• Journal of Korean Society of Environmental Engineers
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• v.22 no.5
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• pp.837-847
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• 2000

For the treatment of wastewaters generated from beer industry and petrochemical company with high organic and nitrogen contents, laboratory scale of A/O Pure-Oxygen Biofilm (POB) process was developed and studied by means of the comparative economic analysis with extended aeration process. When the wastewater of beer company was initially treated by the A/O POB process in the ranges of 70 to 150 mg TOC/L diluted with tap water, higher than 92% of TOC removal was accomplished in the all ranges. In case of petrochemical wastewater, the initial TOC removal was as low as 52%, though, it increased to 86% after 32 days of operation and also the TKN removal marked 71% after 27 days. Continuous high removal rates were monitored in both the TOC and TKN parameters during the experimental period. Due to the cost for PSA (Pressure Swing Adsorption) setting and biomass supporting media installation, the initial construction cost of A/O POB process was 2.9 times higher than that of extended aeration process. However, the advantages such as low sludge production, no need for sludge recycling and low energy consumption allow the A/O POB process to have 2.5 times lower operation and maintenance costs. Consequently, in the long term of operation, it is likely that A/O POB process would show higher performance as well as cost effectiveness compared to extended aeration process.

• Journal of Information Processing Systems
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• v.17 no.2
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• pp.242-252
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• 2021

Following the intuition that the local information in time instances is hardly incorporated into the posterior sequence in long short-term memory (LSTM), this paper proposes an attention augmented mechanism for fault diagnosis of the complex chemical process data. Unlike conventional fault diagnosis and classification methods, an attention mechanism layer architecture is introduced to detect and focus on local temporal information. The augmented deep network results preserve each local instance's importance and contribution and allow the interpretable feature representation and classification simultaneously. The comprehensive comparative analyses demonstrate that the developed model has a high-quality fault classification rate of 95.49%, on average. The results are comparable to those obtained using various other techniques for the Tennessee Eastman benchmark process.

• Journal of Environmental Health Sciences
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• v.20 no.3
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• pp.1-12
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• 1994

Wastewaters being treated and final effluents were collected from 3 wastewater treatment plants of petrochemical industries, from August 31 to October 4, 1993 in an interval of 10 days, and further analysed by GC/FID to investigate discharge situation and removal efficiency on polycyclic aromatic hydrocarbons. The results were as follows: 1. The PAHs 294.57 $\mu$g/l were discharged in primary treatment effluent of plant A to manufacture vinyl acetate resin and acryl, and removed 54.51% by aeration and totally 84.71%. 2. The PAHs of the highest concentration were discharged in primary treatment effluent of plant B to manufacture PS resin and ABS resin, but removed 91.65% by activated sludge process and 98.19% by activated carbon to discharge PAHs of the lowest concentration comparing to another treatment operations. 3. The PAHs 99.96 $\mu$g/l of the lowest concentration were discharged in wastewater of plant C to manufacture epoxy resin, and removed 80.48% by activated sludge process. 4. B treatment system including activated carbon showed up the best removal efficiency of PAHs. Activated carbon therefore, seems to be effective as tertiary treatment. 5. Correlation coefficient of components to total PAHs was generally low, and correlation coefficients of phenanthrene, pyrene and acenaphthylene to total PAHs were each 0.98, 0.97 and 0.80, respectively. Correlation coefficient of the sum of phenanthrene, pyrene and acenaphthylene to total PAHs was 0.99, so that the sum of phenanthrene, pyrene and acenaphthylene was available as index to estimated total PAHs. 6. Phenanthrene and Chrysene were very well treated biologically and acenaphthylene and fluoranthene were untreated biologically. 7. Considering EPA standards, it seems that the concentration of phenanthrene, pyrene, fluoranthene, and benzo(k)fluoranthene is high level.

• Journal of the Korean Institute of Gas
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• v.13 no.4
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• pp.53-60
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• 2009

For the case of the facilities using utilities such as cooling water and steam, risk of the facilities is zero because the consequence of failure (COF) through equipment damage area is zero. Therefore, to improve the estimation method of the risk by COF through equipment damage area in the risk-based inspection (RBI), this study developed the procedures of RBI, in which the risk was estimated by COF through financial loss. And, the RBI program (KS-RBI Ver 3.1) was developed to establish inspection interval based on the risk of the facilities estimated by COF through equipment damage area and financial loss, simultaneously, and the developed RBI program was applied to a petrochemical process. As a result, risks of the facilities estimated by COF through financial loss were similar to risks by COF through the equipment damage area. But, for the case of the facilities using utilities or expensive facilities, the estimation method of the risk by COF through financial loss was more accurate than through equipment damage area.

• Journal of Korea Multimedia Society
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• v.17 no.7
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• pp.858-865
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• 2014

In the case of system like MES, various sensors collect the data in real time and save it as a big data to monitor the process. However, if there is big data mining in distributed computing system, whole processing process can be improved. In this paper, system to analyze the cause of operation deviation was built using the big data which has been collected from deasphalting process at the two different plants. By applying multivariate statistical analysis to the big data which has been collected through MES(Manufacturing Execution System), main cause of operation deviation was analyzed. We present the example of analyzing the operation deviation of deasphalting process using the big data which collected from MES by using multivariate statistics analysis method. As a result of regression analysis of the forward stepwise method, regression equation has been found which can explain 52% increase of performance compare to existing model. Through this suggested method, the existing petrochemical process can be replaced which is manual analysis method and has the risk of being subjective according to the tester. The new method can provide the objective analysis method based on numbers and statistic.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.24 no.1
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• pp.52-58
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• 2014

Objectives: Using laborers participating in the petrochemical factory turnaround process as subjects, this study aims to identify exposure to benzene in the air and examine the relationship between exposure and the excretion of urinary metabolites by measuring concentrations of urinary trans, trans-muconic acid (t,t-MA). Methods: A passive sampler was used to measure the level of benzene in the air. In order to analyze urinary metabolites, the urine of laborers participating in the turnaround process was collected twice daily, both before and after work. In addition, a survey was conducted on work factors and lifestyle habits as factors affecting the concentration of urinary metabolites. Results: During the survey period, benzene was detected in the samples from all workers, and its average concentration was $0.16{\pm}0.22ppm$. The average concentration of t,t-MA after work was $1.20{\pm}1.86mg/g$ creatinine, and the results of analyzing urinary metabolites concentration before and after work showed statistically significant differences(p=0.003). There was also a statistically significant correlation (r=0.52, p=0.002) between benzene in the air and the concentration of after-work urinary t,t-MA. Conclusions: During the turnaround process, the average benzene concentration in workers was $0.16{\pm}0.22ppm$, which was below the exposure limit. However, their average t,t-MA concentration was $1.20{\pm}1.86mg/g$ creatinine, which exceeded the exposure limit of 1mg/g creatinine. The characteristics of turnaround process work require considerations such as underestimating the passive sampler being used and the skin absorption of benzene, and there needs to be a simultaneous assessment of working environment measurements and biological monitoring.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.331-331
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• 2006

Polylactic acid (PLA) is a promising polymer because it can be derived from renewable resources and provides a biodegradable alternative to petrochemical based polymers. This research aims to synthesize PLA, through direct polycondensation and also tries to avoid the occurrence of separation by-product and the use of catalysts in the process. The polymerization of lactic acid was done at three different temperatures $150^{\circ}C,\;180^{\circ}C\;and\;200^{\circ}C$ for 90 h without catalysts and organic solvent. The proposed process provides results that are comparable to those that incorporate catalysts; during polymerization temperature was $180^{\circ}C$ the molecular weight of PLA obtained reached 42448 Da. The thermal properties of PLA analysis by Differential Scanning Calorimetry (DSC).

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.11 no.4
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• pp.180-184
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• 2012

3-way ball valves have been mostly used for high temperature/high pressure valves using in petrochemical carriers and oil tankers, which requires high quality products with confidentiality and durability. As a larger disaster may be generated by leakage of oil or gas from valves, thus the present research applied a numerical analysis method with thermal-structural coupled field analysis and the performance test. The Max stress by parts was confirmed through thermal-structural coupled field analysis and develop the 3-way ball valve design, which is safe on operating condition. And its performance was verified by carrying out pressure test, leakage test and durability test for the manufactured 3-way ball valves with satisfying it's regulations.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 1999.10a
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• pp.443-444
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• 1999

악취는 냄새를 유발하는 기체상 물질이 사람의 후각을 자극하여 불쾌감이나 혐오감을 주는 상태를 말한다. 악취물질은 정유공장, 화학공장, 하수처리장, 분뇨 및 축산 폐수처리장, 매립장 등의 다양한 발생원이 있으며, 여러가지 복합된 화합물이 원인이 되어 악취를 유발한다. 단위 물질로서 황화수소(H$_2$S)는 계란 썩는 냄새, 메르캅탄(mercaptan)류는 야채 썩는 냄새, 아민류는 생선냄새 등의 특이한 냄새를 유발하며, 최저 감지값은 물질별로 상당한 차이를 나타내고 있다(이광묵, 1993).(중략)

• Journal of Institute of Convergence Technology
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• v.11 no.1
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• pp.13-18
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• 2021

It is widely accepted that the prevention of global warming requires significant reductions in greenhouse gases, particularly CO₂ emissions. Although fossil fuel-based power plants account for the majority of CO₂ emissions, it is urgent to reduce CO₂ emissions in industries that emit large amounts of CO₂ such as steel, petrochemical, and oil refining. This paper examines the current status of CO₂ emission in the domestic oil refining industry and CO₂ emission sources in each unit process in the oil refining industry. Focusing on the previously developed CO₂ capture process, cases and applicability of greenhouse gas reduction in FCC and hydrogen manufacturing processes, which are major processes constituting the oil refining industry, are reviewed.