• 한국수소및신에너지학회논문집
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• 제27권6호
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• pp.712-720
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• 2016

When bioethanol and water are mixed at a proper ratio, phase separation can occur because of the immiscibility of biobutanol with water. Phase separation in bioethanol blends fuels is a major problem for gasoline vehicle users due to effect of octane number and component corrosion. Thus, in this study, the phase separation of bioethanol was examined effect of bioethanol blends (E3 (3 vo.% bioethanol in gasoline), E5 and E10) in presence of water. The effect were evaluated behavior with phase separation test, simulation test of fuel tank in gas station according to water addition volume and it was investigated change of water content, bioethanol content and octane number for gasoline phase in bioethanol blends (E3, E5 and E10) every 1 week after water addition. The E3 occurred phase separation more easily than the E5 and E10 in small water contents because solubility of water on ethanol content difference in gasoline-ethanol. It was kept a initial level of water content, bioethanol content, and octane number by repeated sample replacing in simulation test of fuel tank.

• 대한기계학회논문집B
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• 제24권6호
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• pp.886-893
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• 2000

The Characteristics of dividing the dispersed bubble, plug, and slug steam-water flow in the horizontal junctions with horizontal branches have been experimentally investigated. The experimental investigation of the separation phenomena in a $45^{\circ}$ horizontal wye with equal pipe inner diameter of 25 mm is presented to provide a data base for the development and verification of the analytical models. The phase separation and pressure distribution in the three legs of each test section are obtained through the set of measurements made in the present work. And the dependence of phase separation on different parameters, such as inlet quality and mass flux, is discussed.

• 설비공학논문집
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• 제16권9호
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• pp.828-837
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• 2004

The present study investigated two-phase flow distribution, phase separation and pressure drop in multi-microchannel tubes under adiabatic condition. The test section consisted of inlet and outlet headers with the inner diameter of 19.4㎜ and 15 parallel microchannel tubes. Each microchannel tube brazed to the inlet and outlet headers and had 8 rectangular ports with the hydraulic diameter of 1.32㎜. The key experimental parameters were orientation of header (horizontal and vertical), flow direction of refrigerant into the inlet header (in-line, parallel and cross flow) and inlet quality (0.1, 0.2 and 0.3). It was found that the orientation of the header had relatively large effect on the flow distribution and phase separation, while the inlet quality didn't affect much on them. The horizontal header showed the better flow distribution and phase separation characteristics than the vertical one. The parallel flow condition with the horizontal header showed the best performance for the flow distribution and phase separation characteristics under the test conditions. Two-phase pressure drops through the microchannel tubes with the horizontal header were higher than those of the microchennel tubes with the vertical header due to gravitational effect.

• 한국세라믹학회지
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• 제34권8호
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• pp.886-896
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• 1997

To investigate an effect of phase separation on precipitation characteristics of CuCl nanocrystals in CuCl doped nonlinear optical glasses, borosilicate glass systems with 9 different compositions with ~2wt% of CuCl were selected and CuCl doped glasses were prepared by melting and precipitation method. Microstructural properties of the CuCl doped glasses were analyzed by optical absorption spectroscopy, acid elution test, TEM, and EDXS. While phase separation did not occur in Glass A~D, interconnected and droplet microstructures due to phase separation were found in Glass E, F and Glass G~I, respectively. In the particular composition of the matrix glasses in this study, the precipitation of the CuCl particles was observed in the phase separable glasses, not in phase non-separable glasses. The CuCl particles were precipitated in both silica-rich phase region and boronrich phase region of the glass matrix. In the case of 7.7Na2O-36.6B2O3-52.7SiO2(mole%) glass, the larger CuCl particles than those in the silica-rich phase region were observed in the boron-rich phase region.

• FOCUS: LIFE SCIENCE
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• 제1호
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• pp.9.1-9.5
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• 2024

Method development for complex low molecular mass (LMM) samples using reversed-phase (RP) separation conditions presents significant challenges due to the presence of many unknown analytes over wide concentration ranges. This guide aims to optimize method parameters-column length (L), temperature (T), flow rate (F), and final mobile phase conditions (Øfinal)-to maximize separation peak capacity. Validated by prior research, this protocol benefits laboratories dealing with metabolomics, natural products, and contaminant screening. This practical guide provides a structured approach to maximizing peak capacity for complex LMM separations. It complements computational optimization strategies and offers a step-by-step method development process. The Snyder-Dolan test is highlighted as essential for determining the need for gradient or isocratic elution and guiding column length decisions. The decision tree framework helps analysts prioritize variable optimization to develop effective separation methods for complex samples.

• Archives of Pharmacal Research
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• 제22권6호
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• pp.614-618
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• 1999

A reversed-phase high-performace liquid chromatographic method was developed to determine the optical purity of metoprolol enantiomers. The enantiomers were converted to diastereomeric derivatives using (-)-menthyl chloroformate reagent. Separation of the enantiomers as diastereomers was achieved by reversed-phase HPLC within 30 min using Inertsil C8 column. This method allowed determination of 0.05% of either enantiomer in the presence of its stereoisomer and method validation showed adequate linearity over the required range. Owing to the reaction condition during the derivatization with (-)-menthyl chloroformate, the possibility of racemization had to be established. Different ratios of (S)-(-)-metoprolol and (R)-(+)-metoprolol were prepared. Enantiomeric separation of these mixtures took place on a chiralcel OD column or, after derivatization with (-)-menthyl chloroformate, on a C8 column. The results form the these two independent separation systems were compared with trace racemization and were in very good agreement. No racemization was found during the experiment.

• Elastomers and Composites
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• 제43권3호
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• pp.191-198
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• 2008

아스팔트 개질재로 쓰이고 있는 폴리에틸렌은 아스팔트와의 비중차와 비상용성으로 인하여 상분리가 일어난다고 알려지고 있다. 본 연구에서는 상분리를 억제하기 위하여 폴리에틸렌을 가교시킬 수 있는 것으로 알려지고 있는 과산화물을 사용하여 상분리 억제를 시도하였다. 폴리에틸렌 수지로는 폐비닐을 사용하였으며, 과산화물로는 디큐밀퍼옥사이드와 로로일퍼옥사이드를 사용하였다. 현미경상으로는 과산화물이 첨가되어 상분리가 억제되었다. 그러나 유변물성을 측정한 결과는 아스팔트와 폴리에틸렌은(비록 폴리에틸렌이 가교된다 하더라도) 분자단위에서는 서로 섞일 수 없음을 보여주고 있다. 기계적 시험(인장강도, 마샬안정도, 동적안정도)에서는 매우 우수한 물성을 보여주어 소성변형에 대한 저항성이 크게 향상된 것으로 나타났고, 이는 기존의 슈퍼팔트보다 우수한 것으로 나타났다.

• 산업기술연구
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• 제19권
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• pp.189-195
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• 1999

A study on the separation Cu, Ni, and Co was carried out using LIX 84 leachate, chelate extractant. For this test, artificial test solution was prepared by varing concentrations of Cu, Ni, Co, $(NH_4)_2CO_3$ and $(NH_4)_2SO_4$. It found that pH of the solution was very important factor for the separation of nickel from copper. The results showed that nickel was effectively extracted from copper by using LIX 84 at pH 1.0 to 1.2. The volume ration or organic to aqueous phases was 1.0. According to the McCabe-Thiele diagram, the extraction rate of copper was 99 percents at the equal ratio of organic to aqueous phase in three stages.

• 한국막학회:학술대회논문집
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• 한국막학회 2003년도 The 4th Korea-Italy Workshop
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• pp.103-105
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• 2003

A chiral stationary phase (CSP) was synthesized by the modification of the chitosan using N-nicotinoyl phenylalanine and 3, 5-dimethylphenylisocyanate . The CSP based on the chitosan was then characterized in terms of their chemical structure and physical properties. To test its performance as a CSP, the silica powder with 5 ${\mu}{\textrm}{m}$ of diameter were coated with the CSP to pack a column for High Performance Liquid Chromatograph (HPLC). Using the packed column, several racemates were tried to separate under various separation conditions with different compositions of eluents.

• The Journal of Advanced Prosthodontics
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• 제2권3호
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• pp.102-105
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• 2010

PURPOSE. The aims of this study were to suggest a method of fabrication of the record base using a light-polymerized resin by applying the two-phase fabrication method for the improvement of the fit of the record base and to compare the degree of fit according to the separation site. MATERIALS AND METHODS. In the edentulous cast of maxilla, four test groups were considered. In the first, second, third, and fourth test groups (n = 12 in each group) the separation was done at 0, 5, 10, and 15 mm, respectively below the alveolar crest along the palatal plane. For the control group, the record base was made without separating the two sections. The light-body silicone material was injected into the fitting surface of the record base. It was then placed onto the cast and finger pressure was applied to stabilize it in a seated position followed by immediate placement onto the universal test device. Finally, the mass of the impression material was measured after it was removed. ANOVA was performed using the SAS program. For the post-hoc test, the Wilcoxon Rank-Sum test and the Tukey-Kramer HSD test were performed ($\alpha$ = 0.05). RESULTS. The control group and Group 3, 4 showed significant differences. The Group 3 and 4 showed significantly smaller inside gaps than the control group which was not made with the two-phase fabrication method. CONCLUSION. The two-stage polymerized technique can improve the fit of the denture base particularly when the separation was made at 10 to 15 mm from the alveolar crest.