• Title/Summary/Keyword: Photovoltaic device

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Flexible ITO/PEDOT:PSS Hybrid Transparent Conducting Electrode for Organic Photovoltaics

  • Lim, Kyounga;Jung, Sunghoon;Kang, Jae-Wook;Kim, Jong-Kuk;Kim, Do-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.299-299
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    • 2013
  • Indium Tin Oxide (ITO) has widely been used as a transparent conductive oxide (TCE) for photovoltaic devices. Lately, flexibility of ITO becomes an issue as demand of flexible device increases. Several scientists have tried to substitute ITO to different materials such as conductive polymer, graphene, CNT, and metal nanowire because of ITO brittleness. Among the substitute materials, PEDOT:PSS has mostly paid attention because PEDOT:PSS has excellent flexibility and good conductivity. The conductivity of PEDOT:PSS increases up to 1000 S/cm with additives such as DMSO, EG, sorbitol, and so on. In our research group, we introduce a conductive polymer PEDOT:PSS as a buffer layer to improve not only flexibility but also conductivity. As PEDOT:PSS layer forms beneath ITO thin film (20 nm), sheet resistance decreases from $230{\Omega}$/${\Box}$ to $85{\Omega}$/${\Box}$ and crack initiation decreases from 4.5 mm to 3.5 mm as well. We have fabricated organic photovoltaic device and power conversion efficiencies using conventional ITO electrode and ITO/PEDOT:PSS hybrid electrode. The photovoltaic property such as power conversion efficiency for ITO/PEDOT:PSS hybrid electrode is comparable to the value obtained using conventional ITO electrode on glass substrate.

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A Simulation of Photocurrent Loss by Reflectance of the Front Glass and EVA in the Photovoltaic Module (전면 유리와 EVA의 광 반사에 의한 PV모듈의 광전류 손실 예측 시뮬레이션)

  • Lee, Sang-Hun;Song, Hee-Eun;Kang, Gi-Hwan;Ahn, Hyung-Keun;Han, Deuk-Young
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.1
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    • pp.76-82
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    • 2013
  • The solar cell is a device to convert light energy into electric, which supplies power to the external load when exposed to the incident light. The photocurrent and voltage occurred in the device are significant factors to decide the output power of solar cells. The crystalline silicon solar cell module has photocurrent loss due to light reflections on the glass and EVA(Ethylene Vinyl Acetate). These photocurrent loss would be a hinderance for high-efficiency solar cell module. In this paper, the quantitative analysis for the photocurrent losses in the 300-1200 wavelength region was performed. The simulation method with MATLAB was used to analyze the reflection on a front glass and EVA layer. To investigate the intensity of light that reached solar cells in PV(Photovoltaic) module, the reflectance and transmittance of PV modules was calculated using the Fresnel equations. The simulated photocurrent in each wavelength was compared with the output of real solar cells and the manufactured PV module to evaluate the reliability of simulation. As a result of the simulation, We proved that the optical loss largely occurred in wavelengths between 300 and 400 nm.

Characterization of Light Effect on Photovoltaic Property of Poly-Si Solar Cell by Using Photoconductive Atomic Force Microscopy (Photoconductive Atomic Force Microscopy를 이용한 빛의 세기 및 파장의 변화에 따른 폴리실리콘 태양전지의 광전특성 분석)

  • Heo, Jinhee
    • Korean Journal of Materials Research
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    • v.28 no.11
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    • pp.680-684
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    • 2018
  • We investigate the effect of light intensity and wavelength of a solar cell device using photoconductive atomic force microscopy(PC-AFM). A $POCl_3$ diffusion doping process is used to produce a p-n junction solar cell device based on a polySi wafer, and the electrical properties of prepared solar cells are measured using a solar cell simulator system. The measured open circuit voltage($V_{oc}$) is 0.59 V and the short circuit current($I_{sc}$) is 48.5 mA. Moreover, the values of the fill factors and efficiencies of the devices are 0.7 and approximately 13.6 %, respectively. In addition, PC-AFM, a recent notable method for nano-scale characterization of photovoltaic elements, is used for direct measurements of photoelectric characteristics in limited areas instead of large areas. The effects of changes in the intensity and wavelength of light shining on the element on the photoelectric characteristics are observed. Results obtained through PC-AFM are compared with the electric/optical characteristics data obtained through a solar simulator. The voltage($V_{PC-AFM}$) at which the current is 0 A in the I-V characteristic curves increases sharply up to $18W/m^2$, peaking and slowly falling as light intensity increases. Here, $V_{PC-AFM}$ at $18W/m^2$ is 0.29 V, which corresponds to 59 % of the average $V_{oc}$ value, as measured with the solar simulator. Furthermore, while the light wavelength increases from 300 nm to 1,100 nm, the external quantum efficiency(EQE) and results from PC-AFM show similar trends at the macro scale but reveal different results in several sections, indicating the need for detailed analysis and improvement in the future.

Effect of cooling patches on performance of photovoltaic-thermoelectric hybrid energy devices (쿨링패치 부착에 따른 태양광-열전 융합소자의 성능 연구)

  • Lee, Jaehwan;Cho, Kyoungah;Park, Yoonbeom;Kim, Sangsig
    • Journal of IKEEE
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    • v.25 no.4
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    • pp.716-720
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    • 2021
  • In this study, we examine the availability of a cooling patch to enhance the output power of a hybrid energy device (HED) comprising a photovoltaic cell (PVC) and a thermoelectric generator (TEG). The cooling patch attached on the back of the TEG drops the temperature of the PVC via the TEG and makes a large thermal gradient across the TEG under irradiances in a range of 200 to 1000 W/m2. The cooling patch is more effective for the output power of the HED as the irradiance increases, and it enhances the maximum output power of the HED to 42.1 mW at an irradiance of 1000 W/m2. The increment in the maximum output power reaches 27% owing to the attachment of the cooling patch that does not consume any power.

Photovoltaic Properties of Organic Solar Cell using Zinc phthalocyanine(ZnPc)/$C_{60}$ devices (Zinc phthalocyanine(ZnPc)/$C_(60)$ 소자를 이용한 유기 광소자의 광기전특성)

  • Lee, Ho-Sik;Hur, Sung-Woo;Lee, Won-Jae;Shin, Hoon-Kyu;Kim, Tae-Wan;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1712-1714
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    • 2004
  • During the last 20 years organic semiconductors have attracted considerable attention due to their interesting physical properties followed by various technological applications in the area of electronics and opto-electronics. It has been a long time since organic solar cells were expected as a low-cost energy-conversion device. Although practical use of them has not been achieved, technological progress continues. Morphology of the materials, organic/inorganic interface, metal cathodes, molecular packing and structural properties of the donor and acceptor layers are essential for photovoltaic response. We have fabricated solar cell devices based on zinc-phthalocyanine(ZnPc) as donor(D) and fullerine($C_{60}$) as electron acceptor(A) with doped charge transport layers, $Alq_3$ as an electron transport or injection layer. We observed the photovoltaic characteristics of the solar cell devices using the Xe lamp as a light source.

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Effects of Oxygen Plasma Treatment on the Electrical Properties of Organic Photovoltaic Cells (유기 광기전 소자의 전기적 특성에 미치는 산소 플라즈마 처리의 영향)

  • Oh, Dong-Hoon;Lee, Young-Sang;Park, Hee-Doo;Shin, Jong-Yeol;Kim, Tae-Wan;Hong, Jin-Woong
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.12
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    • pp.2276-2280
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    • 2011
  • An indium-tin-oxide (ITO) is normally used as a substrate in organic photovoltaic cells. We examined the effects of an oxygen ($O_2$) plasma treatment on the electrical properties of an organic photovoltaic cell. Experiments with four-point probe method and atomic force microscope revealed the lowest surface resistance of 17.64 ${\Omega}$/sq and the lowest average surface roughness of 1.39 nm at the plasma treatment power of 250 W. A device structure of ITO/CuPc/$C_{60}$/BCP/$Cs_2CO_3$/Al was fabricated by thermal evaporation with and without the plasma treated ITO substrate. It was found that the power conversion efficiency of the cell with the plasma treated ITO is 65 % higher than the one without the plasma treated ITO.

Evaluation of Heat Transfer Characteristics of PV Module with Different Backsheet (백시트 종류에 따른 태양전지 모듈의 방열 특성 평가)

  • Bae, Soohyun;Oh, Wonwook;Kang, Yoonmook;Lee, Hae-Seok;Kim, Donghwan
    • Current Photovoltaic Research
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    • v.6 no.2
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    • pp.39-42
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    • 2018
  • When the PV module is illuminated in a high temperature region, solar cells are also exposed to the high temperature external environment. The operating temperature of the solar cell inside the module is increased, which causes the power drops. Various efforts have been made to reduce the operating temperature and compensate the power of solar cells according to the outdoor temperature such as installing of a cooling system. Researches have been also reported to lower the operating temperature of solar cells by improving the heat dissipation properties of the backsheet. In this study, we conducted a test to measure the internal temperature of each module components and the external temperature when the light was irradiated according to the surrounding temperature. Backsheets with different thermal conductivities were compared in the test. Finally, in order to explain the temperature difference between the solar cell and the outside of the module, we proposed an evaluation method of the heat transfer characteristics of photovoltaic modules with different backsheet.

Dynamic Analysis and Controller Design for Standalone Operation of Photovoltaic Power Conditioners with Energy Storage

  • Park, Sun-Jae;Shin, Jong-Hyun;Park, Joung-Hu;Jeon, Hee-Jong
    • Journal of Electrical Engineering and Technology
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    • v.9 no.6
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    • pp.2004-2012
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    • 2014
  • Energy storage devices are necessary to obtain stable utilization of renewable energy sources. When black-out occurs, distributed renewable power sources with energy storage devices can operate under standalone mode as uninterruptable power supply. This paper proposes a dynamic response analysis with small-signal modeling for the standalone operation of a photovoltaic power generation system that includes a bidirectional charger/discharger with a battery. Furthermore, it proposes a DC-link voltage controller design of the entire power conditioning system, using the storage current under standalone operation. The purpose of this controller is to guarantee the stable operation of the renewable source and the storage subsystem, with the power conversion of a very efficient bypass-type PCS. This paper presents the operating principle and design guidelines of the proposed scheme, along with performance analysis and simulation. Finally, a hardware prototype of 1-kW power conditioning system with an energy storage device is implemented, for experimental verification of the proposed converter system.

Solar Photovoltaic According to Installation of Cooling System (냉각시스템에 의한 태양광 발전의 효율 개선)

  • Yum, Sung-Bae;Choi, Hong-Kyoo;Choi, Young-Jun;Hong, Seong-Goo;Kim, Tae-Hoon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.23 no.5
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    • pp.66-71
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    • 2009
  • The solar photovoltaic power generator can get more power with the higher solar radiation quantity. However, if the higher solar radiation quantity on cell becomes high temperature, the efficiency of generate will be reduced. To install cooling system for this kind of device can be the way to solve high temperature problem on cell but another problems after install it such as increasing of solar generated quantity problem cost to install cooling system and cost to be maintained cooling system weren't discussed to practical use this system. So the present paper described about effect and commercial business possibility of cooling system. After installing a cooling system the results of experiment about 5.76[%] average annual increasing of solar photovoltaic can expect.

New Low-Band Gap 2D-Conjugated Polymer with Alkylthiobithiophene-Substituted Benzodithiophene for Organic Photovoltaic Cells

  • Park, Eun Hye;Ahn, Jong Jun;Kim, Hee Su;Kim, Ji-Hoon;Hwang, Do-Hoon
    • Journal of the Korean Chemical Society
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    • v.60 no.3
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    • pp.194-202
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    • 2016
  • Two conjugated semiconducting copolymers consisting of 4,7-bis(4-(2-ethylhexyl)-2-thiophene)-2,1,3-benzothiadiazole (DTBT) and benzo[1,2-b:4,5-b']dithiophene with 5-(2-ethylhexyl)-2,2'-bithiophene (BDTBT) or 5-(2-ethylhexylthio)- 2,2'-bithiophene (BDTBT-S) were designed and synthesized as donor materials for organic photovoltaic cells (OPVs). Alkylthio-substituted PBDTBT-S-DTBT showed a higher hole mobility and lower highest occupied molecular orbital (HOMO) energy level (by 0.08 eV) than the corresponding alkyl-substituted PBDTBT-DTBT. An OPV fabricated using PBDTBT-S-DTBT showed higher VOC and JSC values of 0.83 V and 7.56 mA/cm2, respectively, than those of a device fabricated using PBDTBT-DTBT (0.74 V) leading to a power conversion efficiency of 2.05% under AM 1.5G 100 mW/cm2 illumination.