• Title/Summary/Keyword: Phase evolution

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Effects of Competition between Phase Separation and Ester Interchange Reactions on the Phase Behavior in a Phase-Separated Immiscible Polyester Blend: Monte Carlo Simulation

  • Youk, Ji-Ho;Jo, Won-Ho
    • Fibers and Polymers
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    • v.2 no.2
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    • pp.81-85
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    • 2001
  • The effects of rate of phase separation to ester interchange reactions and the repulsive pair interaction energy on the phase behavior in a phase-separated immiscible polyester blend are investigated using a Monte Carlo simulation method. The time evolution of structure factor and the degree of randomness are monitored as a function of homogenization time. When the phase separation is dominant over ester interchange reactions, the domain size slowly increases with homogenization time. However, when the pair interaction becomes less repulsive, the domain size does not significantly change with homogenization time. On the other hand, when ester interchange reactions are dominant over the phase separation, the homogenization proceeds without a change in the domain size. The higher the extent of phase separation, the lower the increasing rate of the DR. However, when the phase separation is sufficiently dominant, the effect of the extent of phase separation on the increasing rate of the degree of randomness become less significant.

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Microstructural Evolution and Dielectric Response Characteristics During Crystallization of Amorphous Pb(Fe2/3W1/3)O3

  • Kim, Nam-Kyung;David A. Payne
    • The Korean Journal of Ceramics
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    • v.1 no.2
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    • pp.75-80
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    • 1995
  • Development of phases, evolution of microstructures, and dielectric response characteristics of amorphous lead iron tungstates during crystabllization were investiageted. A series of mircographs showing the evolution sequence of microstructures is presented. Crystallization was observed to initiate from inside of the amorphous material. A cubic perovskite phase developed fully at $760^{\circ}C$ from amorphous state via intermediate metastable crystalline structures. Dielectric constant of amorphous PFM was totally insensitive to the temperature change around the Curie temperature of crystalline material. Sintered pellet, with relative density of 96% and an almost pore-free dense internal microstructure, could be prepared from amorphous powder.

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Prediction of Daily Solar Irradiation Based on Chaos Theory (혼돈이론을 이용한 일적산 일사량의 예측)

  • Cho, S. I.;Bae, Y. M.;Yun, J. I.;Park, E. W.;Hwang, H.
    • Journal of Biosystems Engineering
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    • v.25 no.2
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    • pp.123-130
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    • 2000
  • A forcasting scheme for daily solar irradiance on agricultural field sis proposed by application of chaos theory to a long term observation data. It was conducted by reconstruction of phase space, attractor analysis, and Lyapunov analysis. Using the methodology , it was determined whether evolution of the five climatic data such as daily air temperature , water temperature , relative humidity, solar radiation, and wind speed are chaotic or not. The climatic data were collected for three years by an automated weather station at Hwasung-gun, Kyonggi-province. The results showed that the evolution of solar radiation was chaotic , and could be predicted. The prediction of the evolution of the solar radiation data was executed by using ' local optimal linear reconstruction ' algorithm . The RMS value of the predicting for the solar radiation evolution was 4.32 MJ/$m^2$ day. Therefore, it was feasible to predict the daily solar radiation based on the chaos theory.

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Observation of Ferroelectric Domain Evolution Processes of Pb(Zr,Ti)O3 Ceramic Using Piezoresponse Force Microscopy (Piezoresponse Force Microscopy를 이용한 Pb(Zr,Ti)O3 세라믹의 단계적 Poling에 의한 강유전체 도메인 진화 과정 관찰)

  • Kim, Kwanlae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.1
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    • pp.20-24
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    • 2019
  • Ferroelectric material properties are strongly governed by domain structures and their evolution processes, but the evolution processes of complex domain patterns during a macroscopic electrical poling process are still elusive. In the present work, domain-evolution processes in a PZT ceramic near the morphotropic phase-boundary composition were studied during a step-wise electrical poling using piezoresponse force microscopy (PFM). Electron backscatter diffraction was used with the PFM data to identify the grain boundaries in the region of interest. In response to an externally the applied electric field, growth and retreat of non-$180^{\circ}$ domain boundaries wasere observed. The results indicate that ferroelectric polarization-switching nucleates and evolves in concordance with the pattern of the pre-existing domains.

Hardness prediction based on microstructure evolution and residual stress evaluation during high tensile thick plate butt welding

  • Zhou, Hong;Zhang, Qingya;Yi, Bin;Wang, Jiangchao
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.12 no.1
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    • pp.146-156
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    • 2020
  • Two High Tensile Strength Steel (EH47) plates with thickness of 70 mm were butt-welded together by multi-pass Submerged Arc Welding (SAW), also the hardness and welding residual stress were investigated experimentally. Based on Thermal-Elastic-Plastic Finite Element (TEP FE) computation, the thermal cycles during entire welding process were obtained, and the HAZ hardness of multi-pass butt welded joint was computed by the hardenability algorithm with considering microstructure evolution. Good agreement of HAZ hardness between the measurement and computational result is observed. The evolution of each phase was drawn to clarify the influence mechanism of thermal cycle on HAZ hardness. Welding residual stress was predicted with considering mechanical response, which was dominantly determined by last cap welds through analyzing its formation process.

Evolution of primary stars in Pop III binary systems

  • Lee, Hunchul;Yoon, Sung-Chul
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.77.4-78
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    • 2016
  • Binary interactions may have significant impact on Pop III stellar evolution. Pop III single star evolution indicates that for primary masses less than $20M_{\odot}$, no significant binary mass transfer would occur before core helium exhaustion. We perform binary system evolution for various primary masses ($20M_{\odot}$ < $M_1$ < $60M_{\odot}$) and initial periods under same mass ratio $M_2/M_1=0.9$, and follow the evolution and mass transfer of the primary star. If binary mass transfer occurs during post main sequence, the primary star does not evolve into naked helium star and still contain significant hydrogen in the envelope. During the post mass transfer phase, the primary star evolves redward, and does not become sufficiently hot to enhance the number of ionizing photons, compared to the case of single star evolution for a given initial mass. This result implies that primary stars of massive Pop III binary systems would have little contribution to the reionization in the early universe. Given the large hydrogen content ($0.326-1.793M_{\odot}$), the primary stars that underwent stable mass transfers would explode as a Type IIb supernova, and it would be difficult for Pop III binary stars to produce Type Ib/c supernovae that look similar to those found in the local universe.

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Nitrogenase Derepression and Associated Metabolism in a Microaerophilic Cyanobacterium, Plectonema boryanum

  • Pandey, Kapil Deo;Sukla, Sarkar;Naz, Shaheen;Smita, Chaturvedi;Ajaikumar, Kashyap
    • Journal of Microbiology and Biotechnology
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    • v.11 no.2
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    • pp.179-185
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    • 2001
  • Nitrate grown cells of cyanobacterium Plectonema boryanum, transferred to nitrogen stress, evolved nitrogenase catalyzed $H_2$ under microaerophilic condition. Nitrogen ($N_2$) in gs phase, low light intensity, and reducing substances in incubation phase stimulated $N_2$fixation ($H_2\;evolution$). Cyanobacterium grew slowly under microaerobic condition with a low intracellular ammonia pool. Nitrogen sources (${NO_3}^-,{NH_4}^+,\;and\;CH_3NH_3$) inhibited nitrogenase and glutamine synthetase (GS) transferase activity, and methylamine behaved like an ammonical nitrogen source. Depletion of molybdenum (Mo) and addition of tungsten (W) in the incubation medium inhibited $H_2$ evolution, Cyanobacterium was able to take up nitrate and expressed nitrate reductase (NR) activity under microaerophilic condition at an extremely slow rate.

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Evolution of Microstructure and Mechanical Properties of a Ni Base Superalloy during Thermal Exposure (니켈기 초내열합금의 열간노출에 따른 미세조직 및 기계적 특성 변화)

  • Kim, In-Soo;Choi, Baig-Gyu;Jung, Joong-Eun;Do, Jeong-Hyeon;Jung, In-Yong;Jo, Chang-Yong
    • Journal of Korea Foundry Society
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    • v.36 no.5
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    • pp.159-166
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    • 2016
  • The microstructural evolution of a cast Ni base superalloy, IN738LC, has been investigated after long term exposure at several temperatures. Most of the fine secondary ${\gamma}^{\prime}$ particles resolved after 2000 hour exposure at $816^{\circ}C$. At higher temperatures of $871^{\circ}C$ and $927^{\circ}C$, secondary ${\gamma}^{\prime}$ resolved after 1000 hours of exposure, and cuboidal primary ${\gamma}^{\prime}$ grew with exposure time. During the thermal exposure, ${\sigma}$ phase formed at all tested temperatures, and ${\eta}$ phase was observed around interdendritic regions due to carbide degeneration. The influence of microstructural evolution during thermal exposure on the mechanical properties has been analyzed. The effects of ${\gamma}^{\prime}$ particle growth are more pronounced on the high temperature creep properties than on the room temperature tensile properties.

Abell 2261: a fossil galaxy cluster in a transition phase

  • Kim, Hyowon;Ko, Jongwan;Kim, Jae-woo;Smith, Rory;Song, Hyunmi;Hwang, Ho Seong
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.2
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    • pp.33.2-33.2
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    • 2018
  • Fossil galaxy cluster has a dominant central elliptical galaxy (${\Delta}M12$ >2 in 0.5Rvir) embedded in highly relaxed X-ray halo, which indicates dynamically stable and passively evolved system. These features are expected as a final stage of the cluster evolution in the hierarchical structure formation paradigm. It is known that Abell 2261(A2261 hereafter) is classified as a fossil cluster, but has unusual features such as a high central X-ray entropy (i.e., non-cool core system), which is not expected in normal fossil clusters. We perform a kinematic study with a spectroscopic data of 589 galaxies in the A2261 field. We define cluster member galaxies using the caustic method and discover a new second bright galaxy at ~1.5 Rvir (nearly the splash-back region). It implies the current fossil state of the cluster can break in the near future. In addition, with three independent substructure finding methods, we find that A2261 has many substructures within 3 Mpc from the center of the cluster. These findings support that A2261 is not in a dynamically stable state. We argue that A2261 is in a transitional phase of dynamical evolution of the galaxy cluster and maybe previously defined fossil cluster does not mean the final stage of the evolution of galaxy clusters.

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Macro-environmental Drivers and Technological Evolution of Complex Product System: Evidence from Nuclear Power Plant (거시환경요인과 복합제품시스템의 기술진화: 원자력 발전 플랜트의 사례를 중심으로)

  • Kwak, Kiho;Kim, Wonjoon;Kim, Minki;Cho, Chang Yeon
    • Journal of Technology Innovation
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    • v.25 no.2
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    • pp.89-125
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    • 2017
  • Complex product systems (CoPs) is a engineering-intensive products with high-ended design technology, which are closely linked with national economic growth and development of social infrastructures. Accordingly, in order to understand the technological evolution of CoPs, it is necessary to identify the macro-environmental drivers surrounding the CoPs and their impact on the technological evolution of the CoPS. Therefore, we investigate the effect of policy, economic and social drivers on the technological evolution of CoPS by implementing the longitudinal case study on nuclear power plant during the periods between 1950 and 2010s. Based on the analysis of various sources of secondary data and primary data through interviews, we found that the technological evolution of nuclear power plant is progressed as "Phase 1: Application research for peaceful utilization of nuclear energy" between 1950s and 1960s, "Phase 2: The first renaissance of nuclear energy" during 1970s, "Phase 3: Enhancement of safety and the catch-up of latecomers in nuclear energy" between 1990s and 2000s, and "Phase 4: Top prioritization of safety and the development of next generation reactors for the second renaissance of nuclear energy" since 2010s. We also found that various kinds of policy, economic and social drivers, such as energy policy, investment in technology development, economic growth and energy demand, social acceptability and environmental concern, have affected the technology evolution of nuclear power plant at each phase. We emphasize the role of macroenvironmental drivers in the technological evolution of CoPS. We also suggest that countries that endeavor to develop CoPs need to utilize those drivers for enhancing competitiveness and sustaining leadership.