• Title/Summary/Keyword: Passivation

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Influence of Perfluorinated Polymer Passivation on AlGaN/GaN High-electron-mobility Transistors (질화갈륨계 고전자이동도 트랜지스터에 대한 불소계 고분자 보호막의 영향)

  • Jang, Soohwan
    • Korean Chemical Engineering Research
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    • v.48 no.4
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    • pp.511-514
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    • 2010
  • Perfluorinated polymer($Cytop^{TM}$) was deposited on selective area of AlGaN/GaN HEMT structure using low cost and simple spin-coating method, and the electrical characteristics of the device was analyzed for application of passivation layer on semiconductors. Gate lag measurement results of $Cytop^{TM}$ passivated and unpassivated HEMT were compared. Passivated device shows improved 65 % pulsed drain current of dc mode value. Rf measurements were also performed. $Cytop^{TM}$ passivated HEMT have similar rf performance to PECVD grown $Si_3N_4$ passivated device. $Cytop^{TM}$ passivation layer may play an important role in mitigating surface state trapping in the region between gate and drain.

Passivation of organic light emitting diodes with $Al_2O_3/Ag/Al_2O_3$ multilayer thin films grown by twin target sputtering system

  • Jeong, Jin-A;Kim, Han-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.420-423
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    • 2008
  • The characteristics of $Al_2O_3/Ag/Al_2O_3$ multilayer passivaton prepared by twin target sputtering (TTS) system for organic light emitting diodes. The $Al_2O_3/Ag/Al_2O_3$ multilayer thin film passivation on a PET substrate had a high transmittance of 86.44 % and low water vapor transmission rate (WVTR) of $0.011\;g/m^2$-day due to the surface plasmon resonance (SPR) effect of Ag interlayer and effective multilayer structure for preventing the intrusion of water vapor. Using synchrotron x-ray scattering and field emission scanning electron microscope (FESEM) examinations, we investigated the growth behavior of Ag layer on the $Al_2O_3$ layer to explain the SPR effect of the Ag layer. This indicates that an $Al_2O_3/Ag/Al_2O_3$ multilayer passivation is a promising thin film passivation scheme for organic based flexible optoelectronics.

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Thin composite film passivation through RF sputtering method For Large-sized Organic Display Devices

  • Lee, Joo-Won;Kim, Young-Min;Park, Jung-Soo;Bea, Sung-Jin;Kim, Na-Rae;Kim, Jai-Kyeong;Jang, Jin;Ju, Byeong-Kwon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1480-1483
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    • 2005
  • Transparent thin composite films (TCFs) were deposited on OLED devices by means of RF sputtering method and their passivation-properties were evaluated by comparing to the e-beam evaporating method. This composite film formed by mixed ratio of MgO (3wt %): $SiO_2$ (1wt %) was developed from pallet as a source of e-beam evaporator to 6-inch size target for sputtering in order to apply for large-sized organic display devices. Water Vapor Transmission Rates (WVTR) of the deposited films were measured as a function of thickness to assess the effectiveness of this film as a passivation layer and it applied to real devices. From this study, we can confirm that the passivation layer formed by TCFs using RF sputtering method sufficiently shows the potentiality of application to passivation layer for organic display devices.

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Studies on the deposition of ${Si_3}{N_4}$ for the passivation of PHEMT's (PHEMT Passivation을 위한 ${Si_3}{N_4}$)

  • Sin, Jae-Wan;Park, Hyeon-Chang;Park, Hyeong-Mu;Lee, Jin-Gu
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.39 no.1
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    • pp.25-30
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    • 2002
  • In this paper, high quality silicon nitride film is achieved using Plasma Enhanced Chemical Deposition(PECVD) system, and applied in passivating PHEMT's. Passivated PHEMT's(60 ${\mu}{\textrm}{m}$$\times$2 fingers) showed an increase of 2.7 % and 3 % in the drain saturation current and the maximum transconductance, respectively. The current gain cut-off frequency of 53 ㎓ and maximum oscillation frequency of 105 ㎓ were obtained from the fabricated PHEMT's.

Study on the Electrical Stability of poly-Si TFT through the Passivation Treatment with $NH_3$ or $N_2$ Precursors ($NH_3$$N_2$ 활성기 처리를 통한 Poly-SiliconTFT의 전기적 안정도에 관한 연구)

  • Jun, J.H.;Choi, H.S.;Park, C.M.;Choi, K.Y.;Han, M.K.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1443-1445
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    • 1996
  • Hydrogen passivation enhances the electrical characteristics of poly-Si TFT(Thin Film Transistor). However, the weak Si-H bonds, generated during hydrogenation, degrade the stability of the device. So, we carried out the passivation treatment with $NH_3$ or $N_2$. We compared the effect of $NH_3$ or $N_2$ passivation treatments with that of hydrogenation in terms of stability. Through the $NH_3$ passivation treatment, we obtained the most improved subthreshold swing of 1.2V/decade from the initial subthreshold swing of 1.56V/decade. When electrical stress was given, the $NH_3$ passivated devices showed best electrical stability.

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ONO Back Surface Passivation and Laser Fired Contact for c-Si Solar Cells

  • Kim, Sang-Seop;Lee, Jun-Gi;Choe, Byeong-Deok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.402-402
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    • 2011
  • 본 연구에서는 결정질 태양전지 제작에 있어 재료비 절감과 기존의 Screen Printing 공정 기술에서의 단점을 보완하기 위한 방안으로 후면 passivation 구조와 레이저를 이용한 국부적 후면 전극 형성(Laser Fired Contact) 방법에 대한 실험을 진행하였다. 후면 passivation 층으로 SiO2/ SiNx/SiO2 삼중막 구조와 SiNx 단일막 구조를 형성시킨 후 anneal 온도에 따른 소수캐리어의 lifetime 변화를 비교하였다. LFC 형성은 2 ${\mu}m$ 두께의 Al이 증착된 기판 후면에 1,064 nm 파장의 레이저를 통해 diameter와 dot pitch 등의 파라미터를 가변 하여 실시하였다. 실험 결과 800$^{\circ}C$의 고온 열처리 후 ONO 삼중막에서의 lifetime 향상이 우세하여 SiNx 단일 막 보다 열적 안정성이 우수함을 확인하였다. LFC 결과 diameter가 40, 50, 60 ${\mu}m$로 가변된 조건에서는 40 ${\mu}m$ 일 경우와 dot pitch가 200, 500, 1,000 ${\mu}m$로 가변된 조건에서는 1,000 ${\mu}m$일 경우 610 mV의 Voc 값을 보였다. 이는 레이저를 통해 국부적으로 Al-Si 간 alloy를 형성시킴으로써 접촉 면적이 최소화됨에 따라 후면에서의 캐리어의 재결합속도를 감소시키고, passivation 효과를 극대화시키기 때문이다.

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Environment-friendly Trivalent Chromate Treatment for Zn Electroplating (아연도금용 친환경 3가 크로메이트 표면처리기술)

  • Kim, Soo Won;Lee, Chul Tae
    • Applied Chemistry for Engineering
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    • v.17 no.5
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    • pp.433-442
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    • 2006
  • Hexavalent chromium passivation, as very effective anti-corrosion method, can not be used in the field of surface treatment for metal, any more. Throughout the world, this regulations which was applied to automotive industries will be extended to all industries including electronics industries in the near future. Therefore a new anti-corrosion method should be established without delay, and trivalent chromium passivation as an alternatives replace the hexavalent chromium passivation for the time being. This paper gives an overview of the currently available trivalent chromium passivation processes, and then it attempts to give an insight to develop a more effective trivalent chromium conversion coating process for possible substitution of the hexavalent chromium passivation process.

Characterization of the Polymer-based Organic Light Emitting Diode having Inorganic Thin Film Passivation Layer (무기 박막형 보호층을 이용한 고분자 유기발광 다이오드의 특성 평가)

  • Kim, Hoon;Kim, Kwang-Ho;Kim, Jae-Kyung;Lee, Yun-Hi;Han, Jeong-In;Do, Lee-Mi;Ju, Byeong-Kwon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.1
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    • pp.60-64
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    • 2003
  • In this study, the inorganic thin-film passivation layer was newly adopted to protect the organic layer from moisture and oxygen. Using the electron beam evaporation system, the various kinds of inorganic thin-films were deposited onto the organic layer and their interface properties between organic and inorganic layer were investigated. In this investigation, the MgO layer showed the most suitable properties, and based on this result, the time dependent emission properties were estimated for the OLED with and without passivation layer. In this experiment, we can see that the time-dependent emission properties of MgO passivated OLED had longer life-time compared to non-passivated OLED. Therefore, we can consider that the MgO thin film is one of the most suitable candidates for the thin-film passivation layer of OLED.

Improvement of Corrosion Resistance for Copper Tube by Electrochemical Passivation (전기화학적 부동태화에 의한 동관의 내식성 개선 연구)

  • Min, Sung-Ki;Kim, Kyung-Tae;Hwang, Woon-Suk
    • Corrosion Science and Technology
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    • v.10 no.4
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    • pp.125-130
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    • 2011
  • This study was performed to improve the corrosion resistance and the stability of passive film on copper tube by potentiostatic polarization method in synthetic tap water. Formation of passive film was carried out by anodic potentiostatic polarization at various passivation potentials and passivation times in 0.1 M NaOH solution. Stability of passive film and corrosion resistance was evaluated by self-activation time, ${\tau}_0$ from passive state to active state on open-circuit state in 0.1 M NaOH solution. Addition of polyphosphate in NaOH solution prolonged the self-activation time and improved the corrosion resistance, and the addition of 5 ppm polyphosphate was most effective. It was also observed that better corrosion resistance was obtained by potentiostatic polarization at 1.0 V (vs. SCE) than at any other passivation potentials. Passivated copper tube showed perfect corrosion resistance for the immersion test in synthetic tap water showing that the anodic potentiostatic polarization treatment in 0.1 M NaOH with 5 ppm polyphosphate solution would be effective in improving the corrosion resistance and preventing the blue water problem.

A Study on ALD $Al_2O_3$ Films for Rear Surface Passivation of Crystalline Silicon Solar Cells (결정질 태양전지의 후면 패시베이션을 위한 ALD $Al_2O_3$ 막 연구)

  • Roh, Si-Cheol;Seo, Hwa-Il
    • Journal of the Semiconductor & Display Technology
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    • v.10 no.1
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    • pp.57-61
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    • 2011
  • To develop high efficiency crystalline solar cells, the rear surface passivation is very important. In this paper, $Al_2O_3$ films deposited by thermal ALD(atomic layer deposition) method were studied for rear surface passivation of crystalline solar cells and their passivation properties were evaluated. After the deposition of $Al_2O_3$ films on p-type Si wafers, the lifetime was increased very much due to the reduction of interface state density and the field effects of the negative fixed charge in the films. Also, optimum annealing condition and effects of SiNx capping layer were investigated. The best lifetime was obtained when the films were annealed at $400^{\circ}C$ for 15min. And the lifetime degradation of the $Al_2O_3$ films with SiNx capping layers was improved compared to those without the capping layers.