• Journal of the Optical Society of Korea
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• v.19 no.6
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• pp.705-710
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• 2015

The fabrication process of thin boron-doped nanocrystalline diamond (B-NCD) microelectrodes on fused silica single mode optical fiber cladding has been investigated. The B-NCD films were deposited on the fibers using Microwave Plasma Assisted Chemical Vapor Deposition (MW PA CVD) at glass substrate temperature of 475 ℃. We have obtained homogenous, continuous and polycrystalline surface morphology with high sp³ content in B-NCD films and mean grain size in the range of 100-250 nm. The films deposited on the glass reference samples exhibit high refractive index (n=2.05 at λ=550 nm) and low extinction coefficient. Furthermore, cyclic voltammograms (CV) were recorded to determine the electrochemical window and reaction reversibility at the B-NCD fiber-based electrode. CV measurements in aqueous media consisting of 5 mM K₃[Fe(CN)₆] in 0.5 M Na₂SO₄ demonstrated a width of the electrochemical window up to 1.03 V and relatively fast kinetics expressed by a redox peak splitting below 500 mV. Moreover, thanks to high-n B-NCD overlay, the coated fibers can be also used for enhancing the sensitivity of long-period gratings (LPGs) induced in the fiber. The LPG is capable of measuring variations in refractive index of the surrounding liquid by tracing the shift in resonance appearing in the transmitted spectrum. Possible combined CV and LPG-based measurements are discussed in this work.

• Nuclear Engineering and Technology
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• v.23 no.1
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• pp.66-80
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• 1991

The LOFT intermediate break experiment L5-1, which simulates 12 inch diameter ECC line break in a typical PWR, has been analyzed using the reactor thermal/hydraulic analysis code RELAP5/MOD2, Cycle 36.04. The base calculation, which modeled the core with single flow channel and two heat structures without using the options of reflood and gap conductance model, has been successfully completed and compared with experimental data. Sensitivity studies were carried out to investigate the effects of nodalization at reactor vessel and core modeling on major thermal hydraulic parameters, especially on peak cladding temperature(PCT). These sensitivity items are : single flow channel and single heat structure (Case A), two flow channel and two heat structures (Case B), reflood option added (Case C) and both reflood and gap conductance options added (Case D). The code, RELAP5/MOD2 Cycle 36.04 with the base modeling, predicted the key parameters of LOFT IBLOCA Test L5-1 better than Cases A,B,C and D. Thus, it is concluded that the single flow channel modeling for core is better than the two flow channel modeling and two heat structure is also better than single heat structure modeling to predict PCT at the central fuel rods. It is, therefore, recommended to use the reflood option and not to use gap conductance option for this L5-1 type IBLOCA.