• Title/Summary/Keyword: Phase potential

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Synergistic Effect of Reductase and Keratinase for Facile Synthesis of Protein-Coated Gold Nanoparticles

  • Gupta, Sonali;Singh, Surinder P.;Singh, Rajni
    • Journal of Microbiology and Biotechnology
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    • v.25 no.5
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    • pp.612-619
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    • 2015
  • We have synthesized gold nanoparticles (GNPs) using chicken feathers (poultry waste) and Bacillus subtilis RSE163. Disulfide reductase and keratinase produced by Bacillus subtilis during the degradation of chicken feather has been used to reduce Au3+ from HAuCl4 precursor to produce gold nanoparticles. The synthesized biogenic GNPs were characterized by UV-visible spectroscopy, transmission electron microscopy (TEM), and zeta potential measurements. Fourier transform infrared (FTIR) spectroscopy indicated the presence of protein capping on synthesized GNPs, imparting multifunctionality to the GNP surface. Furthermore, the nontoxic nature of biogenic GNPs was insured by interaction with Escherichia coli (ATCC11103), where TEM images and enhancement of growth rate of E. coli in log phase signified their nontoxic nature. The results indicate that the synthesis of biocompatible GNPs using poultry waste may find potential applications in drug delivery and sensing.

Electrical Properties of Pr-doped ZnO Varistors (Pr-첨가 ZnO 바리스터의 전기적 특성)

  • 곽민환;이상기;조성걸
    • Journal of the Korean Ceramic Society
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    • v.34 no.12
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    • pp.1275-1281
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    • 1997
  • ZnO varistors containing 5.0 at% Co3O4 and Pr6O11, ranging from 0.1 to 1.0 at%, were sintered at 130$0^{\circ}C$ and 135$0^{\circ}C$. The I-V characteristics and nonlinear coefficients of the specimens were investigated with respect to Pr addition and sintering temperature. In general the specimens sintered at 130$0^{\circ}C$ showed better varistor characteristic than those fired at 135$0^{\circ}C$, which seemed to be related with the liquid phase formation during sintering. The barrier heights obtained from C-V relations, 0.29-1.36 eV, were different from those acquired using resistivity-temperature plots measured at low voltage per grain boundary. Therefore the estimation of potential barrier heights using C-V relations is better suited for the specimens prepared in this study. The carrier densities obtained using C-V relations were ~1018 cm-3.

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Removal of Se(IV) by the Fe(III)-impregnated Sea sand - Zeta potential approach to depict the binding between Fe(III) and Sea sand (표면 처리한 Sea sand를 이용한 Se(IV) 제거 - Zeta potential을 통한 Fe(III)간의 반은 메카니즘 연구)

  • 박상원;강혜정
    • Journal of Environmental Science International
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    • v.8 no.2
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    • pp.205-209
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    • 1999
  • Iron hydroxides are good adsorbents for uncomplexed metals, some metal-ligand complexes and many metal oxyanions. However, their adsorption properties of these precipitations are not fully exploited in wastewater treatment operations because of difficulties associated with their separation from the aqueous phase. This study describes experiments in which iron hydroxides were coated onto the surface of ordinary adsorbents(Sea sand) that are very resistant to acids, The coated adsorbents were used in adsorption of oxyanionic metals. The process was successful in removing some anions such as $SeO_3(-II)$ over a wide range of metal concentrations and sorption of oxyanionic metals increased with decreasing pH. Formation of two surface complexes for oxyanionic metals adsorption on iron hydroxides comprise (1) complexation of the free anion by a positively charged surface site, and (2) protonation of the adsorbed anion (or alternatively adsorption of a protonated form from solution) The coated adsorbents are inexpensive to prepare and could serve as the basis of a useful oxyanionic metal removal.

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Status and Outlook of World Geothermal Energy Utilization (세계 지열에너지 활용 현황 및 전망)

  • Song, Yoon-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.669-673
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    • 2005
  • World geothermal resources potential is estimated to supply 189 EJ annually, which can take charge approximately a half of annual world energy consumpt ion, from considering identified resources and supplies in USA and Iceland. Present annual use of geothermal energy, on the other hand, is only $0.1\%$ of its potential, but still has $70\%$ share among total new renewables. World-wide installed capacity of geothermal power generation reaches 8,900 MWe and 27,825 MWt for direct uses in 2005 which is almost two-fold increase over 2000. This increase is mainly due to exploding expansion of geothermal heat pump utilization: USA and western European countries lead these trends. Although geothermal heat pump distribution in Korea is still in its starting phase, comparing to Swiss achievement in terms of areal utilization sense, we expect to come up with national supply of over 600,000 toe in near future.

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Study on the Adsorption Behavior of FeS in Anaerobic Conditions (혐기성 조건에서 FeS의 흡착 거동 연구)

  • 김정배
    • Journal of Environmental Science International
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    • v.6 no.5
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    • pp.505-512
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    • 1997
  • The Interfacial characteristics between various heavy metals and hydrous FeS were investigated. Heavy metals which have lower sulfide solubilities than FeS undergoes the lecttice exchange reaction when these metal tons contact FeS In the aqueous phase. For heavy metals which have higher suede solubilities than FeS, these metal ions adsorb on the surface of FeS. Such characteristic reactions were interpreted by the soled solution formation theory. The presence of ligand such as EDTA reduced largely metal removal efficiency due to formation of metal-ligand complex In the solution. In an attempt to elucidate the Interfacial characteristics, zeta potential of the hydrous FeS In the absence and In the presence of various metal loons were measured and analyzed.

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Use of Plant Leaf in Biosensing for Some Odour Compounds

  • Matsuoka, Hideaki
    • Korean Journal of Pharmacognosy
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    • v.20 no.4
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    • pp.205-214
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    • 1989
  • The sensing of odour compounds in gas phase is an attractive target in recent sensor technology. Based on the finding that a plant leaf can respond to various gas molecules by changing its potential, biosensing system using a plant leaf has been investigated for the detection of odour compounds. A leaf of some plant species responded to odour compounds directly by changing its potential $5{\sim}10\;mV$. That the leaf was actually sensing an odour was much more remarkably detected from the difference between the response profile to pure $CO_2$ gas and that to $CO_2$ gas containing odour compounds. Then the quantitative study (ppb level) is now being performed on the response of a tobacco leaf to benzyl acetate; a component of jasminelike odours. The concept of biosensing and its significance are also described from the viewpoint of sensor technology.

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A Study on the Surface Degradation Properties of Epoxy / Glass fiber Treated with Ultraviolet Rays (자외선 처리된 Epoxy/Glass Fiber의 표면 열화 특성에 관한 연구)

  • Lee, Baek-Su;Lee, Deok-Chul
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.2
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    • pp.86-91
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    • 1999
  • In order to analyse the degradation process of epoxy/glass fiber for outdoor condition, FRP laminate was exposed to the wavelength of ultraviolet rays and evaluated by comparing contact angle, surface resistivity, surface potential decay, and ESCA spectrum respectively. As irradiation energy are increased, the surface properties were steeply decreased in the range of 300[nm]. But the measured values within the scope of400[nm]∼440[nm] showed a increase as compared with the untreated ones. Also, fromthe result of ESCA spectrum, it was confirmed plenty of oxygen groups on the spot showing the maximum decrease of surface properties and the existence of ether groups on the surface of coloring phase. We can conclude that the degradation phenomena on the surface of epoxy composites are dominated by the induction of ester and carboxyl groups.

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Molecular Dynamics Study on Atomistic Details of the Melting of Solid Argon

  • Han, Joo-Hwan
    • Journal of the Korean Ceramic Society
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    • v.44 no.8
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    • pp.412-418
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    • 2007
  • The atomic scale details of the melting of solid argon were monitored with the aid of molecular dynamics simulations. The potential energy distribution is substantially disturbed by an increase in the interatomic distance and the random of set distance from the lattice points, with increasing temperature. The potential energy barriers between the lattice points decrease in magnitude with the temperature. Eventually, at the melting point, these barriers can be overcome by atoms that are excited with the entropy gain acquired when the atoms obtain rotational freedom in their atomic motion, and the rotational freedom leads to the collapse of the crystal structure. Furthermore, it was found that the surface of crystals plays an important role in the melting process: the surface eliminates the barrier for the nucleation of the liquid phase and facilitates the melting process. Moreover, the atomic structure of the surface varies with increasing temperature, first via surface roughening and then, before the bulk melts, via surface melting.

Potential Induction of Quinone Reductase Activity of Natural Products in Cultured Murine Hepa1c1c7 Cells

  • Heo, Yeon-Hoi;Lee, Sang-Kook
    • Natural Product Sciences
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    • v.7 no.2
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    • pp.38-44
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    • 2001
  • NAD(P)H:quinone reductase (QR), known as DT-diaphorase, is a kind of detoxifying phase II metabolic enzyme catalyzing hydroquinone formation by two electron reduction pathway from quinone type compounds, and thus facilitating excretion of quinoids from human body. With the usefulness of QR induction activity assay system for the modulation of toxicants, in the course of searching for cancer chemopreventive agents from natural products, the methanolic extracts of approximately two hundreds of oriental medicines were primarily evaluated using the induction potential of quinone reductase (QR) activity in cultured murine Hepa1c1c7 cells. As a result, several extracts including Hordeum vulgare, Momordica cochinchinensis, Strychnos ignatii, Houttuynia cordata, and Polygala japonica were found to significantly induce QR activity. In addition, the methylene chloride fraction of H. vulgare, one major dietary food source, showed potent induction of QR activity $(CD=6.4{\mu}g/ml)$. Further study for isolation of active principles from these lead extracts is warranted for the discovery of novel cancer chemopreventive agents.

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Friction Stir Welding of Aluminium alloys and Its Application (알루미늄합금의 마찰교반접합 및 그 적용)

  • 연윤모;정승부;박종목
    • Proceedings of the KSR Conference
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    • 2000.11a
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    • pp.226-234
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    • 2000
  • The friction stir welding technique is a derivative of conventional friction welding, which enables the advantages of solid-phase welding to be applied to the fabrication of long butt and lap joints, with very little postweld distortion. Friction stir welding is a remarkable new welding technique for joining aluminum alloys and has the potential for welding other ferrous materials. It has already been developed beyond a laboratory curiosity and has been proved as a potential practical welding technique offering low-distortion, high-quality, low-cost welds from simple concept machine tool welding equipment. To bring this remarkable method of welding aluminum alloys to the attention of Industry, this article introduces the basic principle of friction stir welding, pointing out the practical advantages and most important of all, describes the exceptionally good metallurgical and mechanical properties.

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