• Title/Summary/Keyword: Phase change behavior

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Investigation on the Sintering Behavior of P/M Al-Zn-Mg-Cu Alloy

  • Shahmohammadi, M.;Simchi, A.;Danninger, H.;Arvand, A.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.536-537
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    • 2006
  • In the present work, the sintering behavior of high strength Al-5.6Zn-2.5Mg-1.6Cu (in wt.%) alloy compacts prepared from elemental powders was investigated. Microstructural evaluation was accompanied by XRD and DSC methods in order to determine the temperature and chemical composition of the liquid phases formed during sintering. It was found that three transient liquid phases are formed at 420, 439 and 450 $^{\circ}C$. Microstructural study revealed the progressive formation of sintered contacts due to the presence of the liquid phases, although the green compact expands as a result of the melt penetration along the grain boundaries. While Zn melts at ${\sim}420\;^{\circ}C$, the intermetallic phases formed between Al and Mg were found to be responsible for the formation of liquid phase and the dimensional change at higher temperatures.

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A Study of Chaotic Responses of an Elastic-Plastic Beam Model to Periodic Impulsive Force (주기적인 충격력을 받는 탄소성 보의 케이오틱거동 연구)

  • 이재영
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.5
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    • pp.1158-1167
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    • 1995
  • In this study, the dynamic instabilities of a beam, subjected to periodic short impulsive loading, are investigated using simple 2-DoF beam model. The behaviors of beam model whose axial motions are constrained are studied for the case of elastic and elastic-plastic behavior. In the case of elastic behavior, the chaotic responses due to the periodic pulse are identified, and the characteristics of the behavior are analysed by investigating the fractal attractors in the Poincare map. The short-term and long-term responses of the beam are unpredictable because of the extreme sensitivities to parameters, a hallmark of chaotic response. In the case of elastic-plastic behavior, the responses are governed by the plastic strains which occur continuously and irregularly as time increases. Thus the characteristics of the response behavior change continuously due to the plastic strain increments, and are unpredictable as well as the elastic case.

Experimental Study of Close-Contact Melting of Phase-Change Medium Partially Filled in a Horizontal Cylinder (수평원관내 부분적으로 채원진 상변화물질의 융해과정)

  • 서정세;노승탁
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.9
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    • pp.2249-2260
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    • 1995
  • An experiment of close contact melting of phase-change medium partially filled in an isothermally heated horizontal cylinder is performed which involves the volume expansion of liquid induced by the solid-liquid density difference. The solid-liquid interface motion and the free surface behavior of liquid were reported photographically. The experimental results show that the curvature of upper solid-liquid interface varied to flat as melting progresses. In addition to the varying interface shape, the melting rate increases with the lower initial height of solid and the free surface height of liquid increases linearly. The experimental results of molten mass fraction were expressed in a function of dimensionless time Fo.Ste$^{3}$4/ and agreed well with the analytical solutions.

A Study of the Characteristics of Cast Ni-Ti Alloy for Biomaterial with Compositional Change (정밀 주조한 생체용 Ni-Ti합금의 조성변화에 따른 특성 연구)

  • 권오원;김교한
    • Journal of Biomedical Engineering Research
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    • v.14 no.3
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    • pp.283-290
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    • 1993
  • In thls study, the effects of the composltional change of cast Ni-Ti alloys on its characteristics including mechanical properties, phase transformation temperature, and ion releasing rate were investigated. brittle:behavior was shown in the stress-strain curve of the alloy containing low Ti content (Ni-44.0%Ti). By increasing the Ti content, the trend in stress-strain curves changed from that of superelasticity to that of shape memory effect(Ni-44.4%Ti, Ni-45.1%Ti, Ni-45, 5%Ti). Phase transformation temperature ($A_f, {\;}M_5$ point) increased with increasing the Ti content. lon releasing rate of four types of Mi-Ti alloys was very low compared to that of the dental commerical Ni-Cr alloy.

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Numerical Calculation of Transformation Plasticity Using a FE Analysis Coupled with n Phase Field Model (상장모델과 유한요소법의 연계해석을 통한 변태소성 전산모사)

  • Cho, Y.G.;Kim, J.Y.;Cha, P.R.;Lee, J.K.;Han, H.N.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.318-321
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    • 2009
  • Transformation plasticity is that when a phase transformation of ferrous or non-ferrous alloys progresses even under an extremely small applied stress compared with a yield stress of the material, a permanent deformation occurs. One of widely accepted description for the transformation was proposed by Greenwood and Johnson [1]. Their description is based on an assumption that a weaker phase of an ideal plastic material could deform plastically to accommodate the externally applied stress and the internal stress caused by the volumetric change accompanying the phase transformation. In this study, an implicit finite element model was developed to simulate the deformation behavior of a low carbon steel during phase transformation. The finite element model was coupled with a phase field model, which could simulate the kinetics for ferrite to austenite transformation of the steel. The thermo-elasto-plastic constitutive equation for each phase was adopted to confirm the weaker phase yielding, which was proposed by Greenwood and Johnson [1]. From the simulation, the origin of the transformation plasticity was quantitatively discussed comparing with the other descriptions of it.

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Effect of Cooling Rate on Microstructural and Mechanical Properties of SAF 2205 Duplex Stainless Steel (SAF 2205 듀플렉스 스테인레스강의 미세조직 및 기계적 특성에 미치는 냉각속도의 영향)

  • Oh, Y.J.;Yang, W.J.;Lee, J.H.;Kim, D.H.;Yoo, W.D.;Lee, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.26 no.1
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    • pp.14-20
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    • 2013
  • Duplex stainless steel, which is a kind of stainless steel with a mixed microstructure of about equal proportions of austenite and ferrite, is generally known as a unique material with excellent corrosion resistance and high strength. However, toughness, strength, and corrosion resistance of the steel could be reduced due to precipitation of topologically closed packed phases such as sigma phase during cooling. In case of large forged products, they have strong possibility that ${\sigma}$-phase precipitates due to difference of cooling rate between surface and inner of the products. Investigation on sigma phase precipitation behavior of duplex stainless steel with change of cooling rate was carried out in this study. Forged SAF 2205 duplex stainless steel was used as specimens to examine the cooling rate effect. Dissolution behavior of sigma phase was also discussed through resolution test of duplex stainless steel containing lots of sigma phase. Experimental results revealed that impact energy was very sensitive to precipitation of small amount sigma phase. However, sigma phase could be removed by short term resolution treatment and impact resistance of the duplex stainless steel was restored.

Numerical Analysis of Phase Behavior and Flow Properties in an Injection Tubing during Gas Phase CO2 Injection : Application of Demonstration-scale Offshore CO2 Storage Project in the Pohang Basin, Korea (기체상태의 CO2 주입시 주입관내 상변화 및 유동 특성의 수치해석적 연구 : 포항분지 해상 중소규모 CO2 지중저장 사업에 적용)

  • Jung, Woodong;Sung, Wonmo;Han, Jeong-Min;Song, Youngsoo;Wang, Jihoon
    • Journal of the Korean Institute of Gas
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    • v.25 no.4
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    • pp.10-18
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    • 2021
  • CO2 storage technology in an aquifer is one of the most effective way to decrease global warming due to a high storage capacity and economics. A demonstration-scale offshore CO2 storage project was performed in a geological deep aquifer in the Pohang Basin, Korea for a technological development of large-scale CO2 storage. A challenging issue in the early design stage of the project was to establish the proper injectivity during CO2 injection. To solve this issue, injection conditions were calculated by calculating injection rate, pressure, temperature, CO2 phase change, and thermodynamic properties. For this study, we simulated and numerically analyzed CO2 phase change from gas to supercritical phase and flow behavior in transport piping and injection tubing using OLGA program. Our results provide the injectivity conditions of CO2 injection system combined with a bottomhole pressure of an aquifer.

The Effect of Calcium on Microstructure of AZ61 Magnesium Alloy during Annealing Heat Treatment (AZ61 마그네슘 합금의 어닐링 중 Ca의 첨가에 따른미세조직 변화에 미치는 영향)

  • Kim, Kibeom;Jeon, Joonho;Kim, Kwonhoo
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.2
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    • pp.53-59
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    • 2021
  • Due to high specific strength and low density, AZ series magnesium alloys have been receiving high interest as a lightweight material. However, their industrial application is limited due to the phenomenon that the strength decreases at elevated temperature by the occurrence of softening effect because of the Mg17Al12 phase decomposition. To solve this problem, many research were conducted to increase the high-temperature strength by forming a thermal stable second-phase component by adding new elements to the AZ magnesium. Especially, adding Ca to AZ magnesium has been reported that Ca forms the new second-phase. However, studies about the analysis of decomposition or precipitation temperature, formation composition, and components to understand the formation behavior of these precipitated phases are still insufficient. Therefore, the effect of Ca addition to AZ61 on the phase change and microstructure of the alloy during annealing was investigated. As a result of analysis of the initial and heat-treated specimen, AZ61 formed α-Mg matrix and precipitated phase of Mg17Al12, and AZX611 formed one more type of precipitated phase, Al2Ca. Also, Al2Ca was thermal stable at high temperatures. And after annealing, the laves phase was decomposed to under 10 ㎛ size and distributed in matrix.

L-CAA : An Architecture for Behavior-Based Reinforcement Learning (L-CAA : 행위 기반 강화학습 에이전트 구조)

  • Hwang, Jong-Geun;Kim, In-Cheol
    • Journal of Intelligence and Information Systems
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    • v.14 no.3
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    • pp.59-76
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    • 2008
  • In this paper, we propose an agent architecture called L-CAA that is quite effective in real-time dynamic environments. L-CAA is an extension of CAA, the behavior-based agent architecture which was also developed by our research group. In order to improve adaptability to the changing environment, it is extended by adding reinforcement learning capability. To obtain stable performance, however, behavior selection and execution in the L-CAA architecture do not entirely rely on learning. In L-CAA, learning is utilized merely as a complimentary means for behavior selection and execution. Behavior selection mechanism in this architecture consists of two phases. In the first phase, the behaviors are extracted from the behavior library by checking the user-defined applicable conditions and utility of each behavior. If multiple behaviors are extracted in the first phase, the single behavior is selected to execute in the help of reinforcement learning in the second phase. That is, the behavior with the highest expected reward is selected by comparing Q values of individual behaviors updated through reinforcement learning. L-CAA can monitor the maintainable conditions of the executing behavior and stop immediately the behavior when some of the conditions fail due to dynamic change of the environment. Additionally, L-CAA can suspend and then resume the current behavior whenever it encounters a higher utility behavior. In order to analyze effectiveness of the L-CAA architecture, we implement an L-CAA-enabled agent autonomously playing in an Unreal Tournament game that is a well-known dynamic virtual environment, and then conduct several experiments using it.

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Effect of Isochronic Aging on Transformation Behavior in Ti-50.85at%Ni Alloy (Ti-50.85atNi 합금의 변태거동 및 형상기억특성 미치는 시효처리의 영향)

  • Kim, J.I.;Sung, J.H.;Kim, Y.H.;Lee, J.H.;Miyazaki, S.
    • Journal of the Korean Society for Heat Treatment
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    • v.22 no.2
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    • pp.101-107
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    • 2009
  • Effect of isochronic aging on transformation behavior of Ti-50.85at%Ni alloy were investigated by differential scanning calorimeter (DSC). The martensitic transformation temperature increases with increasing annealing temperature until reaching a maximum, and then decreases with further increasing annealing temperature. This can be rationalized by interaction between the distribution of $Ti_3Ni_4$ precipitates and Ni content in the matrix. The R-phase transformation temperature increases with increasing annealing temperature until reaching a maximum, and then decreases with a further increase of annealing temperature. This is attributed to the change of Ni content in the matrix caused by precipitation of $Ti_3Ni_4$. The occurrence of the multiple-stage martensitic and R-phase transformation is attributed to precipitation-induced inhomogeneity of the matrix, both in terms of composition and of internal stress fields.