• Title/Summary/Keyword: Photoluminescence intensity

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Size Control and Optical Properties of ZnO nanoparticles by Zinc-Lithium-Acetate System (Zinc-Lithium-Acetate System을 통한 ZnO 분말 크기제어 및 광학 특성 연구)

  • Yu, Ri;Kim, YooJin
    • Journal of Powder Materials
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    • v.20 no.5
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    • pp.371-375
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    • 2013
  • ZnO nanoparticles in the size range from 5 to 15 nm were prepared by zinc-lithium-acetate system. The morphologies and structures of ZnO were characterized by TEM, XRD and FT-IR spectra. UV-visible results shows that the absorption of ZnO nanoparticles is blue shifted with decrease in particles size. Furthermore, photoluminescence spectra of the ZnO nanoparticles were also investigated. The ZnO nanoparticles have strong visible-emission intensity and their intensities depend upon size of ZnO nanoparticles.

Synthesis and photoluminescence of polyurethane containing confined phenylenevinylene segment (주쇄에 Phenylenevinylene를 가진 PU-PV의 합성과 PL)

  • Lee, Mun-Hag;Yang, Jong-Heon;Chung, Su-Tae;Son, Se-Mo;Kim, Sung-Bin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1016-1018
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    • 2002
  • Poly[bis (3,5-di-t-butyl-1,2-phenylene-1,2-thenylene)-1,4-phenylene-bis(11-oxyundecanylphenyl urethane)] (PV-PU) consisting of alternating a confined phenylenevinylene and a nonconjugated urethane segment in the main chain was synthesized by multistep, photoluminescence of PV-PU is emitted in the blue region with a maximum intensity at about 337 nm.

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Search for new red phosphors under NUV/blue excitation - the stimulating future for solid state lighting

  • Vaidyanathan, Sivakumar;Jeon, Duk-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1350-1352
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    • 2008
  • Research on down conversion phosphor materials is the key for the development of solid state lighting (SSL). Especially finding alternative red phosphor for white LEDs based on blue or NUV LEDs are important research task. Under this view, we have synthesized a series of $Eu^{3+}$ substituted $La_2W_{2-x}Mo_xO_9$ (x = 0 ~ 2, insteps of 0.1) red phosphor and characterized by X-ray diffraction (XRD) and photoluminescence. XRD results reveal a phase transition from triclinic to cubic structure for $x\;{\geq}\;0$. All the compositions show broad charge transfer band due to charge transfer from oxygen to tungsten/molybdenum and red emission due to $Eu^{3+}$ ions. Select compositions show high red emission intensity compared to the commercial red phosphor under NUV/blue ray excitation. Hence, this candidate can be possible red emitting phosphors for white LEDs.

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Effect of $Bi^{3+}$ addition on photoluminescence of (Y,Gd)(V,P)$O_4$:Eu phosphor

  • Kyung, Hyun-Ai;Choi, Sung-Ho;Seong, Tae-Yeon;Jung, Ha-Kyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.569-571
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    • 2008
  • The structural and optical properties on $Bi^{3+}$ addition in (Y,Gd)(V,P)$O_4:Eu^{3+}$ red phosphor were investigated. With the addition of $Bi^{3+}$, the band edge in excitation spectrum shifts toward longer wavelength region, resulting in remarkable enhancement of the red emission intensity at 619 nm.

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Red-shift of the photoluminescence peak of N-doped ZnO phosphors

  • Kim, Jun-Kwan;Lim, Jung-Wook;Kim, Hyun-Tak;Yun, Sun-Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.895-897
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    • 2008
  • ZnO films were fabricated using rf-magnetron sputter deposition process with different $N_2$ ambient. N-content in N-doped ZnO films was less than 1%. The wavelength of the highest intensity PL peak of N-doped ZnO was shifted to higher wavelength with increasing $N_2$ flow rate in the deposition ambient. These results indicated that the optical property of ZnO was significantly affected by the defect level created by doping with a very small amount of N.

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UVU characteristics of $YBO_{3}$:Tb green phosphor prepared by spray pyrolysis

  • Jung, Kyeong-Youl;Kim, Eun-Joung;Kang, Yun-Chan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.1001-1004
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    • 2003
  • We applied the spray pyrolysis technique to prepare fine $YBO_{3}$:Tb particles with high photoluminescence, which could be used in the plasma display device as a green phosphor. Several preparation conditions were investigated in order to tail the vacuum ultraviolet characteristics of $YBO_{3}$:Tb particles when they were prepared by the spray pyrolysis. As a result, the optimized $YBO_{3}$:Tb particles showed the high photoluminescence intensity as well as fine size in comparison with the commercial one.

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Photoluminescence from glass packaged porous silicon diaphragm (유리로 패키징된 다공질 실리콘 다이어프램의 PL특성)

  • Kang, Chul-Goo;Kang, Mook-Sik;Jin, Joon-Hyung;Hong, Suk-In;Min, Nam-Ki
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1902-1904
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    • 2001
  • 본 논문은 마이크로머시닝 기술을 응용하여 다공질 실리콘 다이어프램을 제작하여 air, $N_2$, Ar 분위기에서 유리로 패키징하였다. 유리로 패키징된 소자들과 유리 패키징을 하지 않는 소자를 시간 경과에 따른 다공질 실리콘의 PL(Photoluminescence) 스펙트럼 (peak wavelength, intensity)과 저항 변화를 측정하였다. 또한, 패키징 분위기에 따른 다공질 실리콘의 aging 효과를 서로 비교하여 다공질 실리콘 다이어프램을 이용한 PIN 구조의 소자를 광센서로써 응용 가능성을 살펴보았다.

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Luminescent characteristic of ZnS:Mn,Cu yellow phosphors for Light Emitting Diodes (백색 LED용 ZnS:Mn,Cu 황색 형광체의 발광 특성)

  • Lee, Ji-Young;Yu, Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.141-141
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    • 2010
  • ZnS:Mn yellow phosphors doped with Cu for white light emitting diodes were synthesized by solid state reaction method. Photoluminescence excitation spectra originated from $Mn^{2+}$ were ranged from 450 nm to 500 nm. The yellow emission at around 580 nm was associated with $^4T_1{\rightarrow}^6A_1$ transition of $Mn^{2+}$ ions in ZnS:Mn,Cu phosphors. The highest photoluminescence intensity of the phosphors under 405 nm excitation was obtained at Cu concentration of 0.02 mol%.

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A Study of Oxygen Vacancy on SnO2 Thin Films (SnO2 박막의 산소 빈자리에 관한 연구)

  • Jeong, Jin;Choi, Seung-Pyung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.2
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    • pp.109-115
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    • 2005
  • The study of Oxygen Vacancy on SnO$_2$ thin films grown by thermal chemical vapor deposition were investigated with different substrate temperature. X-ray diffraction showed that the crystallinity of the grown thin films increased with increasing substrate temperature. Two narrow peaks and two broad peaks were observed from the photoluminescence measurements at 6 K. The intensity and shape of the broad peaks were changed with increasing substrate temperature. It was concluded that the origin of the broad peak at 2.4 eV was due to oxygen vacancies and that of peak at 3.1 eV was related to structural defects. Hall effect measurements showed that the carrier density was decreased as increasing deposition time from 10 to 30 min., but increased for the deposition of 60 min.

Photoluminescence Characteristics of Eu-doped Yttrium Oxide Submicron-sized Particles Prepared by Aerosol Pyrolysis

  • Park, Il-Woo;Park, Chang-Kyun;Lee, Deok-Jin;Yoo, Jea-Soo
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.1
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    • pp.29-33
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    • 2003
  • Europium doped yttrium oxide submicron-sized particles were prepared by ultrasonic aerosol pyrolysis. To examine the size effect of submicron-sized-particle, the photoluminescence of the particles was investigated. The particle size was controlled by pH, reaction temperature, molar concentration of yttrium in precursor solution. The PL intensity of submicron-sized particles was decreased with particles size. When the particle size is above about 150 times of Bohr radius of Y$_2$O$_3$, the optical property of the particles shows the bulk characteristics.