• Title/Summary/Keyword: Phosphorus acid

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Flame Retardancy of Cellulose Fabrics Treated with 3-(Hydroxyphenyl Phosphinyl) Propanoic Acid

  • Zhang, Lianping;Kim, Sam-Soo;Lee, Jae-Woong
    • Textile Coloration and Finishing
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    • v.20 no.5
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    • pp.1-6
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    • 2008
  • 3-(Hydroxyphenyl phosphinyl) propanoic acid (HPPA) has been one of the most commonly used durable flame retardant agents for polyethylene terephthalate (PET) for many years. We intended to explore the application of HPPA to cellulose fabrics as formaldehyde-free phosphorus based flame retardants (FRs) through green chemistry process. The flame retardancy of the flame-retardant treated cellulose fabrics were characterized by using inductively coupled plasma spectroscopy (ICP) and limiting oxygen index (LOI). Structural changes of the treated cellulose fabrics were carried out by thermogravimetric analysis (TGA) and Fourier transform infrared (FT-IR) spectroscopy. To enhance the flame retardancy of HPPA treated cellulose fibers, glycerol polyglycidyl ether (GPE), a crosslinking agent was employed. Both HPPA and GPE treated cotton fabric imparted an LOI value over 26.

Composition of Amino Acid and Minerals in Cancerous Tissues (암 조직의 아미노산과 무기질의 조성)

  • Ji, Sung-Kyu
    • Korean Journal of Food Science and Technology
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    • v.31 no.4
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    • pp.1124-1127
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    • 1999
  • In order to investigate the nutrients, such as amino acids and minerals concerned to propagate the cancer cells, cancerous tissues such as neuroblastoma with liver meta, cancer in situs. CIS, meta. squ. cell cancer, R/O squ. cell cancer, macro. RIF, metastatic papillary cancer. neck, stomach cancer, lung cancer, intestinal obs., 3 kinds of rectal cancers were analyzed. Tryptophane, a fat soluble amino acid, and minerals such phosphorus, sulfur and iron were contained exceptionally high in cancerous tissues than that of normal cells. And copper and zinc minerals were contained very low level in cancerous cells. Therefore, we can deduce that those constituents might be concerned to the formation of cancerous tissues.

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Preparation of Reactive Flame Retardant Coatings Containing Phosphorus;I. Synthesis of Pyrophosphoric Modified Polyesters (반응형 인계 난연도료의 제조;I.피로포스포릭 변성폴리에스테르의 합성)

  • Chung, Dong-Jin;Jung, Choong-Ho;Park, Hong-Soo;Kim, Tae-Ok;Park, Shin-Ja
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.1
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    • pp.57-63
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    • 2003
  • An intermediate, tetramethylene bis (orthophosphate), was prepared by the esterification of pyrophosphoric acid and l,4-butanediol. Then pyrophosphoric-containing modified polyesters (ATTBs) were synthesized by polycondensation of tetramethylene bis(orthophosphate), trimethylolpropane, adipic acid, and l,4-butanediol. The content of l,4-butanediol was varied from 10 to 20wt% for the reaction. The increase of the amount of l,4-butanediol in the synthesis of ATTBs resulted in increase in average molecular weight and decrease in kinematic viscosity owing to the excellent flowability and reactivity of l,4-butanediol.

Synthesis of Acryl Phosphate Antistatic Agent and Its Effect on the Antistatic, Thermal and Mechanical Properties of PMMA

  • Park, Eu-Soo;Cho, Eun-Bum;Kim, Duk-Joon
    • Macromolecular Research
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    • v.15 no.7
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    • pp.617-622
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    • 2007
  • A simple and economic antistatic agent, (2-methacryloyloxyethyl)acid phosphate (acryl phosphate), was synthesized via the reaction of 2-hydroxyethyl methacrylate with phosphorus pentoxide. The acryl phosphate antistatic agent, synthesized in this study, was introduced into poly(methyl methacrylate) (PMMA) resin via copolymerization with MMA. This antistatic agent provides the PMMA matrix with excellent antistatic properties, including surface resistance and electric charge. A comparison of the present antistatic agent with other commercial agents demonstrated the excellence of not only its electrical, but also its thermal and mechanical properties.

A Study on the Extraction Time and Component Analysis of Goat Meat with Bone Extract (흑염소 육골액의 적정 추출시간 및 성분 분석에 관한 연구)

  • 조길석
    • Food Science and Preservation
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    • v.9 no.4
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    • pp.396-399
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    • 2002
  • An attempt was made in this study to investigate the optimum extracting time from meat with bone of goat and the nutritional component of its extract. for the trials, the mixtures of meat with bone and water were adjusted to the ratios of five to four by weight and extracted for 6, 9 and 12 hours at 120$\^{C}$ under autoclave. Judging from the content of mineral and amino acid, nonenzymatic browning and yield, the optimum extracting time was 9 hours. The major components of mineral were composed of 47.7mg% potassium, 12.7mg% calcium, 150.0mg% sodium, 105.3mg% phosphorus and 0.5mg% iron, and of amino acids composed of 1,308.0mg% glutamic acid, 1,464.2mg% glycine, 750.2mg% alanine and 828.lmg% proline in extract. The yield of extract was 32.1 percentage by dry basis.

Effect of Phosphorous Acid Concentration on Mechanical Properties of Ni-P Electrodeposits (니켈-인 도금 층의 기계적 성질에 미치는 아인산 농도의 영향)

  • Kang, Soo Young;Yang, Seung gi;Hwang, Woon suk
    • Journal of the Korean institute of surface engineering
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    • v.48 no.3
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    • pp.100-104
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    • 2015
  • The nickel alloys gets a great deal of attention due to their good mechanical, chemical and magnetic properties. Especially Ni-P alloy systems are very attractive due to their good corrosion resistance and the wear resistance in important technological applications. In this study, the effects of phosphorus acid concentration in plating solution on composition of Ni-P alloy coatings were studied. The Ni-P electrodeposits of the various P contents were investigated in order to understand effect of the composition on mechanical properties of Ni-P electrodeposits. The mechanical properties of electrodeposits increased as the P content in electrodeposits increase. The results of mechanical properties were explained by grain size and P solid solution effect. The effects of heat treatment on mechanical properties of Ni-P alloy coatings were also studied.

Effects of Feeding Oxalate Containing Grass on Intake and the Concentrations of Some Minerals and Parathyroid Hormone in Blood of Sheep

  • Rahman, M.M.;Nakagawa, T.;Niimi, M.;Fukuyama, K.;Kawamura, O.
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.7
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    • pp.940-945
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    • 2011
  • In order to determine whether oxalate from grasses affects feed intake, blood calcium (Ca) and other blood parameters of adult sheep, two feeding trials were conducted. In Trial 1, one group of sheep received guineagrass (0.47% soluble oxalate) and another group received setaria (1.34% soluble oxalate) for 28 d. In Trial 2, one group of sheep received guineagrass while another group received the same grass treated with an oxalic acid solution (at a rate of 30 g oxalic acid/kg dry matter of hay) for 72 d. All sheep received concentrate mixtures (0.5% of body weight) throughout the experiment. In both trials, it was observed that plasma Ca concentration (11.0-11.7 mg/dl) was significantly (p<0.05) lower in sheep fed high oxalate-containing grasses than in sheep fed low oxalate-containing grasses (12.4-13.7 mg/dl). No differences (p>0.05) were observed in concentrations of magnesium, phosphorus and parathyroid hormone in plasma between the feeding of low and high oxalate-containing grasses. In addition, no differences (p>0.05) were observed in roughage dry mater (DM) intake, total DM intake or body weight of sheep. This study suggests that sheep may consume oxalate-rich forage, but Ca bioavailability may decrease with increasing oxalate levels in the ration.

Effects of thinning intensity on nutrient concentration and enzyme activity in Larix kaempferi forest soils

  • Kim, Seongjun;Han, Seung Hyun;Li, Guanlin;Yoon, Tae Kyung;Lee, Sang-Tae;Kim, Choonsig;Son, Yowhan
    • Journal of Ecology and Environment
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    • v.40 no.1
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    • pp.5-11
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    • 2016
  • Background: As the decomposition of lignocellulosic compounds is a rate-limiting stage in the nutrient mineralization from organic matters, elucidation of the changes in soil enzyme activity can provide insight into the nutrient dynamics and ecosystem functioning. The current study aimed to assess the effect of thinning intensities on soil conditions. Un-thinned control, 20 % thinning, and 30 % thinning treatments were applied to a Larix kaempferi forest, and total carbon and nitrogen, total carbon to total nitrogen ratio, extractable nutrients (inorganic nitrogen, phosphorus, calcium, magnesium, potassium), and enzyme activities (acid phosphatase, ${\beta}$-glucosidase, ${\beta}$-xylosidase, ${\beta}$-glucosaminidase) were investigated. Results: Total carbon and nitrogen concentrations were significantly increased in the 30 % thinning treatment, whereas both the 20 and 30 % thinning treatments did not change total carbon to total nitrogen ratio. Inorganic nitrogen and extractable calcium and magnesium concentrations were significantly increased in the 20 % thinning treatment; however, no significant changes were found for extractable phosphorus and potassium concentrations either in the 20 or the 30 % thinning treatment. However, the applied thinning intensities had no significant influences on acid phosphatase, ${\beta}$-glucosidase, ${\beta}$-xylosidase, and ${\beta}$-glucosaminidase activities. Conclusions: These results indicated that thinning can elevate soil organic matter quantity and nutrient availability, and different thinning intensities may affect extractable soil nutrients inconsistently. The results also demonstrated that such inconsistent patterns in extractable nutrient concentrations after thinning might not be fully explained by the shifts in the enzyme-mediated nutrient mineralization.

Effects of Simulated Acid Rain on Mineral Nutrient Movement in Soil (인공산성비 처리가 토양의 무기양분 이동에 미치는 영향)

  • Ryu, Kwan-Shig
    • Korean Journal of Environmental Agriculture
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    • v.17 no.4
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    • pp.362-367
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    • 1998
  • To investigate the effects of simulated acid rain(SAR) on the downward movement of mineral nutrients, SARs of different pH were applied to the soil. SAR of pH 2.0 decreased the soil pH greatly, while SAR of pH 4.0 and 6.0 did not change the soil pH to compare to that of SAR of pH 2.0. Decrease in soil pH was in the order of sandy loam > loam > clay loam. The amoumt of leached exchangeable and soluble bases from the soil due to the penetration of SAR was in the order of Ca >Mg > K. After application of 1200mm SAR of pH 2.0 in to the soil downward mean movements of the exchangeable and soluble bases was in the order of Mg > Ca > K in sandy loam and loam soil and Ca > Mg > K in clay loam soil. Downward movements of the those bases under pH 4.0 into the soil was in the order of Mg > K > Ca in sandy loam and clay loam, and K > Mg > Ca in loam soil. Available phosphorus moved slightly downward with increasing acidity of the SAR.

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Effects of Supplemental Synthetic Amino Acids to the Low Protein Diets on the Performance of Growing Pigs

  • Jin, C.F.;Kim, J.H.;Han, In K.;Bae, S.H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.11 no.1
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    • pp.1-7
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    • 1998
  • A total of 120 pigs $(L\;{\times}\;LW\;{\times}\;D)$ averaged 14.16 kg of body weight were reared under six dietary treatments to evaluate the effects of amino acid supplementation on their performances. Treatments were 1) 18% CP diet (control); 2) 15% CP+0.28% Lys (B, 15L); 3) B+0.06% Met (15LM); 4) B+0.13% Thr (15LT) ; 5) B+0.06% Met+0.13% Thr (15LMT); 6) B+0.06% Met+0.13% Thr+0.05% Trp (15LMTT). Each treatment had 4 replicates with 5 pigs per replicate. The daily weight gains were statistically similar in 15LMT, 15LMTT and control groups. Threonine and methionine supplementation resulted in improved growth performance and nutrient digestibilities, while tryptophan supplementation had little beneficial effect. However, the best feed conversion was found in the control group. Dry. matter and CP digestibilities were improved in the 15LMT and 15LMTT groups. Gross energy, crude fat and phosphorus digestibilities were not affected by the treatment. Among the 15% CP groups, nitrogen digestibility showed the tendency to be increased as the more synthetic amino acids were added. Dry matter and nitrogen excretions were significantly reduced by feeding low protein, amino acid fortified diets, while phosphorus excretion was not influenced. Essential amino acids digestibility was higher in 15LT, 15LMT and 15LMTT groups and lower in the control. The 15LT group showed the best lysine digestibility, and methionine digestibilities were higher in all treated groups than control one. Threonine digestibilities higher in 15LT 15LMT, and 15LMTT than the control. The result shows that threonine and methionine should be added to the diet containing 15% CP diet, fortified with lysine to get same performance of 18% CP diet.