• Title/Summary/Keyword: Peroxide

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Nickel-Based Catalysts for Direct Borohydride/Hydrogen Peroxide Fuel Cell (직접 수소화붕소나트륨/과산화수소 연료전지를 위한 니켈 기반 촉매)

  • OH, TAEK HYUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.6
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    • pp.587-595
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    • 2020
  • Nickel-based bimetallic catalysts were investigated for use in direct borohydride/hydrogen peroxide fuel cells. For anode and cathode, PdNi and AuNi catalysts were used, respectively. Nickel-based bimetallic catalysts have been investigated through various methods, such as inductively coupled plasma optical emission spectroscopy, transmission electron microscopy, scanning electron microscopy, and energy dispersive spectroscopy. The performance of the catalysts was evaluated through fuel cell tests. The maximum power density of the fuel cell with nickel-based bimetallic catalysts was found to be higher than that of the fuel cell with the monometallic catalysts. The nickel-based bimetallic catalysts also exhibited a stable performance up to 60 minutes.

Effect of Fluoride Treatment after Bleaching with Hydrogen Peroxide exposed to Plasma Arc (고농도 과산화수소와 플라즈마 아크를 이용한 미백 치료에 있어서 불소의 효과)

  • Chung, Sun-Young;Lee, Young-Eun;Ahn, Sang-Hun;Yang, Hae-Young;Jeon, Eun-Suk;Choi, Youn-Hee;Song, Keun-Bae
    • Journal of dental hygiene science
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    • v.11 no.4
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    • pp.375-380
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    • 2011
  • This study evaluated whether fluoride treatment can affect recovery of the irregularity of enamel surface after tooth whitening with a high concentration of hydrogen peroxide (HP) activated by plasma arc light. A total of 36 bovine teeth stained with coke were used in this experiment. The specimens were classified into following three groups (two different commercial plasma arc groups and a control group without light curing source): (1) 35% HP gel only, (2): 35% HP gel and Plasma arc A, and (3) 35% HP gel and Plasma arc B. To measure color changes and surface morphologies before and after the bleaching, colorimeter and scanning electron microscopy were used, respectively. When the specimens were bleached with hydrogen peroxide and plasma arc lights, the bleaching effect was greater than when only hydrogen peroxide gels were used (Kruskal-Wallis test, p<0.05). In addition, plasma arc B showed the more color changes than plasma arc A (Bonferroni post-hoc test, p<0.05). The surfaces of the teeth treated with fluoride gel after the whitening treatment came to be smooth. Therefore, the results of this study suggested that the fluoride application for patients who got tooth whitening therapy with a high concentration of hydrogen peroxide gels activated by plasma arc light will be effective to recover rough enamel surfaces.

Modeling of a Pervaporation Process for Concentrating Hydrogen Peroxide (과산화수소 농축을 위한 투과증발공정 모델링)

  • Nguyen, Huu Hieu;Lee, Sung Taek;Choi, Soo Hyoung
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.560-564
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    • 2011
  • The objective of this study is to propose a mathematical model for a pervaporation process for concentrating hydrogen peroxide. The process was developed by NASA, which consists of a shell and membrane tubes, where a liquid hydrogen peroxide solution flows in the shell, and a sweep gas flows in the tubes countercurrent to each other. The liquid retentate is concentrated as more water molecules permeate and evaporate through the membrane than hydrogen peroxide. For this process, a mathematical model has been developed in the form of a system of nonlinear partial differential algebraic equations based on a sorption-diffusion mechanism for permeation, an Arrhenius relationship for the temperature dependency of the permeate flux, and mass and momentum balances for the liquid concentrations and flows in the membrane module. The dynamic behavior of the concentration of hydrogen peroxide in the retentate side has been simulated by solving a simplified version of the proposed model, and the result is compared with the experimental data reported in the NASA patent.

Effects of the Extract of Samjasan on the Nitric Oxide Synthase Activity and the Level of Lipid Peroxide in Penis of Rats (삼자산(三子散)이 흰쥐 음경조직의 Nitric Oxide Synthase 활성 및 과산화지질 함량에 미치는 영향)

  • We, Young-Taek;Park, Jong-Hyuck;Yoon, Cheol-Ho;Jeong, Ji-Cheon;Shin, Uk-Seob;Min, Gun-Woo
    • The Journal of Internal Korean Medicine
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    • v.22 no.1
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    • pp.53-61
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    • 2001
  • Objectives : The following are the results of the experimental studies of Samjasan (SJS) extract on the nitric oxide synthase (NOS) activity and the level of lipid peroxide in the penises of rats. Methods : Cnidii Fructus, Cuscutae Semen, Schizandrae Fructus constitute SJS. 150 g of crushed crude drug was extracted with methyl alcohol, under reflux, for 24 hours, three times; the total extractive was evaporated under reduced pressure to give 28.6 g. Results : In vitro, the SJS extract didn't effect the activity of NOS. However, the SJS extract decreased the activities, the ratio of type conversion of xanthine oxidase, the levels of lipid peroxide, In vitro, after administration of the SJS extract to rats, the activities and ratio of type conversion of xanthine oxidase decreased, but the activity of NOS and the content of nitrite increased. Also, the levels of the superoxide anion radical and lipid peroxide decreased in the penises of rats. But, after administration of the SJS extract to rats, the levels of glutathione did not increase. The effects of the SJS extract did better as the dosage and the length of treatment increased. Conclusions : These results suggest that the SJS extract decreases the activities of free radical generating enzymes which form lipid peroxide and increases the NOS activity in the penises of rats. Therefore, the SJS extract is capable of improving of sexual ability in rats.

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대기압 플라즈마를 이용한 우치(牛齒) 미백 효과에 대한 분석

  • Sim, Geon-Bo;Kim, Yong-Hui;Park, Chan-Yeong;Kim, Jeong-Mo;Yun, Hyeon-Sik;Lee, Dong-Hyeon;Jeong, Ju-Eun;Park, Dae-Hun;No, Seok-Ho;Eom, Hwan-Seop;Choe, Eun-Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.541-541
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    • 2013
  • 현재 병원에서 사용하는 치아미백은 고농도의 과산화수소와 carbamide peroxide가 함유된 미백제를 이용하여 전문성을 가진 의사가 직접 시술을 하고 있다 [1]. 과산화수소의 농도가 높을수록 미백효과가 높지만 [2] 과산화수소의 농도가 지나치게 높으면 인체에 유해하다 [3,4]. 따라서, 고농도의 과산화수소가 함유된 미백제의 사용은 전문가만 시술할 수 있도록 이를 제한하고 있다. 이로 인해, 일반 가정용으로 판매되는 다양한 미백제품들은 저농도(최대6%)의 과산화수소가 함유되어 있으며 장기간 지속적으로 사용해야만 치아미백효과를 볼 수 있다. 우리는 가정에서도 보다 안전하고 단기간에 효율적으로 치아의 미백효과를 보기 위하여, 식품의약품안정청에서 규제하고 있는, carbamide peroxide (15%)와 저온 대기압 플라즈마 제트를 사용하여 미백효과를 관찰하였다. 플라즈마 제트의 유량은 200 sccm이며, 공기를 사용하였다. 미백효과를 보기 위한 대상으로는 우치(牛齒)를 사용하였으며, 플라즈마를 처리하여 미백효과를 관찰하였다. 실험 대조시료군으로는 carbamide peroxide (15%)를 처리하지 않은 우치와 처리한 우치, 그리고 carbamide peroxide (15%)를 처리한 우치에 수증기(0.2~1%)를 첨가한 다음, 이들 세가지 시료에 각각 공기 플라즈마를 조사하여 비교해보았다. 모든 실험의 플라즈마 처리시간은 최대 20분까지로 하였다. 수증기를 첨가한 이유는 활성산소의 농도를 높이기 위함이며, 이로써 탁월한 미백효과를 얻을 수 있다. 이는 활성산소와 치아의 유기질이 반응하여, 색이 진한 탄소고리 화합물을 밝은 색의 사슬구조로 바꿔주기 때문이다. 실험을 통하여 우치에 carbamide peroxide (15%)와 수증기(0.2~1%)를 처리한 경우 플라즈마의 미백효과가 탁월함을 보였다. 이때 CIE색좌표 ($L^*a^*b^*$)에서 명도도가 최대 2배 이상 높아짐을 보았다. 미백효과에 대한 측정은 측색분광기(CM-3500d)를 이용하였다.

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Estimation of Environmental Distribution for Benzoyl peroxide Using EQC Model

  • Kim, Mi-Kyoung;Bae, Heekyung;Kim, Su-Hyon;Song, Sanghwan;Koo, Hyunju;Kim, Hyun-Mi;Lee, Moon-Soon;Jeon, Seong-Hwan;Na, Jin-Gyun;Park, Kwangsik
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.05a
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    • pp.150-151
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    • 2003
  • Benzoyl peroxide is a high production volume chemical, which was produced about 1,375 tons/year in Korea as of 2001 survey. Most of them are used as initiators in polymerization, catalysts in the plastics industry, bleaching agents for flour and medication for acne vulgaris. The substance is one of the sever chemicals of which human and environmental risks are being assessed by National Institute of Environmental Research under the frame of OECD SIDS Program. It has a melting point of 104-106 $^{\circ}C$ and has solubility of 9.1 mg/1 in water at 25 $^{\circ}C$. The substance was readily biodegradable (83 % after 21days) and had toxic effects to aquatic organisms. The range of 72 hr-EbC50 (biomass) for algae was 0.07-0.44 mg/1 and 48 hr-EC50 for daphnia was 0.07-2.91 mg/1. The LC50 of acute toxicity to fish was 0.24-2.0 mg/1. Although the toxic effects of benzoyl peroxide to aquatic organisms were investigated, environmental monitoring data were not studied. In this study, distribution of the chemical among multimedia environment was estimated using EQC model based on the physical-chemical properties to evaluate the risk of benzoyl peroxide in environment. In level I, II calculation the chemical was distributed to soil (68.3 %) and water (28.7 %). In level III calculation it was primarily distributed to soil (99.9 %) and overall residence time of 3.4 years was estimated. Benzoyl peroxide could be persistent in environment.

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Optimized Mixing Design of Lightweight Aerated Concrete by Response Surface Analysis (반응표면분석법에 따른 경량기포콘크리트 최적배합 도출에 관한 연구)

  • Lee, Sang-An;Jung, Chan-Woo;Kim, Wha-Jung;Ahn, Jung-Hyun
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.745-752
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    • 2009
  • This paper presents the optimized mixing design of lightweight aerated concrete using hydrogen peroxide. Design of experiments in order to the optimized mixing design was applied and commercial program (MINITAB) was used. Statistical analysis was used to Box-Behnken (B-B) method in response surface analysis. The influencing factors of experimental are unit cement content, water ratio and hydrogen peroxide ratio. According to the analysis of variance, at the hardened state, water ratio and hydrogen peroxide ratio affects on dried density, compressive strength and bending strength of lightweight aerated concrete, but unit cement content affects on only dried density. In the results of response surface analysis, to obtain goal performance, the optimized mixing design for lightweight aerated concrete using hydrogen peroxide were unit cement content of 800 kg/$m^3$, water ratio of 44.33% and hydrogen peroxide ratio of 10%.

Effects of Fel Ursi, Bezoar Bovis and Ung-Whang Tang on the Galactosamine-induced Acute Hepatitis in Rats (웅담(熊膽), 우황(牛黃) 및 웅황탕(熊黃湯)이 galactosamine에 의한 흰쥐의 급성 간염에 미치는 영향)

  • Park, Tae-Ho;Seong, Nak-Sul;Lee, Young-Jong
    • The Korea Journal of Herbology
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    • v.20 no.2
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    • pp.127-136
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    • 2005
  • Objectives : The present study attempted to reveal the effects of the combination of Fel Ursi and Bezoar on the improvement of the function of the liver, through examining the effects of Fel Ursi, Bezoar, and Woong-Whang Tang composed of Fel Ursi and Bezoar. Method : Acute hepatitis was induced by galactosamine to rats, and then Fel Ursi, Bezoar Bovis, and Woong-Whang Tang were introjected to measure the influence of serums such as AST, ALT, ALP, ${\gamma}GT$, and lipid peroxide of liver tissues which are considered as the index of the function of the liver. Results : 1. Fel Ursi decreased the lipid peroxide of ALT, ${\gamma}FT$, and liver tissue and that of mitochondria in liver tissues of the rats with galactosamine-induced acute hepatitis, but it did not have any significant effect on AST and ALP. 2. Bezoar Bovis decreased the lipid peroxide of AST, ALT, ALP, ${\gamma}GT$, and the liver tissues among serum of the rats suffering from acute hapatitis induced by galactosamine, but it did not have any significant effect on that of mitochondria of the liver tissues. 3. Woong-Whang Tang had a significant effects on the lipid peroxide of AST, ALT, ALP, ${\gamma}GT$, and the liver tissues, and on the decrease of lipid peroxide of mitochondria, among serum of the rats suffering from acute hapatitis induced by galactosamine. Conclusion : Fel Ursi and Bezoar Bovis were judged to be effective on the acute hepatitis of the liver by galactosamine. In particular, Woong-Whang Tang which was composed of the combination of Fel Ursi and Bezoar Bovis was more efficient in the improvement of the function of the liver and the amount of lipid peroxide than the respective use of Fel Ursi or Bezoar Bovis.

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