• Title/Summary/Keyword: Passive resistance

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Influence of Corrosion Potential and Current Density on Polarization Curve Variations using Polycarbonate[III]

  • Park, Chil-Nam;Yang, Hyo-Kyung;Kim, Sun-Kyu;Kim, Myung-Sun;Cheong, Kyung-Hoon
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.1
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    • pp.43-50
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    • 2000
  • In this study, experiments were carried out to measure the variations in the corrosion potential and current density of polarization curves using polycarbonate. The results were particularly examined to identify the influences affecting the corrosion potential including various conditions such as temperature, pH, catalytic enzyme, and salt. The lines representing the active anodic dissolution were only slightly shifted in the potential direction by temperature, pH, enzyme, and salt. The tafel slope for the anodic dissolution was determined based on the polarization effect with various conditions. The slope of the polarization curves describing the active-to-passive transition region were noticeably shifted in direction. Also, from the variation in the conditions, the optimum conditions were established for the most rapid transformation, including temperature, pH, corrosion rate, and resistance of corrosion potential. The second anodic current density peak and maximum passive current density were designated as the critical corrosion sensitivity(Ir/If). The value of Ir/If was then used in measuring the extent of the critical corrosion sensitivity of the polycarbonate. The potentiodynamic parameters of the corrosion were obtained using a Tafel plot.

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Voltage-Activated Electrochemical Reaction for Electrochemical Mechanical Polishing (ECMP) Application (ECMP 적용을 위한 전압활성영역의 전기화학적 반응 고찰)

  • Han, Sang-Jun;Lee, Young-Kyun;Seo, Yong-Jin;Lee, Woo-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.163-163
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    • 2008
  • 반도체 소자가 고집적화 되고 고속화를 필요로 하게 됨에 따라, 기존에 사용되었던 알루미늄이나 텅스텐보다 낮은 전기저항, 높은 electro-migration resistance으로 미세한 금속배선 처리가 가능한 Cu가 주목받게 되었다. 하지만 과잉 디싱 현상과 에로젼을 유도하여 메탈라인 브리징과 단락을 초래할 있고 Cu의 단락인 islands를 남김으로서 표면 결함을 제거하는데 효과적이지 못다는 단점을 가지고 있었다. 특히 평탄화 공정시 높은 압력으로 인하여 Cu막의 하부인 ILD막의 다공성의 low-k 물질의 손상을 초래 할 수 있는 문제점을 해결하기 위하여 기존의 CMP에 전기화학을 결합시킴으로서 낮은 하력에서의 Cu 평탄화를 달성 할 수 있는 기존의 CMP 기술에 전기화학을 접목한 새로운 개념의 ECMP (electrochemical-mechanical polishing) 기술이 생겨나게 되었다. 따라서 본 논문에서는 최적화된 ECMP 공정을 위하여 I-V곡선과 CV법을 이용하여 active. passive. trans-passive 영역의 전기화학적 특징을 알아보았고. Cu막의 표면 형상을 알아보기 위해 Scanning Electron Microscopy (SEM) 측정과 Energy Dispersive Spectroscopy (EDS) 분석을 통해 금속 화학적 조성을 조사하였다.

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Detection of SCC by Electrochemical Noise and In-Situ 3-D Microscopy

  • Xia, Da-Hai;Behnamian, Yashar;Luo, Jing-Li;Klimas, Stan
    • Corrosion Science and Technology
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    • v.16 no.4
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    • pp.194-200
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    • 2017
  • Stress-corrosion cracking (SCC) of alloy 600 and alloy 800 in 0.5 mol/L thiosulfate solution during constant strain was investigated using electrochemical noise (EN) combined with 3-D microscope techniques. The in-situ morphology observation and EN results indicate that the SCC process could be divided into three stages: (1) passive film stabilization and growth, (2) crack initiation, (3) and crack growth. Power Spectral Density (PSD) and the probability distribution obtained from EN were used as the "fingerprint" to distinguish the different processes. During passive film stabilization and growth, the current noise signals resembled "white noise": when the crack initiated, many transient peaks could be seen in the current noise and the wavelet energy at low frequency as well as the noise resistance decreased. After crack propagation, the noise amplitudes increased, particularly the white noises at low and high frequencies ($W_L$ and $W_H$) in the PSDs. Finally, the detection of metal structure corrosion in a simulated sea splash zone and pipeline corrosion in the atmosphere are established.

Modeling and Feedback Control of LLC Resonant Converters at High Switching Frequency

  • Park, Hwa-Pyeong;Jung, Jee-Hoon
    • Journal of Power Electronics
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    • v.16 no.3
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    • pp.849-860
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    • 2016
  • The high-switching-frequency operation of power converters can achieve high power density through size reduction of passive components, such as capacitors, inductors, and transformers. However, a small-output capacitor that has small capacitance and low effective series resistance changes the small-signal model of the converter power stage. Such a capacitor can make the converter unstable by increasing the crossover frequency in the transfer function of the small-signal model. In this paper, the design and implementation of a high-frequency LLC resonant converter are presented to verify the power density enhancement achieved by decreasing the size of passive components. The effect of small output capacitance is analyzed for stability by using a proper small-signal model of the LLC resonant converter. Finally, proper design methods of a feedback compensator are proposed to obtain a sufficient phase margin in the Bode plot of the loop gain of the converter for stable operation at 500 kHz switching frequency. A theoretical approach using MATLAB, a simulation approach using PSIM, and experimental results are presented to show the validity of the proposed analysis and design methods with 100 and 500 kHz prototype converters.

The effect of base isolation and tuned mass dampers on the seismic response of RC high-rise buildings considering soil-structure interaction

  • Kontoni, Denise-Penelope N.;Farghaly, Ahmed Abdelraheem
    • Earthquakes and Structures
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    • v.17 no.4
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    • pp.425-434
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    • 2019
  • The most effective passive vibration control and seismic resistance options in a reinforced concrete (RC) high-rise building (HRB) are the base isolation and the tuned mass damper (TMD) system. Many options, which may be suitable or not for different soil types, with different types of bearing systems, like rubber isolator, friction pendulum isolator and tension/compression isolator, are investigated to resist the base straining actions under five different earthquakes. TMD resists the seismic response, as a control system, by reducing top displacement or the total movement of the structure. Base isolation and TMDs work under seismic load in a different way, so the combination between base isolation and TMDs will reduce the harmful effect of the earthquakes in an effective and systematic way. In this paper, a comprehensive study of the combination of TMDs with three different base-isolator types for three different soil types and under five different earthquakes is conducted. The seismic response results under five different earthquakes of the studied nine RC HRB models (depicted by the top displacement, base shear force and base bending moment) are compared to show the most suitable hybrid passive vibration control system for three different soil types.

Research on flow characteristics in supercritical water natural circulation: Influence of heating power distribution

  • Ma, Dongliang;Zhou, Tao;Feng, Xiang;Huang, Yanping
    • Nuclear Engineering and Technology
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    • v.50 no.7
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    • pp.1079-1087
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    • 2018
  • There are many parameters that affect the natural circulation flow, such as height difference, heating power size, pipe diameter, system pressure and inlet temperature and so on. In general analysis the heating power is often regarded as a uniform distribution. The ANSYS-CFX numerical analysis software was used to analyze the flow heat transfer of supercritical water under different heating power distribution conditions. The distribution types of uniform, power increasing, power decreasing and sine function are investigated. Through the analysis, it can be concluded that different power distribution has a great influence on the flow of natural circulation if the total power of heating is constant. It was found that the peak flow of supercritical water natural circulation is maximal when the distribution of heating power is monotonically decreasing, minimal when it is monotonically increasing, and moderate at uniform or the sine type of heating. The simulation results further reveal the supercritical water under different heat transfer conditions on its flow characteristics. It can provide certain theory reference and system design for passive residual heat removal system about supercritical water.

Confinement model for RC columns strengthened with direct-fastened steel plates

  • Shan, Z.W.;Looi, D.T.W.;Su, R.K.L.
    • Steel and Composite Structures
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    • v.39 no.4
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    • pp.367-381
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    • 2021
  • Reinforced concrete (RC) columns can be strengthened by direct fastening of steel plates around a column, forming composite actions. This method can increase both the total load bearing area and the concrete confinement stress. To predict the axial load resistance of strengthened RC columns, the equivalent passive confinement stress of the stirrups and the steel jacket should be accurately quantified, which requires the stress in the stirrups and shear force in the connections to be first obtained. In this paper, parameters, i.e., the stress ratio of the stirrups and shear force ratio of steel plate connectors are utilized to quantify the stress of the stirrups and shear force in the connections. A mechanical model for determining the stress ratio of the stirrups and shear force ratio of steel plate connectors is proposed and validated using the experimental results in a previous study. The model is found to be robust. Subsequently, a parametric study is conducted and the optimum stress ratios of the stirrups and the optimum shear force ratios of connectors are proposed for engineering designs.

The Effect of Welding Method on the Electrochemical Behavior of Austenitic Stainless Steel Sheet

  • Kim, Young-Hune;Kim, Kyoo-Young
    • Corrosion Science and Technology
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    • v.9 no.3
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    • pp.122-128
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    • 2010
  • The corrosion of the flexible tube in the automobile exhaust system is caused by the ambient water and chloride ions. Since welding is one of the key processes for the flexible tube manufacturing, it is required to select a proper welding method to prevent the flexible tube corrosion and to increase its lifetime. There are many studies about the efficiency of the welding method, but no systematic study is performed for the effect of welding method on the corrosion property of the austenitic stainless weldment. The aim of the present study is to provide information on the effect of two different welding methods of TIGW (tungsten inert gas welding) and PAW (plasma arc welding) on the corrosion property of austenitic stainless steel weldment. Materials used in this study were two types of the commercial austenitic stainless steel, STS321 and XM15J1, which were used for flexible tube material for the automotive exhaust system. Microstructure was observed by using optical microscopy (OM) and scanning electron microscopy (SEM). To evaluate the corrosion behavior, potentiodynamic and potentiostatic tests were performed. The chemical state of the passive film was analyzed in terms of XPS depth profile. Metallurgical analysis show that the ferrite content in fusion zone of both STS321 and XM15J1 is higher when welded by PAW than by TIGW. The potentiodynamic and potentiostatic test results show that both STS321 and XM15J1 have higher transpassive potential and lower passive current density when welded by PAW than by TIGW. XPS analysis indicates that the stable $Cr_2O_3$ layer at the outermost layer of the passive film is formed when welded by PAW. The result recommends that PAW is more desirable than TIGW to secure corrosion resistance of the flex tube which is usually made of austenitic stainless steel.

1 Selector + 1 Resistance Behavior Observed in Pt/SiN/Ti/Si Structure Resistive Switching Memory Cells

  • Park, Ju-Hyeon;Kim, Hui-Dong;Kim, Tae-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.307-307
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    • 2014
  • 정보화 시대로 접어들면서 동일한 공간에 더 많은 정보를 저장할 수 있고, 보다 빠른 동작이 가능한 비휘발성 메모리 소자에 대한 요구가 증가하고 있다. 하지만, 최근 비휘발성 메모리 소자 관련 연구보고에 따르면, 메모리 소자의 소형화 및 직접화 측면에서, 전하 저장을 기반으로 하는 기존의 Floating-Gate(FG) Flash 메모리는 20 nm 이하 공정에서 한계가 예측 되고 있다. 따라서, 이러한 FG Flash 메모리의 한계를 해결하기 위해, 기존에 FET 기반의 FG Flash 구조와 같은 3 terminal이 아닌, Diode와 같은 2 terminal로 동작이 가능한 ReRAM, PRAM, STT-MRAM, PoRAM 등 저항변화를 기반으로 하는 다양한 종류의 차세대 메모리 소자가 연구되고 있다. 그 중, 저항 변화 메모리(ReRAM)는 CMOS 공정 호환성, 3D 직접도, 낮은 소비전력과 빠른 동작 속도 등의 우수한 동작 특성을 가져 차세대 비휘발성 메모리로 주목을 받고 있다. 또한, 상하부 전극의 2 terminal 만으로 소자 구동이 가능하기 때문에 Passive Crossbar-Array(CBA)로 적용하여 플래시 메모리를 대체할 수 있는 유력한 차세대 메모리 소자이다. 하지만, 이를 현실화하기 위해서는 Passive CBA 구조에서 발생할 수 있는 Read Disturb 현상, 즉 Word-Line과 Bit-Line을 통해 선택된 소자를 제외하고 주변의 다른 소자를 통해 흐르는 Sneak Leakage Current(SLC)를 차단하여 소자의 메모리 State를 정확히 sensing하기 위한 연구가 선행 되어야 한다. 따라서, 현재 이러한 이슈를 해결하기 위해서, 많은 연구 그룹에서 Diodes, Threshold Switches와 같은 ReRAM에 Selector 소자를 추가하는 방법, 또는 Self-Rectifying 특성 및 CRS 특성을 보이는 ReRAM 구조를 제안 하여 SLC를 차단하고자 하는 연구가 시도 되고 있지만, 아직까지 기초연구 단계로서 아이디어에 대한 가능성 정도만 보고되고 있는 현실 이다. 이에 본 논문은 Passive CBA구조에서 발생하는 SLC를 해결하기 위한 새로운 아이디어로써, 본 연구 그룹에서 선행 연구로 확보된 안정적인 저항변화 물질인 SiN를 정류 특성을 가지는 n-Si/Ti 기반의 Schottky Diode와 결합함으로써 기존의 CBA 메모리의 Read 동작에서 발생하는 SLC를 차단 할 수 있는 1SD-1R 구조의 메모리 구조를 제작 하였으며, 본 연구 결과 기존에 문제가 되었던 SLC를 차단 할 수 있었다.

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A Study on the Subjectivity of Skin Care (일반여성의 피부미용관리에 대한 주관성 연구)

  • Yang, Eun-Soon
    • Journal of the Korean Society of Fashion and Beauty
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    • v.2 no.3 s.3
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    • pp.1-10
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    • 2004
  • The purpose of this study is to find out the operant factors, or types of skin care, and, more importantly, to propose the intervention for more effective skin care and marketing strategies in this business. That is the main reason that the study employes Q methodology which measures human subjectivity objectively and scientifically. This study finally revealed three distinctive factors : Type I, The Passive Follower, Type II, The Active Needs, and Type III, The Independent Judgment. The first type includes people who show passive recognition. They want to be put in charge of experts in the skin care center and to buy cosmetics recommended by experts, and are deep interest in the reaction of other people. The second type contains people who desire things actively. To live delightfully and fashionably, they think of the necessity of skin and body care as an important thing, and feel that it is necessary to take care of the skin beauty actively and regularly for the aging resistance. The third type includes people who judge independently. In general, they recognize and desire the necessity of the skin care, but they think of the skin care as a part of the health care more widely rather than a special thing. These three types are not fixed, but continuously changed in the accordance with the condition and interaction with the circumstance, the results will be utilized as basic materials for the skin and health care through the application according to the characteristic of each type they belong.

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