• Title/Summary/Keyword: Passive sampling

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The Development of Exposure Assessment Tools for Risk Assessment of Volatile Organic Compounds (VOCs의 위해성 평가를 위한 노출분석 방법 연구)

  • Jo, Seong-Joon;Shin, Dong-Chun;Chung, Yong;Lee, Duck-Hee;Breysse, Patrick N.
    • Environmental Analysis Health and Toxicology
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    • v.17 no.2
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    • pp.147-160
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    • 2002
  • Volatile organic compounds (VOCs) are an important public health issue in Korea and many important questions remain to be addressed with respect to assessing exposure to these compounds. Because they are ubiquitous and highly volatile, special techniques must be applied in their analytic determination Valid Personal exposure assessment methods are needed to evaluate exposure frequency, duration and intensity, as well as their relationship to personal exposure characteristics. Biological monitoring is also important since it may contribute significantly in risk assessment by allowing the estimation of effective absorbed doses. This study was on ducted to establish the environmental measurement, personal dosimetry and biological monitoring methods for VOCs. These methods are needed to compare blood, urinary and exhalation breath VOC levels and to provide tools for risk assessment of VOC exposure. Passive monitors (badge type) and a active samplers (trap) for the VOCs collection were used for air sampling. Methods development included determining the minimum detectable amounts of VOCs in each media, as well as evaluating collection methods and developing analytical procedures. Method reliability was assessed by determining breakthrough volumes and comparing results between laboratories and with other methods. A total capacity of trap used in this study was 60ι. Although variable by compound, the average breakthrough was 20%. Also, there was no loss of compounds in trap even if keep for 45 day in -7$0^{\circ}C$. The recovery of active and passive methods was 69% ~ 126% and method detection limit was 0.24 $\mu\textrm{g}$/trap and 0.07 $\mu\textrm{g}$/badge. There was no statistical difference (P > 0.05) between active and passive methods.

Efficient Localization of a Mobile Robot Using Spatial and Temporal Information from Passive RFID Environment (수동 RFID 환경에서의 공간/시간 정보를 이용한 이동로봇의 효율적 위치 추정 기법)

  • Kim, Sung-Bok;Lee, Sang-Hyup
    • Journal of the Institute of Convergence Signal Processing
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    • v.9 no.2
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    • pp.164-172
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    • 2008
  • This paper presents the efficient localization of a mobile robot traveling on the floor with tags installed, using the spatial and temporal information acquired from passive RFID environment. Compared to previous research, the proposed localization method can reduce the position estimation error and also cut down the initial cost tag installation cost. Basically, it is assumed that a mobile robot is traveling over a series of straight line segments, each at a certain constant velocity, and that the number of tags sensed by a mobile robot at each sampling instant is at most one. First, the velocity and position estimation of a mobile robot starting from a known position, which is valid for all segments except the first one. Second, for the first segment in which the starting position is unknown, the velocity and position estimation is made possible by enforcing a mobile robot to traverse at least two tags at a constant velocity with the steering angle unchanged. Third, through experiments using our passive RFID localization system, the validity and performance of the mobile robot localization proposed in this paper is demonstrated.

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A Review on the Sampling and Analytical Methods for Ammonia in Air

  • Das, Piw;Kim, K.H.;Sa, J.H.;Kim, J.C.;Lee, S.R.;Jeon, E.C.
    • Journal of the Korean earth science society
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    • v.28 no.5
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    • pp.572-584
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    • 2007
  • The quantification of ammonia concentrations has received a lot of scientific attention. Numerous devices for the quantification of $NH_3$ in the ambient air have been developed to provide more technical possibilities for research in abating $NH_3$ emission from various source processes. For the proper quantification of $NH_3$, a number of sampling methods have been discussed by grouping them into different categories based on the principle of functioning. In general, active samplers employ pumps to draw air in, while passive samplers are exposed to air over a certain period of time to obtain integrated signature of $NH_3$. In case of the former, impingers and absorption flasks can be employed simultaneously with suitable absorbents to capture $NH_3$ passing through them. The methods of analysis include both in-situ and laboratory determination. In the laboratory, colorimetric or ion chromatographic methods are generally used for its quantification. In the field, a number of real time analyzers have been proven to be useful. These real time analyzers can be grouped according to their principle of operation. These analyzers may use the principle of spectroscopy (e.g. DOAS), photoacousticics (e.g. photoacoustic monitor) or Chemiluminescence ($NO_x$ analyzer). The automated annular denuder sampling system with on-line analyzer is also suitable for continuous monitoring of ammonia in air.

The effects of face velocity and path length on the uptake rates of volatile organic compounds measured by diffusive samplers (확산포집기로 공기중 ppb 농도수준의 휘발성유기물질 포집시 확산길이와 기류변화가 시료포집속도에 미치는 영향)

  • Byeon, Sang-Hoon;Stock, Thomas H.;Morandi, Maria T.;Afshar, Masoud;Cross, Jay
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.11 no.1
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    • pp.34-41
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    • 2001
  • Passive samplers have been used for personal, indoor, and outdoor air monitoring of VOCs at ppb concentrations in community and office environments. The path length of modified passive sampler was shortened, so it was intended to increase an uptake rate. The performance of the modified 3M 3500 organic vapor monitor(OVM) as a tool for assessing exposures to toxic air pollutants in nonoccupational community environments was evaluated using combined controlled test atmospheres of six selected target volatile organic compounds(VOCs): benzene, methyl tert-butyl ether(MTBE), chloroform, 1,4-dichlorobenzene, tetrachloroethylene, and toluene. The experiments were conducted by exposing the dosimeters to concentrations of $50{\sim}100{\mu}g/m^3$ on six face velocity(0.00, 0.02, 0.06, 0.12, 0.20, 0.30 m/sec) for 24 hours. If the uptake rate was increased, that means that we could use the passive sampler more effectively. The uptake rates were increased linearly according to reduce the path length. Although the diffusion path length was shortened, the change of uptake rate was within ${\pm}25%$ of theoretical value, indicating that the modified passive sampler(TM) can be effectively used over the range of concentrations and environmental conditions tested with a 24-h sampling period if the face velocities were over 0.12 m/s for 6 components of VOCs. But when the face velocities were less than 0.12 m/s, uptake rates were reduced more than expected values. So, the passive sampler with the shortened path length should be used at indoor or outdoor environment where the face velocity should be over about 0.10 m/s. If the path length was shortened more, the uptake rate was more effected by starvation.

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High Resolution Hydroacoustic Investigation in Shallow Water for the Engineering Design of Railroad Bridge (철도교량 설계 지반조사를 위한 고분해능 수면 탄성파반사법의 응용 사례)

  • ;Swoboda Ulrich
    • Proceedings of the Korean Geotechical Society Conference
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    • 2001.03a
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    • pp.231-238
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    • 2001
  • To investigate the underground structure of shallow water, Han-river near Yangsou-Ri, high resolution hydroacoustic measurements were carried out for the engineering design of railroad bridge. The acoustic source was a Boomer with an energy of 90 to 280J and in a frequency range up to about 16KHz. The reflected signals were received by using both traditional hydrophones(passive element) and a specially devised receiver unit(active element) mainly composed of piezofilms and preamplifier. They are connected to the "SUMMIT" data acquisition system(DMT-GeoTec company), where the sampling interval was set to 1/32㎳. The source position was continuously monitored by a precision DGPS system whose positioning accuracy was on the order of loom. For the quality control purposes, two different source-receiver geometries were taken. That is to say, the measurements were repeated along the profile everytime depending on the different source energy(175J, 280J), the receiving elements(passive, active) and two different source-receiver geometries. It was shown that the data resolution derived from a proper arrangement with the active hydrophone could be greatly enhanced and hence the corresponding profile section caused by the regular data processing system "FOCUS" accounted excellently for the underground formation below the shallow water.w the shallow water.

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Iontophoretic Transport of GHRP-6 (성장호르몬방출펩타이드-6 (GHRP-6)의 경피투과)

  • Choi, Bo-Kyung;Oh, Seaung-Youl
    • Journal of Pharmaceutical Investigation
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    • v.31 no.4
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    • pp.273-279
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    • 2001
  • The purpose of this study is to characterize the iontophoretic transport of growth hormone releasing peptides (GHRP-6) through hairless mouse skin from aqueous solution. The effect of various factors, such as pH, poloarity, current profile, current density, current duration, ionic strength, drug concentration, and enhancer application was studied to obtain basic knowledge on the transport. We have also studied the stability of GHRP-6 in solution with/without current. The donor chamber was filled with phosphate buffer solution containing GHRP-6 and the receptor chamber was filled with phosphate buffer solution (pH 7.4). Ag/AgCl electrode was used for their stability and reversibility. At a predetermined time interval, sampling was made and the concentration of drug was analysed using HPLC system. The results showed that, compared to passive flux, the total amount of drug transported increased markedly by the application of anodal current. Cathodal flux was similar to passive flux. Flux increased with the current density, the duration of current application and drug concentration. The effect of enhancers on the flux was studied using hydrophilic (5% N-methyl pyrrolidone) and hydrophobic (5% propylene glycol monolaurate, 5% oleic acid) enhancers. Application of enhancer also increased the flux.

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VHDL Implementation of GEN2 Protocol for UHF RFID Tag (RFID GEN2 태그 표준의 VHDL 설계)

  • Jang, Il-Su;Yang, Hoon-Gee
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.32 no.12A
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    • pp.1311-1319
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    • 2007
  • This paper presents the VHDL implementation procedure of the passive RFID tag operating in Ultra High Frequency. The operation of the tag compatible with the EPCglobal Class1 Generation2(GEN2) protocol is verified by timing simulation after synthesis and implementation. Due to the reading range with relatively large distance, a passive tag needs digital processor which facilitates faster decoding, encoding and state transition for enhancement of an interrogation rate. In order to satisfy linking time, the pipe-line structure is used, which can minimize latency to serial input data stream. We also propose the sampling strategy to decode the Preamble, the Frame-sync and PIE symbols in reader commands. The simulation results with the fastest data rate and multi tags environment scenario show that the VHDL implemented tag performs faster operation than GEN2 proposed.

A Digital Readout IC with Digital Offset Canceller for Capacitive Sensors

  • Lim, Dong-Hyuk;Lee, Sang-Yoon;Choi, Woo-Seok;Park, Jun-Eun;Jeong, Deog-Kyoon
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.12 no.3
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    • pp.278-285
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    • 2012
  • A digital readout IC for capacitive sensors is presented. Digital capacitance readout circuits suffer from static capacitance of sensors, especially single-ended sensors, and require large passive elements to cancel such DC offset signal. For this reason, to maximize a dynamic range with a small die area, the proposed circuit features digital filters having a coarse and fine compensation steps. Moreover, by employing switched-capacitor circuit for the front-end, correlated double sampling (CDS) technique can be adopted to minimize low-frequency device noise. The proposed circuit targeted 8-kHz signal bandwidth and oversampling ratio (OSR) of 64, thus a $3^{rd}$-order ${\Delta}{\Sigma}$ modulator operating at 1 MH was used for pulse-density-modulated (PDM) output. The proposed IC was designed in a 0.18-${\mu}m$ CMOS mixed-mode process, and occupied $0.86{\times}1.33mm^2$. The measurement results shows suppressed DC power under about -30 dBFS with minimized device flicker noise.

Exposure Assessment of Hazardous Chemical Agents for Dental Technicians in Ulsan City (울산지역 치과기공사들의 화학적 유해요인 노출 평가)

  • Hong, Youngho;Choi, Sangjun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.21 no.4
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    • pp.215-221
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    • 2011
  • Objectives: This study was conducted to evaluate the exposure level of hazardous chemical agents for dental technicians in Ulsan. Methods: We measured airborne total dusts and metals such as Nickel, Manganese, Cobalt, and Chromium in 10 dental laboratories by the NIOSH Methods 0500 and 7300, respectively. Methyl methacrylate (MMA), a key ingredient in acrylic resin, was also monitored using passive samplers for long-term sampling and Tenax tubes for short-term sampling. Results: Measured levels of all items were below 10% of the Korean exposure limit except for Nickel. The geometric mean concentration and geometric standard deviation of total dust, Nickel, and MMA were $0.14mg/m^3$ (2.16), $165.3{\mu}g/m^3$ (3.31), and 0.2 ppm (2.5) respectively. Airborne Nickel concentration of two dental laboratories exceeded the exposure limit ($1000{\mu}g/m^3$). The major emission sources of Nickel were metal trimming and casting processes. Conclusions: We found that Nickel, a carcinogen, should be controled most urgently to protect dental technicians.

The Study on the Effects of Air Pollution on the Material Damages in Northeast Asia

  • Kim, Sun-Tae;Yasuaki Maeda
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.E2
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    • pp.51-61
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    • 2003
  • The material exposure tests have been carried out since 1993 to evaluate the relationship between air pollution and material corrosion with the cooperation of the researchers in Japan, China, and Korea. The test pieces such as bronze, copper, marble, and carbon steel have been exposed under both unsheltered and rain-sheltered outdoor condition separately at 18 sampling sites in East Asia. At the same time, the concentration of SO$_2$ and NO$_2$ has been measured simultaneously with passive sampler. The meteorological data were collected from the AWS (Auto-mated weather station) In each country and chemical compositions of wet deposition were also analyzed by the bulk sampling of rainfall every month. As the results, it was found that the corrosion rates of test pieces in the ambient air were appeared to be in the order of carbon steel > marble > bronze copper. The corrosion rates of test pieces in the unsheltered outdoor condition were 2.34 to 5.88 times larger than those in rain-sheltered condition. It was also found that the corrosion rate in the heavy polluted area in China was the highest, and the corrosion rates of the metal pieces were generally proportional to SO$_2$ concentration. Between two sites in Korea, the test pieces at Daegu site showed higher corrosion rates that would be due to the higher SO$_2$ concentration.