• 제목/요약/키워드: Photo-Fenton

검색결과 42건 처리시간 0.019초

Degradation of toxic azo dye (AO7) using Fenton's process

  • Sharma, Ashish;Verma, Manisha;Haritash, A.K.
    • Advances in environmental research
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    • 제5권3호
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    • pp.189-200
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    • 2016
  • This study aimed at advanced oxidation of hetero tri-functional reactive dye Acid orange 7 using photo-Fenton conditions in a lab-scale experiment. Decolourisation of Acid Orange 7 dye by Fenton's process was dependent on concentration of Hydrogen peroxide, Ferrous sulphate, pH, and contact time. A $2^3$ factorial design was used to evaluate the effects of these key factors: pH, Fe(II), and $H_2O_2$ concentration, for a dye concentration of 50 mg/L with COD of 340 mg/L at pH 3.0. The response function was removal of colour under optimised conditions; pH 3.0, [Fe(II)] 40.83 mg/L, [$H_2O_2$] 4.97 mmol/L; 13.6 min. of treatment resulting in 100% colour removal. The final COD of treated wastewater was nil suggesting that AOP is a potentially useful process of color removal and dye degradation/mineralisation of effluent having AO7. Minimum contact time for complete decolourisation was at 5 mmol/l $H_2O_2$ concentration. Increase in $FeSO_4$ (mg/l) concentration resulted in decrease of time for complete decolourisation. Box-Behnken Design was used to optimize the process variables. Maximum and minimum levels of pH (3-5), $H_2O_2$ (4-6 mmol/l), $FeSO_4$ (30-46 mg/l) and contact time (5-15 minutes) were used. The statistical analysis revealed a value of 0.88 for coefficient of regression ($R^2$) indicating a good fit of model. Calculated F-value was found higher than the tabulated value confirming to significance of the model. Based on student's t-test, Ferrous sulphate, pH, and contact time have a positive effect on the percent decolourisation of Acid Orange 7.

ACF/TiO2 복합체의 제조 및 유기 염료에 의한 광활성 (Fabrication of Fe-ACF/TiO2 composites and their photonic activity for organic dye)

  • 장간;맹칙달;고원배;오원춘
    • 분석과학
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    • 제22권3호
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    • pp.254-262
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    • 2009
  • 철 화합물을 처리한 활성탄소섬유(Fe-ACF)를 사용하여 Fe-활성탄소섬유/$TiO_2$ (Fe-ACF/$TiO_2$) 복합체 촉매를 제조하였다. 또한, Fe-ACF/$TiO_2$ 복합체 촉매는 BET, SEM, XRD 와 EDX 기기를 사용하여 특성화하였다. BET 표면적은 각각의 복합체들에 대한 흡착 특성과 관계 있음을 나타내었다. SEM 결과는 ACF의 표면상에 Fe 화합물과 이산화 티탄이 분포해 있음을 나타내었다. XRD 결과는 Fe-ACF/$TiO_2$ 복합체가 철 중간체 화합물과 함께 아나타제 구조를 가지고 있음을 나타내었다. EDX 결과는 Fe-ACF/$TiO_2$ 복합체내에 C, O, Ti와 Fe 피크의 존재를 보였다. 광촉매 분해 효과로부터, 이들 복합체에 의한 유기염료의 분해를 관찰 하였다. 다른 분해 효과는 Fe의 포토-펜톤 반응의 탓으로 여겨진다. 즉 Fe-ACF/$TiO_2$의 복합적인 반응은 MB 분해에 대한 강력한 포토-펜톤 반응을 생성한 것으로 여겨진다.

GROWTH INHIBITION OF Acanthamoeba BY HYDROPEROXYNAPHTALIMIDES UPON PHOTOIRRADIATION

  • Matsugo, Seiichi;Takeuchi, Rie;Takehara, Yoshimi;Tsuruhara, Takashi
    • Journal of Photoscience
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    • 제4권3호
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    • pp.127-132
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    • 1997
  • Acanthamoeba strains were photoirradiated in the presence of light-sensitive organic peroxides (hydroperoxynaphthalimide derivatives) including a Photo-Fenton reagent at 366 nm. The survival rates of Acantharnoeba strains determined after 20 h culture showed a significant decrease only upon photoirradiated conditions. The most effective hydroperoxynaphthalimides among these compounds was the bromohydroperoxynaphthalimide (Br-HPO II). The minimum inhibitory concentration (MIC) of Br-HPO II is 100 times lower than that of hydrogen peroxide.

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Preparation of Fe-AC/$TiO_2$ composites and pH dependence of their Photocatalytic activity for methylene blue

  • Meng, Ze-Da;Zhang, Kan;Oh, Won-Chun
    • 한국결정성장학회지
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    • 제19권5호
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    • pp.268-276
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    • 2009
  • In this study, activated carbon (AC) was treated with ferric ion by a sol-gel method. The compound (Fe-AC) was employed for the preparation of Fe-activated carbon/$TiO_2$, (Fe-AC/$TiO_2$) composites. The prepared Fe-AC/$TiO_2$ composites were characterized with surface properties, structural crystallinity, elemental identification and photocatalytic activity. The SEM results showed that ferric compounds and titanium dioxide were fixed onto the AC surfaces. The XRD results showed that Fe-AC/$TiO_2$ composites mostly contained anatase phase. EDX showed the presence of C, O, and Ti with Fe peaks in all samples. Its photocatalytic degradation effect was evaluated with the degradation behavior of the methylene blue (MB) solution. MB degradation could be attributed to the synergetic effects of adsorption, photo-degradation of $TiO_2$ and photo-Fenton of Fe component. The degradation rate for this photocatalysis was evaluated as a function of the concentration of the dye, the amount of $TiO_2$ and the pH. Photocataytic activity is good at activity pH.

Photonic Aspects of MB Degradation on Fe-carbon/TiO2 Composites under UV Light Irradiation

  • Zhang, Kan;Meng, Ze-Da;Oh, Won-Chun
    • 한국세라믹학회지
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    • 제47권5호
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    • pp.433-438
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    • 2010
  • Fe-carbon/$TiO_2$ composites were prepared by a sol-gel method using AC, ACF, CNT and $C_{60}$ as carbon precursors and were characterized by means of BET surface area, X-ray diffraction (XRD), scanning electron microscopy (SEM), Transmission Electron Microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX). The activity of the prepared photocatalysts was investigated by degradation reaction of methylene blue (MB) irradiated with UV lamp. Effects of different carbon sources and irradiation time on photocatalytic activity were also investigated. The results showed that the photocatalytic activity of the Fe-carbon/$TiO_2$ composites was much higher than that of pristine $TiO_2$ and Fe/$TiO_2$ composites. The prominent photocatalytic activity of Fecarbon/$TiO_2$ composites could be attributed to both the effects of photo-adsorption and electron transfer by carbon substrate. In addition, the higher photocatalytic activity of Fe-carbon/$TiO_2$ composites can be compared with that of carbon/$TiO_2$ and Fe /$TiO_2$ composites due to cooperative effects between Fe and carbon.

회전원판 광촉매 반응기(Rotating Disk Photocatalytic Reactor)를 이용한 Rhodamine B의 색 제거 (Decolorization of Rhodamine B using Rotating Disk Photocatalytic Reactor)

  • 박영식
    • 한국물환경학회지
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    • 제21권1호
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    • pp.46-51
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    • 2005
  • The photocatalytic oxidation of Rhodamine B (RhB) was studied using immobilized $TiO_2$ and rotating disk photocatalytic reactor. Immobilized $TiO_2$ onto the surface of the aluminum plate was employed as the photocatalyst and two 20 W germicidal lamps and two 20 W UV-BLB lamps were used as the light source and the reactor volume was 1.0 L. The effects of parameters such as the number of rotating disk, rpm of rotating disk, the number of coating, $H_2O_2$ and photo-fenton amounts, and the concentrations of anions and cations ($NO_3{^-}$, $SO_4{^{2-}}$, $Cl^-$, $Ca^{2+}$, $Zn^{2+}$, $Na^+$) were examined.

Photodecomposition of Different Organic Dyes Using Fe-CNT/TiO2 Composites under UV and Visible Light

  • Zhang, Kan;Meng, Ze-Da;Oh, Won-Chun
    • 한국세라믹학회지
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    • 제47권2호
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    • pp.169-176
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    • 2010
  • The Fe-treated CNT/$TiO_2$ photocatalysts mixed with anatase and rutile phase have been developed for the decomposition of non-biodegradable different organic dyes like methylene blue (MB), rhodamine B (Rh.B), and methyl orange (MO) in two conditions as ultraviolet and visible light respectively. The results indicate that all the Fe-CNT/$TiO_2$ composites proved to be more efficient photocatalysts since degradation of MB at higher reaction rates, tthe decomposition rate of different dyes increases with an increase of $Fe^{3+}$ concentration in composites the highest rate of decomposition of different dyes was noted under UV irradiation. These results can indicate that the large CNT network is facilitate the electron transfer and strongly adsorb dye molecules on the texted photocatalysts, iron is reactive in the photo-Fenton process resulting in high production of OH radicals and also high activity of the photocatalyst. And Fe particles can generate more photoinduced electrons to conduction band of $TiO_2$ under visible light irradiation. The composites of Fe-CNT/$TiO_2$ photocatalysts synthesized by a sol-gel method were characterized by BET, TEM, SEM, XRD and EDX.

커피 찌꺼기의 카페인 용출 및 산화분해 특성 (Extraction of Caffeine from Spent Coffee Grounds and Oxidative Degradation of Caffeine)

  • 신민정;김영훈
    • 한국환경과학회지
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    • 제27권12호
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    • pp.1205-1214
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    • 2018
  • During the past few decades, significant increase in the consumption of coffee has led to rapid increase in the production of coffee waste in South Korea. Spent coffee waste is often treated as a general waste and is directly disposed without the necessary treatment. Spent Coffee Grounds (SCGs) can release several organic contaminants, including caffeine. In this study, leaching tests were conducted for SCGs and oxidative degradation of caffeine were also conducted. The tested SCGs contained approximately 4.4 mg caffeine per gram of coffee waste. Results from the leaching tests show that approximately 90% of the caffeine can be extracted at each step during sequential extraction. Advanced oxidation methods for the degradation of caffeine, such as $UV/H_2O_2$, photo-Fenton reaction, and $UV/O_3$, were tested. UV radiation has a limited effect on the degradation of caffeine. In particular, UV-A and UV-B radiations present in sunlight cause marginal degradation, thereby indicating that natural degradation of caffeine is minimal. However, $O_3$ can cause rapid degradation of caffeine, and the values of pseudo-first order rate constants were found to be ranging from $0.817min^{-1}$ to $1.506min^{-1}$ when the ozone generation rate was $37.1g/m^3$. Additionally, the degradation rate of caffeine is dependent on the wavelength of irradiation.

Fe-ACF/TiO2 복합체의 특성화와 가시광선조건에서 MB 용액의 광촉매활성 (Characterization of Fe-ACF/TiO2 composite and photocatalytic activity for MB Solution under visible light)

  • 장간;맹칙달;오원춘
    • 분석과학
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    • 제23권3호
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    • pp.225-232
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    • 2010
  • 본 연구에서 종래의 졸-겔법을 사용하여 Fe-ACF/$TiO_2$ 광촉매 복합체를 제조하였고, 이들 광촉매의 분해능은 메틸렌블루 (MB) 용액의 분해에 의하여 나타내었다. 제조된 이들 복합체에 대한 입자크기, 표면구조, 결정상 및 원소분석을 BET, SEM, XRD 및 EDX에 의하여 각각 특성화 하였다. 가시광선 조건에서 분해된 MB 농도에 대한 스펙트라는 UV/Vis 분광기에 의하여 얻어 졌다. 이와 같이 얻어진 스펙트라는 MB의 제거된 농도로부터 광촉매 활성을 입증하였다. 이들 광촉매 활성은 가시광선 조건에서 복합체 광촉매 내에 존재하는 ACF, $TiO_2$ 및 Fe 사이에 강력한 시너지 반응에 의해 유도된 것으로 여겨진다.

Kinetic Study of the Visible Light-Induced Sonophotocatalytic Degradation of MB Solution in the Presence of Fe/TiO2-MWCNT Catalyst

  • Zhang, Kan;Oh, Won-Chun
    • Bulletin of the Korean Chemical Society
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    • 제31권6호
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    • pp.1589-1595
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    • 2010
  • In order to effective degradation of organic dye both under visible light or ultrasonic irradiation, the MWCNTs (multiwalled carbon nanotube) deposited with Fe and $TiO_2$ were prepared by a modified sol-gel method. The Fe/$TiO_2$-MWCNT catalyst was characterized by surface area of BET, scanning electron microscope (SEM), Transmission Electron Microscope (TEM), X-ray diffraction (XRD), and energy dispersive X-ray (EDX) and ultraviolet-visible (UV-vis) spectroscopy. The low intensity visible light and low power ultrasound was as an irradiation source and the methylene blue (MB) was choose as the model organic dye. Then degradation experiments were carried out in present of undoped $TiO_2$, Fe/$TiO_2$ and Fe/$TiO_2$-MWCNT catalysts. Through the degradation of MB solution, the results showed the feasible and potential use of Fe/$TiO_2$-MWCNT catalyst under visible light and ultrasonic irradiation due to the enhanced formation of reactive radicals as well as the possible visible light and the increase of ultrasound-induced active surface area of the catalyst. After addition of $H_2O_2$, the MB degradation rates have been accelerated, especially with Fe/$TiO_2$-MWCNT catalyst, in case of that the photo-Fenton reaction occurred. The sonophotocatalysis was always faster than the respective individual processes due to the more formation of reactive radicals as well as the increase of the active surface area of Fe/$TiO_2$-MWCNT catalyst.