• Title/Summary/Keyword: Pb band

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A Study on IR Spectrum Characteristics of $PbTiO_3$ Thin Film and Pyroelectric Detector Modeling. ($PbTiO_3$ 박막의 적외선 스펙트럼특성과 초전감지소자의 모델링에 관한 연구)

  • Kim, Sung-Min;Lee, Moon-Key;Kim, Bong-Ryul
    • Proceedings of the KIEE Conference
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    • 1987.07a
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    • pp.439-443
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    • 1987
  • $PbTiO_3$ thin film is prepared by rf sputtering method to implement the pyroelectric infrared detector at room temperature. Annealing of $PbTiO_3$ thin film is done from $400^{\circ}C$ to $550^{\circ}C$ each for 2 hours in furnace. The spectral response to recrystallization process of $PbTiO_3$ thin film is measured by IR photospectro meter. Pyroelectric detector Modeling is studied for implementing device using electrical equivalent circuit model. It is found that $PbTiO_3$ thin film has two IR absorption band within $1000-400\;cm^{-1}$ (10um-25um) and it's spectral response is improved as annealing temperature increase. As a result of pyroelectric detector modeling, we find the possibility of implementing optimum device structure.

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Simple Fabrication of Green Emission and Water-Resistant CsPbBr3 Encapsulation Using Commercial Glass Frits (상업용 유리프릿의 소결 공정을 이용한 내수성을 갖는 CsPbBr3/Glass 세라믹 복합체의 제작)

  • Mun, Na-eun;Kim, Sunghoon
    • Korean Journal of Materials Research
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    • v.31 no.1
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    • pp.54-59
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    • 2021
  • In this work, narrow-band green-emitting CsPbBr3 particles are embedded in commercialized glass composites by a facile dry process. By optimizing the method through sintering in glass frit (GF) composites including CsBr and PbBr2, used as precursors, the encapsulation of CsPbBr3 particles made them waterproof with green fluorescence. To improve the fluorescent properties by reducing aggregation of CsPbBr3, fumed silica (FS) is additionally used to help particles avoid bulking up in the glass matrix. The CsPbBr3 perovskite/glass composites are characterized using scanning electron microscopy (SEM) images and energy-dispersive X-ray spectroscopy (EDS) maps, which support the existence of CsPbBr3 particles in the glass matrix. The photoluminescence (PL) properties demonstrate that the emission spectrum peak, full width at half maximum (FWHM), and photoluminescence quantum yield (PLQY) values are 519 nm, 17 nm, and 17.7 %. We also confirm the water-resistant properties. To enhance water/moisture stability, the composite sample is put directly into water, with its PLQY monitored periodically under UV light.

Facile and Room Temperature Preparation and Characterization of PbS Nanoparticles in Aqueous [EMIM][EtSO4] Ionic Liquid Using Ultrasonic Irradiation

  • Behboudnia, M.;Habibi-Yangjeh, A.;Jafari-Tarzanag, Y.;Khodayari, A.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.1
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    • pp.53-56
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    • 2009
  • At room-temperature, a facile, seedless, and environmentally benign green route for the synthesis of star like PbS nanoclusters at 7 min in aqueous solution of 1-ethyl-3-methylimidazolium ethyl sulfate, [EMIM] [$EtSO_{4}$], room-temperature ionic liquid (RTIL), via ultrasonic irradiation is proposed. The X-ray diffraction studies display that the products are excellently crystallized in the form of cubic structure. An energy dispersive X-ray spectroscopy (EDX) investigation reveals the products are extremely pure. The absorption spectra of the product exhibit band gap energy of about 4.27 eV which shows an enormous blue shift of 3.86 eV that can be attributed to very small size of PbS nanoparticles produced and quantum confinement effect. A possible formation mechanism of the PbS nanoparticles using ultrasonic irradiation in aqueous solution of the RTIL is presented.

Efficient Resource Allocation Scheme for Improving the Throughput in the PB/MC-CDMA System (PB/MC-CDMA 시스템에서 처리량 향상을 위한 효율적인 자원 할당 기법)

  • Lee, Kyujin;Seo, HyoDuck;Han, DooHee
    • Journal of Convergence Society for SMB
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    • v.4 no.1
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    • pp.1-6
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    • 2014
  • PB/MC-CDMA is an efficient system which divides the whole frequency band into several blocks, unlike a conventional MC-CDMA system. We propose an efficient resource allocation scheme in Multi-Block PB/MC-CDMA (Partial Block Multi-Carrier Code Division Multiple Access). This system aims to improve frequency efficiency and maximize the total throughput while satisfying predefined threshold over various channel conditions. Through computer simulations, we confirm that the performance of the proposed system is more effective in terms of throughput.

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TOWARDS A SAFER ENVIRONMENT: 3) PHOSPHATIC CLAYS AS SOLUTION FOR REMOVING PB2+ FROM WASTEWATER

  • ABDALLAH SAMY MOHAMED
    • Proceedings of the Korea Water Resources Association Conference
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    • 2005.09b
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    • pp.1179-1180
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    • 2005
  • To immobilize the pollutants from wastewater in situ, two phosphatic clays collected from different areas in Egypt (eastern and western Sebaia, Aswan-Isna, Upper Egypt) used to remove contaminant ions from industrial wastewater. Obtained results confirmed the strong relationship between phosphatic clay and Pb elimination from wastewater. The sensitivity classification of phosphatic clay toward ions retained as described in three categories: highly sensitive to retain Pb , Al and Cr ; moderately sensitive for Mn; and weakly sensitive for Band Zn. Data suggested that large fraction of Pb removed by phosphatic clays stayed intact under a wide variation in extracting solution pH (3-11). In situ immobilization is considered a promising technique that has the potential to remove contaminant ions from wastewater. Two important factors need to be considered when applying this technique: The first, is the clay must be effective and selective under different composition of wastewater. The second, is the immobilized ions should be stable and non-leacheable under varying water conditions. Phosphatic clays with $Pb^{2+}$ were suitable to achieve these two factors. Possible mechanism for removal $Pb^{2+}$ by phosphatic clays is the formation of fluoropyromorphite through the dissolution of fluoro and hydroxyl apatite by its precipitation from solution, beside, Pb complexation at phosphatic clay surface at P-OH sites.

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Temperature Driven Phase Transition of Organic-Inorganic Halide Perovskite Single Crystals

  • Byun, Hye Ryung;Kim, Hyo In;Byun, Su Jeong;Park, Dae Young;Jeong, Mun Seok;Byeon, Clare Chisu
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1729-1734
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    • 2018
  • Organic-inorganic halide perovskite single crystals undergo phase transition of being cubic, tetragonal, or orthorhombic depending on the temperature. We investigated the $CH_3NH_3PbBr_{3-x}I_x$ single crystals grown by the inverse temperature crystallization method with temperature-dependent UV-Vis absorption and photoluminescence. From the temperature-dependent absorption measurement, the optical band gap is extracted by derivation of absorption spectrum fitting and Tauc plot. In our results, $CH_3NH_3PbBr_{3-x}I_x$ single crystals show that an abrupt change in optical band gap, PL peak position and intensity appears around 120 K - 170 K regions, indicating the phase transition temperature.

Exposure dose reduce of Dental Panoramagraphy using a Pb band (자체제작 Pb 밴딩을 이용한 피폭선량 감소)

  • Kim, Chang-Gyu
    • Proceedings of the KAIS Fall Conference
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    • 2011.05b
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    • pp.586-589
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    • 2011
  • 치과 진료시 파노라마 장치를 이용한 검사에서 유리선량계를 사용하여 피검자의 피폭선량을 측정하였다. 특히 방사선에 민감한 수정체의 피폭선량을 줄이기 위하여 자체 제작한 Pb 밴딩의 크기에 따라 수정체 피폭선량을 측정한 결과 Pb밴딩의 크기에 따라서 수정체의 피폭선량이 다르다는 것을 확인할 수 있었다. Pb밴딩의 크기가 3*20*0.2cm에서는 정상치보다 피폭선량이 증가하는 경향을 보였으며 5*20*0.2cm 이상의 크기에서는 피폭선량이 감소하는 결과를 보였다. 또한 획득되어진 영상 7*20*0.2cm 크기에서 진단에 부적합한 영상으로 판정 되었다. 그러므로 피폭선량을 최소화하고 효과적인 파노라마 검사를 수행하기 위해서는 Pb 밴딩 5*20*0.2cm이상 6*20*0.2cm이하 크기를 사용하여 검사에 활용하면 피폭선량이 감소될 것으로 기대한다.

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Development of Highly Sensitive SWIR Photodetectors based on MAPI-capped PbS QDs (MAPI 리간드 치환형 PbS 양자점 기반의 고감도 단파장 적외선 광 검출기 개발)

  • Suji Choi;JinBeom Kwon;Yuntae Ha;Daewoong Jung
    • Journal of Sensor Science and Technology
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    • v.33 no.2
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    • pp.93-97
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    • 2024
  • With the development of promising future mobility and urban air mobility (UAM) technologies, the demand for LIDAR sensors has increased. The SWIR photodetector is a sensor that detects lasers for the 3D mapping of lidar sensor and is the most important technology of LIDAR sensor. An SWIR photodetector based on QDs in an eye-safe wavelength band of over 1400 nm has been reported. QDs-based SWIR photodetectors can be synthesized and processed through a solution process and have the advantages of low cost and simple processing. However, the organic ligands of QDs have insulating properties that limit their ability to improve the sensitivity and stability of photodetectors. Therefore, the technology to replace organic ligands with inorganic ligands must be developed. In this study, the organic ligand of the synthesized PbS QDs was replaced with a MAPI inorganic ligand, and an SWIR photodetector was fabricated. The analysis of the characteristics of the manufactured photodetector confirmed that the photodetector based on MAPI-capped PbS QDs exhibited up to 26.5% higher responsivity than that based on organic ligand PbS QDs.

Design and Fabrication of Thin Microwave Absorbers of ITO/Dielectric Structures Used for Mobile Telecommunication Frequency Bands (ITO박막/세라믹유전체 구조의 이동통신 주파수대역용 박형 전파흡수체의 설계 및 제조)

  • Yoon, Yeo-Choon;Kim, Sung-Soo
    • Korean Journal of Materials Research
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    • v.13 no.4
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    • pp.259-265
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    • 2003
  • For the aim of thin microwave absorbers used in mobile telecommunication frequency band, this study proposed a high permittivity dielectrics(λ/4 spacer) coated with ITO thin films of 377 $\Omega$/sq(impedance transformer). High frequency dielectric properties of ferroelectric ceramics, electrical properties of ITO thin films and microwave absorbing properties of ITO/dielectrics were investigated. Ferroelectric materials including $BaTiO_3$(BT), 0.9Pb($Mg_{1}$3/Nb$_{2}$3/)$O_3$-0.1 $PbTiO_3$(PMN-PT), 0.8 Pb (Mg$_{1}$3/$Nb_{2}$3/)$O_3$-0.2 Pb($Zn_{1}$3$_Nb{2}$3/)$O_3$(PMN-PZN) were prepared by ceramic processing for high permittivity dielectrics,. The ferroelectric materials show high dielectric constant and dielectric loss in the microwave frequency range. The microwave absorbance (at 2 ㎓) of BT, 0.9PMN-0.1PT, and 0.8PMN-0.2PZN were found to be 60%(at a thickness of 3.5 mm), 20% (2.5 mm), and 30% (2.5 mm), respectively. By coating the ITO thin films on the ferroelectric substrates with λ/4 thickness, the microwave absorbance is greatly improved. Particularly, when the surface resistance of ITO films is closed of 377 $\Omega$/sq, the reflection loss is reduced to -20 ㏈(99% absorbance). This is attributed to the wave impedance matching controlled by ITO thin films at a given thickness of high permittivity dielectrics of λ/4 (3.5 mm for BT, 2.5 mm for PMN-PT and PMN-PZN at 2 ㎓). It is, therefore, successfully proposed that the ITO/ferroelectric materials with controlled surface resistance and high dielectric constant can be useful as a thin microwave absorbers in mobile telecommunication frequency band.