• Title/Summary/Keyword: Passive resistance

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The Study of Corrosion of Heat Exchanger Tube for Absorption Refrigeration Machine (흡수식냉동기용 열교환기 세관의 부식에 관한 연구)

  • 임우조;정기철;윤병두
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2002.05a
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    • pp.147-152
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    • 2002
  • This paper was studied on corrosion of heat exchanger tube for absorption refrigeration machine. In the 62 % lithium bromide solution at $60^{\circ}C$, polarization test of Cu, Al-brass, 10 % cupro nickel(90-10 % Cu-Ni) and 30 % cupronickel(70-30 % Cu-Ni) tube was carried out. And polarization behavior, polarization resistance characteristics, open circuit potential, anodic polarization of heat exchanger tube for absorption refrigeration machine were considered. The main results are as following: The open circuit potential of Al-brass tube becomes less noble than that of Cu tube, corrosion current density of that becomes lower than Cu tube. The open circuit potential of cupronickel tube is more noble than that of Cu tube, corrosion current density of that is controlled than Cu tube. The passivation critical current of 30 % Cu-Ni tube is lower than that of 10 % Cu-Ni tube, potential of passive region of that is more wide than 10 % Cu-Ni tube.

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The Anodicc PolarizationBehavior of Fe-Cr-Ni-W alloy in 1N HCI Solution (1N 염산 용액에서 Fe-Cr-Ni-W 합금의 양분극 거동에 관한 연구)

  • 윤재돈;강성군
    • Journal of the Korean institute of surface engineering
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    • v.21 no.4
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    • pp.176-182
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    • 1988
  • Effects of Cr, Ni and W on the anodic polarization behavior were investigated for Fe-Cr-Ni-W alloys in deaerated 1N HCI solution. Surface films formed on the polarization were analysed using AES, SEM and EDAX. A higerconcentration of tungten was found in the surface oxide film compared to the matrix. It played an importanet role on incresing the stability of the passive film. The presence of an adequate amount of Cr was essential to increase the pitting resistance of the alloys in acid chloride media. Under 12 wt%cr,alloys containing 6wt%W did not exhidit any passivity at all. The main role of Ni was to control the microstructure rather than to modify the corrosion resistance. In 23 cr-14Ni-^W alloy, the duplex microstructure of ferrite($\delta$-phase) in an austenic matrix was developed. The reson why proferred pitting appeared in austenite and ferrite/austenite interface was that ferrite had more amount of Cr and W than austenite.

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Design of Hybrid Mount to Naval Shipboard Considering Shock Resistance (내충격 성능을 고려한 함정용 하이브리드 마운트의 설계)

  • Jo, Hye-Young;Shin, Yun-Ho;Moon, Seok-Jun;Jung, Woo-Jin
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2012.10a
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    • pp.102-107
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    • 2012
  • In this study, the design procedure of hybrid active mount by an electro-magnetic actuator is proposed to reduce the transmitted force from naval shipboard equipment to ship hull structure. The hybrid type mount which is composed of a passive rubber element and an electro-magnetic actuator is introduced and, through the vibration measurement for the objective pump system, the required force of the actuator is computed and discussed in detail. The initial designs were supposed for three types, one is moving coil type actuator and the others are moving permanent magnet type actuators. Based on the initial design concept, the final designs considering shock resistance and interference with mover and stator are proposed and examined.

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Corrosion Behavior of Rapidly Solidified Mg-Zn-Y Alloys in NaCl Solution

  • Izumi, Shogo;Yamasaki, Michiaki;Sekigawa, Takahiro;Kawamura, Yoshihito
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1043-1044
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    • 2006
  • Compositional dependence of corrosion behavior of rapidly solidified Mg-rich Mg-Zn-Y alloys in NaCl aqueous solution has been investigated. Mg-Zn-Y ternary alloys containing small amounts of Zn exhibited low corrosion rate, although the $Mg_{98}Y_2$ (at. %) binary alloy showed severe corrosion with violet evolution of hydrogen. The alloy with highest corrosion-resistance was $Mg_{97.25}Zn_{0.75_Y_2$, its corrosion rate was about 1 mm year-1 in 0.17 M (1.0 wt. %) NaCl solution. $Mg_{97.25}Zn_{0.75}Y_2$ alloy exhibited passive region in anodic polarization curves when immersed in NaCl solution. Rapidly solidification and small amount of Zn addition may bring about an increase in electrochemical homogeneity of Mg-Zn-Y alloys, resulting in enhancement of corrosion resistance.

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Effect of Tantalum and Lanthanum Addition on Electrochemical Property of Austenitic Stainless Steel in a Simulated PEMFC Environment

  • Kim, Kwang-Min;Koh, Seong-Ung;Kim, Kyoo-Young
    • Corrosion Science and Technology
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    • v.7 no.6
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    • pp.338-343
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    • 2008
  • The electrochemical properties of W-modified austenitic stainless steels containing Ta and La were evaluated in a $H_{3}PO_{4}$ type PEMFC environment. Electrochemical test was conducted in 0.05 M $H_{3}PO_{4}$ solution at $80^{\circ}C$ and electrical property was conducted by contact resistance test. XPS was conducted to analyze the chemical elements consisting of passive film. Addition of La and Ta in W-modified austenitic stainless steel shows not only better corrosion resistance but also better electrical property.

Active and Passive Behaviours of the Guard Cells for Stomatal Opening and Closing in Heteromeres arbutifolia and Ferocactus acanthodes (Heteromeres arbutifolia 와 Ferocactus acanthodes의 기공개폐를 위한 공변세포의 능.수동적 행동)

  • Nam-Kee Chang
    • The Korean Journal of Ecology
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    • v.4 no.3_4
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    • pp.59-67
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    • 1981
  • Stomatal resistances of the leaves in Heteromeres arbutifolia and of the stems in Ferocactus acanthodes were studied to estimate active and passive behaviors of the guard cells on a theoretical basis. Active and passive stomatal responses to light and water deficit were observed. When the change rate of existent water due to variation of osmotic potential in the guard cells and the loss rate of transpirational water from the guard cells are $\Delta$wi-$\Delta$wt and leaded to active behaviors for opening and closing stomata. However, when stems of F. acanthodes with stomata closecd under the solar irradiation were covered with black cloth and then taken off, behaviors of the guard cells occurred in the condition of $\Delta$wi<$\Delta$wt and were passive. Under the conditiion of $\Delta$wi<$\Delta$wt due to cutout from stems, passive behaviors of the guard cells in H. arbutifolia and F. acanthodes always occurred in spite of the solar irradiation and darkness, respectively. The transpirational resistance coefficients of the guard cells in stems of F. acanthodes (0.380) and Opuntia bigelovii (0.135) wer emuch higher than in leaves of H. arbutifolia (0.034). Moreover, stomatal opening in stems of F. acanthodes during the daytime could be induced by watering. Those results are interpreted as that since the guard cells in desert Crassulacean acid metabolism (CAM) plants always exist in the state of stomatal opening, nocturnal stomatal opening and daytime stomatal closing are exhibited by passive behaviors of the guard cells in the alternant conditioins of $\Delta$wi>$\Delta$wt and $\Delta$wi<$\Delta$wt, respectively.

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The Effect of Post Oxidation on Corrosion Characteristics of Gas Nitrocarburised Carbon Steels (Nitrocarburising 처리된 탄소강의 내식특성에 미치는 Post Oxidation 효과)

  • Kim, Y.H.;Jung, K.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.1
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    • pp.9-20
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    • 1999
  • The effect of post oxidation, water-quenched after holding in air for 5~420 seconds or cooling or furnace cooling, on corrosion resistance and phase formation characteristics of the surface layer of SM20C and SM45C carbon steels after gas nirtrocarbursing in the $NH_3-5%CO_2-N_2$ gas atmosphere at $580^{\circ}C$ for 3hours is studied. The compound layers of two steels consist of ${\varepsilon}-Fe_{2-3}N$, ${\gamma}^{\prime}-Fe_4N$ and $Fe_3O_4$, phases, however, the quantity of ${\gamma}^{\prime}-Fe_4N$ phase increases for the furnace cooled specimen compared to that of air cooling specimen. With increasing $NH_3$ content in the gas mixture and also increasing the keeping time in the air after gas nitrocarburising, the ${\varepsilon}-Fe_{2-3}N$ phase of compound layer increases, while the decreased current density recognizing the improvement of corrosion resistance are shown. the passive current density of SM45C steel is lower than that of SM20C steel at the same nitrocarburising conditions.

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Comparing Resistances to Pitting Corrosion of Additive Manufactured Ti-6Al-4V Alloys in NaCl and NaBr Aqueous Solutions (NaCl과 NaBr수용액에서 적층가공으로 제조된 Ti-6Al-4V 합금의 공식 저항성 비교)

  • Seo, Dong-Il;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.18 no.3
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    • pp.110-116
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    • 2019
  • Resistances to pitting corrosion of additive manufactured (AM) Ti-6Al-4V alloys in 0.6 M NaBr and 0.6 M NaCl aqueous solutions were compared using micro-droplet cell techniques. With respect to the pitting corrosion resistance, this study focused on two different types of halide anions in aqueous solutions, i.e. $Br^-$ and $Cl^-$. The differences between $Br^-$ and $Cl^-$ halide anions for breakdown on passive films of AM Ti-6Al-4V alloy were explained using Langmuir adsorption model with their equilibrium adsorption coefficients. The results of the analysis showed that the lower resistance to pitting potential of AM Ti-6Al-4V alloy in $Br^-$ aqueous solution was attributed to the higher equilibrium adsorption coefficient of Br-. In addition, micro-electrochemical test results showed that the pitting corrosion resistance of dark grains in additive manufactured Ti-6Al-4V alloy was lower as compared to that of bright grains due to the larger volume of ${\alpha}^{\prime}$ phase that caused the susceptibility to pit initiation.

A Study on the Behavior of Reinforced Clay Subjected to Direct Shear (직접전단을 받는 보강점토의 거동에 관한 연구)

  • 유한규
    • Geotechnical Engineering
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    • v.10 no.4
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    • pp.67-82
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    • 1994
  • In this study, a reinforced clay model based on the limit equilibrium of forces under direct shear was proposed to predict shear strength increase in clays induced by the steel inclusion. The model accounted for the effects of orientation of inclusion, length, bonding stress between clay and indclusion and passive soil resistance 1 induced by the inclusion movement, on the behavior of reinforced clays. In order to compare with the theoretical predictions, direct shear tests were performed using a direct shear apparatus formed of an open shear box. Also pull-out tests were conducted to determine the bonding stress between the inclusion and clay. From the experimental results, the increase or decrease in shear strength of reinforced clay samples was found to depend on the orientation of inclusionas well as water content of clay samples. From the comparison of theoretical predictions and experimental results, it was found that the theore tical model predicted reasonably well the influence of orientation of the inclusion as well as passive soil resistance induced by the inclusion movement on the mechanical behavior of reinforced clays.

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Assessment of Corrosion Rate of Reinforcing Steel in Concrete Using Galvanostatic Pulse Transient Technique

  • So, Hyoung-Seok;Millard, Stephen Geoffrey
    • International Journal of Concrete Structures and Materials
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    • v.1 no.1
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    • pp.83-88
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    • 2007
  • This paper discusses a method of measuring transient potential response of a corrosion interface to a small galvanostatic pulse perturbation for a rapid assessment of the corrosion rate of reinforcing steel in concrete structures. Measurements were taken on 100 mm sections of steel bars which were subjected to a wide range of corrosion conditions, from passive steel to actively corroding steel. The duration of the applied galvanostatic pulse was varied between 5s and 180s, and the lateral distance of the point of measurement on the steel bar varied from zero to 400 mm. The result of the electrochemical transient response was investigated using a typical sampling rate of 1 kHz. Analysis of the transient potential response to the applied galvanostatic pulse has enabled the separation of equivalent electronic components so that the components of a series of capacitances and resistances, whose values are dependent on the corrosion condition of the reinforcing steel, could be isolated. The corrosion rate was calculated from a summation of the separate resistive components, which were associated with the corrosion interface, and was compared with the corrosion rate obtained from linear polarization resistance (LPR) method. The results show that the galvanostatic pulse transient technique enables the components of the polarization resistance to be evaluated separately so as to give more reliable corrosion rate values than those obtained from the LPR method. Additionally, this paper shows how the galvanostatic pulse transient response technique can be implemented. An appropriate measurement time for passive and actively corroding reinforcing steel is suggested for the galvanostatic pulse transient response measurements in the field site.