• The Korean Journal of Pesticide Science
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• v.4 no.3
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• pp.75-81
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• 2000

These studies were carried out to investigate the toxicities of 38 registered insecticides to the sweetpotato whitefly (Trialeurodes vaporariorum). Insecticide activities were evaluated by testing systemic action and residual effect in the laboratory, and control efficacy in the greenhouse. All experiments were tested at the recommended concentration(ppm) of each insecticides. Insect growth regulators (IGRs), only pyriproxyfen showed over 90% of ovicidal effect. The insecticides that showed over 90% of larvicidal activity oil 3rd nymphal instars were abamectin, acetamiprid, chlorpyrifos-methyl, imidacloprid, pyripoxyfen, and acetamiprid+ethofenprox. Insecticides with 100% adulticidal activity were abamectin, acephate, acetamiprid, benfurcarb, bifenthrin, furathiocarb, endosulfan, fenitrothion, imidacloprid, phenthoate, pymetrozine, acetamiprid + ethofenprox, ethofenprox + diazinon, furathiocarb + difluberlzuron, and triazamate+${\alpha}$-cypermethrin. Abamectin, acetamiprid, imidacloprid, pyriproxyfen, and acetamiprid + ethofenpox showed both residual effect and systemic activity. In tile control efficacy test on B. tabaci, 90% control values were obtained at 11th day after treatment of the insecticides including abamectin, acetamiprid, imidacloprid, pyripoxyfen and acetamiprid + ethofenprox. These results indicate that abamectin, acetamiprid, imidacloprid, pyriproxyfen and acetamiprid + ethofenprox can be used for tile control of B. tabaci in field.

• Journal of Radiation Industry
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• v.3 no.1
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• pp.19-24
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• 2009

The citrus fruits were irradiated at different doses (25~200 kGy) to remove pesticides such as diuron, dichlorbenil, trifluralin, dimetoate, chlorothalonil, fenitrothion, bromacil, phenthoate and norflurazon, and the rates of degradation were detected by using gas chromatography electron capture detector (GC-ECD). The limit of detection (LOD) was in the range of 0.007~0.105 ppm. The limit of quantification (LOQ) was in the range of 0.024~0.352 ppm, and the recoveries of 9 pesticides were in the range of 71.5~106.5%. The results demonstrated that the ${\gamma}$-irradiation was effective method to remove pesticides such as diuron, dichlorbenil, trifluralin, dimetoate, chlorothalonil, fenitrothion, and norflurazon. However, the bromacil and phenthoate showed lower removal rates in the rate of 40.5 and 54.8%, respectively, at 200 kGy irradiation.

• The Korean Journal of Pesticide Science
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• v.7 no.4
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• pp.288-295
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• 2003

To determine the mechanism of the resistance to organophosphorus insecticide, chlorpyrifos, in diamondback-moth (Plutella xylostella L.), activities of esterases, glutathione-S-transferase (GST) and AChE insensitivity which were known for causing factor of resistance were measured. Also, the relationship between AChE insensitivity and the resistant ratio was investigated to inquiry the cross-resistance. The resistant ratio of chlorpyrifos-resistant strain (CRS) of diamondback-moth at the 6th generation was developed 160 fold compared to susceptible strain (SS) one. Activity of GST that are extracted from CRS was 1.7-fold higher than that from SS. However, activity of total esterases from CRS was similar to that from SS. In AChE insensitivity test, CRS was 11.8-fold less sensitive than that from SS. CRS was ranged from 17.6 to 33.6-fold less sensitive than SS to other insecticides having same target site with chlorpyrifos such as dichlorvos, dimethylvinphos and carbofuran. Insensitivity of AChE to phenthoate-oxon, however, was 1.7-fold. Resistance of CRS was 82-fold, 47-fold and 42-fold higher than SS to dichlorvos, dimethylvinphos and carbofuran, respectively, but 2.3-fold to phenthoate and then we could identify that the resistance development of insecticide might have a lot of difference among the chemicals with the same target site. The relationship between the AChE insensitivity and the resistant ratio was significantly correlated$(r=0.9951^{**},\;p^{(0.01)}$. This result indicates that AChE insensitivity was associated with insecticide resistance. Overall, these results suggest that insensitivity of AChE was an important factors to chlorpyrifos resistance in diamondback-moth, and the slightly increased activity of GST may also have contributed to that.

• Journal of Food Hygiene and Safety
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• v.14 no.1
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• pp.9-16
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• 1999

Effect of storage temperature, washing, and cooking on postharvest-treated pesticide residues in polished rice was investigated. After being treated with each 500 mg/kg of captan, carbaryl, phenthoate, fenthion, fenitrothion, chlorpyriphos-methyl, pirimiphos-methyl, the polished rice was stored for 8 weeks at 4 and 3$0^{\circ}C$, respectively. The penetation rate of carbaryl was the highest as 27.5% and the others, 13 to 18%. The half lives of pesticide residues were estimated as 30 to 230 weeks at 4$^{\circ}C$, but 1 to 12 weeks at 3$0^{\circ}C$. The residues were reduced faster at 3$0^{\circ}C$ than at 4$^{\circ}C$. The half lives of pesticide residues by water washing were estimated as 0.7 to 4.6 trials and the removed with the washing trials. The residues of captan and carbaryl in cooked rice were removed 100 and 98%, respectively, comparing to initial residues concentration in treated rice but those of other 5 pesticides were removed 80%.

• Bulletin of the Korean Chemical Society
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• v.19 no.1
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• pp.45-50
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• 1998

Most organophosphorus pesticides may be metabolized to yield some common phosphates in human or in animals, and these metabolites may be used as the exposure biomarkers to pesticides. In this study, we developed the extraction method of four phosphate metabolites from the spiked human urine in high recovery by the solid phase extraction with a reverse-phase cartridge (cyclohexyl silica) followed by the elution with methanol. The extracted urinary metabolites were derivatized with hexamethyldisilazane/trimethyl-chlorosilane/pyridine (2 : 1 : 10, v/v/v) and identified by gas chromatography/mass spectrometry. Calibration curve obtained from each metabolite standard using by GC/MS/SIM has shown good linearity and detection limits of metabolites were the range of 0.05-0.1 ㎍/㎖ in urine. Phenthoate, one of the organophosphorus pesticides, was orally administrated to rats. Four metabolites were detected in the rat urine. The results of this study may be applied to development of exposure biomarkers for monitoring of environmental pollutants.

• Journal of Sericultural and Entomological Science
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• v.37 no.1
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• pp.74-85
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• 1995

A study was conducted to provide some basic data for controlling the Mulberry scale insect(Pseudaulacaspis pentagona T.). Experiments were carried out with checking their field-life, and a few selected insecticides were tested when mulberry leaves were not in use. About 57% of female were survived from the overwintering attached to the bark. Over 80% of the scale were distributed within the range of 30cm from the base of each stem. One hundred percent and 96.7% of eggs were hatched under 25$^{\circ}C$ and 27$^{\circ}C$ respectively. Eighty percent of pupae emerged both under 25 and 27$^{\circ}C$. The Mulberry scale require about 33 days under 25$^{\circ}C$ and 30 days under 27$^{\circ}C$. This species had 2 generations each year in mulberry field in Suwon. Overwintered as a mated female only. Oviposited about 170 eggs under their scale starting from the late April (in 1994) through the mid May (in 1993). Phenthoate EC sprayed in the mid June against the larvae was very effect with over 96% of control value.

• The Korean Journal of Pesticide Science
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• v.8 no.1
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• pp.71-78
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• 2004

A promising hyperparasite, Ampelomyces quisqualis 94013(AQ94013) was selected as a biological control agent to cucumber powdery mildew caused by Sphaerotheca fusca. Effect of agrochemicals on mycelium growth and spore germination of AQ94013 and effect of spread stickers on hyperparasitical activity of AQ94013 to powdery mildew pathogen were evaluated. Finally it was confirmed that mycelial growth and spore germination of AQ94013 on potato dextrose agar amended with two fungicides for controlling powdery mildew, triadimefon and pyrazophos; five fungicides for controlling downy mildew, dimethomorph, kasugamycin+copper oxychloride, dichlofluanid+copper oxychloride and tribasic copper sulfate; three fungicides for controlling gray mold, iprodione, vinclozolin and procymidone; and six insecticides immidacloprid, teflubenzuron, bifenthrin, ethofenprox, deltamethrin and phenthoate were slightly reduced. Addition of mineral oil in the spore suspension of AQ94013 enhanced 7.9% control value to cucumber powdery mildew.

• Proceedings of the KOR-KST Conference
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• 1996.02a
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• pp.29-58
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• 1996

현재 서울은 교통사고문제, 교통혼잡문제와 자동차로부터 배출되는 유해가스에 의한 대기환경오염문제를 갖고 있다. 본 논문의 목적은 대기환경오염을 악화시키는 자동차의 주된 배출오염가스인 일산화탄소, 탄화수소 및 질소화합물량을 교차로 교통량을 중심으로 어떻게 계산하는가에 있다. 연구의 대상지역은 서울시의 송파구 교차로들과 도심지역의 링크들을 선택하였다. 그리고 교통량, 지체시간, 링크길이, 정지회수, 운행속도, 주행속도 등을 고려하여, 제작차 배출가스 허용기준, 총량기준, 불량차 기준, 속도기준 등에 의한 계수산정 및 TRAF-NETSIM에 의한 시뮬레이션을 통하여 일정 도로상의 제한된 범위내의 배출량 산출을 시도하였다. 본 연구의 결과에 의하면 첫째, 어느 방법이든 실제배출량의 정확한 값을 표현 할 수는 없는 것이고, 단지 상대적인 비교에 의하면 배출가스량의 수준을 추정 할 수 있었다. 또한, 시뮬레이션 배출율표를 우리 현실에 맞는 자료에 의해 수정할 수 있다면, 그 결과는 실제량에 보다 근접할 수 있을 것이다. 둘째, 서울도로의 현재 혼잡상태에서 속도의 저감에 배출량이 민감한 반응을 보이고 있다는 사실이다. 셋째, 교통량변화에 따른 배출량의 변화가 일산화탄소에서 가장 심하게 나타남을 알 수 있었고, 신호운영상의 옵셋값이 잘못 설정되면 탄화수소는 35%, 일산화탄소는 40%, 질소산화물은 75%까지 초과발생할 수 있으며, 유해배출가스량을 최소화시키는 측면에서의 신호최적화를 위해서는 현재의 Stop Penalty는 상향 조정되어야 함이 밝혀졌다. 앞으로는 자동차로 인한 대기환경오염 농도의 저감을 위해서는 도로별 자동차 유해가스 배출 총량규제 방안도 고려해 볼 가치가 있으며, 이를 위해 환경공학과 교통공학의 다학제적 공동연구가 지속적으로 필요하며 교통정책에 반영되어야 할 것이다.분석, 리용수 학모형대이십일세기상해항공운량진행예측, 제출발전상해항공운수적전 략목표급발전중점. 예측2020년 상해항공항총객운탄토량4300만인/년, 화운량달120만돈; 2050년객운량장달18150만인차/년, 화운량518만돈. 사, 발전상해민항기출경제정책, 제출위료$\ll$진흥상해, 개발포동, 복무전국, 면향세계$\gg$ 화도이십일세기중기국민경제달도중등발달국가수 평굉관전략목표적실현, 제료필수재지도사상상파교통운수진정방도전략 산업지위, 환응재관리체제상채취과단유효적개혁조시, 재기출경제정책 상급여대력부지. 오, 전략목표, 위파상해건설성위태평양서안최대적경제, 김융, 무역적중심, 요구상해항공항성위화동지구통향세계각지항선망출발참, 구성대외개방선면축심, 실현국제항선적함접화국내항반적전항, 형성다축심복사식항선망; 가강기장건설, 개피포동제이국제기장건설, 괄응포동개발경제발전적수요. 부화개시일은 각 5월 26일과 5월 22일이었다. 11. 6월 중순에 애벌레를 대상으로 처리한 Phenthoate EC가 96.38%의 방제가로 약효가 가장 우수하였고 3월중순 및 4월중순 월동후 암컷을 대상으로 처리한 Machine oil, Phenthoate EC 및 Trichlorfon WP는 비교적 약효가 낮았다.>$^{\circ}$E/$\leq$30$^{\circ}$NW 단열군이 연구지역 내에서 지하수 유동성이 가장 높은 단열군으로 추정된다. 이러한 사실은 3개 시추공을 대상으로 실시한 시추공 내 물리검층과 정압주입시험에서도 확인된다.. It was resulted from increase of weight of single cocoon. "Manta"2.5ppm produced 22.2kg of cocoon. It is equal to 9% increase i

• The Korean Journal of Pesticide Science
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• v.4 no.1
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• pp.1-10
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• 2000

The purpose of this study is to establish the assessment techniques of hazardous chemicals by the development of analytical method of biological samples. In this study, we have developed an extraction method of nine pesticides used for rice paddy that resulted in high recovery from the spiked human urine by the liquid-liquid extraction with diethyl ether at pH 7.0. Calibration curve obtained from each pesticide standard using by gas chromatography/mass spectrometry/selected ion monitoring has shown good linearity and detection limits were the range of $0.4{\sim}2.0$ ng/mL in urine. As a biological monitoring, urine samples of local farmers exposed directly to nine pesticides in the field were collected and analyzed by GC/MS. Of the tested pesticides, metabolites of phenthoate assumed were identified by GC/MS analysis. No parent compound was detected.

• The Korean Journal of Pesticide Science
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• v.13 no.1
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• pp.28-38
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• 2009

An extrapolation of residue data of seven commonly used pesticides namely bifenthrin, chlorothalonil, cypermethrin, diazinon, fenvalerate, phenthoate and procymidone on a total of 22 minor crops has been carried out in an experimental field trial. The pesticides were applied to 11 leafy-, 5 root- and 6 stem-crops grown in the experimental green-house and the crops and plants were randomly collected at 1, 3, 5, 7 days after application. The average recoveries of applied pesticides were ranged from 72.0 to 117.0% in leafy crops, from 81.3 to 105.0% in stem crops and from 70.1 to 108.1% in the root-crops. Limits of detection (LODs) were 0.005-0.1 mg/kg in the leafy crops and 0.001-0.005 mg/kg in both the stem & root crops. Based on the results of residual dissipation pattern and their morphology, all crops were classified into high and low residual groups. The results showed that it might be possible to extrapolate residual data of stem-crops to root-crops within the same group. Crops that have currently no registered pesticide for use, would be possible to use the pesticides which are already been registered for the similar crops.