• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.17 no.1
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• pp.1-13
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• 2019

The accident at the Fukushima Dai-ichi Nuclear Power Plant (FDNPP) resulted in the deposition of large quantities of radionuclides over parts of eastern Japan. Radioactive contaminants have been observed over a large area including forests, cities, rivers and lakes. Due to the strong adsorption of radioactive cesium by soil particles, radioactive cesium migrates with the eroded soil, follows the surface flow paths, and is delivered downstream of population-rich regions and eventually to coastal areas. In this study, we developed a model to simulate the transport of contaminated sediment in a watershed hydrological system and this model was compared with observation data from eroded soil observation instruments located at the Korea Atomic Energy Research Institute. Two methods were applied to analyze the soil particle size distribution of the collected soil samples, including standardized sieve analysis and image analysis methods. Numerical models were developed to simulate the movement of soil along with actual rainfall considering initial saturation, rainfall infiltration, multilayer and rain splash. In the 2019 study, a numerical model will be used to add rainfall shield effect by trees, evaporation effect and shield effects of surface water. An eroded soil observation instrument has been installed near the Wolsong nuclear power plant since 2018 and observation data are being continuously collected. Based on these observations data, we will develop the numerical model to analyze long-term behavior of radionuclides on land as they move from land to rivers, lakes and coastal areas.

• Journal of the Korean earth science society
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• v.43 no.6
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• pp.762-776
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• 2022

The purpose of this study was to determined the conceptual structure used by earth science teachers to classify metamorphic rocks as well as the criteria applied in the process of classifying metamorphic rocks. To this end, the researchers collected verbal data uttered in the process of classifying metamorphic rock using think-aloud from 21 earth science teachers in middle and high schools in Jeollabuk-do, Republic of Korea. The collected verbal data were analyzed using the semantic network analysis method, and the following results were obtained. First, in the process of classifying metamorphic rocks, earth science teachers classified them based on characteristics such as color, compositional minerals, and particle size, which can be generally observed in rocks, and foliation that appears in metamorphic rocks. Second, earth science teachers recognize the classification criteria for metamorphic rocks and focus on metamorphism such as contact metamorphism or regional metamorphism. However, there were cases where rocks were mistakenly classified through incorrect identification. Therefore, it is necessary to provide sufficient observational information about, and experience of, metamorphic rocks to enable earth science teachers to recognize and relate to the scientific process of identifying metamorphic rocks through the phenomena observed.

• Journal of the Korean Applied Science and Technology
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• v.33 no.2
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• pp.247-254
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• 2016

Since microzirconia has excellent thermal and mechanical properties with high chemical and electrical resistance, it can be used in various fields. When the surface of zirconia becomes hydrophilic, its dispersibility in water will be improved as well as the resistance to most hydrophobic contaminants will be increased. In this study, we investigated the introduction of a hydrophilic groups on the microzircornia surface through hydrolysis and condensation reactions with two different silanes containing hydrophilic functional groups, such as ${\gamma}$-aminopropyltrimethoxysilane (APS) and ${\gamma}$-ureidopropyltrimethoxysilane (UPS) at different pH and concentration conditions. A covalent bond formation between the surface hydroxyl groups of zirconia and that of hydrolyzed silanes was confirmed by ninhydrin test and FT-IR spectroscopy. However, the presence of Si on the surfaces of both silane modified microzirconias was unable to detect by SEM/EDS technique. In addition, particle size analysis results provide that the size of microzirconia was changed to smaller or bigger than that of original zirconia due to crushing and aggregation during the modification process. The water dispersibility was improved for only APS modifed zirconia (AS-2 and AS-3) under neutral pH condition, but the water dispersibility and stability for all cases of 0.5~2% UPS modifed zirconia (US series) were much improved.

• Journal of Technologic Dentistry
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• v.29 no.1
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• pp.121-131
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• 2007

A preparation process's conditions of aqueous sol which contains anatase-type nano titania particles with photocatalyic properties was established by using Yoldas process, so called, DCS(Destabilization of Colloidal Solution) process in this study. And crystal size change and phase transformation of titania particles in aqueous titania sol depending on reaction conditions was investigated by a light scattering method and XRD analysis of frozen dried powders, respectively. This sol with photo catalytic nano titania particles was used to the following hydrophilic hybrid coating film's fabrication and its properties was evaluated. Subsequently, for coating film using the above mentioned aqueous titania sol, non-aqueous titania sol was prepared without any chemical additives and its time stability according to aging time was investigate. By using the above mentioned aqueous titania sol and non-aqueous sol, a complex oxide coating sol for metal and ceramic substrate and a organic-inorganic hybrid coating sol for polymer substrate was prepared and it's hydrophilicity depending on UV irradiation conditions was evaluated. As a conclusions, the following results were obtained. (1)Aqueous titania sol The average particle size of titania in formed aqueous titania sol was distributed between 20$\sim$90nm range depending on reaction conditions. And the crystal phase of titania powders obtained by frozen drying method was changed from amorphous state to anatase and subsequently transformed to rutile crystal phase and it is attributed to concentration gradient in aqueous sol. (2)Non-aqueous titania sol Non-aqueous titania sol was prepared using methanol as a solvent and a little distilled water for hydrolysis and nitric acid as a catalyst were used. The obtained non-aqueous titania sol was stable at room temperature for 20 days. Additionally, non-aqueous titania sol with addition of chealating reagent such as acethylaceton and ethylene glycol prolonged the stability of sol by six months. (3)Complex sol and hybrid sol with super hydrophilicity The above mentioned aqueous titania sol as a main photocataylic component and non-aqueous titania sol as a binder for coating process was used to prepare a complex sol used for metal, ceramic and wood material substrate and also to prepare the organic-inorganic hybrid sol for polymer substrate such as polycarbonate and polyethylene, in which process APMS(3-Aminopropyltrimethoxysilane), GPTS(3-Glycidoxypropyl-trimethoxysilane) as a hydrophilic silane compound and HEMA(2-Hydroxyethyl methacrylate) as a forming network in hybrid coating film were used. The hybrid coating film such as prepared through this process showed a superhydrophilicity below 1$10^{\circ}$ depending on processing conditions and a pencil's hardness over 6 H.

• Asian Journal of Turfgrass Science
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• v.23 no.1
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• pp.61-76
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• 2009

The purpose of this study are to investigate the reasonable maintenance expense of golf course according to the size and management system of each golf course. The maintenance cost per hole per golfer of 29 golf courses and the maintenance cost for items and locations of 8 golf courses were analyzed. 1. As golfers per hole increased, maintenance cost per hole per golfer decreased. 2. The decisive cost factors for maintenance cost of golf course are the number of annual golfers, the total course size, the management system, and automation of course facilities. 3. Maintenance cost of golf courses contained the landscaping areas except for building and parking lots is $869^{\}/_{m^2}$ Korean won. 4. Average maintenance cost of 8 golf courses is $44,325,000^{\}/_{hole}$. 5. Labor cost marked the largest portion in the total cost. Among the items of labor cost, repair cost for green ball mark was the highest with the ratio of 26%(\4,163,000). 6. Material cost for Fairways which reaches 30% of the total area was composed of $22%{\sim}44%$ of the total cost of materials. Cost of imported fertilizers, pestcides for insects and diseases, and sands for top dressing was the highest. 7. Material cost for Green which reaches 2% of the total area was composed of $28%{\sim}36%$ of the total cost. Cost of imported products such as particle-shaped fertilizers, micro mineral fertilizers, and soil conditioners was the highest. 8. There is no difference in cost between chemical fertilizers and the environmentally friendly fertilizers even if environmentally friendly fertilizers using microorganism or chitosan materials are also expensive.

• Journal of the Korean Chemical Society
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• v.45 no.4
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• pp.341-350
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• 2001

Aluminum Hydroxide was employed as a thermal retardent and flame retardent for Chloropolyethylene (CPE) rubbery materials which is the construction material of automotive oil cooler hose. and then cure characteristics, physical properties, thermal resistance and flame retardation of compounded rubber were investigated, and optimum mixing conditions of rubber and flame retarding agent were deduced from the experimental results. CPE rubber material which has excellent properties of chemical corrosion resistance and cold resistance and inexpensive in price was used to prepare rubber specimen. The by-product of ething, produced from the process of surface treatment of aluminum was processed to aluminum hydroxide via crushing and purification, which is characterized by XRD, PSA, SEM and ICP-AES techniques in terms of phase, size, distribution, morphology and components of particles and then mixed to CPE rubber materials in the range of 0~80 phr. Hardness, tensile strength, elongation and thermal properties of compounded rubber specimens were tested. The optimum mixing ratio of rubber to additives to give maximum effect on thermal resistance and flame retardation, within the range of tolerable specification for rubber materials, was determined to be 40 phr. The flame retardation of CPE rubber materials was found to be increased by 5 times at this mixing ratio.

• Proceedings of the Korean Society for Rock Mechanics Conference
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• 2000.09a
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• pp.67-75
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• 2000

The numerical simulation of Brazilian fracture toughness test is carried out using PFC code and the influence parameters are analyzed such as shape of loading plane, size of Brazilian disc and unit panicle of model, loading angle and loading rate. The flattened Brazilian disc is adopted for applying uniform load. The range of loading angle(2$\alpha$) necessary to induce the tensile crack at disc center and to obtain the load-displacement curve giving the critical load for the stable crack propagation is shown as 20$^{\circ}$~40$^{\circ}$. In condition that the loading angle is 20$^{\circ}$, the mode-I fracture toughness is evaluated almost constant in the range of particle size less than I mm and loading rate less than 0.01 mm/s. This range of influence parameters seems appropriate condition for the tensile crack initiation at disc center and the control of stable crack propagation, which can give the reliance in evaluation of fracture toughness by Brazilian test.

• Journal of Korean Neurosurgical Society
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• v.63 no.6
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• pp.698-706
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• 2020

Objective : To study the physiochemical characteristics of podophyllotoxin (PPT) conjugated stearic acid grafted chitosan oligosaccharide micelle (PPT-CSO-SA), and evaluate the ability of the potential antineoplastic effects against glioma cells. Methods : PPT-CSO-SA was prepared by a dialysis method. The quality of PPT-CSO-SA including micellar size, zeta potential, drug encapsulation efficiency and drug release profiles was evaluated. Glioma cells were cultured and treated with PPT and PPT-CSO-SA. The ability of glioma cells to uptake PPT-CSO-SA was observed. The proliferation of glioma cells was determined by 3-[4, 5-dimethyl-2-thiazolyl]-2, 5-diphenyl-2H-tetrazolium bromide (MTT) assay. The apoptosis and morphology of U251 cells were observed by 4',6-Diamidino-2-phenylindole dihydrochloride (DAPI) dye staining. Cell cycle analysis was performed by flow cytometry. The migration ability of U251 cells was determined by wound healing test. Results : PPT-CSO-SA had nano-level particle size and sustained release property. The encapsulation efficiency of drug reached a high level. The cellular uptake percentage of PPT in glioma cells was lower than that of PPT-CSO-SA (p<0.05). The inhibitory effect of PPT-CSO-SA on glioma cells proliferation was significantly stronger than that of PPT (p<0.05). The morphologic change of apoptosis cell such as shrinkage, karyorrhexis and karyopyknosis were observed. The percentage of U251 cells in G2/M phase increased significantly in the PPT-CSO-SA group compared with PPT group (p<0.05). Compared with the PPT group, the cell migration ability of the PPT-CSO-SA group was significantly inhibited after 12 and 24 hours (p<0.05). Conclusion : PPT-CSO-SA can effectively enhance the glioma cellular uptake of drugs, inhibit glioma cells proliferation and migration, induce G2/M phase arrest of them, and promote their apoptosis. It may be a promising anti-glioma nano-drug.

• Economic and Environmental Geology
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• v.43 no.2
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• pp.177-184
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• 2010

When cement grout is used for waterproofing of grounds, important roles are played by fluidity, particle size and bleeding. The most important element which determines their characteristics is the water/cement ratio of grout. Moreover in order to improve the efficiency of soil permeation, micro cement with a smaller average diameter is used in addition to ordinary portland cement. Besides the mixing ratio and cement diameter, the condition of ground is also of fundamental importance in the efficiency of permeation. In order to evaluate grout in terms of permeation ability into ground, we need a field test of grounting, which is cost and time consuming. In this paper we present a laboratory test method in which the suitability and efficiency of grouts are simply and more practically tested. In Korea neither a test standard nor devices are available to simulate grouting in a laboratory. We devised a grout injection equipment in which grouting was reproduced in the same condition with different materials, and suggested a standard for the production of specimens. Our tests revealed that the efficiency of injection increases with the water/cement ratio. We also found that more efficiently injected is the grout with the order of decreasing size; MS8000, micro cement, and ultra fine cements, and colloidal super cement.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.26 no.5
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• pp.193-200
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• 2016

Characteristics of $SrAl_2O_4:Eu^{2+}$, $Dy^{3+}$ phosphorescent phosphors synthesized by solid state reaction and polymerized complex method were comparatively analyzed. In order to evaluate thermal stability of $SrAl_2O_4:Eu^{2+}$, $Dy^{3+}$ phosphorescent phosphors at high temperature, phosphorescent properties of $SrAl_2O_4:Eu^{2+}$, $Dy^{3+}$ were investigated with thermal treatment at $1250^{\circ}C$ under reducing atmosphere, which was the general heat treatment conditions for ceramic manufacturing process. The phosphorescent properties of thermally treated $SrAl_2O_4:Eu^{2+}$, $Dy^{3+}$ phosphors synthesized by solid state reaction and polymerized complex method were investigated. The crystal structure and crystallite size were observed through XRD analysis. Microstructure and particle size of thermally treated $SrAl_2O_4:Eu^{2+}$, $Dy^{3+}$ phosphors were analyzed by SEM and PSA. Photoluminescence and afterglow characteristics of thermally treated $SrAl_2O_4:Eu^{2+}$, $Dy^{3+}$ phosphorescent phosphors were measured by spectrofluorometer.