• 제목/요약/키워드: Photochemical oxidation and reduction

검색결과 8건 처리시간 0.018초

Photosynthetic Responses to Dehydration in Green Pepper(Capsicum annuum L.)Leaves

  • Lee, Hae-Yeon;Jun, Sung-Soo;Hong, Young-Nam
    • Journal of Photoscience
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    • 제5권4호
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    • pp.169-174
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    • 1998
  • Photosynthetic responses to dehydration were examined by the simulataneous measurement of O2 evolution and chlorophyll (Chl) fluorescence in green pepper leaves. Dehydration was induced by immersing the plant roots directly in the Hoagland solution containing varying concentration (2-30%) of polyethylene glycol(PEG-6000) . Water potential of the leaf was decreased time-and concentation -dependently by PEG-treatment. The decrease in water potential of leaf was correlated with the decrease in both the maximal photosynthesis (Pmax) and quantum yield of O2 evolution, but Pmax dropped more rapidly than quantum yield at all water deficit conditions tested. However, Chl fluorescence parameters were not affected much. Dehydration did not change the initial fluorescence (Fo) and maximum photochemical efficiency(Fv/Fm) of photosystem(PS) II. Both the photochemical quenching (qP) and non-photochemical quenching(NPQ) were not changed by dehydration under low PFR(50 $\mu$mols m-2s-1 ). In contrast, under high PFR(270$\mu$mols m-2s-1)qP was slightly decreased while NPQ was greatly increased. The fast induction kinetics of Chl fluroecence showed no change in Chl fluorescence pattern by dehydration at high PFR (640 $\mu$mols m-2s-1 ), but exhibited a significant drop in peak level(Fp)at low PRFR (70$\mu$mols m-2s-1 ). PS I oxidation and reduction kinetics revealed normal reduction but delayed oxidation to P-700+, suggesting no lesionin electron flow from PSII to PSI , but impaired electron transport to NADP+,These results suggest that water stress caused by PEG-treatment results in the reduction of photosynthesis, promarily due to the reducted electron trasport from PSI to NADP+ or hampered subsequent steps involving Calvin Cycle.

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재사용을 위한 하수처리장 방류수의 고급산화처리 (Advanced Oxidation Processes of Secondary Effluent for Reuse)

  • 조일형;송경석;성기석;정문호;이홍근;조경덕
    • 한국환경보건학회지
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    • 제26권3호
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    • pp.61-68
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    • 2000
  • The use of photo-catalytic processes in pollution abatement and resource has a significant economic importance. Therefore, the applications of photochemical oxidation of secondary effluent driven by UV, TiO2, TiO2/UV, H2O2/UV and TiO2/H2O2/UV, have been investigated in order to treat the secondary effluent from municipal sewage. Various experimental parameters such as BOD, CODcr, Nurbidity, total P, and SPC were examined in each photo-catalytic reaction system. The results showed that the application of single oxidant such as UV, TiO2 only has a minor effect on parameters reduction (CODcr, BOD, etc) to treat the secondary effluent, whereas the combinations of oxidants increase the removal efficiency. The best removal efficiency in every parameters was achieved by the combination of TiO2, H2O2 and UV. It was also found that the optimum amount of TiO2 for the treatment was 1g/ι to achieve water reuse standard. From the results, the photocatalytic reaction system can be an alternative as a post-treatment to treat the secondary effluent from municipal sewage.

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Development of the Assessment Framework for the Environmental Impacts in Construction

  • Tahoon Hong;Changwoon Ji;Kwangbok Jeong;Joowan Park
    • 국제학술발표논문집
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    • The 5th International Conference on Construction Engineering and Project Management
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    • pp.196-203
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    • 2013
  • Environmental problems like global warming have now become important issues that should be considered in all industries, including construction. In South Korea, many studies have been conducted to achieve the government's goals of reduction in environmental impacts. However, the research on buildings has only focused on CO2 emission as a research target despite the fact that other environmental impacts resulting from ozone depletion and acidification should also be considered, in addition to global warming. In this regard, this study attempted to propose assessment criteria and methods to evaluate the environmental performance of the structures from various aspects. The environmental impact category can be divided into global impacts, regional impacts, and local impacts. First, global impacts include global warming, ozone layer depletion, and abiotic resource depletion, while regional impacts include acidification, eutrophication, and photochemical oxidation. In addition, noise and vibration occurring in the building construction phase are defined as local impacts. The evaluation methods on the eight environmental impacts will be proposed after analyzing existing studies, and the methods representing each environmental load as monetary value will be presented. The methods presented in this study will present benefits that can be obtained through green buildings with a clear quantitative assessment on structures. Ultimately, it is expected that if the effects of green buildings are clearly presented through the findings of this study, the greening of structures will be actively expanded.

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MMO 촉매 하에서 N2O 분해에 대한 메탄 SCR 반응 및 CO 생성 효과의 비교 연구 (Comparative Reaction Characteristics of Methane Selective Catalytic Reduction with CO Generation Effect in the N2O Decomposition over Mixed Metal Oxide Catalysts)

  • 박선주;박용성
    • 공업화학
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    • 제19권6호
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    • pp.624-628
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    • 2008
  • $N_2O$는 주요 온실가스 성분의 하나로서 광화학 스모그의 유발, 산성비의 전구체 등 온실효과에 상당한 기여를 하고 있는 물질이다. 이러한 $N_2O$ 및 질소산화물을 제거하기 위하여 환원제를 이용한 Selective Catalytic Reduction (SCR) 반응 공정이 널리 사용되고 있다. 본 연구에서는 Hydrotalcite 형태의 전구체로부터 Mixed Metal Oxide 촉매를 제조하고 그를 사용하여 $N_2O$ 분해를 위한 메탄 SCR 반응 및 CO의 생성효과를 비교 연구하였다. 실험결과 $CH_4$ 환원제의 첨가는 $N_2O$의 분해 반응에 긍정적인 영향을 미치며, 최적화된 $O_2/CH_4$ 비율의 조건에서 메탄의 부분산화에 의한 SCR 반응이 가장 높은 효율을 나타내는 것을 확인할 수 있었다.

Quantification of Total Mercury in Antarctic Surface Snow using ICP-SF-MS: Spatial Variation from the Coast to Dome Fuji

  • Han, Yeong-Cheol;Huh, Young-Sook;Hong, Sung-Min;Hur, Soon-Do;Motoyama, Hideaki;Fujita, Shuji;Nakazawa, Fumio;Fukui, Kotaro
    • Bulletin of the Korean Chemical Society
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    • 제32권12호
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    • pp.4258-4264
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    • 2011
  • The total mercury concentration ($Hg_T$) of surface snow samples collected along a ~1500 km transect in east Queen Maud Land was determined using inductively coupled plasma sector field mass spectrometry to address the behavior of Hg on the Antarctic Plateau. Due to the volatile nature of mercury, measures were taken against Hg loss from standard solutions by choosing appropriate container material and stabilizing agents. Glass bottles with Teflon-lined caps were superior to Teflon and polyethylene containers in protecting against Hg loss, but addition of gold chloride ($AuCl_3$) or bromine chloride (BrCl) was necessary to ensure preservation of Hg. As Hg loss was also observed in snowmelt samples, our analysis may underestimate the actual amount of HgT in the snow. Even so, the measured HgT was still very low (< 0.4-10.8 pg $g^{-1}$, n = 44) without a signal of depositional enhancement accompanying photo-oxidation of atmospheric elemental mercury in austral midsummer. Moreover, the dynamic variation along the traverse implies spatial and temporal heterogeneity in its source processes.

Development of the Assessment Framework for the Environmental Impacts in Construction

  • Hong, Tahoon;Ji, Changwoon;Jeong, Kwangbok;Park, Joowan
    • Journal of Construction Engineering and Project Management
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    • 제3권3호
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    • pp.1-9
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    • 2013
  • Environmental problems like global warming have now become important issues that should be considered in all industries, including construction. In South Korea, many studies have been conducted to achieve the government's goals of reduction in environmental impacts. However, the research on buildings has only focused on CO2 emission as a research target despite the fact that other environmental impacts resulting from ozone depletion and acidification should also be considered, in addition to global warming. In this regard, this study attempted to propose assessment criteria and methods to evaluate the environmental performance of the structures from various aspects. The environmental impact category can be divided into global impacts, regional impacts, and local impacts. First, global impacts include global warming, ozone layer depletion, and abiotic resource depletion, while regional impacts include acidification, eutrophication, and photochemical oxidation. In addition, noise and vibration occurring in the building construction phase are defined as local impacts. The evaluation methods on the eight environmental impacts will be proposed after analyzing existing studies, and the methods representing each environmental load as monetary value will be presented. The methods presented in this study will present benefits that can be obtained through green buildings with a clear quantitative assessment on structures. Ultimately, it is expected that if the effects of green buildings are clearly presented through the findings of this study, the greening of structures will be actively expanded.

전과정평가(LCA) 방법을 이용한 건축물에 대한 환경영향 평가 방법 (Environmental Impact Assessment of Buildings based on Life Cycle Assessment (LCA) Methodology)

  • 홍태훈;지창윤;정광복
    • 한국건설관리학회논문집
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    • 제13권5호
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    • pp.84-93
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    • 2012
  • 환경문제에 대한 인식의 확산과 함께 건설산업에서도 건축물로 인한 환경영향을 저감하고자 하는 연구가 수행되었으나, 대부분의 연구는 이산화탄소에 집중되어 왔다. 하지만, 이산화탄소로 대표되는 지구온난화 뿐만 아니라 다양한 환경영향이 존재하며, 해외에서는 이러한 환경영향에 대한 포괄적인 분석이 적극적으로 시행되고 있다. 이에 따라, 본 연구에서는 건축물로 인한 환경영향을 보다 포괄적으로 평가할 수 있도록, 6가지의 환경영향 범주를 정의하였다. 즉, 지구온난화, 오존층파괴, 자원고갈, 산성화, 부영양화, 광화학산화를 환경영향 범주로 정의하고, 평가 기준들을 제시하였다. 그리고 본 연구에서 제시한 환경영향 범주에 대한 평가의 필요성을 검토하기 위하여 2가지 비교 설계안을 대상으로 사례분석을 시행한 결과, 지구온난화만을 평가한 것과는 상이한 결과가 도출되었다. 즉, 이산화탄소로 대표되는 지구온난화 지수를 기준으로 비교하면 2안이 우수한 것으로 판단되었지만, 6가지 영향범주 모두를 평가한 결과에서는 1안이 우수하다는 결과가 도출되었다. 이는 지구온난화 뿐만 아니라 다양한 환경영향을 포함하여 평가하는 것이 보다 타당한 결과 도출을 유도할 수 있다는 것을 의미한다. 따라서 건축물에 대한 환경영향을 평가하기 위하여, 본 연구에서 제시한 6가지 환경영향 범주를 사용한다면, 보다 타당한 결과의 도출이 가능할 것이라 판단된다.

알카리활성 기포콘크리트의 품질특성 및 환경영향 평가 (Quality Characteristics and Environmental Impact Assessment of Alkali-Activated Foamed Concrete)

  • 양근혁;유성원;이현호;김상철
    • 한국건설순환자원학회논문집
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    • 제1권2호
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    • pp.114-119
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    • 2013
  • 본 연구에서는 공동주택의 난방시스템을 위한 단열재로서 지속가능한 알카리활성 기포콘크리트 배합설계를 제시하기 위한 5배합을 실험하였다. 알카리활성 결합재를 위해 73.5%의 고로슬래그와 15%의 고로슬래그가 5%의 수산화칼슘과 6.5%의 규산나트륨에 의해 활성화되었다. 주요 실험변수인 단위 결합재양은 $325kg/m^3$에서 $425kg/m^3$까지 $25kg/m^3$ 단위로 증가하였다. 실험결과 AA 기포콘크리트는 단위 결합재양이 $375kg/m^3$일 때 KS F 4039에서 제시하는 최소 강도조건 및 경제성을 만족시켰다. 또한 보통포틀랜드시멘트 기포콘크리트 대비 알카리활성 기포콘크리트의 환경영향 저감율은 광화학산화물의 경우 99%, 지구온난화의 경우 87~89%, 자원고갈의 경우 78~82%, 그리고 산성화와 인간독성의 경우 70~75% 수준으로서 매우 높았다.