• 제목/요약/키워드: Perovskite material

검색결과 391건 처리시간 0.022초

소결온도에 따른 $Ba(Zn_{1/3}Ta_{2/3})O_3$[BZT] 세라믹스의 구조적 특성 (Structural Properties of $Ba(Zn_{1/3}Ta_{2/3})O_3$[BZT] Ceramics with Sintering Temperature)

  • 이상철;김지헌;김강;이성갑;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 춘계학술대회 논문집 전자세라믹스 센서 및 박막재료 반도체재료 일렉트렛트 및 응용기술
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    • pp.76-79
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    • 2000
  • The $Ba(Zn_{1/3}Ta_{2/3})O_3$ ceramics were prepared by conventional mixed oxide method. The structural properties of the BZT ceramics with the sintering temperature were investigated by XRD, SEM. The BZT ceramics have a complex-perovskite structure. The BZT ceramics sintered at $1550^{\circ}C$ had a superstructure plane of BZT(100). Increasing the sintering temperature, the bulk density and ordering were increased. The bulk density of the BZT ceramics sintered at $1550^{\circ}C$ was $7.50[g/cm^3]$. Increasing the sintering temperature, the average grain size were increased and pore were decreased.

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Peculiarities of SHS and solid state synthesis of $ReBa_{2}Cu_{3}O_{7-x}$ materials

  • Sho, Dea-Wha;Li, Yingmei;Cho, Yong-Joon;Kim, Tae-Wan;Korobova, N.;Isaikina, O.;Mansurov, Z.;Baydeldinova, A.;Ksandopoulo, G.
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.620-623
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    • 2001
  • The peculiarities of using Self-propagating High-temperature Synthesis (SHS) and solid state phase synthesis for production of high temperature superconductor materials are discussed. Oxide superconductors with general formula $ReBa_2$$Cu_3$$O_{7-x}$ (Re= Y, Yb, Sm, Nd) have been made with using barium oxide initial powder instead of traditional barium carbonate. X-ray powder diffraction showed a single phase orthorhombic perovskite structure was produced in all reactions. Phenomena observed during the grinding of the reactant mixture are presented. Mechano-chemical activation - as a pretreatment of the reactant mixture - strongly influences the kinetic parameters, the reaction mechanism, and the composition and structure of the final product.

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스퍼터링 조건에 따른 PZT 박막의 특성에 관한 연구 (The properties of PZT thin film at various sputtering condition)

  • 김홍주;박영;정규원;박기엽;송준태
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.997-1000
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    • 2001
  • Pb(Zr$\sub$0.52/Ti$\sub$0.48/)O$_3$(PZT) thin films have been prepared by rf-magnetron sputtering methods and investigated the structural and electrical properties. In order to investigate the effects of sputtering conditions, input power was controlled during deposition. Crystallization process and microstructure of PZT thin films were largely affected by input power. Highly crystallized PZT films with the perovskite structure were successfully obtained on Pt/Ti bottom electrode. The dielectric constants and polarization of PZT thin films were increased with increasing input power, and the coercive electric field was decreased with increasing input power . The dielectric constant of PZT thin films with input power 150 W was 966 at 1 kHz. we, authors, proposed that preferred orientation of PZT thin films were controlled by input power in sputtering methods.

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BaCO$_3$와 TiO$_2$를 치환한 BaTiO$_3$의 유전특성에 관한 연구 (The Dielectric Characteristics of BaTiO$_3$by Changing both BaCO$_3$ and TiO$_2$)

  • 홍경진;민용기;김태성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1993년도 추계학술대회 논문집
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    • pp.21-24
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    • 1993
  • The microstructure of the cubic perovskite [(Ba$\sub$85.5/ Ca$\sub$15.5)(Ti$\sub$60/ Mn$\sub$40/)O$_2$]-based dielectrics has been investigated. BCTM which control both A-site and B-site has less electrical characteristics than BaTiO$_3$. The dielectric factor was decreased and the dielectric loss factor was improved because BaMnO$_3$was formed in the solide reaction method.

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후속 열처리 온도에 따른 SBT 커패시터의 전기적 특성 (Electrical Properties SBT capacitor with post-annealing)

  • 조춘남;김진사;신철기;최운식;박용필;김충혁;이준웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.672-675
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    • 2001
  • The Sr$\sub$0.8/Bi$\sub$2.4/Ta$_2$O$\sub$9/(SBT) thin films are deposited on Pt-coated electrode(Pt/TiO$_2$/SiO$_2$/Si) using RF magnetron sputtering method. With increasing annealing tempera ture from 600[$^{\circ}C$] to 850[$^{\circ}C$], Bi-layered perovskite phase was crystallized above 650[$^{\circ}C$]. The maximum remanent polarization and the coercive electric field is 11.60[${\mu}$C/$\textrm{cm}^2$], 48[kV/cm] respectively. The dielectric constant and leakage current density is 213, 1.01${\times}$10$\^$-8/ A/$\textrm{cm}^2$ respectively at annealing temperature of 750[$^{\circ}C$].

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AFE 영역 PLZT 박막의 전기 및 광학 특성 (Electrical and Optical Characteristics of PLZT Thin Films in AFE region)

  • 류완균;최형욱;장낙원;강종윤;백동수;박창엽
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 추계학술대회 논문집
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    • pp.1.1-4
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    • 1995
  • In this study, PLZT thin films in AFE region prepared by sol-gel processing were investigated. And PLZT stock solutions were spin-coated on ITO-glass. The PLZT thin films were annealed by RTA. Hysteresis curves, dielectric characteristics and optical transmittances were measured in order to investigates the characteristics far the thin films. The PLZT thin films were crystallized at 750$^{\circ}C$ for 5 mimutes by RTA and the rosette structure composed of perovskite observed in the thin films. In case La content was 2/90/10 antiferroelectric-ferroelectric phase boundary was 2/90/10 PLZT thin film, and its hysteresis curve was good for application of optical information storage.

Screen-printing법으로 제작한 BSCT 후막의 구조적 특성 (The Structural properties of BSCT thick films fabricated by screen-printing method)

  • 허영식;이성갑;박상만;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.545-548
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    • 2002
  • $(Ba_{0.6-x}Sr_{0.4}Ca_x)TiO_3$(BSCT) (x=0.10, 0.15, 0.20) powders were prepared by the sol-gel method and BSCT thick films were fabricated by the screen-printing method. The structural properties as a faction of the composition ratio were studied. As a result of the differential thermal analysis (DTA), exothermic perk was observed at around $860^{\circ}C$ dne to the formation of the polycrystalline perovskite phase. The BSCT thick films sintered at $1350^{\circ}C$ for 2h showed the average grain size of $2{\sim}7{\mu}m$. The average thickness of BSCT thick films, obtained by 3 times of screen-printing, was approximately $85{\mu}m$.

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$La_2O_3$와 NiO의 혼합물로부터 $LaNiO_3$의 메카노케미칼 합성 (Mechanochemical synthesis of $LaNiO_3$ from mixtures of $La_2O_3$ and NiO)

  • 김대영;서병준;손세모;김강언;정수태
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.621-624
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    • 2002
  • Lanthanum nickel oxide$(LaNiO_3)$ powders have been prepared via a mechanochemical processing without any additional heat treatment. When a mixed lanthanum and nickel oxide was mechanically activated for 6 hours with 450 rpm, a stable and single phase perovskite powder was successfully synthesized and its crystallite size of about 90 nm is calculated by using the Scherrer equation.

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FED용 Al 및 Pr 첨가 SrTiO3 적색 형광체의 제조와 발광특성 (Preparation and Luminescent Properties of SrTiO3 : Al, Pr Red Phosphors for the FED)

  • 박창섭;이정운;유일
    • 한국전기전자재료학회논문지
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    • 제18권9호
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    • pp.846-850
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    • 2005
  • [ $SrTiO_3$ ]:Al, Pr red phosphors for FED were synthesized by solid state reaction method. The dependence of their luminescent properties on Sr and Al concentration was investigated. The $SrTiO_3$: Al, Pr phosphors showed the characteristic X-ray diffraction patterns of the perovskite structure. Photoluminescence intensity and lattice constant in $SrTiO_3$: Al, Pr phosphors changed in quite a similar manner with Sr concentration. Photoluminescence intensity increased with increasing lattice constant, and the decrease of photoluminescence intensity and lattice constant occurred in the vicinity of 1 mol Sr concentration.

소결온도에 따른 BSCT 후막의 구조적 특성 (Structural Properties of BSCT Thick Films with variation of Sintering Temperature)

  • 박상만;이성갑;윤상은;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.212-213
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    • 2006
  • BSCT(60/30/10) powder specimens were fabricated by sol-gel method and BSCT thick films were fabricated by screen-printing method. The coating and drying procedure was repeated 6 times. Then the structural properties as a function of the sintering temperature. As a result of the TG-DTA, exothermic peak was observed at around $670^{\circ}C$ due to the crystalline phase. The BSCT sintered at $1430^{\circ}C$ showed the cubic perovskite structure. The prosity and thickness of the BSCT thick films was decreased with sintering temperature. The thickness of BSCT thick films at $1420^{\circ}C$ was approximately $40{\mu}m$.

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