• 제목/요약/키워드: Pd complex

검색결과 179건 처리시간 0.028초

한반도의 일사량 추정을 위한 청천일 모델의 비교 평가 (Evaluation of Clear Sky Models to Estimate Solar Radiation over the Korean Peninsula)

  • 송아람;최원석;윤창열;김용일
    • 한국측량학회지
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    • 제33권5호
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    • pp.415-426
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    • 2015
  • 구름의 영향 없이 지표면에 도달하는 일사량을 추정하는 것은 일사량 자원지도의 궁극적인 목표이며, 이는 청천일 모델(clear sky model)을 사용하여 이론적으로 추정할 수 있다. 일사량 지도의 정확도는 청천일 모델의 정확도와 연결되기 때문에 연구목적과 연구지역에 적합한 청천일 모델을 선정하고 분석하는 것은 매우 중요하다. 본 연구에서는 대기혼탁 인자를 사용하여 일사량을 추정하는 고차원 모델(ESRA, Dumortier, MODTRAN)과 태양고도를 변수를 하는 일차원 모델(Bourges, PdBV)을 사용하여 한반도의 청천일 일사량을 추정하였으며, 실제 측정 자료와 비교하여 한반도에 적합한 청천일 모델을 분석하고자 하였다. 천리안 기상위성의 가시영상을 사용하여 구름이 없는 청명일을 참조자료로 추출하였으며, RMSE와 MBE를 계산하여 모델별 오차를 분석하였다. 연구결과, Bourges와 PdBV 모델이 실측치와 가장 낮은 RMSE를 가졌으며, PdBV는 계절에 상관없이 비교적 일정한 MBE값을 가졌다. 또한 봄-초여름 기간에 일차원모델은 일사량을 과소 추정하는 경향을 보였으며, 고차원모델은 겨울에 일사량을 과대 추정하는 것으로 나타났다. 추후 모델별로 나타난 오차의 경향 및 계절에 따른 오차를 보정하는 추가 연구를 통하여, 한반도에 최적화된 청천일 일사량 모델을 수정 및 개발할 예정이다.

희귀분석을 이용한 복합 시스템의 열화진단 (Degradation Diagnosis of Complex System Using Regression Analysis)

  • 김성홍;송재주
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 기술교육위원회 창립총회 및 학술대회 의료기기전시회
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    • pp.60-66
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    • 2001
  • 절연체 내부의 보이드로 인하여 부분방전이 발생하면 국부파괴와 완전절연파괴의 원인이 된다. 부분방전으로 생기는 트리잉은 절연재료를 열화 시키고 절연 수명을 단축시키는 중요한 원인이 되므로 절연파괴를 미연에 하여 절연재료 수명을 예측할 수 있는 방법에 대한 연구는 매우 중요하다. 이러한 관점에서 본 연구는 부분방전 및 음향방출 시스템을 이용한 컴퓨터 시스템을 개발하여 각 시스템의 장점을 이용함으로써 열화진단을 실시하였다. 부분방전 시스템의 장점은 음향에 비하여 검출 신호가 양호하고, 고전압 절연 장치의 신뢰성을 평가하기에 적합하다. 또한 음향방출 시스템의 장점은 전자기의 영향을 받지 않고, 열화 과정을 실시간으로 관찰할 수 있다는 것이다. 이 두 가지의 장점을 복합적으로 이용하면 절연재료 내부에서 발생하는 트리의 위치와 부분방전을 효과적으로 할 수 있다. 열화분석 방법으로 먼저 부분방전 펄스와 음향방출 펄스를 희귀분석하여 T검정에 의한 상관계수와 결정계수를 구하여 비교해본 결과 부분방전과 음향방출 펄스는 대체적으로 비슷한 형태를 보였다. 이것은 Yoshimura와 Fujita의 연구 결과와 일치하였다.

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복합 감지 시스템을 이용한 부분방전의 절연열화 수명추정 (A Life Prediction of Insulation Degradation Using Complex Sensing System)

  • 김성홍;김재환;박재준;최재관;윤헌주;이영상
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 추계학술대회 논문집 학회본부
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    • pp.348-350
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    • 1997
  • Because of internal voids ininsulators give rise to partial discharge(PD), which cause local breakdown and even entire insulation breakdown. Treeing due to PD is one of the main causes of breakdown of the insulating materials and reduction of the insulation life. Therefore the necessity for establishing a method to diagnose the aging of insulation materials and to predict the breakdown of insulation has become important. From this viewpoint, our studies diagnose insulation degradation using the method of computer sensing system, which has the advantages of PD and acoustic emission(AE) sensing system. To use advantages of these two methods can be used effectively to search for treeing location and PD in some materials. In analysis method of degradation. We analyzed the PD pulse and AE pulses by regression analysis, compared to these obtained the correlation coefficient and determination coefficient by T-distribution and saw that PD and AE pulses show a similar pattern on the whole. Finally using statically operator such as the center of gravity(G), the gradient of the discharge distribution(C), we have analyzed for the prediction of life which we can be obtained the time, occurred of many pulse of small discharge amplitude.

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회귀분석을 이용한 복합 시스템의 열화진단 (Degradation Diagnosis of Complex System Using Regression Analysis)

  • 김성홍;박재준;김재환
    • 조명전기설비학회논문지
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    • 제13권1호
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    • pp.39-45
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    • 1999
  • 부분방전 및 음향방출측정시스템을 이용한 컴퓨터 시스템을 개발하여 이용함으로써 열화진진을 실시하였다. 부분방전 시스템의 절연체 내부의 보이드로 인하여 부분방전이 발생하면 국부파괴와 완전절연파괴의 원인이 된다. 부분방전으로 생기는 트리잉은 절연재료를 열화 시키고 절연 수명을 단축시키는 중요한 원인이 되므로 절연파괴를 미연에 방지하여 절연재료 수명을 예측할 수 있는 방법에 대한 연구는 매우 중요하다. 이러한 관점에서 본 연구는 부분방전 및 음향방출 장점은 음향에 비하여 검출 신호가 양호하고, 고전압 절연장치의 신뢰성을 평가하기에 적합하다. 또한 음향방출 시스템의 장점은 전자기의 영향을 받지 않고, 열화 과정을 실시간으로 관찰할 수 있다는 것이다. 이 두 가지의 장점을 복합적으로 이용하면 절연재료 내부에서 발생하는 트리의 위치와 부분방전을 효과적으로 할 수 있다. 열화 분석 방법으로 먼저 전기적 펄스와 음향방출 펄스를 회귀분석하여 T검정에 의한 상관계수와 결정계수를 비교해본 결과 부분방전과 음향방출 펄스는 대체적으로 비슷한 형태를 보였다. 이것은 Yoshimura와 Fujital[1, 2]의 연구 결과와 경향이 유사하였다.

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MARS-PD: Meridian Activation Remedy System for Parkinson's Disease

  • Miso S. Park;Chan-young Kim;In-woo Choi;In-cheol Chae;Wangjung Hur;SangSoo Park;Horyong Yoo
    • 대한한방내과학회지
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    • 제44권1호
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    • pp.1-11
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    • 2023
  • Objective: There are currently no disease-modifying medications or definite long-term sustainable interventions for patients with Parkinson's disease (PD), indicating an unmet treatment need. Our goal was to create a long-term sustainable intervention for PD patients that can be used in Korean medicine clinics. Methods: The Meridian Activation Remedy System (MARS) was created to stimulate a patient's 12 meridians and sinew channels using a combination of acupoint stimulation and exercise. The acupoints and motions used in MARS were selected through literature studies and expert advice. The methodologies were refined using observational and case studies. With slow and fast movements, the MARS intervention was intended to activate both slow- and fast-twitch muscle fibers. Intradermal acupuncture and motion that shift the center of gravity were employed to enhance the patient's balance and proprioception. In addition, the intervention included alternating movement exercises to address the complex cognitive decline commonly occurring in PD patients. Results: The following acupoints were chosen for the MARS intervention: bilateral Hegu (LI4), Houxi (SI3), Waiguan (TE5), Neiguan (PC6), Zhongchong (PC9), Yuji (LU10), Zusanli (ST36), Yanglingquan (GB34), Taichong (LR3), Kunlun (BL60), and Taixi (KI3). We also developed actions that can stimulate the body's 12 meridians. Conclusion: We developed the MARS intervention, which combines acupuncture and exercise, to address the unmet therapeutic needs of PD patients. We hope that with additional research, the MARS intervention can be set as an effective therapeutic program for PD patients.

An Attention-based Temporal Network for Parkinson's Disease Severity Rating using Gait Signals

  • Huimin Wu;Yongcan Liu;Haozhe Yang;Zhongxiang Xie;Xianchao Chen;Mingzhi Wen;Aite Zhao
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제17권10호
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    • pp.2627-2642
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    • 2023
  • Parkinson's disease (PD) is a typical, chronic neurodegenerative disease involving the concentration of dopamine, which can disrupt motor activity and cause different degrees of gait disturbance relevant to PD severity in patients. As current clinical PD diagnosis is a complex, time-consuming, and challenging task that relays on physicians' subjective evaluation of visual observations, gait disturbance has been extensively explored to make automatic detection of PD diagnosis and severity rating and provides auxiliary information for physicians' decisions using gait data from various acquisition devices. Among them, wearable sensors have the advantage of flexibility since they do not limit the wearers' activity sphere in this application scenario. In this paper, an attention-based temporal network (ATN) is designed for the time series structure of gait data (vertical ground reaction force signals) from foot sensor systems, to learn the discriminative differences related to PD severity levels hidden in sequential data. The structure of the proposed method is illuminated by Transformer Network for its success in excavating temporal information, containing three modules: a preprocessing module to map intra-moment features, a feature extractor computing complicated gait characteristic of the whole signal sequence in the temporal dimension, and a classifier for the final decision-making about PD severity assessment. The experiment is conducted on the public dataset PDgait of VGRF signals to verify the proposed model's validity and show promising classification performance compared with several existing methods.

Anionic Indicators on the Surface of Submicrospheres Consisting of Ionic Palladium(II) Complex

  • Kim, Cho-Rong;Noh, Tae-Hwan;Yoo, Kyung-Ho;Yoo, Bok-Ryul;Jung, Ok-Sang
    • Bulletin of the Korean Chemical Society
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    • 제30권12호
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    • pp.3057-3060
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    • 2009
  • Ionic palladium(II) complex, [($Me_4en)Pd(L)]_2(ClO_4)_4\;(Me_4$en = N,N,N',N'-tetramethylethylenediamine; L = bis-(4-(4-pyridylcarboxyl)phenyl)methane), allows to form a monodisperse submicrosphere without any template or additive. Surface-perchlorates on the submicrosphere have been exchanged by anionic pH indicators such as thymol blue, bromothymol blue, and bromocresol green. The ionic and amphiphilic properties of the palladium(II) complex appear to be primarily associated with the formation and easy surface-anion exchange of submicrosphere. The surface-anion exchange through the electrostatic interaction is a very good tool for the surface-modification. The color of the pH indicator-exchanged submicrospheres is very sensitive to pH and Hg$^{2+}$ cation, and thus they are promising to submicrospherical indicators.

Interaction Studies of a Novel, Water-Soluble and Anti-Cancer Palladim(II) Complex with Calf Thymus DNA

  • Mansouri-Torshizi, H.;Saeidifar, M.;Divsalar, A.;Saboury, A.A.;Shahraki, S.
    • Bulletin of the Korean Chemical Society
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    • 제31권2호
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    • pp.435-441
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    • 2010
  • We report the preparation and characterization of a new and water soluble complex of palladium(II) with 1,10- phenanthroline and butyldithiocarbamate ligands. This compound has been studied through spectroscopic techniques, $^1H$ NMR, IR, electronic spectra and elemental analysis and conductivity measurements. The complex shows 50% cytotoxic concentration ($Ic_{50}$) value against chronic myelogenous leukemia cell line, K562, much lower than that of cisplatin. Thus the mode of binding of this complex to calf thymus DNA have been extensively investigated by isothermal titration UV-visible spectrophotometry, fluorescence, gel filteration and other methods. UV-visible studies show that the complex exhibits cooperative binding with DNA and remarkably denatures the DNA at extremely low concentration ($~13\;{\mu}M$). Fluorescence studies indicate that the complex intercalate into DNA. Gel filtration studies suggest that the binding of Pd(II) complex with DNA is strong enough that it does not readily break. In these interaction studies, several thermodynamic and binding parameters are also determined which may reflect the mechanism of action of this type of compound with DNA.

Greening에 따른 유채 자엽의 엽록소-단백질 복합체 형성 (Formation of Chlorophyll-Protein Complexes in Greening Rape Cotyledons)

  • 이진범
    • Journal of Plant Biology
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    • 제26권2호
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    • pp.91-99
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    • 1983
  • The formation of chlorophyll-protein complexes (CP-complexes) during the greening of rape cotyledons (Brassica napus cv. Yongdang) was investigated by the SDS-polyacrylamide gel electrophoresis. The total chlorophyll content and Chl a/b ratio were also determined. In addition, the effects of dark treatment on the CP-complex patterns during greening have been examined with respect to their photosynthetic electron transport activity. Greening has brought about the increasein total chlorophyll content and the decrease in Chl a/b ratio, but there have been no changes in Chl a/b ratio after 24 hrs of greening. The light-harvesting chlorophyll a/b-protein complex (LHCP-complex0 was predominant during the initial greening period. Thereafter, the amout of chlorophyll a-protein complex (CP I-complex) was gradually increased. Twenty-four-hr dark treatment immediately after illumination for 6 hrs and 12 hrs resulted in the increase of the Chl a/b ration and the CP I complex, otherwise the decrease of the LHCP-complex. The LHCP/CP I ratio was gradually decreased with further greening, and appeared no change after 48 hrs illumination. The investigation of the photosynthetic electron transport activity indicated that photosystem (PS) II activity (H2Olongrightarrowp-PD*+FeCy**) did not change, but the activity of PS I was increased suddenly due to the dark treatment. The data suggests that the increase of CP I-complex may result in that of P-700, that is, the increase of PS I activity.

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The Plant Cellular Systems for Plant Virus Movement

  • Hong, Jin-Sung;Ju, Ho-Jong
    • The Plant Pathology Journal
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    • 제33권3호
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    • pp.213-228
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    • 2017
  • Plasmodesmata (PDs) are specialized intercellular channels that facilitate the exchange of various molecules, including sugars, ribonucleoprotein complexes, transcription factors, and mRNA. Their diameters, estimated to be 2.5 nm in the neck region, are too small to transfer viruses or viral genomes. Tobacco mosaic virus and Potexviruses are the most extensively studied viruses. In viruses, the movement protein (MP) is responsible for the PD gating that allows the intercellular movement of viral genomes. Various host factors interact with MP to regulate complicated mechanisms related to PD gating. Virus replication and assembly occur in viral replication complex (VRC) with membrane association, especially in the endoplasmic reticulum. VRC have a highly organized structure and are highly regulated by interactions among the various host factors, proteins encoded by the viral genome, and the viral genome. Virus trafficking requires host machineries, such as the cytoskeleton and the secretory systems. MP facilitates the virus replication and movement process. Despite the current level of understanding of virus movement, there are still many unknown and complex interactions between virus replication and virus movement. While numerous studies have been conducted to understand plant viruses with regards to cell-to-cell movement and replication, there are still many knowledge gaps. To study these interactions, adequate research tools must be used such as molecular, and biochemical techniques. Without such tools, virologists will not be able to gain an accurate or detailed understanding of the virus infection process.