• Food Science and Preservation
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• v.5 no.3
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• pp.239-246
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• 1998

Polyimide membrane system was designed for manufacturing nitrogen-enriched gas, and basic technical data was suggested for appling this system to controlled atmosphere storage. The permeability characteristics of pure oxygen and nitrogen could be explained by dual-mode sorption model. There was substantial decrease in the permeation rates of oxygen, which is the more permeable gas, through the polyimide membrane due to the presence of nitrogen in comparison with pure oxygen. However, the permeation rates of nitrogen was increased by the presence of oxygen. The ideal separation factor was in the range of 5 to 6 in the range of temperature and pressure difference studied, and the separation factor of air was lower than the ideal separation factor. The increase of ideal separation factor with increasing temperature is due to the fact that the activation energy for oxygen is larger than that for nitrogen. Nitrogen concentration decreased rapidly with increasing product recovery, and it was found that this is a major operating factor to obtain nitrogen concentration required for controlled atmosphere storage. A relation equation, by which nitrogen concentration in storehouse can be predicted, was suggested under the establishment of a hypothetical model for controlled atmosphere storage process using polyimide membrane system.

• Proceedings of the Membrane Society of Korea Conference
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• 1997.10a
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• pp.69-70
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• 1997

Polyimides and related polymers, when synthesized from aromatic monomers, have generally rigid chain structures resulting in a low gas permeability. The rigidity of polymer chains reduces the segmental motion of chains and works as a good barrier against gas transport. To overcome the limit of use as materials of gas separation membranes due to low gas permeability, block copolymers with the incorporation of flexible segments like siloxane linkage and ether linkage have been studied. These block copolymers have microphase-separated structures composed of microdomains of flexible poly(dimethylsiloxane) or polyether segments and of rigid polyimides segments. In case of rigid-flexible block copolymers, the characteristics of both phases for gas permeation are of great difference. The permeation of gas molecules occurs favorably through microdomains of flexible segments, whereas those of rigid segments hinder the permeation of gas molecules. Accordingly the increase of content of flexible segments in a rigid polymer matrix will increase the gas permeability of the membrane linearly. However, this prediction does not satisfy enough many experimental results and in particular the drastic increase of the permeability is observed in a certain volume fraction. It was proposed that the gas transport mechanism is dominated by diffusion rather than gas solubility in a certain content of flexible phase if solution-diffusion mechanism is adopted. However, the transition from solubility-dependent to diffusion-dependent cannot be explained by the understanding of mechanism itself. Therefore, we consider an effective chemical path which permeable phase can form in a microheterogenous medium, and percolation concept is introduced to describe the permeability transition at near threshold where for the first time a percolation path occurs. The volume fraction of both phases is defined as V$_{\alpha}$ and V$_{\beta}$ in block copolymers, and the volume of $\beta$ phase in the threshold forming geometrically a traversing channel is defined as V$_{\betac}$. The formation mechanism of shortest chemical channel is schematically depicted in Fig. 1.

• Membrane Journal
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• v.26 no.1
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• pp.32-37
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• 2016

The poly(vinyl alcohol) $(PVA)/AgCF_3SO_3/Al(NO_3)_3$ electrolyte membrane was fabricated to prepare for highly permeable facilitated olefin transport membrane, compared with poly(vinylpyrrolidone) $(PVP)/AgCF_3SO_3/Al(NO_3)_3$ complex. In order to examine the characteristics of $PVA/AgCF_3SO_3/Al(NO_3)_3$ membrane, we used the analytical methods such as SEM, FT-IR, and FT-Raman. The best separation performance was observed at the mole ratio of 1 : 1 : 0.01 $PVA/AgCF_3SO_3/Al(NO_3)_3$ among various $Al(NO_3)_3$ concentration. As a result, the selectivity was 12 and mixed-gas permeability was 3.5 Barrer. Furthermore, the selectivity and permeability remained constant for up to 115 h.

• Membrane Journal
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• v.26 no.4
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• pp.266-272
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• 2016

The separation and purification of lysozyme enzyme from chicken egg white (CEW) solution was studied using the dead-end filtration. The optimum operation conditions of the dead-end filtration reveal that the maximum value of permselectivity of lysozyme to the other proteins of ovalbumin and conalbumin in the CEW solution was tested with change of molecular weight cut-off (MWCO) of ultrafitration membrane and pH of the CEW solution. The optimum operation conditions for the efficient permeable separation of lysozyme from the CEW solution are that the membrane MWCO is 30 kD and the pH of CEW solution is 11. At this optimum operation conditions, the maximum value of permselectivity of lysozyme to total proteins in CEW solution is about 83.

• Journal of Soil and Groundwater Environment
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• v.16 no.3
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• pp.17-27
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• 2011

Recently, a physically based model of water-table fluctuation due to precipitation is developed based on aquifer water balance model. In the model, it was assumed that the water infiltration into ground surface is advection dominant and immediately reaches to water-table. The assumption may be suited for the sites where the water-table is shallow and/or the permeability of the unsaturated zone is high. However, there are more cases where the model is not directly applicable due to thick and low permeable unsaturated zone. For the low permeability unsaturated zone, the pattern of water flux passing through unsaturated zone is diffusive as well as advective. In this study, to improve the previously developed water-table fluctuation model, we combined the delayed drainage model, which has long been used in well hydraulics, to the water-table fluctuation model. To test the validity of the development, we apply the developed model to 5 different domestic sites. The model parameters are calibrated based on the groundwater hydrograph and the precipitation time series, and the correlation analyses among the parameters are pursued. The overall analyses on the delineated model parameters indicate that the delayed drainage parameters or delay index used in the developed model are able to reveal drainage information in the unsaturated zones.

• Journal of the Korean GEO-environmental Society
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• v.10 no.2
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• pp.51-59
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• 2009

This study is based on field data obtained from rock grouting such as RQD value, Unit cement grout volume, Lugeon value(Lu), and Maximum grout pressure in four different dam sites. The relationship were analyzed and compared as follow. The cut-off effect after rock grouting in dam-foundation which are mostly consist of metamorphic rock is better than that of Sedimentary rock. And the impermeable effect after consolidation grouting is more efficiency than the impermeable effect after curtain grouting. The unit cement grout volume are increased as RQD value is higher in rock mass. But there is no relationship between RQD value and Lugeon value. In the sedimentary rock, which is more permeable than metamorphic rock, Lugeon value (Lu) is a linear function (Lu=0.22Vc) of unit cement grout volume (Vc). Cut-off effect of curtain grouting is less influential at each near holes which are already grouted than that of consolidation grouting. And the behavior characteristics of Lugeon value vs. the unit cement grout volume as the order of installations are almost the same.

• Journal of the Korean GEO-environmental Society
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• v.15 no.11
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• pp.13-19
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• 2014

Permeable reactive barrier has been recognized as the one of representative methods for remediation of contaminated groundwater. Reactive barrier system containing two and more reactive materials can remove multiple contaminants such as nutritive salts and heavy metals. In this study, removal efficiency of multiple contaminants was evaluated when both zeolite and basic oxygen furnace slag were used as reactive materials. Sequential batch test which consists of two materials was performed to evaluate removal efficiency comparing the reaction order of them against nutritive slats including ammonium and phosphate and heavy metal including cadmium. As a result, zeolite-basic oxygen furnace slag sequence batch test showed the best efficiency for removal of multiple contaminants including nutritive salts and heavy metal.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2008.11a
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• pp.227-233
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• 2008

Porous concrete has large continuous voids of 20-30 % by volume, and this concrete is attractive as environmental material in Japan i.e. permeable road pavement, river bank protection with vegetation and green roof system which influence thermal environment. It is necessary to confirm the frost resistance when constructing porous concrete structure in cold region. However applicable test method and evaluation criterion of porous concrete has not defined yet. Therefore, the object of this study is to investigate the frost resistance of porous concrete and this investigation attempts to address this concern by comparing 4 kinds of specified freezing and thawing tests methods (JIS A1148 procedure A/B and RILEM CIF/CDF test) in consideration of actual environment. RILEM freeze-thaw tests are different from JIS A1148 freeze-thaw tests, which are widely adopted for evaluating the frost resistance of conventional concrete in Japan, in water absorption, cooling rate, length of freezing and thawing period, and number of freezing and thawing cycles. RILEM CIF test measures internal damage and is primarily applicable for pure frost attack. CDF test is appropriate for freeze-thaw and de-icing salt attack. JIS A1148 procedure A/B showed extremely low frost resistance of porous concrete if the large continuous voids were filled with water and the ice expansion in the large continuous voids set in during cooling. Frost resistance of porous concrete was improved by mixing coarse aggregate (G7) which particle size is smaller and fine aggregate in JIS freezing and thawing tests. RILEM CIF/CDF test showed that freeze-thaw and de-icing resistance of porous concrete was seems to be superior in that of conventional concrete.

• Proceedings of the Korean Geotechical Society Conference
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• 2005.03a
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• pp.545-552
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• 2005

For the purpose of studying on the seepage characteristics of embedded gravel layer in embankment, laboratory model tests were carried out. The embedded layer under embankment was $19{\sim}26mm$ diameter of gravel and those embankment materials were Saemangum dredged sand, river sand and mixed(1:1) sand with dredged and river one. Those permeability coefficients of three different sands are $5.00{\times}10^{-5}$, $3.00{\times}10^{-4}$, $7.50{\times}10^{-5}m/s$, respectively. Seepage characteristics of these results are as follows; 1) The Reynolds number of water flow through embedded gravel layer in three different permeable soils is less then 10, it is laminar flow. 2) These flow velocities through embedded gravel layer in soils are in proportion to these hydraulic gradients, it is Darcy flow. 3) These Darcian permeability coefficients of water flow through embedded gravel layer in soils show as $2.95{\times}10^{-3}$, $1.38{\times}10^{-2}$, $3.33{\times}10^{-3}$m/s, respectively, by varying permeability of embankment soils and embankment lengths. It is approximately 100 times of those permeability coefficients of embankment materials.

• Journal of Hydrogen and New Energy
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• v.14 no.1
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• pp.17-23
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• 2003

$H_2$ permeation flux though a $100{\mu}m-thick$ Pd-Ru (6wt%) membrane was measured at various temperatures and pressures. The permeation flux followed the Sievert's law and thus the rate-limiting step of the hydrogen permeation was the bulk atomic diffusion step. The activation energy of the permeation flux was obtained at 17.9 kJ/mol and this value is consistent with those published previously. While no degradation of the permeation flux wasfound in the membrane exposed to the $O_2$ and $CO_2$ environments for 100 hours, the membrane exposed to $N_2$ environment for 100 hours showed the degradation in the $H_2$ permeation flux. The $H_2$ permeation was decreased as the exposure temperature to $N_2$, environment was increased. The $H_2$ permeation flux was fully recovered after the membrane was kept in the $H_2$ environment for certain time. The permeation flux degradation might be caused by the formation of metal nitride on the membrane surface.