• 제목/요약/키워드: Petroleum by-products

검색결과 150건 처리시간 0.023초

대두유의 Methyl Ester와 수지 분자량에 따른 평판 잉크의 물성 변화에 관한 연구 (The Variation of Offset Ink Properties According to Methyl Ester of Soy Oil and Resin Molecular Weight)

  • 박정민;김성빈
    • 한국인쇄학회지
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    • 제29권1호
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    • pp.45-59
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    • 2011
  • According as gradually increasing the demand for Eco-friendly products it has been progressed fairly development at a field of printing and printing inks. The Inks are used by soy oil beginning of ink industry for preventing environment. Now it is possible to make Eco-friendly inks with vegetable ester. So it is not necessary to use petroleum-based solvents for preventing environment. But There is some problems if using vegetable ester to inks. Vegetable ester has high solubility, it causes misting and low viscosity of the Inks. So resin is required high performance. Thus, in this paper, I studied about the properties variation of the Varnish and inks According to using the phenolic modified rosin ester and Soy oil Methyl esters. The compared in order of average molecular weight by the GPC method, rheological properties were found by rotational rheometer, and emulsion behavior were compared by high speed emulsification tester.

Recovery sub micron-graphitized carbon from oil fly ash

  • Hsieh, Ya-Min;Tsai, Min-Sing;Tsai, Shang-Lin
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.633-637
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    • 2001
  • Oil fly ash is known as one source of raw materials from which vanadium and nickel metals can be recovered. The current recovery process of valuable metals from oil fly ash is mainly the hydrormetallurgy one. Nevertheless, a great amount about 50~80%, of unburned carbon remains as byproduct after hydrormetallursy process. In Taiwan, if hydrormetallursy processes have proceeded, it can be estimated that the annual production of unburned carbon is 25 thousand tons. From the viewpoint of resource recycling, this study is a preliminary study and investigates in recovery of sub micron- graphitized carbon from unburned carbon by a designed process. The designed process included the following steps: 1.selecting a portion with +400mesh size from unburned carbon; 2.treating the selected in ultrasonic waves; 3.using a 400mesh sieve to obtain the product which is under 400mesh; 4.Removal ash from the product. In regard to treatment by ultrasonic waves in the designed process, treating time of ultrasonic waves is a simple and only variance in this study. The results indicate that the production yields increase with the treating time of ultrasonic waves; the production yield in specific conditions of this study can reach about 23%, in which ash content in product is about 2.5%. According to results of SEM, TEM and XRD, the products from the designed process are flakes in shape, several microns in size and graphitized carbon in carbon crystal phase. Except to graphitized carbon, there are a little carbon blacks, which are graphite 2H in carbon crystal phase in the products. Conclusively, the designed process is possibly applicable, by which comes to the recovery of micron- graphitized carbon.

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Fungal Fermentation of Lignocellulosic Biomass for Itaconic and Fumaric Acid Production

  • Jimenez-Quero, A.;Pollet, E.;Zhao, M.;Marchioni, E.;Averous, L.;Phalip, V.
    • Journal of Microbiology and Biotechnology
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    • 제27권1호
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    • pp.1-8
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    • 2017
  • The production of high-value chemicals from natural resources as an alternative for petroleum-based products is currently expanding in parallel with biorefinery. The use of lignocellulosic biomass as raw material is promising to achieve economic and environmental sustainability. Filamentous fungi, particularly Aspergillus species, are already used industrially to produce organic acid as well as many enzymes. The production of lignocellulose-degrading enzymes opens the possibility for direct fungal fermentation towards organic acids such as itaconic acid (IA) and fumaric acid (FA). These acids have wide-range applications and potentially addressable markets as platform chemicals. However, current technologies for the production of these compounds are mostly based on submerged fermentation. This work showed the capacity of two Aspergillus species (A. terreus and A. oryzae) to yield both acids by solid-state fermentation and simultaneous saccharification and fermentation. FA was optimally produced at by A. oryzae in simultaneous saccharification and fermentation (0.54 mg/g wheat bran). The yield of 0.11 mg IA/g biomass by A. oryzae is the highest reported in the literature for simultaneous solid-state fermentation without sugar supplements.

Investigation of gene encoding catechol 1,2-dioxygenase from Phenol-degrading, Rhodococcus sp. EL-GT

  • 이희정;한창민;조순자;박근태;박재림;이상준
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2001년도 추계학술발표대회
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    • pp.549-551
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    • 2001
  • 본 연구는 방향족 화합물질 중 페놀폐수에 대한 생물학적 처리를 위해 본 실험실에서 분리한 페놀분해능이 우수한 Rhodococcus sp. EL-GT를 이용하여 catechol 분해 catechol 1,2-dioxygenase 분해활성을 측정하였고, 이것이 ortho-pathway임을 확인할 수 있었다. 또한 다른 연구에서 보고되 Phodococcus rhodochrous NCIMB임을 확인할 수 있었다. 또한 다른 연구에서 보고된 Rhodococcus rhodochrous NCIMB 13259 균주의 catechol 1,2 dioxygenase를 기초로한 primer를 이용하여 PCR을 수행하였으며 이 분해 유전자의 cloning실험을 수행 중이다. 이들 실험을 통하여 Rhodococcus sp. EL-GT의 페놀분해 균의 유전적 구조 및 특징을 검토하고 이를 이용하여 방향족 화합물의 분해능이 보다 우수한 균주의 개발을 시도하고자 한다.

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The Microcosm study for evaluating biobarrier application on sequential degradation of TCE products by Gasoline-Degradaing Mixed Culture

  • Lee, Jae-Sun;Lee, Si-Jin;Lee, Young-Kee;Chang, Soon-Woong
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2003년도 생물공학의 동향(XIII)
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    • pp.440-444
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    • 2003
  • 본 연구에서는 난분해성 물질인 액상의 TCE가 영가철 표면에서 반응시 완전히 분해가 되지 않은 상태에서 생성되어지는 부산물인 Cis-DCE와 VC의 톨루엔 분해균주에 의한 처리 가능성을 회분식 실험으로 관찰하였다. 각각 2ppm의 Cis-DCE와 VC에 톨루엔 균주를 주입한 결과 1차기질로 톨루엔을 사용하고 그후에 Cis-DCE와 VC를 제거 하는 것으로 나타났다. 또한 동시에 주입시 1차기질로 톨루엔을 사용하는 것은 동일하나 VC를 먼저 사용하고 그후에 Cis-DCE를 제거하며 제거 속도 또한 줄여드는 것으로 나타났다.

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Emergy 분석법에 의한 제조업의 환경친화성지수 개발 (Development of Environmental Responsibility Index for the Manufacturing Industry by Emergy Analysis)

  • 제윤미;이성모
    • 한국환경과학회지
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    • 제13권4호
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    • pp.349-357
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    • 2004
  • Emergy is a measure of the processes required to produce something expressed in units of the same energy form. Emergy based indices can provide insights into the thermodynamic efficiency of the process, the quality of its output, and the interaction between the process and its surrounding environment. However, in an industrial system, the inputs are mostly nonrenewable, renewable energy source is nearly zero, ultimate purpose is pursuit of profits in economic activity. In study, we present two indices based on emergy - EEE(Ecological Economic Efficiency) and ERI(Environmental Responsibility Index). The EEE is taken into account real value of product in market economy. The ERI is shown to be a function of the net yield of the economy, its ‘load’ on the environment and ecological economic efficiency. Manufacturing industry of Korea produced the 30% of total GDP in 2001. We applied these indices to manufacturing industry for environmental management and further sustainable industry. As a results, the highest ERI is 0.34 in recycling industries, the lowest ERI is 0.01 in coke, refined petroleum products which is dominated by ELR. The higher ERI, the more friendly to environment. The suggested indices help us understand relative contributions of various alternatives in company's production and consumption activity, and provide a tool of decision-making for the rearrangement of future industries. Furthermore, they contribute to environmental friendly operation and consumption.

大豆油의 말레酸化生成物의 分別에 關한 硏究 (Studies on the Separation of Maleic Anhydride Adducts of Soybean Oil)

  • 박서호
    • 대한화학회지
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    • 제21권1호
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    • pp.67-72
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    • 1977
  • 말레酸化大豆油의 附加生成物의 分別과 그 特性을 究明하기 위하여 大豆油 助成 成分인 올레酸과 리놀酸을 말레酸無水物과 反應시켜, 이를 TLC에 依하여 分別하였다. 展開溶劑로서는 石油에테르 : 디에틸에테르 = 7 : 3∼5 : 5(vol/vol)에서 가장 分別이 잘 되었으며, 4區分으로 各各 分別되었으며, 이中에서 主生成物인 第 2區分을 IR 및 UV에 依하여 儉素한 結果는 올레酸附加物과 리놀酸附加物은 succinic acid 型 附加를 하고 있으며, 짝지은 디엔 $C_{18}$ 脂肪酸은 cyclohexene型의 附加를 이루고 있음을 確認 하였다.

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동·식물성 유지를 이용한 바이오디젤 생산에 관한 연구 (Yield and Characterization of Various Biodiesel from Vegetable Oils and Animal Fats)

  • 이태성;이영화;김광수;김욱;김관수;장영석;박광근
    • 신재생에너지
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    • 제8권4호
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    • pp.30-37
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    • 2012
  • Biodiesel was produced by "transesterification" of vegetable oils and animal fats as an alternative to petroleum diesel. The research analysed the fuel characteristics of biodiesel, the yield of by-products and biodiesel, using several vegetable oils - rapeseed oil, camellia oil, peanut oil, sesame oil, perilla oil, palm oil, olive oil, soybean oil, sunflower oil and animal fats such as lard, tallow, and chicken fat. The results showed the yields of biodiesel made from the vegetable oils and animal fats were $90.8{\pm}1.4{\sim}96.4{\pm}0.9%$ and $84.9{\pm}1.1{\sim}89.6{\pm}1.5%$ respectively. Production rates and oxidation characteristics were different depending on the fats applied.

Overcoming Electrical Energy Efficiency Gap in Nepal's Residential Sector

  • Thapa, Shahadev;Kim, Yun Seon
    • Asia Pacific Journal of Business Review
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    • 제3권1호
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    • pp.19-38
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    • 2018
  • The energy intensity of Nepal is economically not worthy, lacks eco-friendly and importantly not sustainable, and almost four times the average global energy intensity. Considerable efforts have been exercised to reduce the energy gap yet, it is still much to achieve. Nation priority on energy sector was envisaged with promulgation of investment friendly rules and law in hydropower and renewable technology even though, could not harness the sufficient energy. In amid of this acute energy crisis, the government launched the Nepal Energy Efficiency Programme (NEEP) with technical assistance from German International Cooperation (GIZ). Energy Efficiency (EE) practice is the most cost-effective method to reduce the supply and demand gap, reduce on greenhouse gases and pollution, and deter on import of petroleum products which finally improves on trade imbalance. This paper had proposed a framework of energy management team to promote energy efficient technologies in residential consumer. The energy management teams study the past records of energy use pattern of consumers and suggest appropriate technology for energy saving options. The paper provides some reviews of energy efficiency initiatives undertaken by the concern regulatory body which highlights the current status. The comprehensive knowledge acquired through exploratory research is implemented in this paper to identify the various barriers that domestic consumer is experiencing towards the active participation in energy efficiency program launched by the Government of Nepal.

The impact of corrosion on marine vapour recovery systems by VOC generated from ships

  • Choi, Yoo Youl;Lee, Seok Hee;Park, Jae-Cheul;Choi, Doo Jin;Yoon, Young Soo
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제11권1호
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    • pp.52-58
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    • 2019
  • Marine emissions of Volatile Organic Compounds (VOCs) have received much attention because the International Maritime Organization (IMO) requires the installation of vapour emission control systems for the loading of crude oils or petroleum products onto ships. It was recently recognised that significant corrosion occurs inside these vapour emission control systems, which can cause severe clogging issues. In this study, we analysed the chemical composition of drain water sampled from currently operating systems to investigate the primary causes of corrosion in vapour recovery systems. Immersion and electrochemical tests were conducted under simulated conditions with various real drain water samples, and the impact of corrosion on the marine vapour recovery system was carefully investigated. Moreover, corrosion tests on alternative materials were conducted to begin identifying appropriate substitutes. Thermodynamic calculations showed the effects of environmental factors on the production of condensed sulphuric acid from VOC gas. A model of sulphuric acid formation and accumulation by the characteristics of VOC from crude oil and flue gas is suggested.