• 제목/요약/키워드: Phase evolution

검색결과 645건 처리시간 0.029초

Observation of early photons of Gamma-ray bursts from UFFO/Lomonosov

  • Jeong, Soomin;Park, I.H.
    • 천문학회보
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    • 제41권1호
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    • pp.64.4-65
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    • 2016
  • Observations of the early photons from evolution of optical afterglows or internal shock provides the crucial clues on the nature of the bursts and environments. Hundreds of GRBs afterglow observations in multi-wavelength region have been made mainly thanks to the fast (~ 60 seconds after the trigger) localisation GRB by Swift and its fast alert to the ground telescope. It helps to improve our understandings tremendously, however many enigmas still remain, such as burst mechanism, transition prompt emission to the afterglow, early optical flash, rise phase of the early optical light curve and some missing afterglows. They could be addressed by fast slewing and multi colour and IR follow-up by future telescopes. The primary aim of UFFO/Lomonosov is to follow up optical fast ever, within a couple of seconds after trigger by onboard X-ray telescope. Its optical FOV is $30{\times}30degrees$. As a key instrument, the Slewing Mirror to redirect the optical beam from GRBs rapidly to the Ritchey-Chretien telescope. The status and launch schedule of the UFFO/Lomonosov and its test performance will be reported and prospects for the next missions will be discussed.

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Synthesis and Fragmentation of Furoxanaldehydes in the Gas Phase for Nanopatterned Alkyne Formation on a Solid Surface

  • Kim, Gi-Young;Kim, Ju-Cheon;Lee, Seung-Hee;Kim, Hyung-Jin;Hwang, Kwang-Jin
    • Bulletin of the Korean Chemical Society
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    • 제30권2호
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    • pp.459-463
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    • 2009
  • Furoxanaldehydes possessing phenyl or alkenyl groups at the 3- or 4-position of the furoxan ring were designed for alkyne formation on a solid surface. Furoxans 2 and 3 were prepared from the corresponding alkenes 2a and 3a by the reaction with NaN$O_2$ in acetic acid. Furoxan 4, in which the furoxan ring is conjugated with a double bond, was prepared from bis(bromomethyl)benzene 4a in 5 steps using the Wittig reaction of aldehyde 1 as the key step. The electron beam-mediated fragmentation of furoxanaldehydes 1-4 in a mass spectrometer was exploited by focusing on alkyne formation on the solid surface. The fragmentation of furoxan 3 possessing diaryl groups afforded diarylacetylene at high efficiency, suggesting that the aryl group conjugated with the furoxan ring could facilitate alkyne formation with the evolution of NO.

Synthesis and E-Beam-Mediated Gas Phase Fragmentation of Thiol-Containing Furoxans for Nanopatterned Alkyne Formation on Gold Surface

  • Koo, Hyun-Seo;Park, Kyung-Moon;Hwang, Kwang-Jin
    • Bulletin of the Korean Chemical Society
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    • 제31권12호
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    • pp.3583-3587
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    • 2010
  • Furoxanthiols PFT and BPFT possessing thiomethyl or thiobenzyl groups in the furoxan ring were designed and synthesized as potential light-sensitive alkyne precursors on a gold surface. The synthesis of thiofuroxans PFT and BPFT was performed from the corresponding halofuroxans 1b and 2c, respectively, by the substitution with potassium thioacetate in ethyl acetate/ethanol or DMF, followed by basic hydrolysis as the key reactions. Electron-beammediated fragmentation of furoxans 1c and 2d in a mass spectrometer afforded the corresponding aryl alkyne fragments, with the evolution of NO in high preference. In the cases of thiofuroxans PFT and BPFT, carbon-sulfur bond cleavage was observed as a representative fragmentation, producing M-SH and M-SAc peaks, which competed with the release of NO. In the fragmentation of mono-aryl furoxan 1c, the release of molecule of NO was predominately observed to produce an M-NO fragment as a base peak by the formation of trimembered thiiranium or azirine intermediate.

NaCl과 Na$_2$SO$_4$에 의한 SiC 고온 부식에 미치는 Alumina 첨가량의 영향 (Effect of Alumina Content on the Hot Corrosion of SiC by NaCl and Na2SO4)

  • 이수영;고재웅;김해두
    • 한국세라믹학회지
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    • 제28권8호
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    • pp.626-634
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    • 1991
  • The specimens for the corrosion test were made by hot-pressing of SiC power with 2 wt% Nl2O3 and 10wt% Al2O3 additions at 200$0^{\circ}C$ and 205$0^{\circ}C$. The specimens were corroded in 37 mole% NaCl and 63 mole% Na2SO4 salt mixture at 100$0^{\circ}C$ up to 60 min. SiO2 layer was formed on SiC and then this oxide layer was dissolved by Na2O ion in the salt mixture. The rate of corrosion of the specimen containing 10 wt% Al2O3 was slower than that of the specimen containing 2 wt% Al2O3. This is due to the presence of continuous grain boundary phase in the specimen containing 10 wt% Al2O3. The oxidation of SiC produced gas bubbles at the SiC-SiO2 interface. The rate of corrosion follows a linear rate law up to 50 min. and then was accelerated. This acceleration is due to the disruption oxide layer by the gas evolution at SiC-SiO2 interface. Pitting corrosion has found at open pores and grain boundaries.

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갈색 Type I 다이아몬드의 고압 열처리에 따른 표면 흑연화 생성 연구 (Surface Graphite Formation of the Brown Colored Type I Diamonds During High Pressure Annealing)

  • 송정호;송오성
    • 한국세라믹학회지
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    • 제49권6호
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    • pp.614-619
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    • 2012
  • We investigated color and graphite layer formation on the surface of Type I tinted brown diamonds exposed for 5 minutes under a high-pressure high-temperature (HPHT) condition in a stable graphite regime. We executed the HPHT processes of Process I, varying the temperature from $1600^{\circ}C$ to $2300^{\circ}C$ under 5.2 GPa pressure for 5 minutes, and Process II, varying the pressure from 4.2 to 5.7 GPa at $2150^{\circ}C$ for 5 minutes. Optical microscopy and micro-Raman spectroscopy were used to check the microstructure and surface layer phase evolution. For Process I, we observed a color change to vivid yellow and greenish yellow and the growth of a graphite layer as the temperature increased. For Process II, the graphite layer thickness increased as the pressure decreased. We also confirmed by 531 nm micro-Raman spectroscopy that all diamonds showed a $1440cm^{-1}$ characteristic peak, which remained even after HPHT annealing. The results implied that HPHT-treated colored diamonds can be distinguished from natural stones by checking for the existence of the $1440cm^{-1}$ peak with 531 nm micro-Raman spectroscopy.

사상체질성립기전에 대한 이론적 고찰 (A theoretical study on the forming mechanism of Sasang constitution)

  • 지상은;최선미;조황성
    • 한국한의학연구원논문집
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    • 제4권1호통권4호
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    • pp.47-62
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    • 1998
  • We explicate the forming mechanism of Sasang constitution as the principle of energy distribution which is based on the evolutionary hypothesis. The result was obtained as follows: 1. The principle of form-image (形象) in oriental medicine can be explained with the relation between structure and function that a life acquires through the adaptation and evolution. 2. The Sung-jung (性情) in Sasang constitutional medicine can be explained as the strategy for survival or the pattern of adaptation by which an individual or a species lives in this world. 3. The forming mechanism of Sasang constitutional organic phase (臟局) can be explained as the principle of energy distribution which includes three hypothesis (hypothesis of limited resources, hypothesis of preference and hypothesis of effectiveness). 4. It is postulated that the local hemodynamics is one of the most important factors that determine the difference of Sasang constitutional organic function. 5. The relation of metabolic rate, local hemodynamics and thermo-metabolism is inseparable and it is the important point of forming mechanism of Sasang constitution and the diagnosis of pulse.

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In, Bi가 첨가된 Sn-9wt.%Zn/Cu 접합부의 납땜성 및 기계적 성질 (The Solderability and Mechanical Properties of In, Bi Added Sn-9Zn/Cu Joint)

  • 백대화;이경구;이도재
    • 한국주조공학회지
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    • 제20권2호
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    • pp.116-121
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    • 2000
  • Interfacial reaction and mechanical properties between Sn-Zn-X ternary alloys(X : 3wt.%In, 4wt.%Bi) and Cu-substrate were studied. Cu/solder joints were subjected to aging treatments for up to 50days to see interfacial reaction at $100^{\circ}C$ and then were examined changes of microstructure and interfacial compound by optical microscopy, SEM and EDS. Cu/solder joints were aged to 30days and then loaded to failure at cross head speed of 0.3 mm $min^{-1}$ to measure tensile strength. According to the results of the solderability test, additions of In and Bi in the Sn-9wt.%Zn solder improve the wetting characteristics of the alloy and lower the melting temperature. Through the EDS and XRD analysis of Cu/Sn-9wt.%Zn solder joint, it was concluded that the intermetallic compound was the ${\gamma}-Cu_5Zn_8$ phase. Cu-Zn intermetallics at Cu/solder interfaces played an important role in both the microstructure evolution and failure of solder joints. Cu/solder joint strength was decreased by aging treatment, and those phenomenon was closely related to the thickening of intermetallic layer at Cu/solder joints.

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디지털 공간에서의 보로노이 다이어그램 적용에 관한 연구 (A Study on the Application of the Voronoi Diagram on Digital Space)

  • 강가애;윤재은
    • 한국실내디자인학회논문집
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    • 제17권3호
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    • pp.156-164
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    • 2008
  • Through staggering advancements of technology and network as we know them as digital revolution, we have established a foundation of space in which we can express reality by eliminating the boundaries between expression, space, and movement. There are many ongoing approaches that aim to overcome the physically-fixed property of space where the mathematical-geometric notion of Voronoi Diagram is one of them. Although the repetitive increment based on self-organization during the process in which space is generated by the Voronoi Diagram forms a pattern and focuses on the formation, its pattern is not restricted to a single method of expression but evolves over self-control. The result of having analyzed spaces generated by the Voronoi Diagram in this study can be summarized as follows. First, the Voronoi computation method with self-organization property creates multiple levels, increments, and evolves through feedbacks among changes with the slightest order and in the absence of control. Secondly, after forming a pattern through such feedbacks comes the differentiation phase due to the presence of different properties. Thirdly, a space that has gone through the generation process retransforms through active interaction between changes and it obtains ambiguous boundaries and a repetitive pattern. This leads to an evolution of space through repetitive increments based on self-organization. Such flexible space creation is supported by various digital technologies where we believe a converging application of these studies, sciences, engineering concepts, and space design is and effective and new method in terms of space creation.

Si-N 전구체를 이용한 에폭시/실리카 나노복합재료의 제조 (Novel Preparation of Epoxy/Silica Nanocomposite Using Si-N Precursor)

  • 김이주;윤호규;이상수;김준경
    • 폴리머
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    • 제28권5호
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    • pp.391-396
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    • 2004
  • 기존의 에폭시/실리카 나노복합재료의 제조 방법에서 나타나는 문제점인 경화 반응 중의 휘발성 부산물 생성에 의한 미세기공 형성 및 치수 불안전성 등을 극복하고자 Si-N 전구체를 사용한 새로운 방법을 제안하고자 한다. 실리카 전구체로 부산물이 형성되지 않는 메틸트리페닐실란 (MTPS)을 합성하고 이를 이용하여 솔-젤 반응과 에폭시 경화 반응이 병행되는 동시 복합화 반응을 통하여 무기상의 고른 분산상태를 지닌 에폭시/실리카 나노복합재료를 제조하였으며, 이로부터 뛰어난 투명성뿐 아니라 기계적 물성과 열적특성에서 탁월한 물성의 증가를 얻을 수 있었다.

Layer-by-layer Composition Modulation by Ion-induced Atomic Rearrangement in Metallic Alloys

  • 김병현;김상필;이광렬;정용재
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.359-359
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    • 2010
  • Self-organized nanostructures of dots, holes or ripples produced by energetic ion bombardment have been reported in a wide variety of substrates. Ion bombardment on an alloy or compound also draws much attention because it can induce a surface composition modulation with a topographical surface structure evolution. V. B. Shenoy et al. further suggested that, in the case of alloy surfaces, the differences in the sputtering yields and surface diffusivities of the alloy components will lead to a lateral surface composition modulation [1]. In the present work, the classical molecular dynamics simulation of Ar bombardment on metallic alloys at room temperature revealed that this bombardment induces a surface composition modulation in layer-by-layer mode. In both the $Co_{0.5}Cu_{0.5}$ alloy and the CoAl B2 phase, the element of higher-sputtering yield is accumulated on the top surface layer, whereas it is depleted in lower layers. A kinetic model considering both the rearrangement and the sputtering of the substrate atoms agrees with the puzzling simulation results, which revealed that the rearrangement of the substrate atoms plays a significant role in the observed composition modulation.

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