• Journal of Energy Engineering
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• v.5 no.2
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• pp.115-122
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• 1996

Heat transfer characteristics of low temperature latent heat storage systems have been examined for the circular finned and unfinned tubes using Na$_2$B$_4$O$\_$7/10H$_2$O as a phase change material. In order to reduce the supercooling of PCM, 3 wt% of Na$_2$B$_4$O$\_$7/10H$_2$O was added as the nucleating agent and 2.2 wt% of acrylic acid sodium sulfate was used as the thickener. The heat storage vessel has dimension of 530 mm height, 74 mm 1.D. and inner heat transfer tube is 480 mm height and 13.5 mm O.D. Water was employed as the heat transfer fluid. During the heat recovery experiment, the heat recovery rate was affected by the flow rates and inlet temperature of heat transfer fluid. The enhancement of heat transfer by fins over the unfinned tube system was found to be negligible in the thin finned tube systems, whereas the heat transfer coefficient in the thick finned tube system is approximately 60% higher than that in the unfinned lobe system. The experimentally determined heat transfer coefficient for the unfinned tube and thick finned tube systems are 150-260 W/㎡$^{\circ}C$ and 230-530 W/㎡$^{\circ}C$, respectively. The fin efficiency based on the heat transfer coefficient and area increased by fins was found to be 0.05 and 0.26 for the thin and the thick finned tube systems.

• Solar Energy
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• v.10 no.2
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• pp.28-37
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• 1990

A study was conducted to investigate the feasibility of using a super-absorbent polymer made from a acrylic acid copolymer for a capsule-type ice storage system. In a simple pyrex-tube test, 25% of distilled water samples tested turned out not be frozen at all at $-12^{\circ}C$ and the average supercooling of the samples frozen was $9.8^{\circ}C$. With the addition of 0.5wt% super-absorbent polymer, however, the supercooling of the distilled water was dramatically reduced and more than 35% of samples tested did not show any supercooling. The heat transfer characteristics of a capsule-type ice storage unit was also investigated with a distilled water as the phase-change material. With the addition of 0.5wt% polymer, the supercooling of water was not observed at all and thus an overall heat transfer was enhanced. Based on these results, it was concluded that a super-absorbent polymer is a potential candidate as the nucleating agent for an ice-storage system.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.4
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• pp.572-582
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• 2001

A method of metal-hydride thermal conversion that is an alternative to the traditional method is proposed and investigated. The unit heat pump consists of reactors of two different metal-hydrides are distributed inside parallel channels filled with porous media. The channels are blown through with a heat-transfer agent. Thermal conversion develops as a set of successive heat waves. By a numerical-modeling method it is shown that the maximum thermal effect is attained in synchronous motion of the heat wave and the heat source (or sink) that accompanies the phase transition in the succession of unit metal-hydride pumps. The results are presented in a form convenient for prediction of the thermal and energy efficiency of the proposed thermal-conversion method in real devices.

• Bulletin of the Korean Chemical Society
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• v.13 no.3
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• pp.265-268
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• 1992

Ruthenium(III) unsymmetrical Schiff base complexes, $[Ru(CHBPH-TP)Cl_2]$ and $K[Ru(CHBPH-HB)Cl_2]$ were synthesized, where CHBPH-TP and CHBPH-HB are 5-chloro-2-hydroxybenzophenonethiophencarba aldehydephenylenediimine and 5-chloro-2-hydroxybenzophenonehydroxybenzophe nonephenylenediimine. These Schiff bases were obtained from the reactions of 5-chloro-2-hydroxybenzophenone (CHB) and 2-thiophenecarbaldehyde (TP) or hyroxybenzophenone (HB) and 1,2-diaminobenzene. Elemental analysis, conductivity and infrared studies of the complexes suggest an octahedral geometry around ruthenium. Magnetic moments of the complexes indicate a single unpaired electron in alow spin $d^5$ configuration. The complexes are capable of catalyzing the oxidation of styrene with sodium hypochlorite in the presence of phase transfer agent. Oxidative cleavage of C=C bond is the major reaction pathway to form benzaldehyde for styrene oxidation.

• Transactions of the Korean Society of Automotive Engineers
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• v.20 no.4
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• pp.125-132
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• 2012

Urea-SCR system, which converts nitrogen oxides to nitrogen and water in the presence of a reducing agent, usually AdBlue urea solution, is known as one of the powerful NOx reduction systems for mobile as well as stationary applications. For its consistent and reliable operation in mobile applications, such various problems as transient injection, ammonia slip, and freezing in cold weather have to be resolved. In this work, therefore, numerical study on three-dimensional unsteady heating problems were analyzed to understand the melting and heat transfer characteristics such as urea liquid volume fraction, temperature profiles and generated natural convection behavior in urea solution by using the commercial software Fluent 6.3. After validating by comparing numerical and experimental data with pure gallium melting phenomena, numerical experiment for urea melting is conducted with three different coolant heating models named CH1, 2, and 3, respectively. Finally, it can be found that the CH3 model, in which more coolant is concentrated on the lower part of the urea tank, has relatively better melting capability than others in terms of urea quantity of $1{\ell}$ for start-up schedule.

• Journal of Embryo Transfer
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• v.4 no.1
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• pp.1-13
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• 1989

This paper reviews the most important steps that have generated consistent progress in principles and developmental progress of embryo cryopreservation, and also study on freezing procedure and its application by conventional method and current improved method for freezing procedure and its appilcation of embryo cryopreservation in farm animals. Four were of particular interest: 1.The transport of water across the ccli membrane (zona pellucida) during freezing and thawing accordinglyplays a role in determing whether the celi survives. This movement of water is controlied mainly by extracellular phase changes and by the nature and concentration of any cryoprotective agent present. Therates of cooling, freezing and warming, and the intervals over which they are applied are further decisi've factors in determining whether a cryopreservation procedure allows survival after thawing. 2.The first successful deep freezing experiments with sheep morula and blastocysts during the seventies were based on the early procedures used for mouse embryos.Current research during the eighties is developed with the aim of simplifying and improving current procedures such as one-step dilution and rapid or ultra-rapid cooling by using the model of laboratory animals. 3.The conventional method for the embryo cryopreservation is described. An alternative to this method which may result in high survival and also in reducing of the freezing and thawing time is done by combing a permeable cryoprotectant such as glycerol, DMSO or propanediol and a non-permeable compound such as sucrose, trehalose, raffinose or lactose. 4.Finally a different approach to the preservation of embryos, named vitrification, is introduced. This procedure depends upon the ability of concentrated solutions of cryoprotective agents such as glycerol and propanediol to supercool to very low temperature (-196$^{\circ}C$) during rapid cooling before solidifying without formation of ice. However, more complete data are necessary for successful vitrification of blastocysts.

• Macromolecular Research
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• v.14 no.1
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• pp.87-93
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• 2006

Copolymers composed of hyaluronic acid (HA) and poly(N-isopropylacrylamide) (PNIPAAm) were prepared to create temperature-sensitive injectable gels for use in controlled drug delivery applications. Semi-telechelic PNIPAAm, with amino groups at the end of each main chain, was synthesized by radical polymerization using 2-aminoethanethiol hydrochloride (AESH) as the chain transfer agent, and was then grafted onto the carboxyl groups of HA using carbodiimide chemistry. The result of the thermo-optical analysis revealed that the phase transition of the PNIPAAm-grafted HA solution occurred at around 30$\∼$33$^{circ}C$. As the graft yield of PNIPAAm onto the HA backbone increased, the HA-g-PNIPAAm copolymer solution exhibited sharper phase transition. The short chain PNIPAAm-grafted HA ($M_{w}$=6,100) showed a narrower temperature range for optical turbidity changes than the long chain PNIPAAm-grafted HA ($M_{w}$=13,100). PNIPAAm-grafted HA exhibited an increase in viscosity above 35$^{circ}C$, thus allowing the gels to maintain their shape for 24 h after in vivo administration. From the in vitro riboflavin release study, the HA-g-PNIPAAm gel showed a more sustained release behavior when the grafting yield of PNIPAAm onto the HA backbone was increased. In addition, BSA released from the PNIPAAm-g-HA gels showed a maximum concentration in the blood 12 h after being injected into the dorsal surface of a rabbit, followed by a sustained release profile after 60 h.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.1
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• pp.1-7
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• 2016

A Urea-SCR(Selective Catalytic Reactor) system, which converts nitrogen oxides into nitrogen and water in the presence of a reducing agent, creates a major exhaust gas aftertreatment system for NOx reduction among other compounds. With regard to vehicle applications, a urea solution was chosen based on its eutectic composition of a 32.5wt% urea-water solution. An important advantage of this eutectic composition is that its melting point of $-11.7^{\circ}C$ is sufficiently low to avoid solidification in cold environments. However, the storage tanks must be heated separately in case of low ambient temperature levels to ensure a sufficient amount of liquid is available during scheduled start ups. In this study, therefore, a numerical investigation of three-dimensional unsteady heating problems analyzed to understand the melting processes and heat transfer characteristics including liquid volume fraction, temperature distributions, and temperature profiles. The investigations were performed using Fluent 6.3 commercial software that modeled coolant and electric heater models based on a urea solution. It is shown that the melting performance with the electric heater is higher than a coolant heater and is more efficient.

• Applied Chemistry for Engineering
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• v.35 no.1
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• pp.1-7
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• 2024

Mn-M/Al₂O₃ (M = Cu, Fe, Co, and Ce) catalysts were prepared for simultaneous oxidation of NO, CO, and CH₄, and their oxidation activities were compared. The Mn-Cu/ Al₂O₃ catalyst with the best simultaneous oxidation activity was characterized by XRD, Raman, XPS, and O₂-TPD analysis. The result of XRD indicated that Mn and Cu existed as complex oxides in the Mn-Cu/Al₂O₃ catalyst. Raman and XPS results showed that electron transfer between Mn ions and Cu ions occurred during the formation of the Mn-O-Cu bond in the Mn-Cu/Al₂O₃ catalyst. The XPS O 1s and O₂-TPD analyses showed that the Mn-Cu/Al₂O₃ catalyst has more adsorbed oxygen species with high mobility than the Mn/Al₂O₃ catalyst. The high simultaneous oxidation activity of the Mn-Cu/Al₂O₃ catalyst is attributed to these results. Gas-phase NO promotes the oxidation reactions of CO and CH₄ in the Mn-Cu/Al₂O₃ catalyst while suppressing the NO oxidation reaction. These results were presumed to be because the oxidized NO was used as an oxidizing agent for CO and CH₄. On the other hand, the oxidation reactions of CO and CH₄ competed on the Mn-Cu/Al₂O₃ catalyst, but the effect was not noticeable because the catalyst activation temperature was different.