• 한국환경보건학회지
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• 제36권3호
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• pp.236-246
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• 2010

In preparative anti-corrosive coating experiments, polyaniline was obtained by reacting an oxidizing agent with the monomer aniline. Further, the primer coating was prepared using a variety of widely-used materials such as urethane resin. For the top coating, epoxy resin and acrylic urethane resin were used. Characteristics of the coatings were assessed according to KS and ASTM specifications, and the structure of the polyaniline was characterized using FT-IR and TGA. For analysis of anti-corrosive properties in salt-spray experiments, measurements of the oxidation state of iron and surface atomic analysis were conducted using XPS and SEM-EDX. Unlike general anti-corrosive coatings which exhibit anti-corrosive effects only as a primer coating, the anti-corrosive coatings using polyaniline as the anti-corrosive pigment showed a marked synergistic effect with the top coatings. In other words, the top coatings not only produce a fine view effect, but also increase, through interaction with the primer coatings, the resistance to diffusion of corrosive factors from the external environment. It was also found that, unlike the heavy metal oxide-forming layer of the passive barrier alone, the polyaniline anti-corrosive pigment oxidized iron at the interface with the iron substrate to form a passive barrier in the oxidic layer, and itself formed a potential barrier layer with anti-corrosive factors from the external environment. Although the passive layer was damaged, the damaged area did not become completely oxidized iron; on the contrary, it showed a tendency to reduction. This can be interpreted such that a passive layer is formed again on the damaged area, and that at the same time there is a tendency to self-healing.

• 신재생에너지
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• 제4권1호
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• pp.31-36
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• 2008

Stainless steels have been widely considered as metallic bipolar plates, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the bipolar plates and the electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 추계학술대회 논문집
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• pp.1-5
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• 2008

Stainless steels have been widely considered as metallic separators, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the separators and electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

• 열처리공학회지
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• 제22권6호
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• pp.354-360
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• 2009

This paper reports the oxidation mechanism of epitaxial Ni thin films grown on GaN/sapphire(0001) substrates, investigated by real-time x-ray diffraction and scanning electron microscopy. At the initial stage of oxidation process, a thin NiO layer with a thickness of ${\sim}50\;{\AA}$ was formed on top of the Ni films. The growth of such NiO layer was saturated and then served as a passive oxide layer for the further oxidation process. For the second oxidation stage, host Ni atoms diffused out to the surfaces of initially formed NiO layer through the defects running vertically to form NiO grains, while the sites that were occupied by host Ni, became voids. The crystallographic properties of resultant NiO films, such as grain size and mosaic distribution, rely highly on the oxidation temperatures.

• 한국추진공학회지
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• 제5권3호
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• pp.25-32
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• 2001

본 연구에서는 2차원 압축성 Navier-Stokes 방정식을 이용하여, 약한 수직충격파와 난류 경계층의 간섭현상에 대한 피동제어 유동장을 수치계산법으로 조사하였다. 벽 내부에 공동을 가지는 다공벽을 사용하여 충격파와 난류경계층간 상호간섭을 제어하였다. 본 연구로부터 $\lambda$형 충격파의 하류쪽 가지를 중심으로 하여, 그 하류에서는 주유동이 공동내부로 또 그 상류에서는 공동내부로부터 주유동쪽으로 피이드백되는 유동을 관찰하였으며, 다공벽의 구멍을 통하는 유동은 초크하지 않는다는 것을 알았다.

• 대한기계학회논문집B
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• 제20권3호
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• pp.1083-1095
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• 1996

Shock wave/boundary layer interaction frequently causes the shock wave to oscillate violently and thus the global flow field to unstabilize. In order to stabilize the shock wave system in the diffuser of a supersonic wind tunnel, the present study attempted to control the shock oscillations by using a passive control. A porous wall with the porosity of 19.6% was mounted on a shallow cavity. Experiment was made by means of schlieren optical observation and wall pressure measurements. The flow Mach number just upstream the shock system and Reynolds number based on the turbulent boundary layer thickness were 2.1 and 1.8 * 10$\^$6/, respectively. The results show that the present passive control method on the shock wave/boundary layer interaction in the supersonic diffuser can significantly suppress the oscillations of shock system, especially when the shock system locates at the porous wall.

• International Journal of Precision Engineering and Manufacturing
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• 제4권1호
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• pp.37-42
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• 2003

Active control of flexural vibrations of smart laminated composite beams has been carried out using piezoceramic sensor/actuator and viscoelastic material. The beams with passive constrained layer damping have been analyzed by formulating the equations of motion through the use of extended Hamilton's principle. The dynamic characteristics such as damping ratio and modal damping of the beam are calculated for various fiber orientations by means of iterative complex eigensolution method. This paper addresses a design strategy of laminated composite under flexural vibrations to design structure with maximum possible damping capacity.

• 대한기계학회논문집B
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• 제21권2호
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• pp.329-340
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• 1997

A passive control of interaction of condensation shock wave / boundary layer for reducing the strength of condensation shock was conducted experimentally in a 2.5 * 8 cm$^{2}$ indraft type supersonic wind tunnel. The effects of following factors on passive control were investigated: 1) the thickness of porous wall, 2) the diameter of porous hole, and 3) the orientation of porous hole. On the other hand, the location of nonequilibrium condensation region and condensation shock wave was controlled by regulation of the stagnation conditions. Surface static pressure measurements as well as Schlieren observations of the flow field were obtained, and their effects were compared with the results the cases of without passive control. It was found that thinner porous wall, smaller porous hole and FFH orientation for the same cavity size and porosity of 12% are more favourable than the cases of its opposite.

• 대한치과의사협회지
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• 제58권5호
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• pp.276-283
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• 2020

Objectives: The aim of this study was to evaluate the efficacy of CK files as an ultrasonic instrument, and to determine most efficient file size for smear layer removal. Materials and Methods: Thirty-six extracted human mandibular premolars with single, straight root canals and mature apices were mechanically prepared and randomly divided into three groups. Group 1 (Control) underwent conventional needle irrigation, Group 2 (CKS) underwent passive ultrasonic irrigation with a #20 CK file, and Group 3 (CKL) underwent passive ultrasonic irrigation with a #30 CK file. After preparation and irrigation, all teeth were dried and split with a chisel to obtain the mesial and distal half of their roots. Each sample was evaluated using a scanning electron microscope, and data were analyzed using the Kruskal-Wallis and Mann-Whitney rank sum tests (p<0.05). Results: The CKS group showed less debris in the apical third than the other groups (p<0.05). In this section, no significant difference was observed among the other groups. And, there was no significant difference among any groups for the middle third section. Conclusion: This study showed that PUI with #20 CK file removed more smear layer compared to using #30 CK file at the apical third of the root canal.

• 정보저장시스템학회논문집
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• 제3권3호
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• pp.149-153
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• 2007

Perpendicular patterned magnetic media have been regarded as a prime candidate to achieve an ultra-high magnetic recording density of over 1 Tera-bits/$inch^2$. Patterned magnetic media with nanoscale patterns have been fabricated using various nanopatterning technologies. We focused on the two technical issues of nanoinjection molding technology. Firstly, we have investigated a cost-effective method to fabricate metallic stamps. Secondly, we focused on the analysis of nanoinjection molding with passive heating, where the replication of 50 nm nanopillar arrays was successful. The effect of the thermal insulation layer on the replication quality was examined by analytical and experimental methods. Finally, we deposited a magnetic layer on a injection molded nanopillars and measured. Our methodology can provide cost-effective mass-production for patterned magnetic media.