• Journal of Korean Society on Water Environment
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• v.37 no.6
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• pp.510-519
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• 2021

Volatile Organic Compounds (VOCs) in sediments, which can cause human health problems, have been monitored in Korea since 2014. Measured VOC concentrations can be affected by matrix type and the volatility of target substances. In this study, (1) VOCs volatility and the influence of matrix interference were confirmed, and (2) internal standards (IS) method was applied to improve analytical method. For these purposes, method detection limit (MDL), calibration linearity, precision and accuracy of VOCs were compared in various matrices using the IS. Some of VOCs in sediments showed different peak areas and reduced rates compared to water matrix. It was suggested that adsorption properties of sediments hindered the migration to vapor during heat pretreatment in headspace method. A calibration curve was created in clean sand. Recovery rates for the calibration curve method and IS applying method were 64.1~83.1% and 99.1~119.3%, respectively. Relative standard deviations ranged from 11.1% to 21.6% for the calibration curve method and those for IS ranged 4.7% to 13.7%. In case of real sediment, calibration curve and 1,2-Dichlorobenzene-d4 (ODCB) among IS were not suitable. The average recovery rate of Fluorobenzene (FBZ) increased by 56.4% and Relative Standard Deviation (RSD) by 4.7%. However, the recovery rate was increased in the samples with large values of igniting intensity. This study confirmed that influence of the matrix of VOCs in sediment, and addition of IS materials improved precision and accuracy. Although IS corrects volatilization and adsorption, it is recommended that more than two types of IS should be added rather than single.

• Journal of Soil and Groundwater Environment
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• v.12 no.2
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• pp.55-64
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• 2007

An analytical method using ion-exchange chromatography was developed for simultaneous quantification of low-molecularweight organic acids ($C_1-C_6$ aliphatic carboxylic acids) and inorganic anions, and then applied to the assessment of ground water contaminated by leachates from a municipal solid waste landfill. Peak interferences of halide ions to organic acids were removed by pretreatment of water samples with Ag-containing cartridges. This method allowed accurate detection of low-molecular weight organic acids (i.e., formate, acetate, propionate, pyruvate, succinate, and oxalateas) low as 0.5 mg/L with a linear dynamic range up to 20 mg/L within 11 min run time along with typical inorganic anions. High level of pyruvate and low level of formate and acetate were detected in groundwater and landfill leachates using the analytical method. Pyruvate concentration in groundwater showed a significant correlation with concentrations of $Cl^-$ and $HCO_3^-$, and pyruvate levels decreased along the downgradient from the landfill, indicating the sources of pyruvate are landfill leachate.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.29 no.7
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• pp.477-483
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• 2018

A transparent antenna designed on the front glass of an automobile operating in the FM broadcast band(88~108 MHz) is proposed. A transparent antenna designed on the front glass of the automobile to avoid space limitation is typically positioned as a roof-mounted shark-fin antenna. An antenna designed on the front glass can reasonably solve the problems of low reception sensitivity and radiated interference from antennas for other service bands. The front glass has a unique closed-line structure, and this structure causes the surface current to flow to the front glass's surroundings; thus, the first resonance is caused before the broadcast band. Through the use of this closed-line structure, the surface current distribution is controlled, and an antenna for which the first resonance is operating in the frequency-modulated(FM) band can be designed. Moreover, the use of a micro-metal-mesh film that is a transparent electrode, suitable for designing a radio frequency device, enables the antenna to minimize visual perception through its transparency. The measured reflection coefficient($S_{11}$) of the antenna is less than -6 dB, and the average peak gain is -0.9 dB in the FM band. Experiments show that the transparent antenna on the front glass offers both the space and design freedom required to develop future automotive antennas.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.47 no.2
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• pp.9-17
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• 2010

Recently, there has been much interest in orthogonal frequency division multiplexing (OFDM) for next generation wireless wideband communication systems. OFDM is a special case of multicarrier transmission, where a single data stream is transmitted over a number of lower-rate subcarriers. One of the main reasons to use OFDM is to increase robustness against frequency-selective fading or narrowband interference. However, in the radio systems it is also important to distortion introduced by high power amplifiers (HPA's) such as solid state power amplifier (SSPA) considered in this paper. Since the signal amplitude of the OFDM system is Rayleigh-distributed, the performance of the OFDM system is significantly degraded by the nonlinearity of the HPA in the OFDM transmitter. In this paper, we propose a canonical piecewise-linear (PWL) model based digital predistorter to prevent signal distortion and spectral re-growth due to the high peak-to-average power ratio (PAPR) of OFDM signal and the nonlinearity of HPA's. Computer simulation on an OFDM system under additive white Gaussian noise (AWGN) channels with QPSK, 16-QAM and 64-QAM modulation schemes and modulator/demodulator implemented with 1024-point FFT/IFFT, demonstrate that the proposed predistorter achieves significant performance improvement by effectively compensating for the nonlinearity introduced by the SSPA.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.44 no.7 s.361
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• pp.17-22
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• 2007

OFDM (Orthogonal Frequency Division Multiplexing) is a special case of multicarrier transmission, where a single data stream is transmitted over a number of lower-rate subcarrier. One of the main reasons to use OFDM is to increase robustness against frequency-selective fading or narrowband interference. Unfortunately, an OFDM signal consists of a number of independently modulated subcarriers, which can give a large PAPR (Peak-to-Average Power Ratio) when added up coherently. In this paper, we investigate the performance of a simple PAPR reduction scheme, which requires no change of a receiver structure or no additional information transmission. The approach we employed is clipping in the time and frequency domains. The time-domain clipping is carried out with a predetermined clipping level while the frequency-domain clipping is done within EVM (Error Vector Magnitude). This approach is suboptimal with lower computational complexity compared to the optimal method. This evaluation is carried out on the OFDM system with an nonlinear amplifier. The simulation results demonstrated that the PAPR reduction algorithm is one of ways to reduce the effects of the nonlinear distortion of an HPA (High Power Amplifier).

• Journal of the Korean Chemical Society
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• v.37 no.10
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• pp.881-887
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• 1993

A cobalt(II) ion-selective carbon-paste electrode (CPE) was constructed with ${\iota}$-sparteine. Cobalt(II) ion in aqueous solution was chemically deposited through the complexation with ${\iota}$-sparteine onto the CPE. The surface of CPEs were characterized by cyclic voltammetry and differential pulse voltammetry in an acetate buffer solution, separately. Exposure of the CPEs to an acid solution could regenerate surface to reuse it for the deposition. In more than 5 deposition / measurement / regeneration cycles, the response was reproducible and linear up to $5.0{\times}10^{-6}$M with linear sweep voltammetry. The peaks at 0.17V / 0.27V were correspond to the redox of Co(II)-SP complex deposited on CPE. The anodic peak of which appeared after scan over the cathodic peak of 0.17 V to more negative scan. In case of using the differencial pulse voltammetry (DPV), we have obtained the linear response $2.0{\times}10^{-7}$M with relative standard deviation ${\pm}5.6%$. The detection limit was $1.0{times}10^{-7}$M for 20 minutes of the deposition. We have also investigated the interference effect of various metal ions, which are expected to form the complex with the ligand on the electrode.

• Journal of the Korean Chemical Society
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• v.40 no.5
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• pp.341-346
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• 1996

Electrochemical determination of iodide was carried out by stripping voltammetry with a $(Cin)Cu(NO_3)_2$ modified-carbon paste electrode. Iodide was coordinated onto the electrode surface containing $(Cin)Cu(NO_3)_2$ via ion exchange. The oxidation peak potential of incorporated iodide was ＋0.72 V. The optimum analytical conditions for the determination of iodide were investigated using linear sweep voltammetry. Optimum conditions for the electrochemical determination of iodide were as follows: i) A predeposition solution was 0.1 M $KNO_3.$ ii) The deposition time was 10 min. iii) The composition of the electrode was 40% (w/w). The detection limit for iodide was $1.0{\times}10^{-6}M$ and the relative standard deviation was ${\pm}5.5%\;in\;2.0{\times}10^{-5}M$(four repetitions). The interference effect of other anions were also investigated. $Cl^-,\;Br^-,\;C_2O_4^{2-},\;and\;ClO_4^-$ ions do not interfere for the determination of iodide. When $SCN^-$ was added to the deposition solution, the oxidation peak current of iodide ion was decreased roughly 32%.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.24 no.3
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• pp.299-309
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• 2013

A comprehensive SAR(Synthetic Aperture Radar) simulation is considered to be a complicated task since a full knowledge of the signal propagation characteristics, antenna pattern, system internal errors and interference noises should be taken into account. In high resolution target application modes, the time varying nature of target RCS(Radar Cross Section) strongly affects the generated SAR images. In this paper, in-depth SAR simulations are performed and analyzed incorporating the STK tools and MATLAB software. STK provides realistic orbit parameters while its radar module helps to extract accurate radiometric parameters of ground targets. SAR raw data corresponding to a given target is generated and processed using MATLAB simulator. The performance is measured by PSLR(Peak Sidelobe Ratio) and ISLR(Integrated Sidelobe Ratio) for a point target, which can be used as reference parameters for accurate radiometric calibration. Finally, high resolution target simulations are performed by adopting time varying target RCS characteristics.

• Journal of Power Electronics
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• v.15 no.3
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• pp.621-633
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• 2015

This paper proposes the analysis and design of a DC-side symmetrical zero-current-switching (ZCS) Class-D current-source driven resonant rectifier to improve the low power-factor and high line current harmonic distortion of lighting applications. An analysis of the junction capacitance effect of Class-D ZCS rectifier diodes, which has a significant impact on line current harmonic distortion, is discussed in this paper. The design procedure is based on the principle of the symmetrical Class-D ZCS rectifier, which ensures more accurate results and provides a more systematic and feasible analysis methodology. Improvement in the power quality is achieved by using the output characteristics of the DC-side Class-D ZCS rectifier, which is inserted between the front-end bridge-rectifier and the bulk-filter capacitor. By using this symmetrical topology, the conduction angle of the bridge-rectifier diode current is increased and the low line harmonic distortion and power-factor near unity were naturally achieved. The peak and ripple values of the line current are also reduced, which allows for a reduced filter-inductor volume of the electromagnetic interference (EMI) filter. In addition, low-cost standard-recovery diodes can be employed as a bridge-rectifier. The validity of the theoretical analysis is confirmed by simulation and experimental results.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.7
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• pp.3431-3436
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• 2013

Band-notched ultra-wideband (UWB) antennas using frequency selective surfaces (FSSs) are presented. The proposed antennas utilized the band rejection characteristic of typical FSS unit cells. We loaded the FSS unit cells on the same plane of planar UWB antenna. These antennas are designed to reject the interference from the wireless local area network band, 5.15-5.825 GHz in the UWB band, 3.1-10.6 GHz. The measured peak gains of the proposed antennas are more than 2 dBi at both operation edge and center frequencies, and sufficient to apply for commercial purpose. The antennas are small size and planar shape for the purpose of the small mobile application, and enhanced design freedom by using various existing FSS unit cells.