• 제목/요약/키워드: Passive resistance

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Long-term corrosion-resistance of an uncoated weathering steel and its on-line and in-situ measurements (무도장 내후성강의 장기 내식성 및 그 현장즉시측정법)

  • Park, Jeong Real;Kim, Kyoo Young
    • Journal of Korean Society of Steel Construction
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    • v.16 no.4 s.71
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    • pp.415-423
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    • 2004
  • To investigate the long-term corrosion resistance of an uncoated weathering steel, an important outdoor constructional steel material, skyward surfaces of the weathering steel and a control steel initially exposed to rural and industrial atmospheres for 9 years were electrochemically tested in neutral artificial rain in terms of electrochemical potentials, impedances, and anodic potentiodynamic polarization curves. Their results were then discussed. A quite passive and stable rust layer to the artificial rain was well formed on the skyward surface of the weathering steel exposed to the industrial and rural atmospheres, and its corrosion rate in the artificial rain was measured to be about a low $3{{\mu}m}/y$. Continuous immersion of all the weathered surfaces in the artificial rain revealed the gradual degradation of the weathered corrosion layers on the steel, resulting in a cathodically controlled corrosion of the substrate steel by the electrochemical measurements. Alloy components of the weathering steel were found to retard the degradation of the weathered corrosion layers on the steel in the artificial rain. For better corrosion evaluation of the weathering steel, more electrochemical measurements of surfaces that have been exposed for more than 9 years to more closely simulated atmospheric waters are needed. These measurements are almost non-destructive and can provide online and in situ information on the corrosion rate, the development of corrosion and the conditions of rust layers on any interested surface and at any exposure time of the steel, so they can be effectively applicable to the corrosion evaluation of steel structures such as bridges, towers, and architectures by forming an electrochemical cell on an interested structural surface and by using a portable electrochemical instrument.

Corrosion Characteristics of Fe-Si, Ni-Ti and Ni Alloy in Sulfuric Acid Environments (황산 환경에서 Fe-Si, Ni-Ti계 및 Ni 합금의 내부식성 특성)

  • Kwon, Hyuk-Chul;Kim, Dong-Jin;Kim, Hong-Pyo;Park, Ji-Yeon;Hong, Seong-Deok
    • Korean Journal of Materials Research
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    • v.21 no.1
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    • pp.1-7
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    • 2011
  • Methods of producing hydrogen include steam reforming, electrochemical decomposition of water, and the SI process. Among these methods, the Sulfur iodine process is one of the most promising processes for hydrogen production. The thermochemical sulfur-iodine (SI) process uses heat from a high-temperature-gas nuclear reactor to produce $H_2$ gas; this process is known for its production of clean energy as it does not emit $CO_2$ from water. But the SI-process takes place in an extremely corrosive environment for the materials. To endure SI environments, the materials for the SI environment will have to have strong corrosion resistance. This work studies the corrosion resistances of the Fe-Si, Ni-Ti and Ni Alloys, which are tested in SI-process environments. Among the SI-process environments, the conditions of boiling sulfuric acid and decomposed sulfuric acid are selected in this study. Before testing in boiling sulfuric acid environments, the specimens of Fe-4.5Si, Fe-6Si, Ni-4.5Si, Ni-Ti-Si-Nb and Ni-Ti-Si-Nb-B are previously given heat treatment at $1000^{\circ}C$ for 48 hrs. The reason for this heat treatment is that those specimens have a passive film on the surface. The specimens are immersed for 3~14 days in 98wt% boiling sulfuric acid. Corrosion rates are measured by using the weight change after immersion. The corrosion rates of the Fe-6Si and Ni-Ti-Si-Nb-B are found to decrease as the time passes. The corrosion rates of Fe-6si and Ni-Ti-Si-Nb-B are measured at 0.056 mm/yr and 0.16 mm/yr, respectively. Hastelloy-X, Alloy 617, Alloy 800H and Haynes 230 are tested in the decomposed sulfuric acid for one day. Alloy 800H was found to show the best corrosion resistance among the materials. The corrosion rate of Alloy 800H is measured at -0.35 mm/yr. In these results, the corrosion resistance of materials depends on the stability of the oxide film formed on the surface. After testing in boiling sulfuric acid and in decomposed sulfuric acid environments, the surfaces and compositions of specimens are analyzed by SEM and EDX.

IMPROVEMENT EFFECTS OF ELECTROCHEMICAL STABILITY OF MAGNETIC MATERIALS FOR PROSTHETIC DENTISTRY (치과보철용 자석재료의 전기화학적 안정성 개선효과)

  • Kwack, Jong-Ha;Oh, Sang-Ho;Choe, Han-Cheol;Chung, Chae-Heon
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.5
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    • pp.628-641
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    • 2006
  • Statement of problem: Dental magnetic materials have been applied to removable prosthetic appliances, maxillofacial prostheses, obturator and dental implant but they still have some problems such as low corrosion resistance in oral environments. Purpose: To increase the corrosion resistance of dental magnetic materials, surfaces of Sm-Co and Nd-Fe-B based magnetic materials were plated with TiN and sealed with stainless steels. Materials and methods : Surfaces of Sm-Co and Nd-Fe-B based magnetic materials were plated with TiN and sealed with stainless steels, and then three kinds of electrochemical corrosion test were performed in 0.9% NaCl solution; potentiodynamic, potentiostatic, and electrochemical impedance test. From this study, corrosion behavior, amount of elements released, mean average surface roughness values, the changing of retention force, and magnetic force values were measured comparing with control group of non-coated magnetic materials. Results: The values of surface roughness of TiN coated Sm-Co and TiN coated Nd-Fe-B based magnetic materials were lower than those of non coated Sm-Co and Nd-Fe-B alloy. From results of potentiodynamic test, the passive current density of TiN coated Sm-Co alloy were smaller than those of TiN coated Nd-Fe-B alloy and non coated alloys in 0.9% NaCl solution. From results of potentiostatic and electrochemical impedance test, the surface stability of the TiN coated Sm-Co alloy was more drastically increased than that of the TiN coated Nd-Fe-B alloy and non-coated alloy. The retention and magnetic force after and before corrosion test did not change in the case of TiN coated magnetic alloy sealed with stainless steel. Conclusion: It is considered that the corrosion problem and improvement for surface stability of dental magnetic materials could be solved by ion plating with TiN on the surface of dental magnetic materials and by sealing with stainless steels.

Fabrication process of embedded passive components in MCM-D (MCM-D 기판 내장형 수동소자 제조공정)

  • 주철원;이영민;이상복;현석봉;박성수;송민규
    • Journal of the Microelectronics and Packaging Society
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    • v.6 no.4
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    • pp.1-7
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    • 1999
  • We developed Fabrication process of embedded passive components in MCM-D substrate. The proposed MCM-D substrate is based on Cu/photosensitive BCB multilayer. The substrate used is Si wafer and Ti/cu metallization is used to form the interconnect layer. Interconnect layers are formed with 1000$\AA$ Ti/3000$\AA$ Cu by sputtering method and 3$\mu\textrm{m}$ Cu by electrical plating method. In order to form the vias in photosensitive BCB layer, the process of BCB and plasma etch using $C_2F_6$ gas were evaluated. The MCM-D substrate is composed of 5 dielectric layers and 4 interconnect layers. Embedded resistors are made with NiCr and implemented on the $2^{nd}$ dielectric layer. The sheet resistance of NiCr is controlled to be about 21 $\Omega$/sq at the thickness of 600$\AA$. The multi-turn sprial inductors are designed in coplanar fashion on the $4^{th}$ interconnect layer with an underpass from the center to outside using the lower $3^{rd}$ interconnect layer. Capacitors are designed and realized between $1^{st}$ interconnect layer and $2^{nd}$ interconnect layer. An important issue in capacitor is the accurate determination of the dielectric thickness. We use the 900$\AA$ thickness of PECVD silicon nitride film as dielectric. Capacitance per unit area is about 88nF/$\textrm {cm}^2$at the thickness of 900$\AA$. The advantage of this integration process is the compatibility with the conventional semiconductor process due to low temperature PECVD silicon nitride process and thermal evaporation NiCr process.

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Design and Fabrication of Ka-Band Active PIN Diode Limiter for a Millimeter Wave Seeker (밀리미터파 탐색기용 Ka 대역 능동 PIN 다이오드 리미터 설계 및 제작)

  • Yang, Seong-Sik;Lim, Ju-Hyun;Na, Young-Jin
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.23 no.2
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    • pp.220-228
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    • 2012
  • In this paper, we explained the design technique about Ka-band active limiter for protecting the receiver of a millimeter wave seeker. To implement low flat leakage power, we proposed the control circuit of active limiter to control limiter voltage with PRF(Pulse Repetition Frequency) signal and input power. This active limiter consisted of the conventional 2 stage passive limiter, a feedback circuit with a directional coupler, detector, non-inverting amplifier and over-current protection resistance. As the test result of the fabricated Ka-band limiter, it had 1 GHz bandwidth, 3.5 dB insertion loss at the small input power and -7.5 dBm flat leakage at the 4 W RF input power, respectively.

Characterization of Tribocorrosion Behaviour of CoCr Alloy by Electrochemical Techniques in Several Corrosive Media

  • Escudero, M.L.;Diaz, I.;Martinez Lerma, J.F.;Montoya, R.;Garcia-Alonso, M.C.
    • Corrosion Science and Technology
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    • v.17 no.2
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    • pp.68-73
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    • 2018
  • Substitution of hip and knee joints by CoCr alloys is in great demand due to their high wear resistance and good biocompatibility. Understanding of tribocorrosion in joint replacements requires study of variables such as coefficient of friction and the choice of a proper corrosive medium in wear-corrosion tests carried out in the lab. The objective of this study was to characterize tribocorrosion behaviour of CoCr alloy with low (LCCoCr) and high carbon (HCCoCr) contents in several corrosive media: NaCl, Phosphate Buffer Solution (PBS), and PBS with hyaluronic acid (PBS-HA). Tribocorrosion tests were carried out on a pin-on-disk tribometer with an integrated electrochemical cell. A normal load of 5N was applied on the alumina ball counterpart at a rotation rate of 120 rpm. Coefficient of friction (COF) was measured and tribocorrosion behaviour was characterized by in situ application of electrochemical techniques. HCCoCr alloy immersed in PBS-HA showed the best tribocorrosion behaviour with the lowest COF. In this case, in situ measurement of corrosion potential and the impedance data under wear corrosion process showed an active state while passive film was continuously destroyed without possibility of regeneration.

Electrochemical Properties of Air-Formed Oxide Film-Covered AZ31 Mg Alloy in Aqueous Solutions Containing Various Anions

  • Fazal, Basit Raza;Moon, Sungmo
    • Journal of the Korean institute of surface engineering
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    • v.50 no.3
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    • pp.147-154
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    • 2017
  • This research was conducted to investigate the electrochemical properties of the thin air-formed oxide film-covered AZ31 Mg alloy. Native air-formed oxide films on AZ31 Mg alloy samples were prepared by knife-abrading method and the changes in the electrochemical properties of the air-formed oxide film were investigated in seven different electrolytes containing the following anions $Cl^-$, $F^-$, $SO{_4}^{2-}$, $NO_3{^-}$, $CH_3COO^-$, $CO{_3}^{2-}$, and $PO{_4}^{3-}$. It was observed from open circuit potential (OCP) transients that the potential initially decreased before gradually increasing again in the solutions containing only $CO{_3}^{2-}$ or $PO{_4}^{3-}$ ions, indicating the dissolution or transformation of the native air-formed oxide film into new more protective surface films. The Nyquist plots obtained from electrochemical impedance spectroscopy (EIS) showed that there was growth of new surface films with immersion time on the air-formed oxide film-covered specimens in all the electrolyte. The least resistive surface films were formed in fluoride and sulphate baths whereas the most protective film was formed in phosphate bath. The potentiodynamic polarization curves illustrated that passive behaviour of AZ31 Mg alloy under anodic polarization appears only in $CO{_3}^{2-}$, or $PO{_4}^{3-}$ ions containing solutions and at more than $-0.4V_{Ag/AgCl}$ in $F^-$ ion containing solution.

Dorsalis Pedis Tendocutaneous Delayed Arterialized Venous Flap in Hand Reconstruction (지연처치후 동맥화된 족배 정맥 건피판을 이용한 수부의 재건)

  • Cho, Byung-Chae;Lee, Dong-Hoon
    • Archives of Reconstructive Microsurgery
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    • v.8 no.1
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    • pp.56-63
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    • 1999
  • We report two patients whose acute soft tissue and tendon defects in the hand were treated by the dorsalis pedis tendocutaneous delayed arterialized venous flap between 1994 and 1997. The surviving surface area was 100% in both patients. The flap size was $10{\times}10cm\;and\;6{\times}6cm$. At two weeks postoperatively, active flextion and passive extension commenced, and progressive resistance exercises were performed for an additional 5 weeks. Flaps showed a similar color match and skin texture compared with the normal skin of the hand. Advantages of the tendocutaneous delayed arterialized venous flap are developing a larger flap than can be obtained with pure venous flap or arterialized venous flap, increasing survival rate of the arterialized venous flap which permits using a composite flap, preservation of main artery of the donor site, taking thin non-bulky tissue and easy elevation without deep dissection. The disadvantages are the requirement of a two stage operation, donor site scarring and weak extension of the toe.

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Success Factors in Effecting Cultural Change in Organizations: A Case Study (조직 문화 변화의 성공 요소에 관한 연구 - KM을 변화 플랫폼으로 적용한 기업 사례를 중심으로 -)

  • Roh, Jeong-Ran
    • Journal of the Korean Society for Library and Information Science
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    • v.44 no.2
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    • pp.427-445
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    • 2010
  • In our knowledge-based society, a corporation's main growth engine consists of its unique core competences and how these are organized rather than materialized competitive advantage. Intangible factors such as creative organizational culture, learning capability, brands, marketing ability and technology are notable examples of such core competencies. To ensure constant development of a corporation, it is important to understand the environment in which these factors operate. Drawing on literature research, this paper looks at organizational culture and change, and employees' attitudes and resistance factors to such change. To strengthen the explanation of this study the Korea Asset Management Corporation was used as a case study. From the point of view of information science, knowledge has been viewed as that which is found in books and databases. Such "knowledge" is storable, passive and unchangeable. However, more recently it is seen by many researchers that this approach is limited in that it ignores the knowledge that "sits" in human "bodyminds" and organizations. Such knowledge forms the backbone of organizational culture and should be considered in any meaningful study of information.

Quantification of the Effect of Medication and Deep Brain Stimulation on Parkinsonian Rigidity (파킨슨병 환자의 경직에 대한 약물과 DBS 의 효과의 정량화)

  • Kwon, Yu-Ri;Eom, Gwang-Moon;Park, Sang-Hun;Kim, Ji-Won;Kim, Min-Jik;Lee, Hye-Mi;Jang, Ji-Wan;Koh, Seong-Beom
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.5
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    • pp.559-563
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    • 2013
  • This study aims to quantify the effects of medication (Med) and deep brain stimulation (DBS) on resting rigidity in patients with Parkinson's disease. We tested 10 limbs of five patients under each of four treatment conditions: 1) baseline, 2) DBS, 3) Med, 4) DBS + Med. Rigidity at the wrist joint was assessed using the Unified Parkinson's Disease Rating Scale (UPDRS). The examiner randomly imposed flexion and extension movement on patient's wrist joint. Resistance to passive movement was quantified by viscoelastic properties. Not only rigidity score but also damping constant showed improvements in rigidity by DBS and Med treatments (p<0.05). This indicates that the viscosity can represent the change in rigidity due to DBS as well as Med, which was manifested by UPDRS score.