• 제목/요약/키워드: Pb-free bismuth sodium barium titanate

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비납계 (Bi0.5Na0.5)(1-x)BaxTiO3 압전 세라믹 재료의 최적 조성 (Optimum Compositions for Piezoelectric Properties of Pb-free (Bi0.5Na0.5)(1-x)BaxTiO3 Ceramics)

  • 성연수;여홍구;조종호;송태권;정순종;송재성;김명호
    • 한국재료학회지
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    • 제17권2호
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    • pp.68-72
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    • 2007
  • Optimum compositions for piezoelectric properties of $(Bi_{0.5}Na_{0.5})_{(1-x)}Ba_xTiO_3$ ceramics were investigated in the range of $x=0{\sim}0.1$ covering rhombohedral to tetragonal phase regions. No impurity phases other than a perovskite phase were found and the grain size decreased with increasing x. A two-phase coexisting morphotropic phase area rather than boundary dividing rhombohedral and tetragonal phase regions appeared to exist at $x=0.05{\sim}0.08$. As for piezoelectric properties within morphotropic phase compositions, the piezoelectric constant ($d_{33}$) and the electromechanical coupling factor ($K_p$) showed peak values at x=0.065, 192 pC/N and 34%, respectively, indicating x=0.065 as an optimum composition for piezoelectric $(Bi_{0.5}Na_{0.5})_{(1-x)}Ba_xTiO_3$ ceramics.