• Title/Summary/Keyword: Physical characterization

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Characterization of Peanut stunt virus Isolated from Black Locust Tree (Robinia pseudo-acacia L.)

  • Bang, Ju-Hee;Choi, Jang-Kyung;Lee, Sang-Yong
    • The Plant Pathology Journal
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    • v.22 no.2
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    • pp.125-130
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    • 2006
  • An isolate of Peanut stunt virus (PSV) isolated from black locust tree (Robinia pseudo-acacia L.) showing severe mosaic and malformation symptoms, was designated as PSV-Rp. PSV-Rp was characterized by the tests of host range, physical properties, RNA and coat protein composition and RT-PCR analysis. Nucleotide sequences of the cucumoviruses CP genes were also used for identification and differentiation of PSV-Rp. Six plant species were used in the host range test of PSV-Rp. PSV-Rp could be differentiated from each Cucumovirus strain used as a control by symptoms of the plants. The physical properties of PSV-Rp virus were TIP $65^{\circ}C$, DEP $10^{-3}$, and LIP $2{\sim}3$ days. In dsRNA analysis, PSV-Rp consisted of four dsRNAs, but satellite RNA was not detected. Analysis of the coat proteins by SDS-PAGE showed one major protein band of about 31 kDa. RT-PCR using a part of Cucumovirus RNA3 specific primer amplified ${\sim}950bp$ DNA fragments from the crude sap of virus-infected black locust leaves. RFLP analysis of the RT-PCR product could differential PSV-RP from CMV The nucleotide sequence identity between the PSV-Rp CP and the TAV-P CP genes and the PS-V-RP CP and CMV-Y CP genes were 61.6% and 40.5%, respectively. On the other hand, the nucleotide sequence identity of the PSV-Rp CP gene was $70.9%{\sim}73.4%$ in comparison with those of PSV subgroup I (PSV-ER and PSV-J) and 67.3% with that of PSV subgroup II(PSV-W). Especially, the nucleotide sequence identity of PSV-Rp CP gene and that of PSV-Mi that was proposed recently as the type member of a novel PSV subgroup III was 92.4%.

A rock physical approach to understand geo-mechanics of cracked porous media having three fluid phases

  • Ahmad, Qazi Adnan;Wu, Guochen;Zong, Zhaoyun;Wu, Jianlu;Ehsan, Muhammad Irfan;Du, Zeyuan
    • Geomechanics and Engineering
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    • v.23 no.4
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    • pp.327-338
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    • 2020
  • The role of precise prediction of subsurface fluids and discrimination among them cannot be ignored in reservoir characterization and petroleum prospecting. A suitable rock physics model should be build for the extraction of valuable information form seismic data. The main intent of current work is to present a rock physics model to analyze the characteristics of seismic wave propagating through a cracked porous rock saturated by a three phase fluid. Furthermore, the influence on wave characteristics due to variation in saturation of water, oil and gas were also analyzed for oil and water as wet cases. With this approach the objective to explore wave attenuation and dispersion due to wave induce fluid flow (WIFF) at seismic and sub-seismic frequencies can be precisely achieved. We accomplished our proposed approach by using BISQ equations and by applying appropriate boundary conditions to incorporate heterogeneity due to saturation of three immiscible fluids forming a layered system. To authenticate the proposed methodology, we compared our results with White's mesoscopic theory and with the results obtained by using Biot's poroelastic relations. The outcomes reveals that, at low frequencies seismic wave characteristics are in good agreement with White's mesoscopic theory, however a slight increase in attenuation at seismic frequencies is because of the squirt flow. Moreover, our work crop up as a practical tool for the development of rock physical theories with the intention to identify and estimate properties of different fluids from seismic data.

Characterization of Large-sized Jar-coffins from Youngsan River by the Elemental Analysis (영산강유역 대형옹관의 태토 특성에 의한 분류)

  • Lee, Han-Hyoung;Hong, Jong-Ouk;Hwang, Jin-Ju;Park, Ji-Hee;Moon, Eun-Jung;Kim, Soo-Kyung;Chung, Yong-Sam;Moon, Jong-Hwa
    • 보존과학연구
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    • s.30
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    • pp.103-124
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    • 2009
  • Major and trace elements and cross section textures of the large-sized jar-coffins excavated in the Young San river area have been analyzed for categorization according to geochemical characteristics of the raw materials. As results, we have found out that the jar-coffins of the Oryang-dong and Ungok-dong have very similar characteristics, and those of Songwol-dong and Jangdeung show distinguishable characteristics from the others. In addition, similar characteristics have been detected in some U-shape jar-coffins from several sites such as Oryang-dong, Ungok-dong, Sinchon-ri, Mansu-ri and Yeon-ri posess on trace elements and cross section texture. These results indicate that there was active physical migration although the detail route of the physical migration is unclear at current stage.

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Synthesis and Characterization of Allyl Ester Resin-Layered Silicate Nanocomposite (알릴 에스터 수지-층상 실리케이트 나노복합재료의 합성과 특성)

  • 팽세웅;김장엽;허완수;조길원;이상원
    • Polymer(Korea)
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    • v.28 no.2
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    • pp.177-184
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    • 2004
  • Polymer-clay nanocomposite containing the low amounts of clay shows improved physical, mechanical properties. In this study, allyl ester prepolymer was synthesised by reactions of the diallyl terephthalate monomers and the 1,3-butanediol monomers. Nanocomposites of allyl ester prepolymer and the two kinds of the organically layered silicate were prepared by using the intercalation method as well as the in-situ polymerization method using. By varying the amount of clay content, curing conditions, and feeding conditions. the nanocomposite was studied using X-ray diffraction. From XRD results, allyl ester-Cloisite 30 B nanocomposite made by the in-situ polymerization method shows better exfoliation behavior compared with the intercalation method. It can be said that the transesterification reaction between functional groups (-OH) of intercalant and monomers results in the increased gallery distance. Also mechanical and thermal properties indicate that the dispersity of clay is an important factor for improving physical properties of the nanocomposite.

Preparation and Characterization of Visible Light-Sensitive N-doped TiO2 Using a Sol-gel Method (Sol-gel법을 이용한 백색도가 높은 가시광 응답형 N-doped TiO2 제조 및 특성 평가 연구)

  • Lee, NaRi;Yu, Ri;Kim, Tae Kwan;Pee, Jae-Hwan;Kim, YooJin
    • Journal of Powder Materials
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    • v.24 no.6
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    • pp.477-482
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    • 2017
  • Nitrogen-doped titanium dioxide (N-doped $TiO_2$) is attracting continuously increasing attention as a material for environmental photocatalysis. The N-atoms can occupy both interstitial and substitutional positions in the solid, with some evidence of a preference for interstitial sites. In this study, N-doped $TiO_2$ is prepared by the sol-gel method using $NH_4OH$ and $NH_4Cl$ as N ion doping agents, and the physical and photocatalytic properties with changes in the synthesis temperature and amount of agent are analyzed. The photocatalytic activities of the N-doped $TiO_2$ samples are evaluated based on the decomposition of methylene blue (MB) under visible-light irradiation. The addition of 5 wt% $NH_4Cl$ produces the best physical properties. As per the UV-vis analysis results, the N-doped $TiO_2$ exhibits a higher visible-light activity than the undoped $TiO_2$. The wavelength of the N-doped $TiO_2$ shifts to the visible-light region up to 412 nm. In addition, this sample shows MB removal of approximately 81%, with the whiteness increasing to +97 when the synthesis temperature is $600^{\circ}C$. The coloration and phase structure of the N-doped $TiO_2$ are characterized in detail using UV-vis, CIE Lab color parameter measurements, and powder X-ray diffraction (XRD).

A Study of a Changing of Physical and Chemical Intra-structure on Si-DLC Film during Tribological Test (실리콘 함유 DLC 박막의 마찰마모 시험에 의한 물리적 특성 및 화학적 결합 구조 변화 고찰)

  • Kim, Sang-Gweon;Lee, Jae-Hoon;Kim, Sung-Wan
    • Journal of the Korean Society for Heat Treatment
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    • v.24 no.3
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    • pp.127-132
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    • 2011
  • The silicon-containing Diamond-like Carbon (Si-DLC) film as an low friction coefficient coating has especially treated a different silicon content by plasma-enhanced chemical vapor deposition (PECVD) process at $500^{\circ}C$ on nitrided-STD 11 mold steel with (TMS) gas flow rate. The effects of variable silicon content on the Si-DLC films were tested with relative humidity of 5, 30 and 85% using a ball-on-disk tribometer. The wear-tested and original surface of Si-DLC films were analysed for an understanding of physical and chemical characterization, including a changing structure, via Raman spectra and nano hardness test. The results of Raman spectra have inferred a changing intra-structure from dangling bonds. And high silicon containing DLC films have shown increasing carbon peak ratio ($I_D/I_G$) values and G-peak values. In particular, the tribological tested surface of Si-DLC was shown the increasing hardness value in proportional to TMS gas flow rate. Therefore, at same time, the structure of the Si-DLC film was changed to a different intra-structure and increased hardness film with mechanical shear force and chemical reaction.

Physics-based Algorithm Implementation for Characterization of Gate-dielectric Engineered MOSFETs including Quantization Effects

  • Mangla, Tina;Sehgal, Amit;Saxena, Manoj;Haldar, Subhasis;Gupta, Mridula;Gupta, R.S.
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.5 no.3
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    • pp.159-167
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    • 2005
  • Quantization effects (QEs), which manifests when the device dimensions are comparable to the de Brogile wavelength, are becoming common physical phenomena in the present micro-/nanometer technology era. While most novel devices take advantage of QEs to achieve fast switching speed, miniature size and extremely small power consumption, the mainstream CMOS devices (with the exception of EEPROMs) are generally suffering in performance from these effects. In this paper, an analytical model accounting for the QEs and poly-depletion effects (PDEs) at the silicon (Si)/dielectric interface describing the capacitance-voltage (C-V) and current-voltage (I-V) characteristics of MOS devices with thin oxides is developed. It is also applicable to multi-layer gate-stack structures, since a general procedure is used for calculating the quantum inversion charge density. Using this inversion charge density, device characteristics are obtained. Also solutions for C-V can be quickly obtained without computational burden of solving over a physical grid. We conclude with comparison of the results obtained with our model and those obtained by self-consistent solution of the $Schr{\ddot{o}}dinger$ and Poisson equations and simulations reported previously in the literature. A good agreement was observed between them.

Metallorganic Chemical Vapor Deposition and Characterization of TiO2 Nanoparticles

  • Jung, Oh-Jin;Kim, Sam-Hyeok;Cheong, Kyung-Hoon;Li, W.;Saha, S. Ismat
    • Bulletin of the Korean Chemical Society
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    • v.24 no.1
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    • pp.49-54
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    • 2003
  • TiO₂nanoparticles were synthesized using the metallorganic chemical vapor deposition process. Particles with and without metal ion dopants were obtained. X-ray photoelectron and energy dispersive X-ray spectroscopic measurements confirmed the stoichiometry of the TiO₂nanoparticles. X-ray diffraction patterns showed a polycrystalline anatase structure of TiO₂. Transmission electron microscopy revealed that these particles are of nanoscale dimensions. Exact particle size and size distribution analyses were carried out by dynamic light scattering. The average particle size was determined to be 22 nm. The nanosize particles provided large surface area for photocatalysis and a large number of free surface-charge carriers, which are crucial for the enhancement of photocatalytic activity. To improve the photocatalytic activity, metal ions, including transition metal ions $(Pd^{2+},\;Pt^{4+},\;Fe^{3+})$ and lanthanide ion $(Nd^{3+})$ were added to pure TiO₂nanoparticles. The effects of dopants on photocatalytic kinetics were investigated by the degradation of 2-chlorophenol under an ultraviolet light source. The results showed that the TiO₂nanoparticles with the metal ion dopants have higher photocatalytic activity than undoped TiO₂. The $Nd^{3+}$ ion of these dopant metal ions showed the highest catalytic activity. The difference in the photocatalytic activity with different dopants is related to the different ionic radii of the dopants.

Fabrication and Characterization of Polycrystalline Mereuric Iodide Films using Particle-in-Binder Methods (Particle-in-Binder(PIB) 법을 이용한 다결정 $HgI_2$ 필름 제작 및 특성 연구)

  • Cha, Byung-Youl;Cho, Sung-Ho;Kim, So-Yeong;Woon, Min-Seuk;Nam, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.330-330
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    • 2007
  • Polycrystalline mercuric iodide $HgI_2$) films are being developed as a new detector technology for digital x-ray imaging. The $HgI_2$ is generally vacuum deposited by physical vapor deposition (PVD) process. But the PVD thick deposition has been caused any instability in the biasing due to any defects or cracks. In this work we present a new particle-in-binder (PIB) methodologies used for the $HgI_2$ thick films. These growth techniques can be easily extended to produce much larger film areas. This paper, for the first time, presents results and comparison of polycrystalline $HgI_2$ films derived by various PIB methods. We investigated the structural and morphological properties of the films using X-ray diffraction (XRD) and scanning electron microscopy (SEM) analysis. The films were characterized with respect to their electrical properties and in response to x-ray photons. Physical and electrical results were also compared between conventional polycrystalline PVD and our detectors. Leakage current as low as $350\;pA/cm^2$ at the bias voltage of ~ 200 V has been observed. And high sensitivity and good linearity in the response to x-rays was obtained in the film derived by PIB sedimentation method. Our future efforts will concentrate on optimization of film growth techniques for uniform large area deposition on image readout arrays.

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Effect of H2O2 modification of H3PW12O40@carbon for m-xylene oxidation to isophthalic acid

  • Fang, Zhou-wen;Wen, Di;Wang, Zhi-hao;Long, Xiang-li
    • Korean Journal of Chemical Engineering
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    • v.35 no.11
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    • pp.2172-2184
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    • 2018
  • The production of isophthalic acid (IPA) from the oxidation of m-xylene (MX) by air is catalyzed by $H_3PW_{12}O_{40}$ (HPW) loaded on carbon and cobalt. We used $H_2O_2$ solution to oxidize the carbon to improve the catalytic activity of HPW@C catalyst. Experiments reveal that the best carbon sample is obtained by calcining the carbon at $700^{\circ}C$ for 4 h after being impregnated in the 3.75% $H_2O_2$ solution at $40^{\circ}C$ for 7 h. The surface characterization displays that the $H_2O_2$ modification leads to an increase in the acidic groups and a reduction in the basic groups on the carbon surface. The catalytic capability of the HPW@C catalyst depends on its surface chemical characteristics and physical property. The acidic groups play a more important part than the physical property. The MX conversion after 180 min reaction acquired by the HPW@C catalysts prepared from the activated carbon modified in the best condition is 3.81% over that obtained by the HPW@C catalysts prepared from the original carbon. The IPA produced by the former is 46.2% over that produced by the latter.