• Bulletin of the Korean Chemical Society
• /
• v.33 no.12
• /
• pp.3971-3976
• /
• 2012

A simple method was developed for the analysis of seven stilbene-type fluorescent whitening agents (FWAs) in paper materials by ion-pair reversed-phase high-performance liquid chromatography with fluorescence detection. These stilbene-type FWAs included two disulfonate, two tetrasulfonate, and three hexasulfonate compounds. After optimization of chromatographic conditions, the FWAs were satisfactorily separated using a reversed-phase column (RP-18) with the following isocratic mobile phase: methanol-water (60:40) containing 17.5 mM TBABr and 10 mM citrate buffer (pH = 7.0). The calibration plot was linear in the range from 5 to 500 ng/mL for two disulfo-FWAs and from 1 to 500 ng/mL for the other five FWAs. Precision levels of the calibration curve as indicated by RSD of response factors were 1.2 and 8.1%. Limits of quantitation (LOQ) ranged from 1.2 to 11 ng/mL.

• Applied Chemistry for Engineering
• /
• v.30 no.4
• /
• pp.460-465
• /
• 2019

In this study, the optimization of active materials and the preparation of particulate adsorbents for the application of metal oxide-based adsorbents for the treatment of $H_2S$, an air pollutant and odorant, occurred in various industrial facilities were investigated. The adsorbents were prepared by using $TiO_2$, which has a high physicochemical stability and relatively high specific surface area among metal oxides and also by different kinds and contents of active materials. The correlation between the physicochemical property and adsorption performance of the adsorbents confirmed that the adsorbent containing KI, which is a typical alkali metal among the active metals, showed the highest adsorption performance. The relationship between the contents and the adsorption performance was non-proportional, but a volcano plot. From XRD, SEM and BET analyses, it was confirmed that the active material was exposed to the surface above a certain amount and also the adsorption performance was the best when the specific surface area and pore volume were $40{\sim}100m^2/g$ and $0.1{\sim}0.3cm^3/g$, respectively. For practical application, the adsorbent was granulated or coated on a ceramic support. It was also confirmed that the adsorbent showed high adsorption performance when the adsorbent was coated on the ceramic rather than that of the granulated support.

• Journal of the Korea Society of Computer and Information
• /
• v.23 no.10
• /
• pp.157-164
• /
• 2018

The purpose of this study was to investigate the effect of empowerment in nurses through a systematic literature review and meta-analysis. 23 studies were collected through a systematic process of using several databases such as NDSL, DBPIA, and KISS. Keywords included 'nurse', 'empowerment', and 'correlation' and the reviewed articles were published from 2002 to 2017. In order to estimate the effect size of correlation between empowerment, 3 variables (job satisfaction, organizational commitment, and nursing performance) were considered. Using the R program, meta-analysis was calculated by using random effects model, and effect sizes on three types were estimated. As the result, it was found, first, the effect size of correlation between job satisfaction and empowerment is .50. Second, the effect size of correlation between organizational commitment and empowerment is .45. Third, for the nursing performance and empowerment relationship, the effect of correlation is 0.50. Also, Egger's regression test, fail-safe N, trim-and-fill test, and funnel plot were showed to evaluate the results. These results highlights the need for appropriate policies of the relationship between empowerment and job satisfaction, organizational commitment and nursing performance in nurses.

• Animal Bioscience
• /
• v.36 no.10
• /
• pp.1546-1557
• /
• 2023

Objective: The present study aimed to evaluate the effects of extruded and unextruded feeding on the performance, milk composition, digestibility and ruminal fermentation of dairy cows through a meta-analysis. Methods: The database was compiled from 53 studies in Scopus and PubMed. The data were analyzed using a random effects model in OpenMEE software. Extruded feed was grouped as the experiment group while and the others as control group. The bias of publication in the main parameter of dairy performance was evaluated by a funnel plot. Results: The result showed that extruded feed enhanced the milk yield, dry matter and crude protein digestibility, butyrate and valerate acid production (p<0.05). Meanwhile, the extruded feed significantly decreased the milk fat and protein concentration (p<0.05). Also, the iso-butyrate and iso-valerate in unextruded feeding was significantly higher than the extruded feed (p<0.05). Conclusion: It was concluded from the meta-analysis that extruded feed effectively improved the milk production and milk lactose concentration, dry matter and protein digestibility, but not the milk fat and protein concentration.

• Computers and Concrete
• /
• v.33 no.1
• /
• pp.55-75
• /
• 2024

The present study introduces an optimum performance soft computing model for predicting the compressive strength of high-performance concrete (HPC) by comparing models based on conventional (kernel-based, covariance function-based, and tree-based), advanced machine (least square support vector machine-LSSVM and minimax probability machine regressor-MPMR), and deep (artificial neural network-ANN) learning approaches using a common database for the first time. A compressive strength database, having results of 1030 concrete samples, has been compiled from the literature and preprocessed. For the purpose of training, testing, and validation of soft computing models, 803, 101, and 101 data points have been selected arbitrarily from preprocessed data points, i.e., 1005. Thirteen performance metrics, including three new metrics, i.e., a20-index, index of agreement, and index of scatter, have been implemented for each model. The performance comparison reveals that the SVM (kernel-based), ET (tree-based), MPMR (advanced), and ANN (deep) models have achieved higher performance in predicting the compressive strength of HPC. From the overall analysis of performance, accuracy, Taylor plot, accuracy metric, regression error characteristics curve, Anderson-Darling, Wilcoxon, Uncertainty, and reliability, it has been observed that model CS4 based on the ensemble tree has been recognized as an optimum performance model with higher performance, i.e., a correlation coefficient of 0.9352, root mean square error of 5.76 MPa, and mean absolute error of 4.1069 MPa. The present study also reveals that multicollinearity affects the prediction accuracy of Gaussian process regression, decision tree, multilinear regression, and adaptive boosting regressor models, novel research in compressive strength prediction of HPC. The cosine sensitivity analysis reveals that the prediction of compressive strength of HPC is highly affected by cement content, fine aggregate, coarse aggregate, and water content.

• Asian-Australasian Journal of Animal Sciences
• /
• v.6 no.3
• /
• pp.361-365
• /
• 1993

An experiment was conducted to investigate the effects of feeding fresh cassava roots on the performance and carcass quality of pigs raised from $15{\pm}1kg$ to 85 kg live weight. Fresh unpeeled cassava roots were chopped into chips and offered separately along with a protein concentrate made up of copra cake and meat and bone meal, and a local mineral-vitamin premix. Commercial pig grower and finisher diets served as control. A total of 24 pigs were used in an incomplete randomized split-plot design experiment. Pigs fed fresh cassava-based diet grew as fast, 0.78 vs 0.77 kg/day, and were as efficient, 3.74 vs 3.77 in converting feed into body weight gain as those fed the commercial control diet. Similarly, there were no differences in carcass quality measured in terms of dressing percentage, 77 vs 77; backfat thickness, 2.76 vs 2.78 cm; loin eye muscle area, 29.2 vs $29.1cm^2$ and in the relative proportions of the different carcass cuts between the two dietary treatments. The use of fresh cassava along with the protein and the local mineral-vitamin premix however, resulted in lowered total feed cost and cost per unit of live weight gain. It is concluded that fresh cassava roots can be fed along with copra cake, meat and bone meal protein concentrate and a local mineral-vitamin premix to fattening pigs with no adverse affects on performance and carcass quality.

• Journal of the Korean Society of Manufacturing Technology Engineers
• /
• v.22 no.5
• /
• pp.767-773
• /
• 2013

A high-pressure, high-pressure drop control valve, which transforms the power transfer of a system by reducing the inlet pressure of 345bartothe outlet pressure of 112bar, is a fundamental component in an offshore plant process. With the increasingly growing market share of the maritime industry, this valve has been expected to be a high-value-added product. This study not only analyzes the relation between pressure drop and fluid velocity in a trim by using fluid analysis, but also examines the possibility of cavitation in a valve in addition to the plot for the extension of lifespan. Based on the analysis results, the design and production method of the valve are established, and accordingly, performance evaluation is carried out. It is demonstrated that the pressure drop from 345bar to 112bar is more feasible in the presence of the trim, which can induce a continuous and diminutive pressure drop in order to prevent cavitation in a high-pressure drop control valve. Furthermore, despite the fluid velocity near a seatring being found to be over 30m/s, the lifespan of the valve is determined to be adequate considering the operation condition of a prototype valve of 80%.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.5
• /
• pp.1299-1304
• /
• 2014

The electrochemical performance of Li-S cells was investigated in various ternary electrolyte solutions composed of 1,2-dimethoxyethane (DME), tetra(ethylene glycol) dimethyl ether (TGM), and 1,3-dioxolane (DOX). The discharge capacity values and cycle data obtained at each composition were statistically treated with the Minitab program to obtain mixture contour plots, from which the optimal composition of the ternary solvent systems was predicted. The discharge capacities and capacity retention were quite dependent on the electrolyte composition. It was estimated from the contour plots of the capacity at 1.0 C that the discharge capacity sharply increased with a decrease in the TGM content. High capacities greater than 900 mAh/g at 1.0 C were expected for the electrolyte composition with a volume ratio of DME/TGM/DOX = 1/0/1. In contrast, it was predicted from the mixture contour plot of the capacity retention that the cycle performance would significantly increase with an increase in the DME content.

• International Journal of Aeronautical and Space Sciences
• /
• v.17 no.3
• /
• pp.409-422
• /
• 2016

A parametric study based on an unsteady mathematical model of a pyrotechnically actuated device was performed for design optimization. The model simulates time histories for the chamber pressure, temperature, mass transfer and pin motion. It is validated through a comparison with experimentally measured pressure and pin displacement. Parametric analyses were conducted to observe the detailed effects of the design parameters using a validated performance analysis code. The detailed effects of the design variables on the performance were evaluated using the one-at-a-time (OAT) method, while the scatter plot method was used to evaluate relative sensitivity. Finally, the design optimization was conducted by employing a genetic algorithm (GA). Six major design parameters for the GA were chosen based on the results of the sensitivity analysis. A fitness function was suggested, which included the following targets: minimum explosive mass for the uniform ignition (small deviation), light casing weight, short operational time, allowable pyrotechnic shock force and finally the designated pin kinetic energy. The propellant mass and cross-sectional area were the first and the second most sensitive parameters, which significantly affected the pin's kinetic energy. Even though the peak chamber pressure decreased, the pin kinetic energy maintained its designated value because the widened pin cross-sectional area induced enough force at low pressure.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.11 no.2
• /
• pp.250-261
• /
• 1999

Based on a set of performance plots relating the design variables to the imposed conditions, an easy-to-use and versatile design procedure for chevron-type multipass plate heat exchangers is developed. In order for the present procedure to cover multipass with unequal passes and non-unity ratio of heat capacity rate, each stream number of transfer unit is adopted as the basic design variable instead of the exchanger number of transfer unit. It is found that there exists a unique relation between the stream and exchanger number of transfer units regardless of the chevron angle and the plate length. In addition, for a given value of the pressure drop the heat transfer area per unit mass flow rate can be expressed in terms of the stream number of transfer unit only. These two relationships in the form of simple plots constitute the framework of design. The sample results in comparison with the available data indicate that the present procedure includes the previous ones as a subset, and that every design method is affected essentially by the selection of specific correlations for the heat transfer coefficient and the friction factor.