• 제목/요약/키워드: Phase Behavior

검색결과 2,970건 처리시간 0.028초

Ti3C2Tx MXene의 열처리에 따른 구조적, 전기적 특성 변화 (Changes in the Structural and Electrical Properties of Ti3C2Tx MXene Depending on Heat Treatment)

  • 김자현;노진서
    • 한국재료학회지
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    • 제32권5호
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    • pp.264-269
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    • 2022
  • Ti3C2Tx MXene, which is a representative of the two-dimensional MXene family, is attracting considerable attention due to its remarkable physicochemical and mechanical properties. Despite its strengths, however, it is known to be vulnerable to oxidation. Many researchers have investigated the oxidation behaviors of the material, but most researches were conducted at high temperatures above 500 ℃ in an oxidation-retarding environment. In this research, we studied changes in the structural and electrical properties of Ti3C2Tx MXene induced by low-temperature heat treatments in ambient conditions. It was found that a number of TiO2 particles were formed on the MXene surface when it was mildly heated to 200 ℃. Heating the material to higher temperatures, up to 400 ℃, the phase transformation of Ti3C2Tx MXene to TiO2 was accelerated, resulting in a TiO2/Ti3C2Tx hybrid. Consequently, the metallic nature of pure Ti3C2Tx MXene was transformed to semiconductive behavior upon heat-treating at ≥ 200 ℃. The results of this research clearly demonstrate that Ti3C2Tx MXene may be easily oxidized even at low temperatures once it is exposed to air.

On the wave dispersion and vibration characteristics of FG plates resting on elastic Kerr foundations via HSDT

  • Bennai, Riadh;Fourn, Hocine;Nebab, Mokhtar;Atmane, Redhwane Ait;Mellal, Fatma;Atmane, Hassen Ait;Benadouda, Mourad;Touns, Abdelouahed
    • Advances in concrete construction
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    • 제14권3호
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    • pp.169-183
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    • 2022
  • In this article, vibrational behavior and wave propagation characteristics in (FG) functionally graded plates resting on Kerr foundation with three parameters is studied using a 2D dimensional (HSDT) higher shear deformation theory. The new 2D higher shear deformation theory has only four variables in field's displacement, which means has few numbers of unknowns compared with others theories. The shape function used in this theory satisfies the nullity conditions of the shear stresses on the two surfaces of the FG plate without using shear correction factors. The FG plates are considered to rest on the Kerr layer, which is interconnected with a Pasternak-Kerr shear layer. The FG plate is materially inhomogeneous. The material properties are supposed to vary smoothly according to the thickness of the plate by a Voigt's power mixing law of the volume fraction. The equations of motion due to the dynamics of the plate resting on a three-parameter foundation are derived using the principle of minimization of energies; which are then solved analytically by the Navier technique to find the vibratory characteristics of a simply supported plate, and the wave propagation results are derived by using the dispersion relations. Perceivable numerical results are fulfilled to evaluate the vibratory and the wave propagation characteristics in functionally graded plates and some parameters such wave number, thickness ratio, power index and foundation parameters are discussed in detail.

Fused Deposition Modeling of Iron-alloy using Carrier Composition

  • Harshada R. Chothe;Jin Hwan Lim;Jung Gi Kim;Taekyung Lee;Taehyun Nam;Jeong Seok Oh
    • Elastomers and Composites
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    • 제58권1호
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    • pp.44-56
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    • 2023
  • Additive manufacturing (AM) or three-dimensional (3D) printing of metals has been drawing significant attention due to its reliability, usefulness, and low cost with rapid prototyping. Among the various AM technologies, fused deposition modeling (FDM) or fused filament fabrication is receiving much interest because of its simple manufacturing processing, low material waste, and cost-effective equipment. FDM technology uses metal-filled polymer filaments for 3D printing, followed by debinding and sintering to fabricate complex metal parts. An efficient binder is essential for producing polymer filaments and the thermal post-processing of printed objects. This study involved an in-depth investigation of and a fabrication route for a novel multi-component binder system with steel alloy powder (45 vol.%) ranging from filament fabrication and 3D printing to debinding and sintering. The binder system consisted of polyvinyl pyrrolidone (PVP) as a binder and thermoplastic polyurethane (TPU) and polylactic acid (PLA) as a carrier. The PVP binder held the metal components tightly by maintaining their stoichiometry, and the TPU and PLA in the ratio of 9:1 provided flexibility, stiffness, and strength to the filament for 3D printing. The efficacy of the binder system was examined by fabricating 3D-printed cubic structures. The results revealed that the thermal debinding and sintering processes effectively removed the binder/carrier from the cubic structures, resulting in isotropic shrinkage of approximately 15.8% in all directions. The scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) patterns displayed the microstructure behavior, phase transition, and elemental composition of the 3D cubic structure.

Water film covering characteristic on horizontal fuel rod under impinging cooling condition

  • Penghui Zhang;Bowei Wang;Ronghua Chen;G.H. Su;Wenxi Tian;Suizheng Qiu
    • Nuclear Engineering and Technology
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    • 제54권11호
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    • pp.4329-4337
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    • 2022
  • Jet impinging device is designed for decay heat removal on horizontal fuel rods in a low temperature heating reactor. An experimental system with a fuel rod simulator is established and experiments are performed to evaluate water film covering capacity, within 0.0287-0.0444 kg/ms mass flow rate, 0-164.1 kW/m2 heating flux and 13.8-91.4℃ feeding water temperature. An effective method to obtain the film coverage rate by infrared equipment is proposed. Water film flowing patterns are recoded and the film coverage rates at different circumference angles are measured. It is found the film coverage rate decreases with heating flux during single-phase convection, while increases after onset of nucleate boiling. Besides, film coverage rate is found affected by Marangoni effect and film accelerating effect, and surface wetting is significantly facilitated by bubble behavior. Based on the observed phenomenon and physical mechanism, dry-out depth and initial dry-out rate are proposed to evaluate film covering potential on a heating surface. A model to predict film coverage rate is proposed based on the data. The findings would have reliable guide and important implications for further evaluation and design of decay heat removal system of new reactors, and could be helpful for passive containment cooling research.

복합재료 스트립과 스프링을 갖는 형상기억합금 작동기의 거동 (Behavior of a Shape Memory Alloy Actuator with Composite Strip and Spring)

  • 허석;황도연;최재원;박훈철;구남서
    • Composites Research
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    • 제22권2호
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    • pp.37-42
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    • 2009
  • 이 논문은 형상기억합금 선재를 이용한 굽힘 작동기의 실험적인 설계방법을 다루고 있다. 제안된 굽힘 작동기는 유리섬유 프리프레그를 이용하여 만든 스트립, 스프링 그리고 형상기억합금 선재로 구성된다. 굽힘 작동기에서 스트립은 초기에 형상기억합금 선재에 초기하중을 가하기 위하여 굽힘 형태로 정되며, 스프링은 형상기억합금 선재가 작동 후 빠른 시간내에 초기 형상으로 돌아오기 위한 보조수단으로 사용된다. 먼저 형상기억합금 선재의 특성을 알아보기 위하여 시차주사열량계(DSC)를 이용한 실험, 여러 종류의 초기 하중을 가한 후 작동 성능 실험, 인장 시험, 온도 변화에 따른 기계적 거동을 조사하였다 이를 바탕으로 스트립, 스프링, 인가 전압에 의한 영향을 관찰하고 소모전력을 분석하여 굽힘 작동기를 설계하였다. 특정 조건을 갖는 굽힘 작동기는 낮은 소모전력으로 빠른 응답성능을 나다내었다.

Experimental study on the shear failure model for concrete under compression-shear loading

  • Shu, Xiaojuan;Luo, Yili;Zhao, Chao;Dai, Zhicheng;Zhong, Xingu;Zhang, Tianyu
    • Computers and Concrete
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    • 제29권2호
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    • pp.81-92
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    • 2022
  • The influence of normal stress perpendicular to the potential shear plane was always neglected in existing researches, which may lead to a serious deviation of the shear strength of concrete members in practice designs and numerical analyses. In this study, a series of experimental studies are carried out in this paper, which serves to investigate the shear behavior of concrete under compression shear loading. Based on the test results, a three-phase shear failure model for cohesive elements are developed, which is able to take into consideration the influence of normal stress on the shear strength of concrete. To identify the accuracy and applicability of the proposed model, numerical models of a double-noted concrete plate are developed and compared with experimental results. Results show that the proposed constitutive model is able to take into consideration the influence of normal stress on the shear strength of concrete materials, and is effective and accurate for describing the complex fracture of concrete, especially the failure modes under compression shear loadings.

Improvement and validation of aerosol models for natural deposition mechanism in reactor containment

  • Jishen Li ;Bin Zhang ;Pengcheng Gao ;Fan Miao ;Jianqiang Shan
    • Nuclear Engineering and Technology
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    • 제55권7호
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    • pp.2628-2641
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    • 2023
  • Nuclear safety is the lifeline for the development and application of nuclear energy. In severe accidents of pressurized water reactor (PWR), aerosols, as the main carrier of fission products, are suspended in the containment vessel, posing a potential threat of radioactive contamination caused by leakage into the environment. The gas-phase aerosols suspended in the containment will settle onto the wall or sump water through the natural deposition mechanism, thereby reducing atmospheric radioactivity. Aiming at the low accuracy of the aerosol model in the ISAA code, this paper improves the natural deposition model of aerosol in the containment. The aerosol dynamic shape factor was introduced to correct the natural deposition rate of non-spherical aerosols. Moreover, the gravity, Brownian diffusion, thermophoresis and diffusiophoresis deposition models were improved. In addition, ABCOVE, AHMED and LACE experiments were selected to validate and evaluate the improved ISAA code. According to the calculation results, the improved model can more accurately simulate the peak aerosol mass and respond to the influence of the containment pressure and temperature on the natural deposition rate of aerosols. At the same time, it can significantly improve the calculation accuracy of the residual mass of aerosols in the containment. The performance of improved ISAA can meet the requirements for analyzing the natural deposition behavior of aerosol in containment of advanced PWRs in severe accident. In the future, further optimization will be made to address the problems found in the current aerosol model.

Computational intelligence models for predicting the frictional resistance of driven pile foundations in cold regions

  • Shiguan Chen;Huimei Zhang;Kseniya I. Zykova;Hamed Gholizadeh Touchaei;Chao Yuan;Hossein Moayedi;Binh Nguyen Le
    • Computers and Concrete
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    • 제32권2호
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    • pp.217-232
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    • 2023
  • Numerous studies have been performed on the behavior of pile foundations in cold regions. This study first attempted to employ artificial neural networks (ANN) to predict pile-bearing capacity focusing on pile data recorded primarily on cold regions. As the ANN technique has disadvantages such as finding global minima or slower convergence rates, this study in the second phase deals with the development of an ANN-based predictive model improved with an Elephant herding optimizer (EHO), Dragonfly Algorithm (DA), Genetic Algorithm (GA), and Evolution Strategy (ES) methods for predicting the piles' bearing capacity. The network inputs included the pile geometrical features, pile area (m2), pile length (m), internal friction angle along the pile body and pile tip (Ø°), and effective vertical stress. The MLP model pile's output was the ultimate bearing capacity. A sensitivity analysis was performed to determine the optimum parameters to select the best predictive model. A trial-and-error technique was also used to find the optimum network architecture and the number of hidden nodes. According to the results, there is a good consistency between the pile-bearing DA-MLP-predicted capacities and the measured bearing capacities. Based on the R2 and determination coefficient as 0.90364 and 0.8643 for testing and training datasets, respectively, it is suggested that the DA-MLP model can be effectively implemented with higher reliability, efficiency, and practicability to predict the bearing capacity of piles.

Ensembles of neural network with stochastic optimization algorithms in predicting concrete tensile strength

  • Hu, Juan;Dong, Fenghui;Qiu, Yiqi;Xi, Lei;Majdi, Ali;Ali, H. Elhosiny
    • Steel and Composite Structures
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    • 제45권2호
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    • pp.205-218
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    • 2022
  • Proper calculation of splitting tensile strength (STS) of concrete has been a crucial task, due to the wide use of concrete in the construction sector. Following many recent studies that have proposed various predictive models for this aim, this study suggests and tests the functionality of three hybrid models in predicting the STS from the characteristics of the mixture components including cement compressive strength, cement tensile strength, curing age, the maximum size of the crushed stone, stone powder content, sand fine modulus, water to binder ratio, and the ratio of sand. A multi-layer perceptron (MLP) neural network incorporates invasive weed optimization (IWO), cuttlefish optimization algorithm (CFOA), and electrostatic discharge algorithm (ESDA) which are among the newest optimization techniques. A dataset from the earlier literature is used for exploring and extrapolating the STS behavior. The results acquired from several accuracy criteria demonstrated a nice learning capability for all three hybrid models viz. IWO-MLP, CFOA-MLP, and ESDA-MLP. Also in the prediction phase, the prediction products were in a promising agreement (above 88%) with experimental results. However, a comparative look revealed the ESDA-MLP as the most accurate predictor. Considering mean absolute percentage error (MAPE) index, the error of ESDA-MLP was 9.05%, while the corresponding value for IWO-MLP and CFOA-MLP was 9.17 and 13.97%, respectively. Since the combination of MLP and ESDA can be an effective tool for optimizing the concrete mixture toward a desirable STS, the last part of this study is dedicated to extracting a predictive formula from this model.

자원 이송용 파이프라인의 내리기 단계에서 평면 거동 평가를 위한 해석 모델 (2D Analytical Model to Evaluate Behavior of Pipeline in Lowering Phase)

  • 김정석;안기용
    • 한국건설순환자원학회논문집
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    • 제11권4호
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    • pp.467-475
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    • 2023
  • 본 논문에서는 내리기 시 파이프라인의 단면력 해석을 위한 합리적인 해석 모델을 제안했다. 본 해석 모델은 기하학적 특성과 경계조건을 고려하여 파이프라인을 분할한 후 two parameters Beam On Elastic Foundation과 Euler-Bernoulli 빔으로 모델링했다. 또한 파이프라인과 지반의 상호 작용 뿐만 아니라 파이프라인에 작용하는 축력을 했다. 기존 모델은 정형화된 하중 조건만 적용이 용이했으나 Segmented Pipeline Model로 정의된 제안 모델은 내리기 시 발생되는 대부분의 시공 조건에 대해 고려할 수 있다. 또한 가정을 최소화하고 요소를 세분화하여 모델링의 편의성과 적용성을 향상시켰다. 그럼에도 불구하고 이 모델은 FE 모델에 대비 높은 정확도를 갖고 있으므로 내리기 시 파이프라인의 안전성 평가는 물론 형상관리에도 효율적으로 활용될 수 있을 것으로 기대된다. 또한 시공 단계에서 파이프라인의 안전성을 확보함에 따라 운용 중 내구성 향상에 큰 도움이 될 것으로 판단된다.