• 제목/요약/키워드: Phosphor degradation

검색결과 37건 처리시간 0.022초

원자층증착방법으로 성장한 CaS:Pb 청색 형광체 박막의 열처리 효과와 전자빔 조사에 의한 열화현상 연구 (Studies on thermal annealing effect and electron beam induced degradation of ALD-grown CaS:Pb blue phosphor)

  • 윤선진;박상희;변정우;서경수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 디스플레이 광소자 분야
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    • pp.93-96
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    • 2002
  • 원자층증착법으로 제조한 청색 CaS:Pb 박막 형광체에 대한 열처리 및 전자빔 조사 효과찰 연구하였다. CaS:Pb 형광 박박의 열처리는 500 - $700^{\circ}C$ 온도범위에서 급속 열처리 공정으로 수행하였고, 1 kV, $20{\mu}A/cm^{2}$ 조건의 전자빔을 연속적으로 조사하여 열화를 가속시킨 후 처리 전, 후의 재료 및 cathololuminescence (CL) 특성을 비교 분석하였다. 원자층증착법으로 성장한 CaS:Pb 박막은 화학적 조성과 결정성이 우수하여 후속 열처리에 의해 발광특성이 크게 증가하는 경향을 보이지 않았으며, 전자빔에 의한 열화 정도는 판매되고 있는 형광체에 비하여 오히려 적었다. CL 강도가 초기값의 50%로 감소할 때까지 전자빔을 조사한 후에도 주목할만한 결정성 및 조성의 변화는 관찰되지 않았으나 전자빔 조사에 의해 표변에 두께 10 nm 내외의 탄소오염층이 형성됨을 알 수 있었다.

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Highly Reliable White LEDs Using Nitride Phosphors

  • Xie, Rong-Jun;Hirosaki, Naoto;Takeda, Takashi
    • 한국세라믹학회지
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    • 제49권4호
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    • pp.375-379
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    • 2012
  • Nitride phosphors are now attracting significant attention of material scientists and phosphor engineers, because they promise red-shifted photoluminescence spectra, small Stokes shift, high quantum efficiency and low thermal degradation. A number of interesting nitride phosphors have been developed and practiced for producing white light with LED chips. In this paper, the applications of nitride phosphors in highly reliable wLEDs will be overviewed.

High Luminance $Zn_2SiO_4$:Mn phosphors Prepared by Homogeneous Precipitation Method

  • Jung, Ha-Kyun;Sohn, Kee-Sun;Sung, Bu-Young;Park, Hee-Dong
    • Journal of Information Display
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    • 제1권1호
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    • pp.35-41
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    • 2000
  • Manganese-doped $Zn_2SiO_4$ phosphors well known as a green emitter with high luminescence efficiency were prepared by the homogeneous precipitation method, and their photoluminescence properties under vacuum-ultraviolet (VUV) excitation were investigated. $Zn_2SiO_4$:Mn phosphors obtained by this method have exhibited a high luminance of property and a spherical shape of particles. In particular, the green emission intensity of zinc orthosilicate prepared as containing around 2 mole% of manganese was much stronger than that of the commercial $Zn_2SiO_4$:Mn phosphor, while the decay time was longer. However, addition of $Al^{3+}$ and $Li^+$ into $Zn_2SiO_4$:Mn composition has significantly diminished the decay time of the phosphor without much degradation of the emission intensity.

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Influence of Image Sticking on Electra-Optical Characteristics in Alternating-Current Plasma Display Panels

  • Choi, J.H.;Jung, Y.;Jung, K.B.;Kim, S.B.;Choi, E.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.760-763
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    • 2003
  • We have investigated the electro-optical characteristics of image sticking in AC PDP. Although Image sticking is one of major factors to determine display quality in AC PDP, so far, it has not being reported why it is occurred and how we can prevent it. In this experiment, we have analyzed the effect of MgO protective layer and phosphor on the image sticking and we have measured the difference of firing voltage, brightness and discharge current between sticking image and normal image in AC PDP. As a result, Phosphor degradation is a more major factor than MgO protective layer and the firing voltage of gas discharge in sticking image is higher than that of normal discharge.

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Analysis of Enhancement in Phosphor Performance induced by Surface Treatments

  • Jeon, Duk-Young;Bukesov, Sergey A.;Kim, Jin-Young;Park, Zin-Min;Lee, Dong-Chin
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.370-373
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    • 2003
  • A search for a new phosphor composition of excellent performance in systematic ways requires lots of research efforts, and often turns out to be very timeconsuming and difficult. Thus, usually practical ways are taken to improve the performance of phosphors. A few examples of practical surface treatments on phosphors such as $In_2O_3$ coating on $ZnGa_2O_4:Mn$, phosphoric acid treatment on ZnS:Ag,Cl, and base KOH treatment with ultrasonication on ZnS:Ag,Cl are presented. The reasons for the improvement of luminescence intensity or degradation properties after these treatments are discussed based upon careful analyses on the surface of the phosphors and a proposed model on charge carriers generated by electron beam excitation.

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Protective Metal Oxide Coatings on Zinc-sulfide-based Phosphors and their Cathodoluminescence Properties

  • Oh, Sung-Il;Lee, Hyo-Sung;Kim, Kwang-Bok;Kang, Jun-Gill
    • Bulletin of the Korean Chemical Society
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    • 제31권12호
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    • pp.3723-3729
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    • 2010
  • We investigated the high-excitation voltage cathodoluminescence (CL) performance of blue light-emitting (ZnS:Ag,Al,Cl) and green light-emitting (ZnS:Cu,Al) phosphors coated with metal oxides ($SiO_2$, $Al_2O_3$, and MgO). Hydrolysis of the metal oxide precursors tetraethoxysilane, aluminum isopropoxide, and magnesium nitrate, with subsequent heat annealing at $400^{\circ}C$, produced $SiO_2$ nanoparticles, an $Al_2O_3$ thin film, and MgO scale-type film, respectively, on the surface of the phosphors. Effects of the phosphor surface coatings on CL intensities and aging behavior of the phosphors were assessed using an accelerating voltage of 12 kV. The MgO thick film coverage exhibited less reduction in initial CL intensity and was most effective in improving aging degradation. Phosphors treated with a low concentration of magnesium nitrate maintained their initial CL intensities without aging degradation for 2000 s. In contrast, the $SiO_2$ and the $Al_2O_3$ coverages were ineffective in improving aging degradation.

플라스틱 커플러를 채용한 프로젝션 TV의 휘도저감 (Brightness Degradation of Projection TV with Plastic Coupler)

  • 김남웅;김국원
    • 한국산학기술학회논문지
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    • 제7권6호
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    • pp.1028-1033
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    • 2006
  • 일반적으로 프로젝션 TV의 냉각을 위해서는 알루미늄 커플러와 냉매를 사용한다. 본 연구에서는 비용절감의 차원에서 플라스틱 커플러를 사용하는 경우, 냉각성능 저감에 따른 휘도저감의 문제에 대해 연구하였다. 형광체의 밝기와 온도변화와의 관계를 조사하고, 프로젝션 TV 내 CRT의 온도분포를 유한요소법을 이용하여 해석하였다. 이러한 결과로부터 플라스틱 커플러를 채용하는 프로젝션 TV의 휘도저감을 예측할 수 있었다.

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다꾸찌법을 이용한 자체 발광 유리관용 형광체 열화 특성 (Degradation Characteristics Phosphor Used in Self-Luminous Glass Tube with Taguchi Method)

  • 김경화;윤문영;권오환;염충섭
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 2003년도 춘계 학술발표회 논문집
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    • pp.377-382
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    • 2003
  • 본 연구의 대상인 자체발광 유리관은 밀봉된 유리관 내의 삼중수소에서 방출되는 베타입자와 유리관 내벽의 형광체와의 발광반응 메카니즘을 이용한 것이다. 자발광체는 삼중수소의 자연 붕괴와 형광체의 열화에 의해서 형광 효율이 감소되어 자발광체를 제조한 날로부터 지속적으로 휘도가 줄어들게 된다. 본 연구에서는 자발광체 제조 시 형광체의 열화를 최소화하기 위하여 형광체 열화에 영향을 미치는 요소인 온도, 온도 유지 시간, 공정 시 필요한 분위기를 다꾸지 방법에 의한 실험계획법으로 3인자 3수준의 교호작용을 고려하여 형광체의 음극선 발광 특성을 검토하였다.

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