• 대한기계학회논문집B
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• 제31권7호
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• pp.596-603
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• 2007

As increasing interest for soot emission. etc in combustion systems, various studies are being carried out for the reduction and measurement techniques of soot. Especially, laser induced incandescence is the useful measurement technique which has distinguished spatial and temporal resolution for primary particle size, volume fraction and aggregated particle size etc. Time resolved laser induced incandescence is the technique for measuring primary particle size that is decided to solve the signal decay rate which is related to the cooling behavior of heated particle by pulsed laser. The cooling behavior of heated particle is able to represent the heat and mass transfer model which are involved constants of soot property for surround gas temperature on the our previous work. In this study, it is applied to the time-dependence thermodynamic properties for soot temperature instead of constants of soot property for surround gas temperature and compared two different model results.

• Journal of Welding and Joining
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• 제8권4호
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• pp.58-68
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• 1990

The formation of thermal stresses by plasma spraying is generally considered as adverse. Therefore, the knowledge of stress distribution in the deposited layer during and after plasma spraying will be of special interest. In this study finite difference heat transfer analysis and finite element stress analysis were carried out to predict the change of stress distribution in the plasma coated layer with the variations of preheat temperature, number of scan, particle size, and bond coat. The results of the numerical analysis were as follows: 1) Transient stresses developed in the coated layer were up to the level of yiedl strength at the temperature. 2) The tensile stresses were developed in the deposited layer and the surface of the substrate, but the compressive stresses were developed in the rest of the substrate. 3) Transient and residual stresses were significantly affected by the preheat temperature. 4) The variations of temperature of powder particle and number of torch scan changed tensile stress distribution, but made no difference on the magnitude of the stresses. 5) Bond coated layer reduced the stree level of deposited layer.

• 한국환경보건학회지
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• 제29권4호
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• pp.10-16
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• 2003

Atmospheric samples were conducted from September 2001 to July 2002 with GPS-l PUF sampler in rural site to concentration distributions of gas/particle PCBs and to calculate dry deposition flux of PCBs. $\Sigma$PCBs concentrations of gas/particle PCBs were 59.29$\pm$48.83, 6.56$\pm$6.59 pg/㎥, respectively. Gas contribution (%) of total PCBs (gas + particle) was 90% which existed gas phase in the atmosphere. The particle contribution (%) of PCB congeners increased relatively more of the less volatile congeners with the highest chlorine number. The correlation coefficients (r) between total PCBs and temperature ($^{\circ}C$) showed negative correlation in - 0.62 (p<0.0l) for particle phase, positive correlation in 0.63 (p<0.01) for gas phase. In other word, particle phase PCBs is enriched in colder weather which could be due to greater in corporation of condensed gas phase at low temperature. The calculated dry deposition of total PCBs (gas + particle) was 0.008, 0.008 $\mu\textrm{g}$ $m^{-2}$ da $y^{-l}$ which showed maximum dry deposition flux in December, minimum data in July Bs in the atmosphere. The calculated dry deposition fluxes of total PCBs were influenced by particle phase PCBs even though PCBs in the atmosphere were present primarily in the gas phase.e.

• 한국입자에어로졸학회지
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• 제5권3호
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• pp.123-131
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• 2009

This paper presents simulation results of particle transport in low-pressure, low-temperature plasma environment. The size dependent transport of particles in the plasma is investigated with a two-dimensional simulation tool developed in-house for plasma chamber analysis and design. The plasma model consists of the first two and three moments of the Boltzmann equation for ion and electron fluids respectively, coupled to Poisson's equation for the self-consistent electric field. The particle transport model takes into account all important factors, such as gravitational, electrostatic, ion drag, neutral drag and Brownian forces, affecting the motion of particles in the plasma environment. The particle transport model coupled with both neutral fluid and plasma models is simulated through a Lagrangian approach tracking the individual trajectory of each particle by taking a force balance on the particle. The size dependant trap locations of particles ranging from a few nm to a few ${\mu}m$ are identified in both electropositive and electronegative plasmas. The simulation results show that particles are trapped at locations where the forces acting on them balance. While fine particles tend to be trapped in the bulk, large particles accumulate near bottom sheath boundaries and around material interfaces, such as wafer and electrode edges where a sudden change in electric field occurs. Overall, small particles form a "dome" shape around the center of the plasma reactor and are also trapped in a "ring" near the radial sheath boundaries, while larger particles accumulate only in the "ring". These simulation results are qualitatively in good agreement with experimental observation.

• 한국연소학회지
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• 제4권2호
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• pp.1-10
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• 1999

Pulverized coal is widely used as the source of electrical power generation and industrial processes. Numerical analysis on the transient ignition process of the cloud of pulverized coal particles in various cases is carried out. Particle radius, initial particle temperature, number density are chosen as major parameters that influence the characteristics of ignition and combustion. The result can be summarized as follow. The ignition occurs at the position that is closed to the surface of the cloud. Maximum temperature and velocity appear at ignition point, and the concentrations of gaseous fuel and oxidizer decrease rapidly near the ignition point. The chemical reaction takes place in wider zone as number density and particle radius decrease. The ignition delay is shortest when particle radius is about $50\;{\mu}m$, and tends to be shorter as number density and initial ambient temperature increase.

• 한국인쇄학회지
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• 제16권1호
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• pp.81-93
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• 1998

For the purpose of preparation of monodispersed spherical zinc oxide fine particles, and experimental research on the preparation of zinc oxide particles from zinc salts solutions by high temperature precipitation reaction was performed. Zinc oxide particles were precipitated from all the precipitation solutions tested if the precipitation temperature was higher than 60$^{\circ}$C. As the precipitation temperature increased until 80$^{\circ}$C, the average particle diameter of zinc oxide particles decreased and the narrower particle size distribution were obtained. Spherical zinc oxide fine particles with relativeyl narrow particle size distribution were precipitated from the ZnSo4 solutions with NaOH as precipitant. Final pH of precipitation solution had an effect on the amount of zinc oxide precipitated, but had no effect on the their particle size or size distribution.

• Nuclear Engineering and Technology
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• 제28권4호
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• pp.366-372
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• 1996

The simulated spent PWR fuel pellet which is corresponding to the turnup of 33,000 MWD/MTU is prepared by adding 11 fission-product elements to UO$_2$. The simulated spent fuel pellet is treated at 40$0^{\circ}C$ in air (oxidation), at 110$0^{\circ}C$ in air (high-temperature treatment), and at $600^{\circ}C$ in hydrogen (reduction). The product is treated through additional addition and reduction up to 3 cycles. Pellets are completely pulverized by the first oxidation, and the high-temperature treatment causes particle and crystallite to grow and surface to be smooth, and thus particle size significantly increases and surface area decreases. The reduction following the high-temperature treatment decreases much the particle size by means of the formation of intercrystalline cracks. The particle size decreases a little during the second oxidation and reduction cycle and then remains nearly constant during the third and fourth cycles. Surface area of pounder increases progressively with the repetition of oxidation and reduction cycles, mainly due to the formation of Surface cracks. The degradation of surface area resulting from high-temperature treatment is restored by too subsequent resulting oxidation and reduction cycles.

• 한국분말재료학회지
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• 제16권2호
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• pp.104-109
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• 2009

Niobium powder was made from potassium heptafluoroniobite ($K_2NbF_7$) as the raw material using sodium (Na) as a reducing agent based on the hunter process. The apparatus for the experiment was designed and built specifically for the present study. The niobium particle size greatly increased as the reduction temperature increased from $710^{\circ}C$ to $800^{\circ}C$. The particle size was fairly uniform, varying from $0.09{\mu}m$ to $0.4{\mu}m$ depending on the reduction temperatures. The niobium powder morphology and particle size are very sensitive to a reaction temperature in the metallothermic reduction process. The yield of niobium powder increased from 55% to 80% with a increasing a reaction temperature.

• 한국환경보건학회지
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• 제29권2호
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• pp.45-49
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• 2003

In this study, lots of methods have been studing to utilize energy and decrease contaminated effluents. There has been great progress on IGCC (Integrated gasification combined cycle) to reduce thermal energy losses. The following results have been conducted from desulfurization experiments using waste shell to remove H$_2$S. According to TGA results, temperature had influenced on H$_2$S removal efficiency. As desulfurization temperature increased, desulfurization efficiency increased. Also, maximum desulfurization efficiency was observed at 80$0^{\circ}C$. Desulfurization was related to calcination temperature. Considering temperature ranges of exhausted gas from hot gas gasification equipment were 400~80$0^{\circ}C$. Thus, desulfurization efficiency would be increased desulfurization temperature situation at highly. Experiments by TGA showed that particle size of sorbents had influenced on desulfurization capacity. Maximum desulfurization capacity was observed at 0.631 mm for oyster and clam. Rest of sorbents showed similar capacity within 0.171~0.335 mm particle size range. So, particle size would be considered. When would be used waste shells as IGCC sorbents. According to the results about desulfurization capacity by TGA, oyster had the best desulfurization capacity among limestone and waste shell. We would be identify to substituted oyster for existing sorbents

• 한국재료학회지
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• 제13권5호
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• pp.323-327
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• 2003

Properties of nanoparticles synthesized during gas phase reaction were studied in terms of particle behaviors using real-time particle characterization method. For this study, $TiO_2$ nanoparticles were synthesized in the chemical vapor condensation process(CVC) and their in-situ measurement of particle formation and particle size distribution was performed by scanning mobility particle sizer(SMPS). As a result, particle behaviors in the CVC reactor were affected by both of number concentration and thermal coagulation, simultaneously. Particularly, growth and agglomeration between nanoparticles followed two different ways of dominances from coagulations by increase of number concentration and sintering effect by increased temperature.