• Title/Summary/Keyword: Particle Length

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Structural Analysis of Conductive Polypyrroles Synthesized in an Ionic Liquid

  • Song, Eun-Ah;Jung, Woo-Gwang;Ihm, Dae-Woo;Kim, Jin-Yeol
    • Bulletin of the Korean Chemical Society
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    • v.30 no.5
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    • pp.1009-1011
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    • 2009
  • Nano-structured conducting polypyrroles were synthesized in the ionic liquids (ILs) based on 1-alkyl-3-methylimidazolium family with tetrachloroferrate as an anion ($C_n\;mim\;[FeCl_4]\;with\;n\;=\;4,\;8,\;and\;12$). The polypyrrole nanostructures synthesized in ILs were formed as spherical shapes. For ionic liquids with alkyl side chain length $C_4,\;C_4\;mim\;[FeCl_4]$, the size of particles was ranged around 60-nm with a relatively narrow size distribution. As the length of alkyl chain increases, the particle sizes become larger and their distributions become wider. The self-assembled local structures in the solvent ionic liquids are likely to serve as templates of highly organized nano-structured polymers. The length of the alkyl chain in ionic liquids seems to affect these local structures.

The Survey of Particle Size of Total Mixed Ration in Korea (국내 TMR의 입자도에 관한 조사 연구)

  • Ki, K.S.;Kim, H.S.;Jeong, H.Y.;Lee, H.J.;Ahn, B.S.;Kim, J.S.;Kwang, S.W.;Kim, Y.K.;Ha, J.K.
    • Journal of Animal Science and Technology
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    • v.45 no.5
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    • pp.813-818
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    • 2003
  • This study was carried out to survey operation system of self-making TMR and particle size of self-making and commercial TMR, then to compare TMR particle size recommended by Penn State Particle Size Separator. Daily mixing time in self-making TMR averaged 48.6${\pm}$28.0min., 2 augar type of mixer was most by 55.5% and daily 2 times of mixing in summer and other season was 44.4 and 22.2%, respectively. Percentage of residual feed in upper sieve(19mm diameter), middle sieve(8 to 18mm diameter) and lower pen was 21.5~25.6%, 16.0~25.8%, 52.8~61.4%, respectively, at self-making TMR mixer. Percentage of particle sizes of more than 19mm in self-making and commercial TMR was 24.9${\pm}$1.4 and 26.2${\pm}$1.7%, that of 8-10mm 22.8${\pm}$1.0 and 12.8${\pm}$1.2 and that of less than 8mm 52.3${\pm}$1.7 and 61.0${\pm}$1.5, respectively, which in particle length of 8~13mm in self-making and commercial TMR was lower by 82.6 and 100% compared to that recommended by Penn State particle separator, respectively. Especially there was not particle length of more than 19mm in commercial TMR at all. It is necessary to check the number of cows ruminating in a farm in order to estimate the particle size of TMR; it is recommended to change the TMR mixing time or the TMR formulae if the proportion of ruminating cows in a farm is less than 40 %.

Preparation of Zirconia Nanocrystalline Powder by the Hydrothemal Treatment at low Temperature (수열법에 의한 저온 결정형 지르코니아 나노 분말의 제조)

  • Noh, Hee-Jin;Lee, Jong-Kook;Seo, Dong-Seok;Hwang, Kyu-Hong
    • Journal of the Korean Ceramic Society
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    • v.39 no.3
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    • pp.308-314
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    • 2002
  • The nanocrystalline zirconia powder was synthesized from the zirconium hydroxide precipitate by hydrothermal process with the reaction temperature range 100∼250$^{\circ}$C, reaction time 1∼48 hours and additive concentration 1, 5 N NaOH solutions. The lower hydrothermal treatment temperature, the inner spherical tetragonal zirconia was synthesized. The fraction of monoclinic phase zirconia with rod shape increased with increasing the hydrothermal treatment temperature. As the concentration of the NaOH solution increases, the synthesized particle in breadth and length increased; breadth and length ratio decreased. In the case of the low concentration of NaOH solution, however, the particle length became relatively larger than its breadth resulting in the rod-shaped particles with bigger aspect ratio.

Arrangement of Disposal Holes According to the Features of Groundwater Flow (지하수 유동 특성을 이용한 심층처분의 처분공 배치 방안)

  • Ko, Nak-Youl;Baik, Min-Hoon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.4
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    • pp.321-329
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    • 2016
  • Based on the results of groundwater flow system modeling for a hypothetical deep geological repository site, quantitative and spatial distributions of groundwater flow rates at the positions of deposition holes, groundwater travel length and time from the positions to the surface environment were analyzed and used to suggest a method for determining locations of deposition holes. The hydraulic head values at the depth of the deposition holes and a particle tracking method were used to calculate the ground-water flow rates and groundwater travel length and time, respectively. From the results, an approach to designing a layout of deposition holes was suggested by selecting relatively favorable positions for maintaining performance of the disposal facility and screening some positions of deposition holes that did not comply with specific constraints for the groundwater flow rates, travel length and time. In addition, a method for determining a geometrical direction for extension of the disposal facility was discussed. Designing the layout of deposition holes with the information of groundwater flow at the disposal depth can contribute to secure performance and safety of the disposal facility.

Study of compressive behavior of triple joints using experimental test and numerical simulation

  • Sarfarazi, Vahab;Wang, Xiao;Nesari, Mojtaba;Ghalam, Erfan Zarrin
    • Smart Structures and Systems
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    • v.30 no.1
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    • pp.49-62
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    • 2022
  • Experimental and discrete element methods were used to investigate the effects of triple joints lengths and triple joint angle on the failure behavior of rock mass under uniaxial compressive test. Concrete samples with dimension of 20 cm × 20 cm × 5 cm were prepared. Within the specimen, three imbedded joint were provided. The joint lengths were 2 cm, 4cm and 6 cm. In constant joint lengths, the angle between middle joint and other joints were 30°, 60°, 90°, 120° and 150°. Totally 15 different models were tested under compression test. The axial load rate on the model was 0.05 mm/min. Concurrent with experimental tests, the models containing triple joints, length and joint angle are similar to the experiments, were numerical by Particle flow code in two dimensions (PFC2D). Loading rate in numerical modelling was 0.05 mm/min. Tensile strength of material was 1 MPa. The results show that the failure behaviors of rock samples containing triple joints were governed by both of the angle and the length of the triple joints. The uniaxial compressive strengths (UCS) of the specimens were related to the fracture pattern and failure mechanism of the discontinuities. Furthermore, it was shown that the compressive behavior of discontinuities is related to the number of the induced tensile cracks which are increased by decreasing the joint length. Along with the damage failure of the samples, the acoustic emission (AE) activities are excited. There were only a few AE hits in the initial stage of loading, then AE hits rapidly grow before the applied stress reached its peak. In addition, every stress drop was accompanied by a large number of AE hits. Finally, the failure pattern and failure strength are similar in both methods i.e., the experimental testing and the numerical simulation methods.

Variations of Flow Thalweg Alignment and Separation Region around a Groyne (단일수제 설치에 따른 흐름중심선과 흐름분리영역의 변화)

  • Yeo, Hong-Koo;Roh, Young-Sin;Kang, Joon-Gu;Kim, Sung-Jung
    • Journal of Korea Water Resources Association
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    • v.39 no.4 s.165
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    • pp.313-320
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    • 2006
  • In this study, hydraulic characteristics of thalweg line occurred near the single groyne and recirculation zone around downstream of the structure were discussed from the experiments which conducted in fixed flat-bed channel flume. The thalweg line is the stream line where the maximum velocity occurs and flow separation appeared at the tip of groyne changes the thalweg alignment. In this study, the variations in flow fields which were caused by different length and permeability of groyne were measured by LSPIV(Large Scale Particle Image Velocimetry), and also the characteristics of thalweg line and separation area were analyzed. From these results, it is found that length to thalweg line from the channel wall $T_{CL}$ and height of separation area $S_h$ vary the channel width up to 75%, 50% in the change of length and permeability of groyne, however the Froude number does not affect on $T_{CL}$ and $S_h$. Velocity along the thalweg $U_{CL}$ Increased by twice the mean velocity, and the maximum velocity occurred in downstream where the distance $5{\sim}6$ times of groyne length away from the groyne, which does not get affected by length and permeability of groyne and Froude number.

Performance Prediction of Heat Regenerators with using Spheres: Relation between Heat Transfer and Pressure Drop (구형 축열체를 사용한 축열기의 성능예측: 압력손실과 열전달의 관계)

  • 조한창;조길원;이용국
    • Journal of Energy Engineering
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    • v.12 no.1
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    • pp.35-41
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    • 2003
  • Heat regenerator occupied by regenerative materials improves thermal efficiency of regenerative combustion system through the recovery of heat of exhaust gaset. By using one-dimensional two-phase fluid dynamics model, the unsteady thermal flow of heat regenerator with spherical particles, was numerically simulated to evaluate the heat transfer and pressure drop and thereby to suggest the parameter for designing heat regenerator. It takes about 7 hours for the steady state of the flow field in regenerator, in which heat absorption of regenerative particle is concurrent with the same magnitude of heat desorption. The regenerative particle experiences small temperature fluctuation below 10 K during the reversing process. The performance of thermal flow in heat regenerator varies with inlet velocity of exhaust gas and air, configuration of regenerator (cross-sectional area and length) and diameter of regenerative particle. As the gas velocity increases, the heat transfer between gas and particle enhances and with the increase the pressure losses. As particle diameter decreases, the air is preheated higher and the exhaust gases are cooled more with the increase of pressure losses.

2-Dimensional Moving Particle Simulation for Prediction of Oil Boom Performance in Waves (파랑 중 오일붐 성능 예측을 위한 2차원 입자법 시뮬레이션)

  • Nam, Jung-Woo;Park, Ji-In;Hwang, Sung-Chul;Park, Jong-Chun;Jeong, Se-Min
    • Journal of Ocean Engineering and Technology
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    • v.27 no.4
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    • pp.90-97
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    • 2013
  • Oil booms are one of the most widely used types of equipment for the protection of coastal areas against oil spills. In some situations, however, there are several types of oil leaks from the oil boom. Important factors regarding these phenomena include the surrounding ocean environment, such as waves, the density and viscosity of oil, the length of the oil boom skirt, etc. To estimate the performance of the oil boom, it is necessary to predict the behavior of the spilled oil and oil boom. In the present study, the prediction of oil boom performance in waves was carried out using the Pusan-National-University-modified Moving Particle Semi-implicit (PNU-MPS) method, which is an improved version of the original MPS proposed by Koshizuka and Oka (1996). The governing equations, which consist of continuity and Navier-Stokes equations, are solved by Lagrangian moving particles, and all terms expressed by differential operators in the governing equations are replaced by the particle interaction models based on a kernel function. The simulation results were validated through a comparison with the results of Violeau et al. (2007)..

A Study on the Particle Size and Velocity Profile on a Gasoline Port Injector Using a Phase Doppler Particle Analyzers (PDPA) (위상 도플러 입자 분석기(PDPA)를 이용한 가솔린 포트 인젝터의 입자 크기 및 속도 프로파일에 관한 연구)

  • KIM, HYOJIN;JO, HYUN;TONGCHAI, SAKDA;LIM, OCKTACKE
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.3
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    • pp.300-307
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    • 2017
  • This study is to investigate particle size and velocity profile of gasoline port injector using Phase Doppler Particle Analyzer (PDPA). In this experiment, a GV 250 Delphi port injector used for motorcycles was used for liquid injection. The injector consists of four holes and has a static flow rate of 2.13 g/s. The fuel used in the injection was N-heptane, which is similar to gasoline, as an alternative fuel. The test fuel was injected at an atmospheric temperature of $20^{\circ}C$ and an open atmosphere of 1 atm. The injection time was 10 ms and the injection pressure was 3.5 bar in PDPA experiment. The experimental target position was fiexd at 30, 50 and 75 mm from the nozzle tip and data were collected for a total of 10,000 samples. The experimental results show that the length diameter (D10), the Sauter mean diameter ($D_{32}$), and the mean droplet velocity (MDV) are $45-54{\mu}m$, $99-115{\mu}m$ and 15-21 m/s, respectively.

Effects of Neutral Detergent Fiber Concentration and Particle Size of the Diet on Chewing Activities of Dairy Cows

  • Moon, Y.H.;Lee, S.C.;Lee, Sung S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.11
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    • pp.1535-1540
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    • 2004
  • Six dry Holstein cows were used to evaluate the effect of dietary neutral detergent fiber (NDF) concentration and particle size (PS) on chewing activity. Treatments were arranged in a 3$\times$3 factorial design; total mixed rations contained three NDF concentrations (26, 32, 38%) and three PS (1.0, 1.5, 2.0 cm). NDF levels and particle sizes of diets were adjusted by formulating rate and cutting length of alfalfa hay and rice straw. Cows were fed twice daily at 90% of ad libitum feed intake throughout the experiment. Chewing activity was positively associated with NDF concentration, but not significantly affected by PS of diet. Eating time per unit of NDF intake was affected by PS rather than NDF concentration of diet. Time spent ruminating per unit DM or NDF intake increased with increasing NDF concentration of diet, but was not affected by PS. As the PS of diet increased, the eating time per day increased, but the rumination time decreased. In addition, as the number of rumination bolues decreased the rumination duration increased as well as the chews per bolus. The regression equation induced from relationships of NDF concentrations (NDF, %) and particle sizes (PS, cm) of diet on roughage value index (RVI, min of chewing time/kg DMI) was as follows. RVI=-19.672+1.44$\times$NDF+5.196$\times$PS, ($R^{2}$=0.81).