• 한국결정성장학회지
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• 제31권4호
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• pp.166-173
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• 2021

TiO₂의 rutile 상은 anatase 상에 비해서 고온에서 안정한 상을 형성하지만 anatase의 안정한 온도 영역은 합성조건에 따라 변화된다. 본 연구에서는 TiOSO₄와 에탄올과 증류수의 혼합용매를 사용하여 Sol-gel법으로 나노 사이즈의 TiO₂를 합성하여 pH 및 열처리 온도를 따른 anatase와 rutile의 상변화에 대하여 조사하였다. 제조한 TiO₂의 pH(3, 5, 7, 9)와 열처리 온도(500, 600, 700, 800, 900℃) 조건을 변화시켜 anatase와 rutile의 비율 변화를 관찰하였다. XRD, FE-SEM 분석을 통해 이와 같은 변화를 관찰한 결과, 500℃에서는 anatase TiO₂, 900℃에서는 rutile TiO₂가 관찰되었다. 이 중간 온도인 600, 700, 800℃에서는 pH에 따라 anatase와 rutile의 비율이 변화한다. 700℃를 기준으로 pH = 3, 5는 anatase TiO₂의 비율이 더 크고, pH = 7, 9는 rutile TiO₂의 비율이 더 크다는 결론을 얻었다.

• 공업화학
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• 제10권5호
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• pp.644-651
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• 1999

본 연구에서는 진공 증착법을 이용하여 철프탈로시아닌(FePc) 박막을 실리콘 웨이퍼와 알루미나 기판 위에 합성하였으며, 박막의 증착 온도와 두께를 변화시켜 실험한 후 일부의 박막을 열처리하였다. 박막의 두께 변화에 따른 표면 구조 변화, 상전이와 전기 저항 감도 변화를 SEM, XRD, 그리고 전기저항의 측정으로 관찰하였다. 증착 온도가 $370^{\circ}C$에서 $350^{\circ}C$로 감소함에 따라 $\alpha$상의 (200)면, (011)면, (211)면, 그리고 (114)면이 사라지며 $\beta$상의 (100)면의 피크가 나타났다. 전구물질의 양을 달리하며 고속 증착시켜 박막 두께를 조절한 결과, 두께 증가에 따라 결정 크기가 증가하고 또한 $\alpha$상에서 $\beta$상으로의 상 전이가 일어남을 알 수 있었다. 열처리한 박막의 결정성을 측정한 결과 열처리 온도가 증가함에 따라 $150^{\circ}C$으로부터 $\alpha$상에서 $\beta$상으로의 상 전이가 일어나기 시작하여 $350^{\circ}C$에서 완전히 $\beta$상으로 전이되었다. $NO_x$에 대한 철프탈로시아닌 박막의 온도에 따른 전기저항감도를 측정한 결과 박막의 두께가 얇을수록 더 좋고 안정된 전기 저항 감도를 보여주었다. 즉 박막의 표면구조가 조밀하게 성장할수록 전기 저항 감도가 더욱 좋아짐을 확인하였다.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2000년도 춘계학술발표회 초록집
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• pp.1-1
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• 2000

The results of the modification of metal materials treated by high temperature pulst:d plasma fluxes (HTlPPF) with a specific power of incident flux changing in the $(3...100)10^5{]\;}W/cm^2$ range and a pulse duration lying from 15 to $50{\;}\mu\textrm{s}$ have been presented. The results of HTPPF action were studied on the stainless steels of 18Cr-l0Ni, 16Cr- 15Ni, 13Cr-2Mo types; on the structural carbon steels of (13...35)Cr, St. 3, St. 20, St. 45 types; on the tool steels of U8, 65G, ShHI5 types, and others; on nickel and high nickel alloy of 20Cr-45Ni type; on zirconium- and vanadium-base alloys and other materials. The microstructure and properties (mechanical, tribological, erosion, and other properties) of modified materials and surface alloying of metals exposed to HTPPF action have been investigated. It was found that the modification of materials by HTPPF resulted in a simultaneous increase of several properties of the treated articles: microhardness of the surface and layers of 40...60 $\mu\textrm{m}$ in depth, tribological characteristics (friction coefficient, wear resistance), mechanical properties ({\sigma_y}, {\;}{\sigma_{0.2}}.{\;}{\sigma_r}) on retention of the initial plasticity ($\delta$), corrosion resistance, radistanation erosion under ion irradiation, and others. The determining factor of the changes observed is the structural-phase modification of the near-surface layers, in particular, the formation of the fine cellular structure in the near-surface layers at a depth of $20{\;}{\mu\textrm{m}}$ with dimension of cells changing in the range from 0.1 to $1., 5{\;}\mu\textrm{m}$, depending on the kind of material, its preliminary treatment, and the parameters of plasma fluxes. The remits obtained have shown the possibility of purposeful surface alloying of metals exposed to HTPPF action over a depth up to 20...45 $\mu\textrm{m}$ and the concentration of alloying element (Ni, Cr, V) up to 20 wt.%. Possible industrial brunches for using the treatment have been also considered, as well as some results on modifying the serial industrial articles by HTPPF.

• 전기화학회지
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• 제2권1호
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• pp.5-12
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• 1999

PVA-전구체법을 사용하여, 리튬전지의 양극물질인 $Li_xNi_{1-y}Co_yO_2$의 다결정성 분말을 합성하였다. 합성된 분말을 양극물질로 사용하여 리튬이온전지를 제조하여 전지의 전기화학적 성질을 측정하였다. PVA와 금속이온간의 상대적 양, PVA의 농도 및 중합도, 열처리조건, 금속의 조성비 등 여러 다른 합성조건을 변화시키면서, 그러한 합성상의 조건 변화가 리튬이온전지의 전지특성과 어떠한 상호관계를 갖는지 조사하였다. 전지의 초기성능에 관한 한, PVA-전구체법으로 합성한 $Li_xNi_{1-y}Co_yO_2$의 경우, 최적의 조성은 x=1.0, y=0.26인 것으로 관찰되었다. PVA-전구체법으로 합성할 경우, 전구체에 남는 잔여탄소로 인해 형성되는 $Li_2CO_3$가 전지의 성능을 저하시키는 것으로 관찰되었다. 이를 제거하기 위해 건조 공기의 흐름 속에서 열처리를 하거나, 합성 후 2차 열처리 과정에서 $500^{\circ}C$의 온도에서 건조공기의 흐름을 유지하며 annealing 처리를 하는 것이 전지의 특성을 크게 개선하는 것으로 관찰되었다.

• 한국재료학회지
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• 제17권11호
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• pp.580-586
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• 2007

To enhance the reliability of a newly designed reciprocating compressor applied in a domestic compressor, accelerated life tests were developed using new definitions of the sample size and the $B_1$ life index. In $1^{st}$ accelerated life testing, the compressor was locked due to the fracture of the suction reed valve. The failure modes and mechanisms of the suction reed valve in the accelerated tests were found to be similar to that of the failed product in the field. The root cause of the failure was the overlap between the suction reed valve and the valve plate in the suction port. The missing parameters in the design phase were modified by expanding the trespan size, introducing tumbling process, changing the material and thickness for the valve, introducing a ball peening and brushing process for the valve plate. In $2^{nd}$ accelerated life testing, the compressor was locked due to the interference between the crank shaft and thrust washer. The corrective plan was to heat treat the crank shaft. The $B_1$ life of the compressor improved from 1.5 to 12.9 years.

• 한국세라믹학회지
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• 제30권8호
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• pp.664-670
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• 1993

Potassium tetratitanate (K2Ti4O9) and Potassium hexatitanate (K2Ti6O13) fibers have been prepared by the slow-cooling calcination process in a temperature range from 125$0^{\circ}C$ to 95$0^{\circ}C$ using the K2CO3 and TiO2 as the starting materials. Optimum fiber growth conditions have been also investigated by changing the physical parameters, such as calcination time and temperature, and cooling rate. Relatively long K2Ti4O9 fibers ( 1.2mm) have been grown with quite a high aspect ratio (c/a 500)when the starting material with a nominal composition of K2O and TiO2 with 1:4 was calcined at 115$0^{\circ}C$ for 4h, and then was slowly cooled to 95$0^{\circ}C$ with a rate of 2$0^{\circ}C$/h. In case of a K2O.6TiO2 composition, acicular shaped K2Ti6O13 fibers with 20~300${\mu}{\textrm}{m}$ long and low aspect ratio (c/a 10~15) have been formed irrespective of the coolign rate. The growth condition of fibers have been discussed based upon the phase diagram of K2O-TiOa2.

• 한국염색가공학회지
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• 제16권5호
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• pp.42-47
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• 2004

The main objective of this work is to develop melt-blown nonwoven fabric composite materials have electromagnetic shielding characteristics using thin copper film. Melt-blown nonwoven fabric is the matrix phase and thin copper films are the reinforcement of the composite materials. Thin copper films are incorporated as conductive fillers to provide the electromagnetic shielding property of the melt-blown nonwoven fabric. The width and interval of thin copper films in the nonwoven fabric are varied by changing 1, 3, 5 mm for thin copper film's width and 1, 3, 5 mm for thin copper film's interval. The shielding effectiveness(SE) of various melt-blown nonwoven fabrics is measured in the frequency range of 50 MHz to 1.8 GHz. The variations of SE of melt-blown nonwoven fabric with width and interval of thin copper films are described. Suitability of melt-blown nonwoven fabric for electromagnetic shielding applications is discussed. The results indicate that the melt-blown nonwoven fabric composite material using thin copper film can be used for the purpose of electromagnetic shielding.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.537-537
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• 2013

Cyclotron-accelerated ion beams are used for various researches, such as nuclear physics, nuclear chemistry, biotechnology, and material sciences including radio-isotope production. Recently considerable applications are asked to the cyclotron development undertaken to meet user requirements of various ions'energies, intensities, and their pulsed beams. For instance, a cocktail beam acceleration technique rapidly changing the ion species and energies was developed to irradiating integrated circuit chips. Also a chopping system in a cyclotron injection line is considered for producing a pulsed ion beam with a relatively long period compared with that generated by the resonance frequency. For the research in neutron time-of-flight measurement, a single-pulsed beam with a repetition interval of the order of mili-seconds or longer is necessary to have a good resolution and to remove background events. In this paper a feasibility of pulsed beam with an external ion source is simulated by adopting a combination system of a chopper accompanying with a bunching stage in the injection line and an additional chopper after the exit of the cyclotron in order to produce beam pulses with a range of $1{\mu}s{\sim}1ms$ periods from a resonance RF cycle. The pulseperiod will be adjusted by chopping the number of beam bunches from the injected pulses in the injection line. However, the longer pulses will have reduced number of beam pulses and sacrificed beam currents. Because the beam users need an intense single pulsed beam, a careful tuning of the acceleration phase and a high-intense external ion source are necessary to achieve an intense single-pulsed beam from the cyclotron. It is essential to strictly match the acceleration phase of injected beams in the central region of the cyclotron to improve its efficiency. An effect of space charge at each pulse from the ion source will be also considered.

• Steel and Composite Structures
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• 제1권4호
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• pp.427-440
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• 2001

The growing use of unprotected or partially protected steelwork in buildings has caused a lively debate regarding the safety of this form of construction. A good deal of recent research has indicated that steel members have a substantial inherent ability to resist fire so that additional fire protection can be either reduced or eliminated completely. A performance based philosophy also extends the study into the effect of structural continuity and the performance of the whole structural totality. As part of the structural system, thermal expansion during the heating phase or contraction during the cooling phase in most beams is likely to be restrained by adjacent parts of the whole system or sub-frame assembly due to compartmentation. This has not been properly addressed before. This paper describes an experimental programme in which unprotected steel beams were tested under load while it is restrained between two columns and additional horizontal restraints with particular concern on the effect of catenary action in the beams when subjected to large deflection at very high temperature. This paper also presents a three-dimensional mathematical modelling, based on the finite element method, of the series of fire tests on the part-frame. The complete analysis starts with an evaluation of temperature distribution in the structure at various time levels. It is followed by a detail 3-D finite element analysis on its structural response as a result of the changing temperature distribution. The principal part of the analysis makes use of an existing finite element package FEAST. The effect of columns being fire-protected and the beam being axially restrained has been modelled adequately in terms of their thermal and structural responses. The consequence of the beam being restrained is that the axial force in the restrained beam starts as a compression, which increases gradually up to a point when the material has deteriorated to such a level that the beam deflects excessively. The axial compression force drops rapidly and changes into a tension force leading to a catenary action, which slows down the beam deflection from running away. Design engineers will be benefited with the consideration of the catenary action.

• 한국초등과학교육학회지:초등과학교육
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• 제43권3호
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• pp.385-401
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• 2024

본 연구는 초등학교 교사 5인이 유니티 물리엔진을 활용하여 AR 과학교육 자료를 개발하고 그 과정에서 겪을 수 있는 경험과 논의한 사항에 대하여 단계별로 정리한 것이다. 교사들은 AR 자료개발을 위한 준비 단계에서 AR 기술의 특징을 탐색하였으며, 단원 선정에 대한 논의를 바탕으로 자기 단원에 자기장 관련 실험을 AR 자료로 제작하기로 하였다. 또한 C# 프로그래밍 언어에 대한 배경지식 부족으로 인한 어려움을 준비 단계에서 호소하였다. 자료개발의 단계에서는 유니티 프로그램의 생소한 인터페이스와 기능 조작에 대한 어려움이 있었으나 이는 교사들의 지식 공유와 협력적 의사소통으로 극복하는 모습을 보였다. 최종 개발한 자료는 마커 유형의 AR 자료이며 자석과 나침반 마커의 위치를 변화시키면서 실험 활동을 수행하는 자료였다. 개발한 자료를 바탕으로 교사들은 수업 활동에서의 원활한 활용 방안에 대하여 논의하였다.