• Title/Summary/Keyword: Phase evolution

검색결과 645건 처리시간 0.022초

분진-미스트 시스템을 이용한 실시간 수용성 유기탄소 분석 (Time Resolved Analysis of Water Soluble Organic Carbon by Aerosol-into-Mist System)

  • 조인환;박다정;배민석
    • 한국대기환경학회지
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    • 제31권6호
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    • pp.497-507
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    • 2015
  • Real-time and quantitative measurement of the chemical composition in ambient aerosols represents one of the most challenging problems in the field of atmospheric chemistry. In the present study, time resolved application by Aerosol-into-Mist System (AIMS) following by total organic carbon analyzer (TOC) has been developed. The unique aspect of the combination of these two techniques is to provide quantifiable water soluble organic carbon (WSOC) information of particle-phase organic compounds on timescales of minutes. We also demonstrated that the application of the AIMS method is not limited to water-soluble organic carbon but inorganic ion compounds. By correlating the volume concentrations by optical particle sizer (OPS), water soluble organic carbon can be highly related to the secondary organic products. AIMS-TOC method can be potentially applied to probe the formation and evolution mechanism of a variety of SOA behaviors in ambient air.

국소교란이 있는 난류박리 재부착유동의 이산와류 수치해석 (Discrete Vortex Simulation of Turbulent Separated and Reattaching Flow With Local Perturbation)

  • 정용만;성형진
    • 대한기계학회논문집
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    • 제18권2호
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    • pp.479-491
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    • 1994
  • Discrete vortex method was applied for simulating an active control of turbulent leading- edge separation bubble. The leading-edge separation zone was perturbed by a time-dependent sinusoidal perturbation of different frequencies and levels. In order to describe the local sinusoidal perturbation at the separation point, a source pulsation vortex technique was proposed. The present two-dimensional vortex simulations were qualitatively compared with the experimental results for a blunt circular cylinder, where perturbation was introduced along the square-cut leading edge of the cylinder $(Kiya et al.^{(6,7)}).$ It was found that the reattachment length attained a minimum point at low levels of perturbation and two minima at a moderate higher perturbation frequency. The effects of local perturbation on the evolution of leading-edge separation bubble were scrutinized by comparing the perturbed flow with the natural flow. These comparisons were made for the distributions of mean velocity and its velocity fluctuations, intermittency and wall velocity. The motions of instantaneous reattachment in the space-time domain were demonstrated, which were also compared with the experimental findings. In order to investigate the reduction mehanism of reattachment length in the separation bubble, various cross-correlations for velocity and pressure and the relevant convection velocities were evaluated. It was observed that the convection velocity was closely associated with its corresponding pulsationg frequency.

IN738LC 합금의 열간 노출 및 재생 열처리에 따른 미세조직과 응력 파단 특성의 변화 (Effect of Thermal Exposure and Rejuvenation Treatment on Microstructure and Stress Rupture Properties of IN738LC)

  • 최백규;주동원;김인수;장중철;조창용
    • 한국재료학회지
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    • 제11권10호
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    • pp.833-840
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    • 2001
  • Effects of thermal exposure and rejuvenation treatment on the microstructural evolution and the stress-rupture properties of IN738LC have been investigated. The role of precipitates on the stress- rupture properties has been analyzed through microstructural observations. Thermal exposure at $982^{\circ}C$ for 1000 hours gave rise to precipitation of $\sigma$ phase and coarsening of ${\gamma}$'. The microstructural degradation with thermal exposure at $982^{\circ}C$ deteriorated stress rupture properties of the alloy. All the existing phases except MC carbides have completely dissolved into the matrix with homogenization treatment at $1200^{\circ}C$ for 2 hours. Microstructure and stress-rupture properties of the thermal exposed specimens have been successfully rejuvenated by the proposed treatment.

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Effect of Electromagnetic Stirring on Microstructure Evolution in Solidification of a Near-Eutectic Al-Si Alloy

  • Guo, Qing-Tao;Sim, Jae-Gi;Jang, Young-Soo;Choi, Byoung-Hee;Lee, Moon-Hyoung;Hong, Chun-Pyo
    • 한국주조공학회지
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    • 제28권5호
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    • pp.226-230
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    • 2008
  • 본 논문에서는 공정조성 부근의 Al-Si 합금의 미세구조에 미치는 전자기교반(EMS)의 영향에 대하여 연구하였다. 초정 a 상의 형상에 미치는 전자기교반의 세기의 영향을 조사하기 위하여 각각 교반장치에 60, 80,및 120V의 전압을 가하여 미세조직을 관찰하였다. 60V 이하의 전압이 인가되었을 때 전자기교반의 효과가 나타나지 않은 반면에, 80V 이상의 전압으로 5초 이상 인가되었을 때 구상화된 초정 a 상을 얻을 수 있었다. 인가된 전압이 120V일 때 초정 a 상은 보다 균일한 분포를 가지며 구상화 되었다. 전자기교반의 세기와 함께 교반시간의 영향을 확인하기 위하여 교반시간을 증가시키면서 미세조직을 관찰하였다. 또한 초정 a 상의 형상에 미치는 주조변수의 영향에 대해서도 실험하였다.

3D Radar Objects Tracking and Reflectivity Profiling

  • Kim, Yong Hyun;Lee, Hansoo;Kim, Sungshin
    • International Journal of Fuzzy Logic and Intelligent Systems
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    • 제12권4호
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    • pp.263-269
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    • 2012
  • The ability to characterize feature objects from radar readings is often limited by simply looking at their still frame reflectivity, differential reflectivity and differential phase data. In many cases, time-series study of these objects' reflectivity profile is required to properly characterize features objects of interest. This paper introduces a novel technique to automatically track multiple 3D radar structures in C,S-band in real-time using Doppler radar and profile their characteristic reflectivity distribution in time series. The extraction of reflectivity profile from different radar cluster structures is done in three stages: 1. static frame (zone-linkage) clustering, 2. dynamic frame (evolution-linkage) clustering and 3. characterization of clusters through time series profile of reflectivity distribution. The two clustering schemes proposed here are applied on composite multi-layers CAPPI (Constant Altitude Plan Position Indicator) radar data which covers altitude range of 0.25 to 10 km and an area spanning over hundreds of thousands $km^2$. Discrete numerical simulations show the validity of the proposed technique and that fast and accurate profiling of time series reflectivity distribution for deformable 3D radar structures is achievable.

Andreev reflection in the c-axis transport of $Bi_2$$Sr_2$Ca$Cu_2$$O_{8+x}$ single crystals near $T_c$

  • Chang, Hyun-Sik;Lee, Hu-Jong
    • Progress in Superconductivity
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    • 제3권2호
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    • pp.140-145
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    • 2002
  • An enhancement of the c-axis differential conductance around the zero-bias voltage near the superconducting transition temperature $T_{c}$ has been observed in $Au/Bi_2$$Sr_2$$CaCu_2$$O_{8+x}$ junctions. We attribute such an enhancement to the Andreev reflection (AR) between the surface Cu-O bilayer with suppressed superconductivity and the next superconducting Cu-O bilayer. The continuous evolution of the differential conductance, from gap like depression to an AR-like peak structure, around the zero-bias voltage points to weakening of the barrier strength of the nonsuperconducting layer between adjacent Cu-O bilayers as temperature approaches $T_{c}$ from below. The peak structure disappeared just below the bulk $T_{c}$ value of underdoped Bi2212 single crystals, whereas it survived up to ~1 K above $T_{c}$ in Junctions prepared on slightly overdosed crystals. According to a recently proposed theoretical consideration, a wider temperature range of the AR a bone $T_{c}$ is expected in the underdoped regime when phase-incoherent preformed pairs emerge in the pseudogap state. Our result is in contradiction to the preformed pair scenario. scenario.o.

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선박 및 해양구조물용 극저온 재료의 온도 및 변형률 속도 의존 통합 구성방정식 개발 (Development of Temperature and Strain-Rate Dependent Unified Constitutive Equation for Ships and Offshore Structures)

  • 박웅섭;김정현;전민성;이제명
    • 대한조선학회논문집
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    • 제48권3호
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    • pp.200-206
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    • 2011
  • The mechanical properties of the most widely used cryogenic materials, i.e. austenitic stainless steel (ASS), aluminum alloy and invar steel, strongly depend on temperatures and strain rates. These phenomena show very complicated non-linear behaviors and cannot be expressed by general constitutive equation. In this study, an unified constitutive equation was proposed to represent the effect of temperature and strain rate on the materials. The proposed constitutive equation has been based on Tomita/Iwamoto and Bodner/Partom model for the expression of 2nd hardening due to martensite phase transformation of ASS. To simulate ductile fracture, modified Bodner/Chan damage model was additionally applied to the model and the model validity was verified by comparison of experimental and simulation results.

Effect of Microporosity on Tensile Properties of As-Cast AZ91D Magnesium Alloy

  • 이충도
    • 소성∙가공
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    • 제8권3호
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    • pp.283-283
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    • 1999
  • In the present study, the effect of microporosity on the tensile properties of as-cast AZ91D magnesium alloy was investigated through experimental observation and numerical prediction. The test specimens were fabricated by die-casting and gravity-casting. For gravity-casting, the inoculation and use of various metallic moulds were applied to obtain a wide range of microporosity. The deficiency of the interdendritic feeding of the liquid phase acted as d dominant mechanism on the formation of the micropores in the Mg-Al-alloys, rather than the evolution of hydrogen gas. Although tensile strength and elongation has a nonlinear and very intensive dependence upon microporosity, the yield strength appeared to have a linear relationship with microporosity. However, it was possible to quantitatively estimate the linear contribution of microporosity on the individual tensile property far a range of microporosity, which was below about B %. The numerical prediction suggests that the effect of microporosity on fractured strength and elongation decreased as the strain hardening exponent increased. Furthermore. the shape and distribution of micropores may play a more dominant role than local plastic deformation on the tensile behavior of AZ9lD alloy.

Analysis of Flow around a Rotating Marine Propeller using PIV Techniques

  • Lee Sang Joon;Paik Bu Geun
    • 한국가시화정보학회:학술대회논문집
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    • 한국가시화정보학회 2004년도 Proceedings of 2004 Korea-Japan Joint Seminar on Particle Image Velocimetry
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    • pp.169-175
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    • 2004
  • The characteristics of flow around a rotating propeller were investigated using PIV technique. For each of four different blade phases of $0^{\circ},\;18^{\circ},\;36^{\circ}\;and\;54^{\circ}$four hundred instantaneous velocity fields were ensemble averaged to investigate the spatial evolution of the flow around a propeller. The phase-averaged mean velocity fields show that the viscous wake formed by the boundary layers developed on the blade surfaces and the slipstream contraction in the near-wake region. The out-of-plane velocity component and strain rate had large values at the locations of the tip and trailing vortices. The boundary layer developed along the ship hull bottom surface of the ship stern provides a strong turbulent shear layer, affecting the vortex structure in the propeller near-wake. As the flow develops in the downstream direction, the trailing vortices formed behind the propeller hub move upward slightly due to the presence of the hull wake and free surface. The turbulence intensity has large values around the tip and trailing vortices. As the wake moves downstream, the strength of the vorticity diminishes and the turbulence intensity increases due to turbulent diffusion and active mixing between the tip vortices and adjacent wake flow.

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코발트/니켈 합금박막으로부터 형성된 복합실리사이드 (Characterization of Composite Silicide Obtained from NiCo-Alloy Films)

  • 송오성;정성희;김득중
    • 한국재료학회지
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    • 제14권12호
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    • pp.846-850
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    • 2004
  • NiCo silicide films have been fabricated from $300{\AA}-thick\;Ni_{1-x}Co_{x}(x=0.1\sim0.9)$ on Si-substrates by varying RTA(rapid thermal annealing) temperatures from $700^{\circ}C\;to\;1100^{\circ}C$ for 40 sec. Sheet resistance, cross-sectional microstructure, and chemical composition evolution were measured by a four point probe, a transmission electron microscope(TEM), and an Auger depth profilemeter, respectively. For silicides of the all composition and temperatures except for $80\%$ of the Ni composition, we observed small sheet resistance of sub- $7\;{\Omega}/sq.,$ which was stable even at $1100^{\circ}C$. We report that our newly proposed NiCo silicides may obtain sub 50 nm-thick films by tunning the nickel composition and silicidation temperature. New NiCo silicides from NiCo-alloys may be more appropriate for sub-0.1${\mu}m$ CMOS process, compared to conventional single phase or stacked composit silicides.