• Title/Summary/Keyword: Particle contaminants

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Analysis of the Fine Particulate Matter Particle Size Fraction Emitted from Facilities Using Solid Refuse Fuel (고형연료제품 사용시설에서 배출되는 미세먼지 입경분율 분석)

  • You, Han-Jo;Jung, Yeon-Hoon;Kim, Jin-guil;Shin, Hyung-Soon;Lim, Yoon-Jung;Lee, Sang-Soo;Son, Hae-Jun;Lim, Sam-Hwa;Kim, Jong-Su
    • Journal of Environmental Health Sciences
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    • v.46 no.6
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    • pp.719-725
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    • 2020
  • Objectives: With the growth of national interest in fine particulate matter, many complaints about pollutants emitted from air pollution emitting facilities have arisen in recent years. In particular, it is thought that a large volume of particulate pollutants are discharged from workplaces that use Solid Refuse Fuel (SRF). Therefore, particulate contaminants generated from SRF were measured and analyzed in this study in terms of respective particle sizes. Methods: In this study, particulate matter in exhaust gas was measured by applying US EPA method 201a using a cyclone. This method measures Filterable Particulate Matter (FPM), and does not consider the Condensable Particulate Matter (CPM) that forms particles in the atmosphere after being discharged as a gas in the exhaust gas. Results: The mass concentration of Total Suspended Particles (TSP) in the four SRF-using facilities was 1.16 to 11.21 mg/Sm3, indicating a very large concentration deviation of about 10 times. When the fuel input method was the continuous injection type, particulate matter larger than 10 ㎛ diameter showed the highest particle size fraction, followed by particulate matter smaller than 10 ㎛ and larger than 2.5 ㎛, and particulate matter of 2.5 ㎛ or less. Contrary to the continuous injection type, the batch injection type had the smallest particle size fraction of particulate matter larger than 10 ㎛. The overall particulate matter decreased as the operating load factor decreased from 100% to 60% at the batch input type D plant. In addition, as incomplete combustion significantly decreased, the particle size fraction also changed significantly. Both TSP and heavy metals (six items) satisfied the emissions standards. The measured value of the emission factor was 38-99% smaller than the existing emissions factor. Conclusions: In the batch injection facility, the particulate matter decreased as the operating load factor decreased, as did the particle size fraction of the particulate matter. These results will help the selection of effective methods such as reducing the operating load factor instead of adjusting the operating time during emergency reduction measures.

Preparation of Styrene-Ethyl acylate Core-shell Structured Detection Materials for aMeasurement of the Wall Contamination by Emulsion Polymerization

  • Hwang, Ho-Sang;Seo, Bum-Kyoung;Lee, Dong-Gyu;Lee, Kune-Woo
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2009.06a
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    • pp.84-85
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    • 2009
  • New approaches for detecting, preventing and remedying environmental damage are important for protection of the environment. Procedures must be developed and implemented to reduce the amount of waste produced in chemical processes, to detect the presence and/or concentration of contaminants and decontaminate fouled environments. Contamination can be classified into three general types: airborne, surface and structural. The most dangerous type is airborne contamination, because of the opportunity for inhalation and ingestion. The second most dangerous type is surface contamination. Surface contamination can be transferred to workers by casual contact and if disturbed can easily be made airborne. The decontamination of the surface in the nuclear facilities has been widely studied with particular emphasis on small and large surfaces. The amount of wastes being produced during decommissioning of nuclear facilities is much higher than the total wastes cumulated during operation. And, the process of decommissioning has a strong possibility of personal's exposure and emission to environment of the radioactive contaminants, requiring through monitoring and estimation of radiation and radioactivity. So, it is important to monitor the radioactive contamination level of the nuclear facilities for the determination of the decontamination method, the establishment of the decommissioning planning, and the worker's safety. But it is very difficult to measure the surface contamination of the floor and wall in the highly contaminated facilities. In this study, the poly(styrene-ethyl acrylate) [poly(St-EA)] core-shell composite polymer for measurement of the radioactive contamination was synthesized by the method of emulsion polymerization. The morphology of the poly(St-EA) composite emulsion particle was core-shell structure, with polystyrene (PS)as the core and poly(ethyl acrylate) (PEA) as the shell. Core-shell polymers of styrene (St)/ethyl acrylate (EA) pair were prepared by sequential emulsion polymerization in the presence of sodium dodecyl sulfate (SOS) as an emulsifier using ammonium persulfate (APS) as an initiator. The polymer was made by impregnating organic scintillators, 2,5-diphenyloxazole (PPO) and 1,4-bis[5-phenyl-2-oxazol]benzene (POPOP). Related tests and analysis confirmed the success in synthesis of composite polymer. The products are characterized by IT-IR spectroscopy, TGA that were used, respectively, to show the structure, the thermal stability of the prepared polymer. Two-phase particles with a core-shell structure were obtained in experiments where the estimated glass transition temperature and the morphologies of emulsion particles. Radiation pollution level the detection about under using examined the beta rays. The morphology of the poly(St-EA) composite polymer synthesized by the method of emulsion polymerization was a core-shell structure, as shown in Fig. 1. Core-shell materials consist of a core structural domain covered by a shell domain. Clearly, the entire surface of PS core was covered by PEA. The inner region was a PS core and the outer region was a PEA shell. The particle size distribution showed similar in the range 350-360 nm.

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Distribution and Migration Characteristics of Explosive Compounds in Soil at Military Shooting Ranges in Gyeonggi Province (경기도 북부지역 군용 사격장 토양에 존재하는 화약물질 분포 및 이동 특성 조사)

  • Bae, Bumhan;Park, Jieun
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.6
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    • pp.17-29
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    • 2014
  • A remedial investigation was conducted at five military training ranges in northern Gyeonggi province to collect information necessary for the design of on-site treatment facilities for the abatement of explosive compounds release to the environment. These information includes (i) identification of dominant explosive compounds in each range, (ii) discharge/migration routes, and (iii) contaminant distribution in particle size fraction and settling velocity of the soils. The results of investigation showed that TNT and RDX are the major contaminants but the extent of contamination varied depending on the types of military training practices and topography of the site. RDX was also detected in the subsurface soil and in the nearby stream within the training ranges, suggesting release of contaminants to streams. The median concentrations of explosives in the surface soil were less than 20 mg/kg despite several 'hot spots' in which explosives concentrations often exceeds several hundred mg/kg. The average clay contents in the soil of target area was less than 5 % compared to 12 % in the control, indicating loss of smaller particles by surface runoff during rainfall due to lack of vegetative land cover. Analysis of explosive compounds and particle size distribution showed that the amount of explosive compounds in soil particles smaller than 0.075 mm was less than 10 % of the total. Settling column tests also revealed that the quantity of explosive compounds in the liquid phase of the effluent was greater than that in the solid phase. Therefore, pre-treatment of particulate matter in surface runoff of shooting range with a simple settling basin and subsequent effluent treatment with planted constructed wetlands as polishing stage for explosives in the aqueous phase would provide the shooting ranges with a self-standing, sustainable, green solution.

Electrophoretic Particle Movement in Suspension Considering the Gravitational Settling and Sedimentation of Clayey Soil (중금속으로 오염된 점성토의 동전기영동에 의한 침강 거동에 관한 연구)

  • Lee, Myung-Ho
    • Journal of Soil and Groundwater Environment
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    • v.12 no.3
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    • pp.44-52
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    • 2007
  • Contaminated sediments more than 30 million/$m^3$ is generated from dredging work for harbours and coastal maintenance in Korea. Approximately 300 million/$m^3$ of sediments is dredged to deepen harbours and shipping lanes in US and of which $3{\sim}12million/m^3$ is highly contaminated. Although much is known about technologies for the remediation of heavy metal contaminated soil, much less is known about the treatment of contaminated sediment. In general, negatively charged fine particles will migrate towards positively charged system of electrodes under the influence of electrophoresis. However, the electrically induced migration of colloidal particles contaminated with heavy metals may be hindered by the positively charged heavy metal contaminants adsorbed onto the soil surfaces depending on the contamination level. This paper demonstrates settling behaviour of clayey soil by comparison with electrophoretic particle movement under the effects of heavy metal contamination, applied electric field strength, and its polarity changed by the electrode configuration.

Removal of As, Cadmium and Lead in Sandy Soil with Sonification-Electrokinetic Remediation (초음파동전기기법을 이용한 비소, 카드뮴, 납으로 오염된 사질토 정화 연구)

  • Oh, SeungJin;Oh, Minah;Lee, Jai-Young
    • Journal of Soil and Groundwater Environment
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    • v.18 no.7
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    • pp.1-11
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    • 2013
  • The actively soil pollution by the toxic heavy-metals like the arsenic, cadmium, lead due to the industrialization and economic activity. The uses the electrokinetic remediation of contaminated soil has many researches against the fine soil having a small size in the on going. However, it is the actual condition which the research result that is not effective due to the low surface charge of the particle and high permeability shows in the electrokinetic remediation in comparison with the fine soil in the case of the sandy soil in which the particle size is large. In this research, the electrokinetic remediation and ultrasonic wave fetch strategy is compound applied against the sandy soil polluted by the arsenic, cadmium, and lead removal efficiency of the sandy soil through the comparison with the existing electrokinetic remediation tries to be evaluated. First of all, desorption of contaminants in soil by ultrasonic extraction in the Pre-Test conducted to see desorption effective 5~15%. After that, By conducted Batch-Test results frequency output century 200 Khz, reaction time 30 min, contaminated soil used in experiment was 500 g. Removal efficiency of arsenic, cadmium, lead are 25.55%, 8.01%, 34.90%. But, As, Cd, Pb remediation efficiency less than 1% in EK1(control group).

SOx and NOx removal performance by a wet-pulse discharge complex system (습식-펄스방전 복합시스템의 황산화물 및 질소산화물 제거성능 특성)

  • Park, Hyunjin;Lee, Whanyoung;Park, Munlye;Noh, Hakjae;You, Junggu;Han, Bangwoo;Hong, Keejung
    • Particle and aerosol research
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    • v.15 no.1
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    • pp.1-13
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    • 2019
  • Current desulfurization and denitrification technologies have reached a considerable level in terms of reduction efficiency. However, when compared with the simultaneous reduction technology, the individual reduction technologies have issues such as economic disadvantages due to the difficulty to scale-up apparatus, secondary pollution from wastewater/waste during the treatment process, requirement of large facilities for post-treatment, and increased installation costs. Therefore, it is necessary to enable practical application of simultaneous SOx and NOx treatment technologies to remove two or more contaminants in one process. The present study analyzes a technology capable of maintaining simultaneous treatment of SOx and NOx even at low temperatures due to the electrochemically generated strong oxidation of the wet-pulse complex system. This system also reduces unreacted residual gas and secondary products through the wet scrubbing process. It addresses common problems of the existing fuel gas treatment methods such as SDR, SCR, and activated carbon adsorption (i.e., low treatment efficiency, expensive maintenance cost, large installation area, and energy loss). Experiments were performed with varying variables such as pulse voltage, reaction temperature, chemicals and additives ratios, liquid/gas ratio, structure of the aeration cleaning nozzle, and gas inlet concentration. The performance of individual and complex processes using the wet-pulse discharge reaction were analyzed and compared.

Runoff Characteristics of Non-Point Sources on the Stormwater (강우에 의한 도로 비점오염원 유출 특성)

  • Kim, Seog-Ku;Kim, Young-Im;Kang, Sung-Won;Yun, Sang-Leen;Kim, So-Jung
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.1
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    • pp.104-110
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    • 2006
  • Growth in population and urbanization has progressively increased the loadings of pollutants from non-point sources as well as point sources. Accordingly, release of contaminants from non-point sources, released with surface runoff of rainwater, is influenced by atmospheric phenomena, geology, and topography. This makes the control of non-point source difficult. Therefore, this study intends to reveal the characteristics of runoff and particle size distribution to observe the fundamental characteristics of runoff. Experiments were carried out at inner road of research center. Average concentration of runoff ranged from 26.8 to 126.4 mg/L for SS and $COD_{Cr}\;15.3{\sim}117.7mg/L,\;TN\;0.07{\sim}5.16mg/L,\;TP\;0.06{\sim}0.49mg/L$ and heavy metals $0.00{\sim}0.29mg/L$. First flush, indicated wash off of pollutant at first rain, was observed for all types of pollutants. Most pollutants revealed a very close correlation with SS ($R^2=0.93{\sim}0.99$). After analyzing characteristics of particle, particle was finer than that from previously examined data.

A Study on Membrane Fouling Contaminants and Control in Enhanced Sewage Treatment by Submerged Membrane Bioreactor (침지형 분리막을 이용한 오수고도처리 공정의 막오염 원인물질 및 제어에 관한 연구)

  • Park, Chul-Hwi;Yun, Jae-Gon
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.5
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    • pp.619-627
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    • 2004
  • Purposes of this study were to examine closely the extracellular polymeric substances (EPS) which was a membrane fouling contaminant, to control detected EPS by powdered activated carbon (PAC) dosage etc. and to evaluate the possibility of practical reuse facility. With high removal efficiency of general pollutants, when the PAC is added to MBR, improvement of removal efficiency of $COD_{cr}$, and color was expected and treated wastewater can be reused. It was judged that the correlation between EPS and membrane fouling was very high. Carbohydrate and DNA in the EPS were judged to be cause of membrane fouling. If EPS could be controled, not only membrane fouling would be decreased but also operation time would be extended. In experiment of powdered activated carbon (PAC), characteristics of the best PAC for membrane fouling control were the particle size of $7{\mu}m$, lodine Number of 1,050, surface area of peat of $1,150m^2/g$. In lab test, operation time of MBR by PAC dosage of 200mg/gVSS was longer than one of MBR by without PAC dosage. Because EPS, especially carbohydrate and DNA, was controled successfully by PAC, membrane fouling in MBR could be decreased.

An Experimental Investigation on the Contamination Sensitivity of an Automotive Fuel Pump

  • Lee Jae-Cheon;Shin Hyun-Myng
    • International Journal of Precision Engineering and Manufacturing
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    • v.6 no.3
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    • pp.51-55
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    • 2005
  • This study addresses the contamination sensitivity test of a typical fuel pump for an automotive vehicle. The objective of the study is to find the contamination sensitivity coefficient of a fuel pump on specific contaminant particle sizes so that an optimal fuel filter could be selected. To achieve the objective, the degradation of discharge flow rate of the fuel pump is measured under the experiments of various contaminants size ranges of ISO test dust up to $80\;{\mu}m$. The fundamental theory of contamination sensitivity is introduced and the contamination sensitivity coefficients are estimated using the experimental data. Maximum contamination sensitivity coefficient of $5\chi\;10^{-6}\;L/min{\cdot}Ea$ is found in the contaminant size range of $40\;{\mu}m\~50\;{\mu}m$. The magnified picture of the surface of vane disc reveals that the abrasive wear is the principal cause of discharge flow rate degradation. Hence, this study reveals that a high efficiency filter for contaminant particles especially in the size range of $30\;{\mu}m\~70\;{\mu}m$ especially should be used to maintain the service life of the fuel filter.

Study on Discharge Electrode Design applied for Road Tunnel (터널용 전기집진시스템 개발을 위한 방전극 설계)

  • Kim, Jong-Ryul;Weon, Jong-Oung;Jang, Chun-Man
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.1238-1243
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    • 2009
  • As Social Overhead Capital(SOC) has been expanded, the highway road construction has been accelerated and city road system has been more complicated. So, long road tunnels have been increased and traffic flow rate also has been raised. Accordingly, the exhausting gas of vehicle cars seriously deteriorates the tunnel inside air quality and driving view. In order to improve tunnel inside air quality, it is needed to introduce a compulsory ventilation system as well as natural ventilation mechanism. The former, that is, a special compulsory ventilation facility is very useful and helpful to prevent a tunnel of being contaminated by traffic in most case. In the case of obtaining clearer and longer driving view, the ventilation systems have to be considered in order to remove floating contaminants or exhaust gas from engines. In this paper, discharge electrode design technology will be discussed.

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