• Title/Summary/Keyword: Particulate materials

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Biomimetic Apatite Precipitated on the Surface of Titanium Powder (티타늄분말의 표면에 석출된 생체모방 아파타이트)

  • Kim, Jong-Hee;Sim, Young-Uk;Yang, Tae-Young;Yoon, Seog-Young;Park, Hong-Chae
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.127-131
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    • 2010
  • Biomimetic whisker-like apatite was formed on thermally and NaOH-treated titanium powder in a simulated body fluid (SBF). In the early process of the SBF immersion, the surface structure of the titanium powder was loosened, possibly due to the dissolution of $Na^+$ ions on the surface of the titanium powder into SBF. When immersed for 7 days in SBF, fine precipitates appeared on the titanium surfaces; the coating layer (<200 nm in thickness) consisted of nanostructured, amorphous whisker-like and particulate phase, observed by TEM. With the extension of the immersion time to 16 days, the chrysanthemum flower type morphology of carbonated hydroxyapatite with a nanocrystallinity was developed on the surface of the titanium powder.

Mechanical and Microestructural Properties of Titanium Matrix Composites Reinforced by TiN Particles

  • Romero, F.;Amigo, V.;Salvador, M.D.;Martinez, E.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1026-1029
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    • 2006
  • Particulate reinforced titanium composites were produced by PM rout. Differents volumetric percentages of TiN reinforcements were used, 5,10,15 vol%. Samples were uniaxial pressed and vacuum sintered at differents temperatures between $1200-1300^{\circ}C$. Density, porosity, shrinkage, mechanical properties and microstructure were studied. Elastic properties and strength resistance were analysed by flexural strength and tension tests, and after the test, fractured samples were analysed too, obtaining a correlation between the fracture, interparticulated or intraparticulated, and the reinforcement addition.. Hardness and microhardness test were applied too, in order to complete the study about mechanical properties. In order to study wear resistance pin-on-disc test were used. In addition, the temperature influence, the reactivity between matrix and reinforcement, and the microstructures developed were observed by optical and electron microscopy.

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A Study of the Reduction of Diesel-Engine Emissions for Off-Road Vehicles (비도로 차량용 디젤엔진의 배기가스 저감에 관한 연구)

  • Cho, Gyu-Baek;Kim, Hong-Suk;Kang, Jeong-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.6
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    • pp.577-583
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    • 2011
  • To meet the requirements of the Tier 4 interim regulations for off-road vehicles, emissions of particulate matter (PM) and nitrogen oxides (NOx) must be reduced by 95% and 30%, respectively, compared to current regulations. In this research, both the DPF and HPL EGR systems were investigated, with the aim of decreasing the PM and NOx emissions of a 56-kW off-road vehicle. The results of the experiments show that the DOC-DPF system is very useful for reducing PM emissions. It is also found that the back pressure is acceptable, and the rate of power loss is less than 5%. By applying the HPL EGR system to the diesel engine, the NOx emissions under low- and middle-load conditions are reduced effectively because of the high differential pressure between the turbocharger inlet and the intake manifold. The NOx emissions can be decreased by increasing the EGR rate, but total hydrocarbon (THC) emission increases because of the increased fuel consumption needed to compensate for the power loss caused by EGR and DPF.

An Evaluation on Airborne Particulate and It's Components in the Welding Workplace for the Ship Construction Industry (조선업 용접작업장의 공기중 입자상물질 및 구성성분에 관한 연구)

  • Kang, Yong-Seon;Shin, Joong-Kyu;Lee, Song-Kwon;Yoon, Chung-Sik;Lim, Moo-Hyuk;Park, Man-Chul;Sim, Sang-Hyo
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.17 no.3
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    • pp.245-253
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    • 2007
  • This research was performed to evaluate the airborne personal concentration of hazardouse materials during the process of ship construction and surveyed from May 23 to June 30, 2007 in Kyungnam West Distirct, Korea. The subject was 94 ship construction workers exposed to welding fume and respirable particulate. The airborne concentrations of those were compared to Permissible Exposure Limit(PEL) from the Ministry of Labor in Korea. The airborne concentration of 23 samples(48.9%) of welding fumes was less than $5mg/m^3$, that of 16 (34.0%) was between 5 and $10mg/m^3$, and that of 8 (17.0%) was greater than $10mg/m^3$. The airborne concentration of 27 (57.4%) of respirable particulate masses was less than $5mg/m^3$ and the othere are greater than $5mg/m^3$. The welding fumes were identified containing the heavy metasl such as Fe, Mn, Zn, Mg, Ca, and Cu. The respirable particulates has similiar tendency with welding fumes in the component of heavy metals. But the concentration of Ca, Cu, Cr, and Ni turned out to be higher in welding fumes. Twenty (42.6%) of the 47 samples of welding fumes were exceeded PEL. In the heavy metals in welding fumes, ten (21.3%) of the 47 samples of Mn were exceeded PEL. Based on the results, the higher airborne hazardous materials were still exposed to wokers in ship construction process. It is suggested that the appropriate engineering control be applied to minimize the exposed cocnetration in ship building processes.

Characteristics of Generated Fibrous/Particulate Matters from Asbestos-Containing Building Materials(ACBMs) (해체·제거 작업 시 석면함유 건축자재에서 발생되는 섬유 및 입자상 물질의 특성)

  • Choi, Sungwon;Jang, Kwang Myoung;Park, Kyung Hoon;Kim, Dae Jong;Kim, Hyunwook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.25 no.2
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    • pp.184-193
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    • 2015
  • Objectives: This study focused on three aspects: characterizing concentrations of airborne particles by size distributions and asbestos fibers generated by various building materials; analyzing the characteristics of fibers produced by each simulation and asbestos fibers released from ACBMs; and investigating correlations of airborne asbestos fibers and particles generated and association of particle and asbestos concentrations. Methods: We selected three ACBMs including an insulation board, cement asbestos slate and wallboard. We constructed 4 scenarios; a) crushing with a hammer; b) cutting with a industrial knife; c) brushing with a metal brush; and d) tightening & loosening with a hand drill. We implemented one simulation for 30 seconds followed by 30 seconds resting period. We repeated a total of 5 cycles for 5 minutes. Results: The highest concentration of particulate & fibrous matters was from crushing with a hammer in each scenario followed by brushing with a metal brush, cutting with a industrial knife, and tightening & loosening with a hand drill. For ACBMs studied, asbestos concentrations were highest from an insulation board followed by cement asbestos slate, and wallboard. No difference in terms of concentration was found between an insulation board and asbestos slate. Fibers with $5{\sim}20{\mu}m$ in length were included in 76~90% of total fibrous matters. The distribution of the straight form fibers was greater than that of the curl form. About 90% of $PM_{Total}$ released from ACBMs was consisted of $PM_{10}$ while only 10% of $PM_{Total}$ was $PM_{2.5}$. Particulate matters like $PM_{2.5}$ was significantly correlated with fibrous matters($R^2=0.81$). Conclusions: We found ACBMs can significantly release asbestos fibers as well as $PM_{2.5}$. Concentrations of asbestos generated by ACBMs were well correlated with $PM_{2.5}$.

Experimental determination of design parameters for filtration trench using phosphorus removal granular materials (인 제거 입상소재를 적용한 여과수로 설계인자의 실험적 결정)

  • Jang, Yeoju;Lim, Hyunman;Jung, Jinhong;Ahn, Kwangho;Chang, Hyangyoun;Park, Nari;Kim, Weonjae
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.1
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    • pp.9-16
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    • 2019
  • The algal blooms in stagnant streams and lakes have caused many problems. Excessive algae leads to disturbance of ecosystem and overload of water treatment processes. Therefore, phosphorus(P), source of algal blooms, should be controlled. In this study, a filtration trench has been developed to convert dissolved phosphorus into hydroxyapatite(HAP) so that it could be crystallized on the surface of 'phosphorus removal granular material'; and residual particulate phosphorus could be removed by additional precipitation and filtration. The front and rear parts of filtration trench consisted of 'phosphorus removal granular material contact bed' and 'limestone filtration bed', respectively. As a result of the column test using phosphorus removal granular material and limestone serially, $PO_4-P$ was removed more than 90% when EBCT(empty bed contact time) of the contact bed was over 20 minutes; and T-P represented 60% of removal efficiency when total EBCT was over 1.5 hours. The results of column tests to figure out the sedimentation characteristics showed that more than 90% of particulate phosphorus could be removed within 24 hours. It was necessary to optimize the filtration part in order to increase removal efficiency of T-P additionally. Also, it was confirmed through the simulation of Visual MINTEQ that most of particulate phosphorus in the column tests is the form of HAP. Based on the results of the study, it could be suggested that the design parameters are over 0.5 hour of EBCT for phosphorus removal granular material contact bed and over 1.5 hours of EBCT for limestone filtration bed.

Reheating Process of Particulates Reinforced Metal Matrix Composites for Thixoforming (Thixoforming을 위한 입자강화형 금속복합재료의 Reheating 공정)

  • 이동건;안성수;강충길
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.04a
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    • pp.218-223
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    • 2000
  • A both mixing process of electro-magnetic stirring and mechanical process technique were used to fabricate particulate metal matrix composites(PMMCs) for variation of particle size. The PMMCs were tested for their tensile test for with and without heat treatment with T6. PMMCs fabrication processing conditions for both electrical and mechanical process are also suggested. In order to thixoforming of PMMCs, fabricated billet are reheated by using the optimal coil designed as a function of length between PMMC billet and coil surface, coil diameter and billet length. The effect of reinforcement distribution on billet temperature variation are investigated with calculated solid fraction theory proposed as a function of matrix alloy and volume fraction of reinforcement.

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Fracture Behavior of Alumina-Titania-Monazite Composites

  • Paek, Yeong-Kyeun;Chung, Tai-Soo
    • Journal of the Korean Ceramic Society
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    • v.42 no.6 s.277
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    • pp.443-447
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    • 2005
  • Fracture behavior was investigated in the $Al_2O_3-TiO_2(3 wt{\%})-LaPO_4(25 wt{\%}$) composite ceramics. To improve the fracture toughness of alumina ceramics, $TiO_2$ and $LaPO_4$ as a second phase were introduced. The samples were made by conventional powder processing method. Green compacts were sintered at $1600^{\circ}C$ for 2 h in air. Fracture toughness was tested using Indentation Strength Bending(ISB) method. From the bending test, enhanced fracture toughness was found in the composite, compared to the pure and $TiO_2$-doped alumina. The main factor of the enhancement of fracture toughness seems to be attributed to the weak interphase role of the $LaPO_4$ as a particulate type.

Hot Deformation Behavior of P/M Al6061-20% SiC Composite

  • Asgharzadeh, Hamed;Simchi, Abdolreza
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.855-856
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    • 2006
  • In the present work, hot workability of particulate-reinforced Al6061-20%SiC composite produced by direct hot extrusion technique was studied. Uniaxial hot compression test at various temperatures and strain rates was used and the workability behavior was evaluated from the flow curves and the attendant microstructures. It was shown that the presence of SiC particles in the soft Al6061 matrix deteriorates the hot workability. Bulging of the specimens and flow lines were observed, which indicate the plastic instability during hot working. Microstructure of the composites after hot deformation was found to be heterogeneous, i.e. the reinforcement clusters were observed at the flow lines. The mechanism of deformation was found to be controlled primarily by dynamic recrystallization.

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Application of Scaling Theories to Estimate Particle Aggregation in a Colloidal Suspension

  • Park, Soongwan;Koo, Sangkyun
    • Korean Chemical Engineering Research
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    • v.60 no.2
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    • pp.260-266
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    • 2022
  • Average aggregate size in particulate suspensions is estimated with scaling theories based on fractal concept and elasticity of colloidal gel. The scaling theories are used to determine structure parameters of the aggregates, i.e., fractal dimension and power-law exponent for aggregate size reduction with shear stress using scaling behavior of elastic modulus and shear yield stress as a function of particle concentration. The structure parameters are utilized to predict aggregate size which varies with shear stress through rheological modeling. Experimentally rheological measurement is conducted for aqueous suspension of zinc oxide particles with average diameter of 110 nm. The predicted aggregate size is about 1135 nm at 1 s-1 and 739 nm at 1000 s-1 on the average over the particle concentrations. It has been found that the predicted aggregate size near 0.1 s-1 agrees with that the measured one by a dynamic light scattering analyzer operated un-sheared.