• Title/Summary/Keyword: Physical absorption

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Extracting Gold from Pyrite Roster Cinder by Ultra-Fine-Grinding/Resin-in-Pulp

  • Guo, Bingkun;Wei, Junting
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.337-341
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    • 2001
  • A new method to extract gold from pyrite roster cinder, which combines ultra-fine-grinding with resin-in-pulp, has been studied in this paper. Compared with traditional leaching technology, it can short leaching time, avoid complex filter process, lower sodium cyanide consumption and increase gold recovery by 35%. During leaching, aluminium oxide ball was used as stirred medium, hydrogen peroxide as leaching aid and sodium hexametaphosphate as grinding aid. With the high efficiency and chemistry effect of ultra-fine-grinding, the leaching process was developed and the gold leaching rate may reach 88%. With AM-2 Б resin as abosorber and sulfocarbamide (TU) as eluent, gold was recovered from cyanide pulp by resin-in-pulp. AM-2 Б resin has good adsorbability in cyanide solution(pH=10). It was easy to elude gold from the loaded resin with 0.1㏖/L cholhydric acid and 1㏖/L sulfocabamide. The effect of contact time, temperature and acidity etc. on the gold absorption had been examined with static methods. The results showed that the adsorption and desorption of gold could both reach over 98%. The effects of flow rate of solution on dynamic adsorption and elution of gold had been examined with dynamic methods. Breakthrough curve and elution curve had been drawn in this paper. A mild condition was determined through a number of experiments: leaching time 2 hours, liquid solid ratio 4:1, sodium cyanide 3kg/t, hydrogen peroxide 0.05%, sodium hexametaphosphate 0.05%; adsorption time 30 minutes, temperature 10-3$0^{\circ}C$, resin($m\ell$) solid(g) ratio 1:10, eluent resin ratio 10-20:1, velocity of eluent $1.5m\ell$/min. Under the mild condition, the gold recovery may reach 85%.

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Structure and Reactivity of Bimetallic Catalyst (이원금속 촉매의 구조와 반응성)

  • Yie, Jae-Eue
    • Applied Chemistry for Engineering
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    • v.3 no.1
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    • pp.24-34
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    • 1992
  • Recent studies dealing with the fundamental understanding and applications of bimetallic catalysts are discussed. Bimetallic catalysts have had a major industrial impact, specifically for the reforming of petroleum naphtha, for the hydrogen reduction of carbon monoxide, and for the three way catalytic converter system. The action of the bimetallic catalysts in these reactions may be interpreted in terms of ensembles, electronic influences and surface structure. Various combinations of metal pairs have been considered in order to evaluate the role played by the added metals. For catalyst selectivity control, the possibility of surface enrichment of one element has been recognised. More generally, the influence of preparative variables on the formation of supported catalysts has been clarified, In particular by temperature programmed reduction (TPR). Information on the structure of bimetallic catalysts has been obtained with chemical probes, such as chemisorption and reaction rate measurement and physical probes, such as extended X-ray absorption fine structure (EXAFS), scanning transmission electron microscopy (STEM) and Xe-NMR.

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A Study on the Attraction Factors of the Enetertainment Industry (엔터테인먼트산업의 어트랙션 요소에 관한 연구)

  • 이호숭
    • Archives of design research
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    • v.15 no.2
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    • pp.59-70
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    • 2002
  • The psychological system of human beings has gone through changes from material satisfaction to spiritual satisfaction. That is, $\ulcorner$From real goods to feel goods$\lrcorner$: much attention is not paid to physical consumption of real products but to consumption of time containing information value such as services capable of enriching and entertaining life. Entertainment is a cultural industry based on mass consumption culture. In this context, this research is designed to look into the entertainment tendency of the industrial areas and to take a look at various forms of attraction serving as the factor of absorption to users. The study indicates that the moderns impose much value on invisible goods such as experience. And the most popularized method is to appeal to clients for sensory interaction by presenting the experience of joy. Entertainment in a true sense is generated on the basis of creativity, which is a product of intuition and efforts directed toward the understanding of emotional ties with the general public characterized by uncertainty.

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Performance of Fixing Agents in Controlling Micro-Stickies in Recycled Newsprint Pulp

  • Wang, Li-Jun;Chen, Fu-Shan;Zhou, Lin-Jie
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06a
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    • pp.111-116
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    • 2006
  • The microstickes control effects of some fixing agents, including an inorganic PAC, an organic polyamine (PA) and polydiallydimethyl ammonium chloride (Pdadmac), and a high cationic starch (HCS), were investigated, together with their effects on wet end performances and physical properties of handsheets. Despite that the HCS and Pdadmac had lower cationic charge densities than the PA and PAC (the HCS being even lower), they gave higher zeta potentials to fibers, and lower turbidities, cationic demands and residual COD contents to the pulp liquid phases than the PA and PAC did. In all cases, the HCS showed even better effects than the Pdadmac. In addition, drainage speed was also much higher by the HCS treatments although paper formation was worsened. All the phenomena showed that the HCS can fix more dissolved and colloidal substances to cellulose fibers, indicating that the HCS functioned mainly with flocculation and even hydrogen bonding mechanisms. Data on optical properties further indicated that the HCS interacted preferentially with colloidal substances, since it fixed more 'dirty' microstickes to fibers which decreased more sheet brightness while increasing more sheet opacity (with both higher light absorption and scattering coefficients). Interestingly, the organic fixing agents did not decrease tensile, tearing, and folding strengths of paper sheets made from 100% recycled newsprint pulp, except when they were dosed in high amounts. On the contrary, the inorganic PAC had more serious negative effects on the strength properties, especially on folding endurance. The study suggested that proper use of the HCS can lead to better microstickies control effects than traditional agents and methods.

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Properties of Concrete Using Waste Pottery and Porcelain as Aggregates (폐도자기를 골재로 이용한 콘크리트의 특성)

  • Kang, Sung-Gu;Lee, Wan-Jo;Hwang, In-Dong;Park, Sung;Chung, Yun-Joong
    • Journal of the Korean Ceramic Society
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    • v.42 no.2 s.273
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    • pp.99-103
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    • 2005
  • Nowadays, large amount of waste pottery and porcelain annually are produced. It is needed that they are used as recycled materials in order to prevent environmental pollution and gain economic profits. Therefore, the purpose of this study is to present the method of utilizing the recycled aggregates that are obtained from waste pottery and porcelain as the concrete aggregate. The qualities of the recycled aggregate were compared with those of the crushed aggregate through measuring their physical properties. The test results showed that the replacement of crushed aggregate by recycled aggregate at the levels $10\%,\;20\%$, and $30\%$ had little effect on the compressive strength of the concretes, but higher levels of replacement reduced the compressive strength. Increment of the replacement of recycled aggregate caused increase in absorption ratio. As a conclusion, norman strength recycled aggregate concretes can be produced using less than $30\%$ of recycled aggregate.

Studies on the Manufacturing of Carbon Bond Graphite Crucible (카아본 본드형 흑연 도가니 제조에 관한 연구)

  • 김충일;김문수
    • Journal of the Korean Ceramic Society
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    • v.13 no.1
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    • pp.11-19
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    • 1976
  • This study was focused on the improvement of production techniques of small crucibles in relation with the appropriate selection of raw materials, various batch compositions and physical and chemical characteristics of the crucibles. Various tests gave the optimum batch composition for the carbon bond graphite cructble as follows: Pyontaek graphite flake (refractory aggregate) : 40Part Silicon carbide: 15Part Tar pitch (binder) : 11Part Inorganic additives (to improve the oxidation resistance) : 15 Part Cryolite : 3 Part Ferro manganese : 2 Part Ferrosilicon : 25 Part Crucibles pressed with 400kg/$\textrm{cm}^2$ at 12$0^{\circ}C$. and fired in reducing atmosphere at 120$0^{\circ}C$ brought the most favorable results as follows: Bulk density : 2.31 Apparent density : 2.58 Porosity : 15.2% Oxidation loss at 1, 50$0^{\circ}C$. for 3 hrs : below 3.77% Water absorption : 6.01% Compressive strength : 438kg/$\textrm{cm}^2$ Tensile strength : 256kg/$\textrm{cm}^2$.

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The Effect of Free Silica on the Strength of Chamotte Refractory (Chamotte질 내화물의 강도에 미치는 유이 Silica의 영향)

  • 박금철;최영섭
    • Journal of the Korean Ceramic Society
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    • v.13 no.1
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    • pp.35-44
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    • 1976
  • The effect of quartz which exists in clays, especially in kaolin used for the production of chamotte sagger, on the strength of refractory was examined. In this study, a mixture of chamotte 50%, kaolin 25%, plastic clay 25% in ternary component system was selected as a batch composition. To this mixture 1%, 3% and 5% of feldspar and sericite were added respectively. The plastic clay used here was separated under 170 mesh by dry process. Feldspar and sericite were separated under 325 mesh by dry process. Feldspar and sericite were separated under 325 mesh by dry process. In order to change the particle size and the content of quartz, the kaolin was separated under 60, 115, 170 and 325 mesh by wet process, substituted quartz for coarse parts of it. Chamotte was classified into three grades, coarse (5-10mesh): medium (10-20mesh): fine(20-115mesh) and the ratio was 1:1:1. Samples were formed in 0.8xIx10cm size with 12.5% water at 160kg/$\textrm{cm}^2$ pressure, and fired at 130$0^{\circ}C$ for 1 hr. The fired samples were ivnestigated by means of x-ray diffraction analysis and microscopic observation, and the physical properties of them were also examined, such as firing shrinkage, apparent specific gravity and bulk specific gravity, apparent porosity, water absorption and modulus of rupture. The obtained results are as follows: 1. When screened kaolin with low content of quartz was added to fixed chamotte-plastic clay system, the sample lowered modulus of rupture and increased apparent porosity as the size of kaolin became finer. 2. When kaolin under 325 mesh with 7.2-15.81% quartz between 60-325 mesh was added to fixed chamotte-plastic clay system, the sample had higher apparent porosity and lower modulus of ruputure as the size and the amount of quartz became larger. 3. The addition of feldspar and sericite to chamotte-plastic clay system improved apparent porosity and modulus of rupture. The effect of feldspar was better when quartz content was low, although that of sericite was better than quartz content was high.

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Physico-Chemical Characteristics of Visibility Impairment in a National Park Area (국립공원 지역 시정장애 현상의 물리.화학적 특성)

  • Kim, Kyung-Won
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.4
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    • pp.325-338
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    • 2009
  • National parks provide recreation, health, and science to human being. The provision of beautiful landscape view of the national park improves an economic and social phase of a nation. However, visibility impairment frequently occurred in the national park area of Gyeongju. The purpose of this study is to investigate the physical and the chemical characteristics of visibility reduction observed at the national park area of Gyeongju. Optical, chemical, meteorological characteristics and scenic monitoring were performed at the visibility monitoring station of Gyeongju University located at the Seoak section of Gyeongju national park from April 28 to May 9, 2008. Light extinction, light scattering, and light absorption coefficients were continuously measured using a transmissometer, a nephelometer, and an aethalometer, respectively. In order to investigate the impact of aerosol chemistry on visibility impairment, size-resolved aerosols were collected at intervals of 2-hour (from 8 A.M. to 6 P.M.) and 14-hour (from 6 P.M. to 8 A.M.) interval each sampling day. The average light extinction coefficient and the average visual range were measured to be $270{\pm}135\;Mm^{-1}$ and $14.5{\pm}6.3\;km$ during the intensive monitoring period, respectively. It was revealed that sulfate particle was the largest contributor to the light extinction under hazy condition. Organic mass accounted for about 26% of the average light extinction. The mass extinction efficiencies for $PM_{1.0}$, $PM_{2.5}$, and $PM_{10}$ were estimated to be 9.0, 4.7, and $2.7\;m^2\;g^{-1}$ under the consideration of water growth function of hygroscopic aerosols, respectively.

Preparation and Characterization of Sponge Using Porcine Small Intestinal Submucosa (돼지의 소장 점막하 조직을 이용한 스폰지의 제조 및 특성 결정)

  • 신혜원;김선화;장지욱;김문석;조선행;이해방;강길선
    • Polymer(Korea)
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    • v.28 no.2
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    • pp.194-200
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    • 2004
  • Porcine small intestine submucosa (SIS) has been widely used as a biomaterial without immunorejection responses. Crosslinked SIS sponges were characterized for the possibility of the bio-interactive wound dressings and tissue engineered scaffolds. SIS powders were dissolved in 3% acetic acid aqueous solution at 48hrs followed by pouring into mold and then fabricated by freeze-drying method. SIS sponge was prepared by crosslinked with 1-ethyl-(3-3-dimethyl aminopropyl) carbodiimide hydrochloride (EDC) solution (deionized water: ethanol=5:95) with 1-100mM concentration for 24 hrs and Iyophilized. SIS sponges were characterized by scanning electron microscopy, differential scanning calorimeter, and Fourier transform infrared spectrometer and were tested their porosity and water absorption ability. It was observed that the concentration of EDC might be exceeded 50 mM to get good physical characteristics. In conclusion, it seems that SIS sponge could be very useful for the applications of wound healing and tissue construction.

Fabrication and Characterization of PCL/TiO2 Nanoparticle 3D Scaffold (PCL/TiO2 Nanoparticle 3차원 지지체 제조 및 특성 평가)

  • Kim, Jung-Ho;Lee, Ok Joo;Sheikh, Faheem A.;Ju, Hyung Woo;Moon, Bo Mi;Park, Hyun Jung;Park, Chan Hum
    • Polymer(Korea)
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    • v.38 no.2
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    • pp.150-155
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    • 2014
  • Polycaprolactone (PCL) is a synthetic biodegradable polymer with excellent mechanical properties. $TiO_2$ (titanium dioxide) has a hydrophilic, high density and excellent biocompatibility. In this work, we produced three-dimensional porous scaffolds with PCL and $TiO_2$ nanoparticles using a salt-leaching method. Physical properties of the scaffolds were analyzed by FE-SEM, FTIR, TGA and compressive strength. Interestingly, the addition of $TiO_2$ nanoparticles decreased the water absorption and swelling ratio of the porous scaffolds. However, the compressive strength was increased by $TiO_2$. CCK-8 assay, which is generally used for the analysis of cell growth, shows that $TiO_2$ nanoparticles have no cytotoxicity. Taken together, we suggest that the PLC/$TiO_2$-scaffold can be used for biomedical applications.