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Estimation of the Lower Explosion Limits Using the Normal Boiling Points and the Flash Points for the Ester Compounds (에스테르화합물에 대한 표준끓는점과 인화점을 이용한 폭발하한계 추산)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.22 no.5
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    • pp.84-89
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    • 2007
  • The lower explosion limit(LEL) is one of the major combustion properties used to determine the fire and explosion hazards of the combustible substances. In this study, the lower explosion limits of the ester compounds were predicted by using the normal boiling points and the flash points based on the liquid thermodynamic theory. As a results, the A.A.P.E.(average absolute percent error) and the A.A.D.(average absolute deviation) of the reported and the calculated the LEL for the ester are 8.80 vol% and 0.18 vol%, respectively and the coefficient of correlation was 0.965. From a given results, by the use of the proposed methodology, it is possible to predict the lower explosion limits of the other flammable materials.

Comparative Study on Active Yaw Control Algorithms (능동 요 제어 알고리즘의 비교 연구)

  • Choi, Hansoon;Lee, Hochul;Bang, Johyug
    • Journal of Wind Energy
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    • v.10 no.3
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    • pp.5-11
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    • 2019
  • This paper suggests and compares two algorithms, a moving average filter method and a method developed by the National Renewable Energy Laboratory (NREL), to verify the yaw control algorithm characteristic to reduce yaw error for a wind turbine. A characteristic change for yaw movement in accordance with control parameter change that consists of each control method has been verified. Also, yaw simulations were performed using nacelle wind data measured from two areas with different turbulence intensities and the yaw movement data in each area was compared. These two algorithms and real data were compared by calculating mean absolute error (MSE) and the number of yawing (NY). As a result of the analysis, the MSE values were not significantly different between the two algorithms, but the algorithm proposed by the NREL was found to reduce yaw movement by up to 50 percent more than the moving average filter method.

Compensating time delay in semi-active control of a SDOF structure with MR damper using predictive control

  • Bathaei, Akbar;Zahrai, Seyed Mehdi
    • Structural Engineering and Mechanics
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    • v.82 no.4
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    • pp.445-458
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    • 2022
  • Some of the control systems used in engineering structures that use sensors and decision systems have some time delay reducing efficiency of the control system or even might make it unstable. In this research, in addition to considering the effect of the time delay in vibration control process, predictive control is used to compensate the time delay. A semi-active vibration control approach with the help of magneto-rheological dampers is implemented. In addition to using fuzzy inference system to determine the appropriate control voltage for MR damper, structural behavior prediction system and specifying future responses are also used such that the time delays occurring within control process are overcome. For this purpose, determination of prediction horizon is conducted for one, five, and ten steps ahead for single degree of freedom structures with periods ranging from 0.1 to 4 seconds, subjected to twenty earthquake excitations. The amount of time delay applied to the control system is 0.1 seconds. The obtained results indicate that for 0.1 second time delay, average prediction error values compared to the case without time delay is 3.47 percent. Having 0.1 second time delay in a semi-active control system reduces its efficiency by 11.46 percent; while after providing the control system with structure behavior prediction, the difference in the results for the control system without time delay is just 1.35 percent on average; indicating a 10.11 percent performance improvement for the control system.

Prediction of Minimum Oxygen Concentration(MOC) of Hydrocarbons and Halogenated Hydrocarbons (탄화수소 및 할로겐화탄화수소의 최소산소농도(MOC)의 예측)

  • Ha Dong-Myeong;Jeong Kee-Sin
    • Fire Science and Engineering
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    • v.19 no.2 s.58
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    • pp.1-7
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    • 2005
  • An accurate knowledge of the minimum oxygen concentration(MOC) is important in developing appropriate prevention and control measures in industrial fire protection. In this study, by using the literature data and RSM(response surface methodology), the new equations for predicting the MOC are proposed. The A.A.P.E.(average absolute percent error) and the A.A.D.(average absolute deviation) of the reported and the calculated MOC for hydrocarbons were $3.48\%\;and\;0.37\;vol\%$, respectively and the correlation coefficient was 0.919. The A.A.P.E and the A.A.D of the reported and the calculated MOC for halogenated hydrocarbons and hydrocarbons were $5.06\%$ and $0.59vo1\%$, and the correlation coefficient was 0.938. The values calculated by the proposed equations were in good agreement with the literature data. Therefore, it is expected that this proposed equations will support the use of the research for other flammable substances.

Prediction of Upper Flammability Limit of Paraffinic Hydrocarbons by Numerical Simulation (수치모사에 의한 파라핀족 탄화수소의 연소상한계의 예측)

  • 하동명
    • Journal of the Korean Society of Safety
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    • v.8 no.3
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    • pp.50-55
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    • 1993
  • A new model for predicting upper flammability limits( UFL ) of paraffinic hydrocarbons is developed, based on statistics and numerical simulation. With the proposed model, UFL have been calculated for 24 compounds, and when compared with experimental data, this model produced average percent error of 2.96%. When compared to established methods published by Spakowski and Zabetakis, this model produced more accurate results.

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An Empirical Study of the Recovery Experiment in Clinical Chemistry (임상화학검사실에서 회수율 실험의 실증적 연구)

  • Chang, Sang-Wu;Lee, Sang-Gon;Song, Eun-Young;Park, Yong-Won;Park, Byong-Ok
    • Korean Journal of Clinical Laboratory Science
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    • v.38 no.3
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    • pp.184-188
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    • 2006
  • The purpose of the recovery experiment in clinical chemistry is performed to estimate proportional systematic error. We must know all measurements have some error margin in measuring analytical performance. Proportional systematic error is the type of error whose magnitude increases as the concentration of analyte increases. This error is often caused by a substance in the sample matrix that reacts with the sought for analyte and therefore competes with the analytical reagent. Recovery experiments, therefore, are used rather selectively and do not have a high priority when another analytical method is available for comparison purposes. They may still be useful to help understand the nature of any bias revealed in the comparison of kit experiments. Recovery should be expressed as a percentage because the experimental objective is to estimate proportional systematic error, which is a percentage type of error. Good recovery is 100.0%. The difference between 100 and the observed recovery(in percent) is the proportional systematic error. We calculated the amount of analyte added by multiplying the concentration of the analyte added solution by the dilution factor(mL standard)/(mL standard + mL specimen) and took the difference between the sample with addition and the sample with dilution. When making judgments on method performance, the observed that the errors should be compared to the defined allowable error. The average recovery needs to be converted to proportional error(100%/Recovery) and then compared to an analytical quality requirement expressed in percent. The results of recovery experiments were total protein(101.4%), albumin(97.4%), total bilirubin(104%), alkaline phosphatase(89.1%), aspartate aminotransferase(102.8), alanine aminotransferase(103.2), gamma glutamyl transpeptidase(97.6%), creatine kinase(105.4%), lactate dehydrogenase(95.9%), creatinine(103.1%), blood urea nitrogen(102.9%), uric acid(106.4%), total cholesterol(108.5), triglycerides(89.6%), glucose(93%), amylase(109.8), calcium(102.8), inorganic phosphorus(106.3%). We then compared the observed error to the amount of error allowable for the test. There were no items beyond the CLIA criterion for acceptable performance.

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Measurement and Prediction of Autoignition Temperature(AIT) of Flammable Substances - Methanol and Ethanol - (가연성물질의 자연발화온도 측정 및 예측 - 메탄올과 에탄올 -)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.19 no.2
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    • pp.54-60
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    • 2004
  • Flammable substances are frequently used chemical industry processes. An accurate knowledge of the ALTs(Autoignition Temperatures) is important in developing appropriate prevention and control measures in industrial fire protection. The AITs describe the minimum temperature to which a substance must be heated, without the application of a flame or spark, which will cause that substance to ignite. The AITs are dependent upon many factors, namely initial temperature, pressure, volume, fuel/air stoichiometry, catalyst material, concentration of vapor, ignition delay. This study measured relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for methanol and ethanol. The A.A.P.E.(Average Absolute Percent Error) and the A.A.D.(Average Absolute Deviation) of the experimental and the calculated delay times by the AITs for methanol were 14.59 and 1.76 respectively. Also the A.A.P.E. and the A.A.D. of the experimental and the calculated delay times by the ATIs for ethanol were 8.33 and 0.88.

Interrelationships of Fire and Explosion Properties for Chlorinated Hydrocarbons (염화탄화수소의 화재 및 폭발 특성치 간의 상관관계)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.17 no.4
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    • pp.126-132
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    • 2002
  • By using the reference data, the empirical equations which describe the interrelationships of explosion properties and physical properties of n-chlorinated hydrocarbons have been derived. The properties which have been correlated are the lower and upper explosive limits, the stoichiometric coefficients, the heats of combustion, the carbon numbers. Also, the new equations using the mathematical and statistical methods for predicting the temperature dependence of lower explosive limits(LEL) of chlorinated hydrocarbons on the basis of the literature data are proposed. The fire and explosion properties calculated by the proposed equations in this research were a good agrement with literature data within a few A.A.P.E.(Average Absolute Percent Error) and A.A.D.(Average Absolute Deviation.) From a given explosive properties, by using the proposed equations, it is possible to predict to the fire and explosion characteristics for the other chlorinated hydrocarbons.

A Study on the Holter Data Compression Algorithm -Using Piecewise Self-Affine Fractal Model- (Holter Data 압축 알고리즘에 관한 연구 -Piecewise Self-Affine Fractal Model을 이용한-)

  • 전영일;정형만
    • Journal of Biomedical Engineering Research
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    • v.16 no.1
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    • pp.17-24
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    • 1995
  • This paper presents a new compression method (or ECG data using iterated contractive transformations. The method represents any range of ECG signal by piecewise self-afrine fractal Interpolation (PSAFI). The piecewise self-afrine rractal model is used where a discrete data set is viewed as being composed of contractive arfine transformation of pieces of itself. This algorithm was evaluated using MIT/BIH arrhythmia database. PSAFI is found to yield a relatively low reconstruction error for a given compression ratio than conventional direct compression methods. The compression ratio achieved was 883.9 bits per second (bps) - an average percent rms difference (AFRD) of 5.39 percent -with the original 12b ECG samples digitized at 400 Hz.

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Non Destructive Fast Determination of Fatty Acid Composition by Near Infrared Reflectance Spectroscopy in Sesame

  • Kang, Churl-Whan;Kim, Dong-Hwi;Lee, Sung-Woo;Kim, Ki-Jong;Cho, Kyu-Chae;Shim, Kang-Bo
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.51 no.spc1
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    • pp.283-291
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    • 2006
  • To investigate seed non destructive and fast determination technique utilizing near infrared reflectance spectroscopy (NIRs) for screening ultra high oleic (C18:1) and linoleic (C18:2) fatty acid content sesame varieties among genetic resources and lines of pedigree generations of cross and mutation breeding were carried out in National Institute of Crop Science (NICS). 150 among 378 landraces and introduced cultivars were released to analyse fatty acids by NIRs and gas chromatography (GC). Average content of each fatty acid was 9.64% in palmitic acid (C16:0), 4.73% in stearic acid (C18:0), 42.26% in oleic acid and 43.38% in linoleic acid by GC. The content range of each fatty acid was from 7.29 to 12.27% in palmitic, 6.49% from 2.39 to 8.88% in stearic, 12.59% of wider range compared to that of stearic and palmitic from 37.36 to 49.95% in oleic and of the widest from 30.60 to 47.40% in linoleic acid. Spectrums analyzed by NIRs were distributed from 400 to 2,500 nm wavelengths and varietal distribution of fatty acids were appeared as regular distribution. Varietal differences of oleic acid content good for food processing and human health by NIRs was 14.08% of which 1.49% wider range than that of GC from 38.31 to 52.39%. Varietal differences of linoleic acid content by NIRs was 16.41% of which 0.39% narrower range than that of GC from 30.60 to 47.01%. Varietal differences of oleic and linoleic acid content in NIRs analysis were appeared relatively similar inclination compared with those of GC. Partial least square regression (PLSR) among multiple variant regression (MVR) in NIRs calibration statistics was carried out in spectrum characteristics on the wavelength from 700 to 2,500 nm with oleic and linoleic acids. Correlation coefficient of root square (RSQ) in oleic acid content was 0.724 of which 72.4 percent of sample varieties among all distributed in the range of 0.570 percent of standard error when calibrated (SEC) which were considerably acceptable in statistic confidence significantly for analysis between NIRs and GC. Standard error of cross validation (SECV) of oleic acid was 0.725 of which distributed in the range of 0.725 percent standard error among the samples of mother population between analyzed value by NIRs analysis and analyzed value by GC. RSQ of linoleic acid content was 0.735 of which 73.5 percent of sample varieties among all distributed in the range of 0.643 percent of SEC. SECV of linoleic acid was 0.711 of which distributed in the range of 0.711 percent standard error among the samples of mother population between NIRs analysis and GC analysis. Consequently, adoption NIR analysis for fatty acids of oleic and linoleic instead that of GC was recognized statistically significant between NIRs and GC analysis through not only majority of samples distributed in the range of negligible SEC but also SECV. For enlarging and increasing statistic significance of NIRs analysis, wider range of fatty acids contented sesame germplasm should be kept on releasing additionally for increasing correlation coefficient of RSQ and reducing SEC and SECV in the future.