• Title/Summary/Keyword: Phase evolution

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다중 환경추적자를 이용한 제주도 지하수 유동 및 수질 특성 분석

  • 고동찬;김용재
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.138-141
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    • 2004
  • The environmental tracers tritium/helium-3 (3H/3He) and chlorofluorocarbons (CFCs) were investigated in ground water from Jeju Island, Korea, a basaltic volcanic island. The apparent 3H/3He and CFC-12 ages were in relatively good agreement in samples with low concentrations of terrigenic He. Ground water mixing was evaluated by comparing 3H and CFC-12 concentrations with mixing models, which distinguished old water with negligible 3H and CFC-12, young water with piston flow, and binary mixtures of the two end members. The ground water CFC-12 age is much older in water from wells completed in confined zones of the hydro-volcanic Seoguipo formation in coastal areas than in water from the basaltic aquifer. Comparison of major element concentrations in ground water with the CFC-12 age shows that nitrate contamination processes contribute more solutes in young water than are derived from water-rock interactions in non-contaminated old water. Chemical evolution of ground water resulting from silicate weathering in basaltic rocks reaches the zeolite-smectite phase boundary. The calcite saturation state of ground water increased with the CFC-12 apparent (piston flow) age. In agricultural areas, the temporal trend of nitrate concentration in ground water was consistent with the known history of chemical fertilizer use on Jeju Island, but the response of nitrate concentration in ground water to nitrogen inputs follows an approximate 10-year delay. Based on mass balance calculations, it was estimated that about 40% of the nitrogen applied by fertilizers reached the water table and contaminated ground water resources when the fertilizer use was at the highest level.

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Chemical Properties of Star-Forming Dwarf Galaxies in Different Environments

  • Chung, Jiwon;Rey, Soo-Chang;Sung, Eon-Chang;Lee, Woong;Kim, Suk;Lee, Yongdae
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.1
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    • pp.49.2-49.2
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    • 2017
  • Star forming dwarf galaxies in various environments are attractive objects for investigating the environmental effects on chemical evolution of dwarf galaxies. Using SDSS DR7 spectroscopic data and GALEX ultraviolet (UV) imaging data, we study the chemical properties of star forming dwarf galaxies in various environments of the Virgo cluster, Ursa Major group, and field. We derived gas-phase abundance, galaxy mass, and UV specific star formation rate (sSFR) of subsample, early-type (ETD) and late-type star forming dwarf (LTD) galaxies, which are divided by visually classified galaxy morphology. We found no O/H enhancement of LTDs in cluster and group environments compared to the field, implying no environmental dependence of the mass-metallicity relation for LTDs. LTDs in the Virgo cluster and Ursa Major group have similar sSFR at a given galaxy mass, but they exhibit systematically lower sSFR than those in isolated field environment. We suggest that LTDs in the Virgo cluster are an infalling population that was recently accreted from the outside of the cluster. We found that ETDs in the Virgo cluster and Ursa Major group exhibit enhanced O/H compared to those in the field. However, no distinct difference of N/O of galaxies between different environments. The chemically evolved ETDs in the Virgo cluster and Ursa Major group also show similar mass-sSFR relation, but systematically lower sSFR at a fixed galaxy mass compared to the field counterparts. We suggest that ETDs in the Virgo cluster and Ursa Major group have evolved under the similar local environments. We also discuss the evolutionary path of ETDs and LTDs with respect to the environmental effects of ram pressure stripping and galaxy interaction/merging.

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Microwave Dielectric Properties of (Ba1-xNax)(Mg0.5-2xY2xW0.5-xTax)O3 Ceramics

  • Hong, Chang-Bae;Kim, Shin;Kwon, Sun-Ho;Yoon, Sang-Ok
    • Journal of the Korean Ceramic Society
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    • v.56 no.4
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    • pp.399-402
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    • 2019
  • The phase evolution, microstructure, and microwave dielectric properties of (Ba1-xNax)(Mg0.5-2xY2xW0.5-xTax)O3 (0 ≤ x ≤ 0.05) ceramics were investigated. All compositions exhibited a 1:1 ordered perovskite structure. As the value of x increased, the dielectric constant (εr) exhibited a tendency to increase slightly. The quality factor reached the maximum value at x = 0.01. The temperature coefficient of resonant frequency (τf) increased from -19.32 ppm/℃ to -5.64 ppm/℃ in the positive direction as x increased. The dielectric constant (εr), quality factor (Q × f0), and temperature coefficient of resonant frequency (τf) of the composition x = 0.05, i.e., (Ba0.95Na0.05)(Mg0.4Y0.1W0.45Ta0.05)O3 were 19.9, 128,553 GHz, and -5.6 ppm/℃, respectively.

Cell Age Optimization for Hydrogen Production Induced by Sulfur Deprivation Using a Green Alga Chlamydomonas reinhardtii UTEX 90

  • KIM , JUN-PYO;KANG, CHANG-DUK;SIM, SANG-JUN;KIM, MI-SUN;PARK, TAI-HYUN;LEE, DONG-HYUN;KIM, DUK-JOON;KIM, JI-HEUNG;LEE, YOUNG-KWAN;PAK, DAE-WON
    • Journal of Microbiology and Biotechnology
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    • v.15 no.1
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    • pp.131-135
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    • 2005
  • Under sulfur deprived conditions, PS II and photosynthetic $O_2$ evolution by Chlamydomonas reinhardtii UTEX 90 are inactivated, resulting in shift from aerobic to anaerobic condition. This is followed by hydrogen production catalyzed by hydrogenase. We hypothesized that the photosynthetic capacity and the accumulation of endogenous substrates such as starch for hydrogen production might be different according to cell age. Accordingly, we investigated (a) the relationships between hydrogen production, induction time of sulfur deprivation, increase of chlorophyll after sulfur deprivation, and residual PS II activity, and (b) the effect of initial cell density upon sulfur deprivation. The maximum production volume of hydrogen was 151 ml $H_2$/l with 0.91 g/l of cell density in the late-exponential phase. We suggest that the effects of induction time and initial cell density at sulfur deprivation on hydrogen production, up to an optimal concentration, are due to an increase of chlorophyll under sulfur deprivation.

Fabrication and characterizations of the BSCCO-2212/$SrSO_4$ bulk superconductors (BSCCO-2212/$SrSO_4$ 벌크 초전도체의 제작 및 특성평가)

  • Kim, Kyu-Tae;Jang, Seok-Hern;Park, Eui-Cheol;Hwang, Su-Min;Joo, Jin-Ho;Hong, Gye-Won;Kim, Chan-Joong;Kim, He-Lim;Hyun, Ok-Bae
    • Progress in Superconductivity
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    • v.8 no.1
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    • pp.108-112
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    • 2006
  • We fabricated Bi-2212/$SrSO_4$ bulk superconductors by the casting process and evaluated the effects of the powder mixing method and annealing temperature on the texture, microstructure, and critical current. In the process, the Bi-2212 powders were mixed with $SrSO_4$ by hand-mixing(HM) and planetary ball milling(PBM) method and then the powder mixtures were melted at $1100^{\circ}C{\sim}1200^{\circ}C$, solidified, and annealed. We observed that the rod made by the PBM had a more homogeneous microstructure and smaller $SrSO_4$ and second phases than that of the rod made by the HM, resulting in increased $I_c$. The $I_c$ of the rod also depended on the annealing temperature and the highest $I_c$ was obtained to be 200 A when prepared by HM at $1200^{\circ}C$ and annealed at $810^{\circ}C$ which is probably due to the moderate density and 2212 texture and the smaller and less second phase compared to that at higher temperature. The possible causes of the variations of $I_c$ with the powder mixing method and annealing temperature were related to the microstructural evolution based on the SEM, EPMA, and DTA analyses.

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The strategy and current status of Brassica rapa genome project (배추 유전체 염기서열 해독 전략과 현황)

  • Mun, Jeong-Hwan;Kwon, Soo-Jin;Park, Beom-Seok
    • Journal of Plant Biotechnology
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    • v.37 no.2
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    • pp.153-165
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    • 2010
  • Brassica rapa is considered an ideal candidate to act as a reference species for Brassica genomic studies. Among the three basic Brassica species, B. rapa (AA genome) has the smallest genome (529 Mbp), compared to B. nigra (BB genome, 632 Mbp) and B. oleracea (CC genome, 696 Mbp). There is also a large collection of available cultivars of B. rapa, as well as a broad array of B. rapa genomic resources available. Under international consensus, various genomic studies on B. rapa have been conducted, including the construction of a physical map based on 22.5X genome coverage, end sequencing of 146,000 BACs, sequencing of >150,000 expressed sequence tags, and successful phase 2 shotgun sequencing of 589 euchromatic region-tiling BACs based on comparative positioning with the Arabidopsis genome. These sequenced BACs mapped onto the B. rapa genome provide beginning points for genome sequencing of each chromosome. Applying this strategy, all of the 10 chromosomes of B. rapa have been assigned to the sequencing centers in seven countries, Korea, UK, China, India, Canada, Australia, and Japan. The two longest chromosomes, A3 and A9, have been sequenced except for several gaps, by NAAS in Korea. Meanwhile a China group, including IVF and BGI, performed whole genome sequencing with Illumina system. These Sanger and NGS sequence data will be integrated to assemble a draft sequence of B. rapa. The imminent B. rapa genome sequence offers novel insights into the organization and evolution of the Brassica genome. In parallel, the transfer of knowledge from B. rapa to other Brassica crops would be expected.

Hydrochemical Properties of the Groundwater Used for the Natural Mineral Waters in Precambrian Metamorphic Terrains, Korea (선캄브리아기 변성암지역에 분포하는 먹는 샘물 지하수의 수리화학적 특성)

  • 성익환;추창오;조병욱;이병대;김통권;이인호
    • Journal of the Korean Society of Groundwater Environment
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    • v.5 no.4
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    • pp.203-209
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    • 1998
  • The quality of groundwater used for natural mineral water should be strictly regulated on international level by hydrogeology experts and officials because groundwater is greatly subjected to contaminations and its aquifer system may be easily destroyed by external reasons. A total of 18 natural mineral water plants exist in Precambrian metamorphic terrains of the Gyunggi massif and Yeungam massif. The g개undwater quality for the natural mineral water investigated in hydrochemical aspects shows that pH ranges from 6.85 to 8.02 with an average of 7.52. The electric conductivity (EC) and hardness average 134.1 $\mu$S/cm and 43.5, respectively, which are relatively low to the total average (151.4 $\mu$S/cm and 57.9). The contents of major cations and anions are in the order of $Ca^{2+}$$Na^{+}$>Mg$^{2+}$>K$^{+}$ and HCO$_3$$^{-}$ >SO$_4$$^{2-}$ >Cl$^{-}$ >F$^{-}$ , respectively. The dominant water types determined by Piper diagram are $Ca^{2+}$$Na^{+}$-HCO$^{-}$ $_3$and $Ca^{2+}$-HCO$^{-}$ $_3$, mainly due to the dissolution of plagioclase in the host rocks. Representative correlation coefficients between chemical species are $Ca^{2+}$-HCO$^{-}$ $_3$(0.92), $Ca^{2+}$-Cl$^{-}$ (0.63), $Na^{+}$-F$^{-}$ (0.67), HCO$^{-}$ $_3$-Cl$^{-}$ (0.66), and $Na^{+}$-HCO$^{-}$ $_3$(0.63). The determinative. coefficients between $Ca^{2+}$ and HCO$^{-}$ $_3$, and (Ca$^{2+}$$Na^{+}$+K$^{+}$ and EC art highest among the elements. According to the saturation index, most chemical species are undersaturated with respect to major minerals, except for some silica phases. In viewpoint of phase equilibrium, the chemical evolution of the groundwater may continue to proceed with increasing pH because the groundwater is undersaturated with respect to feldspars.

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Phase Evolution and Thermo-physical Properties of Rare-earth Oxides for Thermal Barrier Systems (열차폐용 희토류 산화물의 상형성과 열물성)

  • Shim, Byung-Chul;Kwak, Kil-Ho;Lee, Sung-Min;Oh, Yoon-Suk;Kim, Hyung-Tae;Jang, Byung-Koog;Kim, Seong-Won
    • Journal of Powder Materials
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    • v.17 no.2
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    • pp.148-153
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    • 2010
  • Thermal barrier systems have been widely investigated over the past decades, in order to enhance reliability and efficiency of gas turbines at higher temperatures. Yttria-stabilized zirconia (YSZ) is one of the most leading materials as the thermal barriers due to its low thermal conductivity, thermodynamic stability, and thermal compatibility with metal substrates. In this work, rare-earth oxides with pyrochlore phases for thermal barrier systems were investigated. Pyrochlore phases were successfully formed via solid-state reactions started from rare-earth oxide powders. For the heat-treated samples, thermo-physical properties were examined. These rare-oxide oxides showed thermal expansion of $9{\sim}12{\times}10^{-6}/K$ and thermal conductivity of 1.2~2.4 W/mK, which is comparable with the thermal properties of YSZ.

Molybdenum Oxides as Diffusion Barrier Layers against MoSe2 Formation in A Nonvacuum Process for CuInSe2 Solar Cells (비진공법 CuInSe2 태양전지에서 MoSe2의 생성을 억제하기 위한 산화 몰리브데늄 확산장벽 층)

  • Lee, Byung-Seok;Lee, Doh-Kwon
    • Current Photovoltaic Research
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    • v.3 no.3
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    • pp.85-90
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    • 2015
  • Two-step processes for preparing $Cu(In,Ga)Se_2$ absorber layers consist of precursor layer formation and subsequent annealing in a Se-containing atmosphere. Among the various deposition methods for precursor layer, the nonvacuum (wet) processes have been spotlighted as alternatives to vacuum-based methods due to their potential to realize low-cost, scalable PV devices. However, due to its porous nature, the precursor layer deposited on Mo substrate by nonvacuum methods often suffers from thick $MoSe_2$ formation during selenization under a high Se vapor pressure. On the contrary, selenization under a low Se pressure to avoid $MoSe_2$ formation typically leads to low crystal quality of absorber films. Although TiN has been reported as a diffusion barrier against Se, the additional sputtering to deposit TiN layer may induce the complexity of fabrication process and nullify the advantages of nonvacuum deposition of absorber film. In this work, Mo oxide layers via thermal oxidation of Mo substrate have been explored as an alternative diffusion barrier. The morphology and phase evolution was examined as a function of oxidation temperature. The resulting Mo/Mo oxides double layers were employed as a back contact electrode for $CuInSe_2$ solar cells and were found to effectively suppress the formation of $MoSe_2$ layer.

Expression Pattern of Early Growth Response Gene 1 during Olive Flounder (Paralichthys olivaceus) Embryonic Development

  • Yang, Hyun;Lee, Jeong-Ho;Noh, Jae Koo;Kim, Hyun Chul;Park, Choul-Ji;Park, Jong-Won;Kim, Kyung-Kil
    • Development and Reproduction
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    • v.18 no.4
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    • pp.233-240
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    • 2014
  • The early growth response protein 1 (Egr-1) is a widely reported zinc finger protein and a well known transcription factor encoded by the Egr-1 gene, which plays key roles in many aspects of vertebrate embryogenesis and in adult vertebrates. The Egr-1 expression is important in the formation of the gill vascular system in flounders, which develops during the post-hatching phase and is essential for survival during the juvenile period. However, the complete details of Egr-1 expression during embryo development in olive flounder are not available. We assessed the expression patterns of Egr-1 during the early development of olive flounders by using reverse transcription polymerase chain reaction (RT-PCR) analysis. Microscopic observations showed that gill filament formation corresponded with the Egr-1 expression. Thus, we showed that Egr-1 plays a vital role in angiogenesis in the gill filaments during embryogenesis. Further, Egr-1 expression was found to be strong at 5 days after hatching (DAH), in the development of the gill vascular system, and this strong expression level was maintained throughout all the development stages. Our findings have important implications with respect to the biological role of Egr-1 and evolution of the first respiratory blood vessels in the gills of olive flounder. Further studies are required to elucidate the Egr-1-mediated stress response and to decipher the functional role of Egr-1 in developmental stages.