• Title/Summary/Keyword: Physical decomposition

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CVD Graphene Synthesis on Copper Foils and Doping Effect by Nitric Acid

  • Oh, Teresa
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.5
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    • pp.246-249
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    • 2013
  • Graphene was obtained on Cu foil by thermal decomposition method. A gas mixture of $H_2$ and $CH_4$ and an ambient annealing temperature of $1,000^{\circ}C$ were used during the deposition for 30 Min., and for the transfer onto $SiO_2/Si$ and Si substrates. The physical properties of graphene were investigated with regard to the effect ofnitrogen atom doping and the various substrates used. The G/2D ratio decreased when the graphene became monolayer graphene. The graphene grown on $SiO_2/Si$ substrate showed a low intensity of the G/2D ratio, because the polarity of the $SiO_2$ layer improved the quality of graphene. The intensity of the G/2D ratio of graphene doped with nitrogen atoms increased with the doping time. The quality of graphene depended on the concentration of the nitrogen doping and chemical properties of substrates. High-quality monolayer graphene was obtained with a low G/2D ratio. The increase in the intensity of the G/2D ratios corresponded to a blue shift in the 2D peaks.

Analysis of Characteristics of Air Pollution Over Asia with Satellite-derived $NO_2$ and HCHO using Statistical Methods (환경 위성관측자료의 통계분석을 통한 동아시아 대기오염특성 연구)

  • Baek, K.H.;Kim, Jae Hwan
    • Atmosphere
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    • v.20 no.4
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    • pp.495-503
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    • 2010
  • Satellite data have an intrinsic problem due to a number of various physical parameters, which can have a similar effect on measured radiance. Most evaluations of satellite performance have relied on comparisons with limited spatial and temporal resolution of ground-based measurements such as soundings and in-situ measurements. In order to overcome this problem, a new way of satellite data evaluation is suggested with statistical tools such as empirical orthogonal function(EOF), and singular value decomposition(SVD). The EOF analyses with OMI and OMI HCHO over northeast Asia show that the spatial pattern show high correlation with population density. This suggests that human activity is a major source of as well as HCHO over this region. However, this analysis is contradictory to the previous finding with GOME HCHO that biogenic activity is the main driving mechanism(Fu et al., 2007). To verify the source of HCHO over this region, we performed the EOF analyses with vegetation and HCHO distribution. The results showed no coherence in the spatial and temporal pattern between two factors. Rather, the additional SVD analysis between $NO_2$ and HCHO shows consistency in spatial and temporal coherence. This outcome suggests that the anthropogenic emission is the main source of HCHO over the region. We speculate that the previous study appears to be due to low temporal and spatial resolution of GOME measurements or uncertainty in model input data.

Investigation on the Change of Ammonia Dissociation for Satellite Thruster According to the Catalyst Loss (위성추력기에서 촉매유실에 따른 암모니아 해리도 변화에 대한 연구)

  • Hwang, Chang-Hwan;Lee, Sung-Nam;Baek, Seung-Wook;Kim, Su-Kyum;Yu, Myoung-Jong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.218-222
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    • 2011
  • During the development of the iridium catalyst for domestic production, the catalyst failure, loss, sintering phenomena are observed by high pressure and temperature. By these abnormal failure of catalyst bed, the performance of thruster is degraded. To figure out the detail phenomena on the damaged catalyst bed, a numerical analysis code is developed by assuming the catalyst bed as an one dimensional porous media. The numerical analysis code is validated with experiment data. Thereby, resulting physical phenomena are examined by considering the variation of catalyst bed characteristics incurred by catalyst granule failure. Through these numerical analyses we figure out the effect of the catalyst loss on the decomposition of hydrazine and ammonia.

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A Adaptive and Fuzzy control of Inspection robot for Underground Pipes (지하매설파이프 검사로봇의 적응퍼지 위치 제어)

  • Kim, Do-Woo;Yang, Hai-Won
    • Proceedings of the KIEE Conference
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    • 1999.11c
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    • pp.670-673
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    • 1999
  • In this paper, we present a robust motion controller based on Adaptive-Fuzzy technique is proposed that multifunctional vehicle(MVR) for two DOF mobile robot can perform detailed inspection of physical conditions of sewage pipes as well as can effectively repair the damaged portions of the inner walls. The main difficulties in controlling this multifunctional robot vehicles lie in the fact that vehicles usually have three degrees of freedom in position and orientation in spite of having only two degrees of freedom for motion control in tracking mode. Decomposition of error between the reference posture and the current posture makes control of speed and steering possible. The Gyro compass part and Inclonometer of the robot is configured in order to realize position of robot. The proposed Adaptive-Fuzzy motion controller has two main characteristics: The one guarantees that the MVR follows the reference trajectory; the other one compensates the dynamics of the MVR. Simulation results are provided to validate the proposed controller. Experiments have been used to verify the effectiveness and robustness of the motion controller.

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A Study on the Optimum Mixture of Sandwich Panel Core Using Lightweight Foamed Concrete (경량기포콘크리트를 이용한 샌드위치 패널 심재의 최적배합에 관한 연구)

  • Ahn, Jung-Hyun;Chun, Woo-Young;Lee, Sang-An;Kim, Wha-Jung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.447-448
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    • 2009
  • On this study, the concrete foaming was maximized using Hydrogen peroxide($H_2O_2$) reciprocal decomposition catalyzed by Manganese dioxide($MnO_2$) and Sodium bicarbonate($NaHCO_3$). Also, we study the physical and mechanical properties of lightweight formed concrete through diverse experiment which is to determine the optimal mixing proportion and require strength of the lightweight formed concrete. As a result of an experiment, it is satisefied with overall quality standard on the KS F 4039 and KS F 2459 provision.

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Development of Work Breakdown Structure for Nuclear Power Plant (원자력발전소 Work Breakdown Structure 개발)

  • Cho, Yeong-Heock;Yang, Myung-Duck
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.52-53
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    • 2014
  • The Work Breakdown Structure (WBS) is a primary tool which provides a framework that defines clear scope of all deliverables throughout the project life cycle. Once the WBS is established in projects, it should allow project team members to measure and manage work performances by the WBS; further, it should provide a reference point when any work scope needs to be redefined. Based on the project information in the Progress and Performance Measurement System (PPMS) of UAE's Barakha Nuclear Power Plant (BNPP) projects, an attempt was made to develop a new WBS which provides hierarchical and systematical decomposition of the total work scope of NPP construction projects while avoiding from the preexistence concept in Korean NPP projects that the WBS is a combination of Physical Breakdown Structure (PBS) and Functional Breakdown Structure (FBS). The unique features of the new WBS are as follows: (1) defined the definition of each level of the WBS, (2) subdivided the WBS into 5 hierarchical levels, and (3) adopted globally used general coding structure. The new WBS provides a basic hierarchical structure for the project scope and can be used as a basic tool for schedule control, performance measurement, project status monitoring, and communication among project participants. In addition, by putting the Work Package (WP) under the WBS, the Earned Value Management System (EVMS) per WP can be utilized for the project.

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Electrochemical Oxidation of Amoxicillin in Its Commercial Formulation on Thermally Prepared RuO2/Ti

  • Auguste, Appia Foffie Thiery;Quand-Meme, Gnamba Corneil;Ollo, Kambire;Mohamed, Berte;Sahi placide, Sadia;Ibrahima, Sanogo;Lassine, Ouattara
    • Journal of Electrochemical Science and Technology
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    • v.7 no.1
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    • pp.82-89
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    • 2016
  • In this work, a ruthenium dioxide electrode has been prepared by thermal decomposition at 400 ℃ then used for the oxidation of commercial amoxicillin. The physical characterization showed that RuO2 electrode presents a mud cracked structure. Its electrochemical characterization has revealed an increase of the voltammetric charge in acid electrolyte compared to neutral electrolyte indicating the importance of protons in its surface redox processes. The voltammetric study of the oxidation of amoxicillin has been investigated. It has been obtained that the oxidation of amoxicillin is controlled by both adsorption and diffusion processes. Moreover, the oxidation of amoxicillin occurs via direct and indirect processes in free or electrolyte containing chlorides. Through preparative electrolysis, enhancement of amoxicillin oxidation was observed in the presence of chloride where the amoxicillin degradation yield reached more than 50 % compared to less than 5% in the absence of chlorides. Spectrophotometric investigations have revealed the degradation of intermediates absorbing at 350 nm.

Effects of Catalyst Granule Failure in Monopropellant Satellite Thruster (단일추진제 위성추력기에서 촉매 파손에 의한 영향)

  • Hwang, Chang-Hwan;Lee, Sung-Nam;Baek, Seung-Wook;Kim, Su-Kyum;Yu, Myoung-Jong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.15 no.6
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    • pp.7-14
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    • 2011
  • Various sizes of hydrazine monopropellant thruster have been used on satellite and space launcher vehicle. The test and handling procedure of hydrazine monopropellant thruster are usually difficult because of the toxicity of hydrazine and its decomposition product gases. Therefore, the numerical analysis can help understand the effects of various design parameters and can reduce the time as well as expenses. In this study, the numerical analysis is performed by modelling the catalyst bed as one dimensional porous medium. Thereby, resulting physical phenomena are examined by considering the variation of catalyst bed characteristics incurred by catalyst granule failure.

Milling tool wear forecast based on the partial least-squares regression analysis

  • Xu, Chuangwen;Chen, Hualing
    • Structural Engineering and Mechanics
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    • v.31 no.1
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    • pp.57-74
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    • 2009
  • Power signals resulting from spindle and feed motor, present a rich content of physical information, the appropriate analysis of which can lead to the clear identification of the nature of the tool wear. The partial least-squares regression (PLSR) method has been established as the tool wear analysis method for this purpose. Firstly, the results of the application of widely used techniques are given and their limitations of prior methods are delineated. Secondly, the application of PLSR is proposed. The singular value theory is used to noise reduction. According to grey relational degree analysis, sample variable is filtered as part sample variable and all sample variables as independent variables for modelling, and the tool wear is taken as dependent variable, thus PLSR model is built up through adapting to several experimental data of tool wear in different milling process. Finally, the prediction value of tool wear is compare with actual value, in order to test whether the model of the tool wear can adopt to new measuring data on the independent variable. In the new different cutting process, milling tool wear was predicted by the methods of PLSR and MLR (Multivariate Linear Regression) as well as BPNN (BP Neural Network) at the same time. Experimental results show that the methods can meet the needs of the engineering and PLSR is more suitable for monitoring tool wear.

Development of Depolymerization Method on the Recycling of Waste Flexible Polyurethane Foam (연질 폐우레탄 폼의 재활용을 위한 해중합법 개발)

  • 엄재열;이병학;신판우;김용렬
    • Journal of Environmental Health Sciences
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    • v.28 no.2
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    • pp.41-49
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    • 2002
  • Resource recovery and recycling of materials and products including polyurethanes are viewed as a necessity in today's society. The problems of recycling polyurethane wastes has major technological, economic and ecological significance because polyurethane itself is relatively expensive and its disposal by burning is also costly. In general, the recycling methods for polyurethane could be classified as mechanical, chemical and physical. In the chemical recycling method, there ate hydrolysis, glycolysis, pyrolysis and aminolysis. This study was carried out glycolysis using new method such as sonication and catalyzed reaction. There are kinds of recycled polyols were produced by current method(glycolysis) but, this study were with catalyzed reaction and sonication as decomposers and the chemical properties were analyzed. The reaction results in the formation of polyester urethane diols and then the OH value which is determined by the quantity of diol used for the glycolysis conditions. The glycolysis rates by sonication and catalyzed reaction for the various glycols, increased as: PPG