development of New Omeprazole-lon Exchange Resin Complex (이온교환수지를 이용한 새로운 오메프라졸 복합체 개발)

  • Rhee, Gye-Ju;Lee, Ki-Myung;Kim, Eun-Young;Lee, Chang-Hyun;Hwang, Sung-Joo
    • YAKHAK HOEJI
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    • v.38 no.3
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    • pp.250-264
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    • 1994
  • Omeprazole(OMZ)-cholestyramine(CHL) and various OMZ-Dowex resin complexes were prepared by reaction between OMZ and activated resins in 0.1N NaOH solution. And their physical properties were tested by means of infrared(IR), differential scaning caloimeter(DSC), X-ray diffraction. Chemical stability of OMZ-CHL was increased markedly compared with OMZ and the decomposition of OMZ-CHL followed the pseudo first-order kinetics and the rate constants were $2.743{\times}10^{-4}/day$ at $20^{\circ}C$, $7.83{\times}10^{-3}day^{-1}$ under 80% RH and $1.68{\times}10^{-2}day^{-1}$ under UV radiation, respectively. On the other hand, the rate constants of OMZ were $2.996{\times}10^{-4}day^{-1}$ at $20^{\circ}C$, $1.17{\times}10^{-2}day^{-1}$ under 85% RH, and $4.07{\times}10^{-2}day^{-1}$ under UV radiation, respectively. The rates of dissolution of OMZ-CHL bulk and OMZ-CHL tablet were 100% and more than 85% in 15 minutes, respectively, which were increased than OMZ base and OMZ-tablet. In the acute toxicological test, the value of oral $LD_{50}$(mouse) was 4.608 g/kg. OMZ-CHL was pelletized using lactose, polyethyle neglycol(PEG), D-sorbitol, Avicel PH 101, sodium laurylsulfate and polyvinylpyrrolidone(PVP) K-30, and enteric coated with HPMCP, Myvacet, acetone, ethanol and cetanol, of which dissolution rate was found to be more than 85% in 10 minutes. From the above results, it was found that OMZ-CHL is a useful means for development of new oral dosage forms of OMZ.

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