• Title/Summary/Keyword: Phase potential

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Stability analysis of gas-liquid interface using viscous potential flow (점성포텐셜유동을 이용한 이상유동장의 표면안정성 해석)

  • Kim, Hyung-Jun;Kwon, Se-Jin
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3033-3038
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    • 2007
  • In this research, Rayleigh instability of gas-liquid flow in annular pipe is studied in film boiling using viscous potential flow. Viscous potential flow is a kind of approximation of gas-liquid interface considering velocity field as potential including viscosity. A dispersion relation is obtained including the effect of heat and mass transfer and viscosity. New expression for dispersion relation in film boiling and critical wave number is obtained. Viscosity and heat and mass transfer have a stabilizing effect on instability and its effect appears in maximum growth rate and critical wave number. And the existence of marginal stability region is shown.

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Early Hydration of Tricalcium Silicate(III) (Tricalcium Silicate의 초기수화반응(III))

  • 오희갑;최상흘
    • Journal of the Korean Ceramic Society
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    • v.24 no.4
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    • pp.385-391
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    • 1987
  • Zeta potential according to the hydration time was studied during the early hydration of C3S with and without CO2 atmosphere. Zeta potential was low as a level of 20mV at the first and second exothermic peaks of heat evolution, but it was rapidly increased up to a level of 300mV. In the CO2 atmosphere, zeta potential was level of 60mV at 10 minutes hydration and it's value became a low gradually according to the hydration time. Zeta potential was also proportioned to the Ca2+ concentration in the liquid phase, i.e., there was positive correlation between zeta potential and Ca2+ concentration. The existence of silicate layer was not found out on the hydrated C3S in the CO2 atmosphere by SEM-EDAX.

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A Functional Representation of the Potential Energy Surface of Non-Identical $S_N2$ Reaction: F- … $CH_3Cl \rightarrow FCH_3$ … Cl-

  • 김정섭;김영훈;노경태;이종명
    • Bulletin of the Korean Chemical Society
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    • v.19 no.10
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    • pp.1073-1079
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    • 1998
  • The potential energy surface (PES) of the non-identical SN2 reactions, F- + CH3Cl → FCH3 + Cl and (H2O)F + CH3Cl → FCH3 + Cl-(H2O), were investigated with ab initio MO calculations. The ab initio minimum energy reaction path (MERP) of the F- + CH3Cl → FCH3 + Cl- was obtained and it was expressed with an intermediate variable t. The ab initio PES was obtained near around t. Analytical potential energy function (PEF) was determined as a function of the t in order to reproduce the ab initio PES. Based on Morse-type potential energy function, a Varying Repulsive Cores Model (VRCM) was proposed for the description of the bond forming and the bond breaking which occur simultaneously during the SN2 reaction. The MERP calculated with the PEF is well agreed with the ab initio MERP and PEF could reproduce the ab initio PES well. The potential parameters for the interactions between the gas phase molecules in the reactions and water were also obtained. ST2 type model was used for the water.

A 3 Dimensional Characteristic Analysis of SLIM by the 2-D Finite Element Method (2차원 유한요소법에 의한 SLIM의 3차원적 특성 해석)

  • Cho, Yun-Hyun;Kim, Yong-Joo;Shin, Pan-Seok;Kang, Do-Hyun
    • Proceedings of the KIEE Conference
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    • 1990.11a
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    • pp.37-42
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    • 1990
  • In order to obtain optimal design criteria and operating parameters, a Single-sided Linear Induction Motor (SLIM) is analysed by using a 2-D finite element method with magnetic and current vector potential. In the analysing procedures, the governing equation is derived from Maxwell's equation combined with the magnetic vector potential. As a forcing term, 3-phase voltage source is employed using the Kirchhoff's voltage law in order to look into effects of the unbalanced 3-phase currents and air gap flux density. Also, 2ndary eddy current distribution, longitudinal end and transverse edge effects are in turns visualized by flux lines in 3 different analysing planes as functions of frequency and input power.

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Suitable Use of Capillary Number for Analysis of NAPL Removal from Porous Media

  • Jeong, Seung-Woo,
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.25-28
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    • 2004
  • The capillary number is used to represent the mobilization potential of organic phase trapped within porous media. The capillary number has been defined by three different forms, according to types of flow velocity and viscosity used in the definition of capillary number. This study evaluated the suitability of the capillary number definitions for representing TCE mobilization by constructing capillary number-TCE saturation relationships. The results implied that the capillary number should be correctly employed, according to interest of scale and fluid flow behavior. This study suggests that the pore-scale capillary number may be used only for investigating the organic-phase mobilization at the pore scale because it is defined by the pore-velocity and the dynamic viscosity. The Newtonian-fluid capillary number using Darcy velocity and the dynamic viscosity may be suitable to quantify flood systems representing Newtonian fluid behavior. For viscous-force modified flood systems such as surfactant-foam floods, the apparent capillary number definition employing macroscopic properties (permeability and potential gradient) may be used to appropriately represent the desaturation of organic-phases from porous media.

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Regulation of Nrf2 Mediated Phase II Enzymes by Luteolin in human Hepatocyte

  • Park, Chung Mu
    • Biomedical Science Letters
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    • v.20 no.2
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    • pp.56-61
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    • 2014
  • This study attempted to confirm the antioxidative potential of luteolin against tert-butyl hydroperoxide (t-BHP) induced oxidative damage and to investigate its molecular mechanism related to glutathione (GSH)-dependent enzymes in HepG2 cells. Treatment with luteolin resulted in attenuation of t-BHP induced generation of reactive oxygen species (ROS) and oxidative stress-mediated cell death. In addition, accelerated expression of GSH-dependent antioxidative enzymes, glutathione peroxidase (GPx) and glutathione reductase (GR), and heme oxygenase (HO)-1, as well as strengthened GSH content was induced by treatment with luteolin, which was in accordance with increased nuclear translocation of nuclear factor-erythroid 2 p45-related factor 2 (Nrf2), a transcription factor for phase 2 enzymes, in a dose-dependent manner. These results suggest that the cytoprotective potential of luteolin against oxidative damage can be attributed to fortified GSH-mediated antioxidative pathway and HO-1 expression through regulation of Nrf2 in HepG2 cells.

Corrosion of rebar in carbon fiber reinforced polymer bonded reinforced concrete

  • Bahekar, Prasad V.;Gadve, Sangeeta S.
    • Advances in concrete construction
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    • v.8 no.4
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    • pp.247-255
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    • 2019
  • Several reinforced concrete structures that get deteriorated by rebar corrosion are retrofitted using Carbon Fiber Reinforced Polymer (CFRP). When rebar comes in direct contact with CFRP, rebar may corrode, as iron is more active than carbon. Progression of corrosion of rebar in strengthened RC structures has been carried out when rebar comes in direct contact with CFRP. The experimentation is carried out in two phases. In phase I, corrosion of bare steel bar is monitored by making its contact with CFRP. In phase II, concrete specimens with surface bonded CFRP were casted and subjected to the realistic exposure conditions keeping direct contact between rebar and CFRP. Progression of corrosion has been monitored by various parameters: Half-cell potential, Tafel extrapolation and Linear Polarisation Resistance. On termination of exposure, to find residual bond stress between rebar and concrete, pull-out test was performed. Rebar in contact with CFRP has shown substantially higher corrosion. The level of corrosion will be more with more area of contact.

Mössbauer Analysis of Cations on Iron Oxyhydroxide Formation

  • Oh, Sei-Jin;Kwon, Soon-Ju
    • Journal of the Korean Magnetics Society
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    • v.15 no.2
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    • pp.85-91
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    • 2005
  • Effect of different cations to the formation of iron oxyhydroxide was studied using $M\ddot{o}ssbauer$ spectroscopy, X-ray diffraction (XRD) and BET. Redox Potential and pH were measured for the determination of the internal reaction rate, as well. The phases of iron oxyhydroxide could not be the same with each other, due to the presence of different cations in solution. Although the oxyhydroxide compound was composed of the same phases, the fraction of each phase was different from each other. The internal reaction rate was varied by the substitution of cation. It could be a cause of the different phase and particle size of oxyhydroxide compound.

Charge-discharge Behaviour of Lithium Ion Secondary Battery Using LiCo$O_2$ Synthesized by a Solution Phase Reaction (액상 반응에 의해 합성한 리튬코발트산화물을 이용한 Lithium ion 2차전지의 충방전 특성)

  • 김상필;조정수;박정후;윤문수;심윤보
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.11
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    • pp.1049-1054
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    • 1998
  • The LiCo$O_2$ powder was synthesized by a solution phase reaction. This shows a high (003) peak intensity and low (104) or (101) peak intensities in X-ray diffraction spectra. The LiCo$O_2$/Li cell shows an initial discharge capacity of 102.9mAh/g and an average discharge potential or 3.877V at a current density of 50mA/g between 3.0~4.2V. The peaks of dQ/dV plot are associated with Li ion intercalation/deintercalation reaction. To evaluate the cycleability of an actual battery system, cylindrical lithium ion cell was manufactured using graphitized MPCF anode and LiCoO$_2$ cathode. After 100th cycle, this cel maintains 80% capacity of 10th cycle value. The LiCoO$_2$/MPCF cell has a high discharge voltage of 3.6~3.7V and a good cycle life performance on cycling between 4.2~2.7V.

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Effect of Phase Separation on Anaerobic Degradation of Phenol (페놀의 혐기성분해에 대한 상분리의 영향)

  • Park, Ju-Seok;Shin, Hang-Sik;Bae, Byung-Uk
    • Journal of Korean Society of Water and Wastewater
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    • v.8 no.1
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    • pp.27-33
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    • 1994
  • With the rapid industrialization, an ever-increasing quantity and kind of new organic compounds pose environmental problems due to their toxicity and physiological effect. However, research on the biodegradation of these compounds under anaerobic condition is very limited inspite of its efficiency and economical advantage. In this research, the pH effect on the ring cleavage of phenol under anaerobic condition was investigated, and the theory of phase separation was applied to the degradation of phenol for investigating the role of acidogenic bacteria. Results, obtained from biochemical methane potential(BMP) assay for 15.5 days of incubation, showed that acidic condition was more desirable for phenol degradation than alkaline condition. By both unacclimated methanogenic granular sludge and two mixed cultures, phenol was completely removed within six weeks of incubation with a gas conversion rate of over 86% of theoretical one. However, phenol was not degraded by unacclimated acidogenic culture, and thus it is considered as a syntrophic substrate. In case of phase separated biochemical methane potential(PSBMP) assay, in which acidogenic and methanogenic culture were seeded separately and consecutively, those that had been subjected to normal acidogens for 3 to 4 weeks showed higher gas production than those seeded with sterile or frozen culture.

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