• Title/Summary/Keyword: Phosphor degradation

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The Degradation Characteristics of Phosphor Layers by Environmental Temperature and Plasma Discharge in AC-PDPs (분위기 온도와 플라즈마 방전에 의한 AC-PDP의 형광막 열화 특성)

  • Kim, Hyun;Jang, Sang-Hun;Tae, Heung-Sik;Choi, Kyung-Cheol
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.9
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    • pp.443-448
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    • 2002
  • The degradation characteristics of R, G, B phosphor layers in AC-PDP, which is due to the discharge of plasma, are still unknown. For the successful commercialization of AC-PDP, the degradation of phosphor layers, caused by the plasma discharge must be investigated and improved. In this paper, the degradation properties of phosphor layers in AC-$PDP_S$ are investigated. It takes long time to investigate the degradation in real condition, so that the device for accelerating the degradation is devised. To prove the performance of the device, the visible emission characteristics of phosphor layers and discharge with the environmental temperature are examined. As a result, it is shown that the phosphor layers are easily degraded when the discharge is sustained under high environmental temperature condition. After accelerating the degradation of blue Phosphor layer((Ba,Eu)Mg$AI_10$$O_17$) for 48 hours, its luminance decreases about 38 % and the corresponding color purity deteriorates severely.

Improvement of Luminescence Degradation of Phosphor Screen by Surface Modification with $H_{3}PO_{4}$ Solution Treatment (인산 처리 공정에 의한 ZnS:Ag,Cl 형광막의 발광 열화특성의 개선)

  • Park, Zin-Min;Jeon, Duk-Young;Cha, Seung-Nam;Jin, Yong-Wan;Kim, Jong-Min
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.04b
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    • pp.49-52
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    • 2002
  • Degradation characteristics of cathodoluminescence (CL) of ZnS:Ag,Cl phosphor were investigated with measurements of CL and photoluminescence (PL). Phosphoric acid treatment was performed to phosphor particles in order to improve CL degradation of phosphor screen that occurred during panel sealing process, and we will discuss mechanisms of degradation and improvement of luminescence mainly with help of AES (auger electron spectroscopy) analysis.

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Thermal degradation properties of blue emitting phosphor particles prepared by the spray pyrolysis for PDP (분무열분해공정에서 제조된 PDP용 청색형광체의 열화특성)

  • Kang, Yun-Chan;Lee, Dong-Youl;Park, Hee-Dong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1060-1062
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    • 2002
  • Spherical and dense BAM phosphor particles were prepared by spray pyrolysis. The key idea of dense BAM particles is to lead gelation in droplets, which was successfully achieved by using the aluminum polycation as the precursor solution for the spray pyrolysis. The BAM phosphor particles prepared by spraying the aluminum polycation solution have completely spherical shape and dense structure. When directly applied to make phosphor film on the glass by the screen-printing method, the prepared spherical BAM phosphor particles showed better packing density and surface morphology than that of commercial one, which has irregular shape and large particle size. It was also found that the thermal degradation in the photoluminescence intensity for dense and spherical BAM particles was less than that of commercial one.

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The comparison and analysis on the phosphor degradation causes in ac PDP

  • Ha, Chang-Hoon;Jeong, Dong-Chul;Kim, Tae-Jun;Bae, Hyun-Sook;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.109-112
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    • 2003
  • In this paper, we investigated the phosphor degradation characteristics on the ultra violet ray (UV) irradiation as well as ion bombardment. We propose a novel experiment method which is related with phosphor degradation causes. The phosphor deterioration experiments were made on the UV irradiation as well as ion bombardment. To carry out the experiment and compare the results, we made up the specific experimental setup. The results show that the deterioration by ion damage is more rigorous than that by vacuum ultra violet (VUV) on the phosphor efficiency.

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Degradation of PDP Phosphors Under VUV Excitation (PDP 형광체의 진공 자외선 조사에 따른 열화 특성)

  • Lee, R.Y.;Lee, S.H.;KIm, Y.H.
    • Korean Journal of Materials Research
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    • v.12 no.9
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    • pp.735-739
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    • 2002
  • $(Y,Gd)BO_3$: Eu, $Zn_2$$SiO_4$ : Mn and $BaMgAl_{10}$ $O_{17}$ : Eu phosphors used in PDP were continuously irradiated by vacuum ultra violet generated from the penning gas (96%Ar+4%Xe) discharge and then the change of emitting intensity with time was investigated. The brightness of these phosphors decreased exponentially with VUV excitation time. The experimental data showed that the degradation rate increased in the order of $Zn_2$$SiO_4$ : Mn>(Y,Gd)$BO_3$: Eu>$BaMgAl_{10}$ $O_{17}$ : Eu phosphor. This different degradation property of phosphors was interpreted in terms of brightness saturation and stability against VUV irradiation. It was found that the degradation property of $(Y,Gd)BO_3$ : Eu red phosphor synthesized by ultrasonic thermal spray was superior to commercial phosphor.

The improvement of discharge characteristics and lifetime of PDP by MgO deposition on the phosphor

  • Ha, Chang-Hoon;Kim, Jae-Sung;Jeong, Dong-Cheol;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.232-235
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    • 2002
  • An alternate application of MgO film for the improvement of discharge characteristics and life time in an ac plasma display panel (PDP) is suggested. In this research, we deposited MgO on the phosphor to get the same address characteristics irrespective of each phosphor. To avoid the luminance and efficiency degradation by MgO deposition on the phosphor, we optimized the MgO thickness through experiments. The results showed that PDP with MgO coated phosphor has a uniform formative delay in address discharge and improved degradation characteristics.

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Reporting on the High Efficiency of Anode Phosphor Electrode for Filed Emission Lamp - Metal Layer (전계방출광원용 아노드 난반사 연구)

  • Yun, Han-Na;Kim, Yun-Il;Kim, Dae-Jun;Kim, Kwang-Bok
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2008.05a
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    • pp.29-32
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    • 2008
  • The electron charging and degradation of anode phosphor layers are showed major problems in high electric field with anode electrode of field emission devices. An AI metal layer on the phosphor layer may get rid of these problems. This Hetero-metal-oxide phosphor layer are formed with the roughness of phosphor surface layer without interlayer and cannot be given rise to enhance the luminance efficiency. In order to enhance the brightness, an anode layer need to be flated between phosphor layer and AI metal layer in anode electrode. After optimizing the anode phosphor layer, an anode layer with AI metal and inter layer increased the brightness and luminescence efficiency 1.2 times more than only phosphor laver in anode.

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Study on the High Efficiency of Anode Phosphor Electrode for Filed Emission Lamp (I) Metal Layer (전계방출광원용 고효율 에노드 형광막 특성 연구(I) - 금속막)

  • Lee, Sun-Hee;Kim, Kwang-Bok;Kim, Yong-Won;You, Yong-Chan
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2007.05a
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    • pp.7-10
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    • 2007
  • The electron charging and degradation of anode phosphor layers are showed major problems in high electric field with anode electrode of field emission devices. An Al metal layer on the phosphor layer may get rid of these problems. This Al metal layer are formed with the roughness of phosphor surface layer without interlayer and cannot be given rise to enhance the luminance efficiency. In order to enhance the brightness, an anode layer need to be flated between phosphor layer and Al metal layer in anode electrode. After optimizing the anode phosphor layer, an anode layer with Al metal and inter layer increased the brightness and luminescence efficiency 1.5 times more than only phosphor layer in anode.

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Study on the High Efficiency of Anode Phosphor Electrode for Filed Emission Lamp (II) - Diffused Reflection Layer (전계방출광원용 고효율 에노드 형광막 특성 연구(II) - 난반사막)

  • Lee, Sun-Hee;Kim, Kwang-Bok;Kim, Yong-Won;You, Yong-Chan;Kim, Do-Jin
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2007.05a
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    • pp.89-91
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    • 2007
  • In order to decrease the degradation of phosphor on anode, many kinds of methods try to do coating of phosphor powders and AI metal layer of anode phosphor, In case of direct coating of phosphor powder, thin and uniform coating process are difficult to cover homogeneous in the surface of phosphor powders and given rise to decrease the brightness, Anti-reflection-layer(ARC) with $TiO_2$, $Al_2O_3$, $Y_2O_3$ showed 103[%] the enhancement of brightness in comparable with normal phosphor layer.

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Preparation and Luminescent Properties of GdOBr:Ce Blue Phosphors for FED (FED용 GdOBr:Ce 청색 형광체의 제조 및 발광특성)

  • Lee, Jun;Park, Joung-Kyu;Han, Cheong-Hwa;Park, Hee-Dong;Yun, Sock-Sung
    • Journal of the Korean Ceramic Society
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    • v.39 no.3
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    • pp.240-244
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    • 2002
  • The GdOBr:Ce phosphor were prepared by solid state reaction using starting chemicals of $Gd_2O_3,\;CeO_2\;and\;NH_4Br$. Under 370nm UV excitation, GdOBr:Ce phosphors showed blue emission band with a spectral range of 410∼430nm. The maximum photoluminescence(PL) emission intensity was observed at 2mol% Ce content. In order to look for feasibility of application for low voltage filed emission display, cathodoluminescence(CL) of GdOBr:Ce phosphors were measured. CL emission spectra was found to be in the range of 410∼430nm, which is the same as PL spectra. The phosphors with 1mol% Ce concentration showed the maximum CL emission intensity. For the comparison of degradation property of the prepared phosphors with commercial ones, the electron beam was applied for 10min. From the result, GdOBr:Ce could be used as a blue phosphor for FED.