• Title/Summary/Keyword: Particle Formation

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Effect of High Temperature Treatment and Subsequent Oxidation anil Reduction on Powder Property of Simulated Spent Fuel

  • Song, Kun-Woo;Kim, Young-Ho;Kim, Bong-Goo;Lee, Jung-Won;Kim, Han-Soo;Yang, Myung-Seung;Park, Hyun-Soo
    • Nuclear Engineering and Technology
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    • v.28 no.4
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    • pp.366-372
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    • 1996
  • The simulated spent PWR fuel pellet which is corresponding to the turnup of 33,000 MWD/MTU is prepared by adding 11 fission-product elements to UO$_2$. The simulated spent fuel pellet is treated at 40$0^{\circ}C$ in air (oxidation), at 110$0^{\circ}C$ in air (high-temperature treatment), and at $600^{\circ}C$ in hydrogen (reduction). The product is treated through additional addition and reduction up to 3 cycles. Pellets are completely pulverized by the first oxidation, and the high-temperature treatment causes particle and crystallite to grow and surface to be smooth, and thus particle size significantly increases and surface area decreases. The reduction following the high-temperature treatment decreases much the particle size by means of the formation of intercrystalline cracks. The particle size decreases a little during the second oxidation and reduction cycle and then remains nearly constant during the third and fourth cycles. Surface area of pounder increases progressively with the repetition of oxidation and reduction cycles, mainly due to the formation of Surface cracks. The degradation of surface area resulting from high-temperature treatment is restored by too subsequent resulting oxidation and reduction cycles.

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Preparation of Pt/C catalyst for PEM fuel cells using polyol process (Polyol Process를 통한 PEM Fuel Cell용 Pt/C촉매 제조)

  • Oh, Hyoung-Seok;Kim, Han-Sung
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.443-446
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    • 2006
  • Carbon-supported Platinum (Pt) is the potential electro-catalyst material for anodic and cathodic reactions in fuel cell. Catalytic activity of the metal strongly depends on the particle shape, size and distribution of the metal in the porous supportive network. Conventional preparation techniques based on wet impregnation and chemical reduction of the metal precursors often do not provide adequate control of particle size and shape. We have proposed a novel route for preparing nano sized Pt colloidal particles in solution by oxidation of ethylene glycol. These Pt nano particles were deposited on large surface area carbon support. The process of nano Pt colloid formation involves the oxidation of solvent ethylene glycol to mainly glycolic acid and the presence of its anion glycolate depends on the solution pH. In the process of colloidal Pt formation glycolate actsas stabilizer for the Pt colloidal particle and prevents the agglomeration of colloidal Pt particles. These mono disperse Pt particles in carbon support are found uniformly distributed in nearly spherical shape and the size distribution was narrow for both supported and unsupported metals. The average diameter of the Pt nano particle was controlled in the range off to 3 nm by optimizing reaction parameters. Transmission electron microscopy, CV and RRDE experiments were used to compliment the results.

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Mutual Localization of swarm robot using Particle Filter (Particle filter를 이용한 군집로봇의 상호위치인식)

  • Jung, Kwang-Min;Sim, Kwee-Bo
    • Journal of the Korean Institute of Intelligent Systems
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    • v.20 no.2
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    • pp.298-303
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    • 2010
  • robots determine the location of the other robot using wireless sensors. Use it to decide how to move his. And go to any location, will make shape of column and line, circle. In this paper, we discuss problem in circle formation enclosing target which moves. It is method about enclosed invader in circle formation based on mutual localization of swarm robot without infrastructure. Therefore, use trilateration that do not need to know the value of the coordinates of reference points. So, Specify enclosed point for the number of robots base on between the relative position of the robot in the coordinate system. And particle filter is proposed to improve the accuracy of the location.

Mechanism of Formation of Three Dimensional Structures of Particles in a Liquid Crystal

  • West, John L.;Zhang, Ke;Liao, Guangxun;Reznikov, Yuri;Andrienko, Denis;Glushchenko, Anatoliy V.
    • Journal of Information Display
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    • v.3 no.3
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    • pp.17-23
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    • 2002
  • In this work we report methods of formation of three-dimensional structures of particles in a liquid crystal host. We found that, under the appropriate conditions, the particles are captured and dragged by the moving isotropic/nematic front during the phase transition process. This movement of the particles can be enhanced significantly or suppressed drastically with the influence of an electric field and/or with changing the conditions of the phase transition, such as the rate of cooling. As a result, a wide variety of particle structures can be obtained ranging from a fine-grained cellular structure to stripes of varying periods to a course-grained "root" structures. Changing the properties of the materials, such as the size and density of the particles and the surface anchoring of the liquid crystal at the particle surface, can also be used to control the morphology of the three-dimensional particle network and adjust the physical properties of the resulting dispersions. These particle structures may be used to affect the performance of LCD's much as polymers have been used in the past.

An Improvement of the Vortex Particle Method (와류입자법의 개선)

  • 박외철
    • Journal of the Korean Society of Safety
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    • v.14 no.4
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    • pp.37-42
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    • 1999
  • Modifications were made in the vortex particle method by reducing the number of numerical parameters and adapting more accurate integration schemes. The method was applied to 0.15, 0.2 and 0.25 rectangles where the original method yielded poor results. Structure of vortex formation and its shedding in the wake was clearly shown, and vortex shedding was more regular than that without the modifications, while the time-averaged drag coefficients were nearly the same. It was confirmed the modified method could be used in the viscous vortex particle method.

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Solid Particle Erosion of CVD Diamond (CVD 다이아몬드 코팅의 고체입자 Erosion 특성)

  • 김종훈;임대순
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1997.04a
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    • pp.69-73
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    • 1997
  • Microwave Plasma assisted CVD (Chemical Vapor Deposition) and DC Plasma CVD were used to prepare thin and thick diamond film, respectively. Diamond coated silicon nitride and fiee standing diamond thick film were eroded by silicon carbide particles. The velocity of the solid particle was about 220m/sec. Phase transformation and the other crack formation were investigated by using Raman spectroscopy and microscopy.

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A New Model for the Analysis of Non-spherical Particle Growth Using the Sectional Method (구간해석방법을 통한 새로운 비구형 입자성장해석 모델)

  • Jeong, Jae-In;Choi, Man-Soo
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.416-421
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    • 2000
  • We have developed a simple model for describing the non-spherical particle growth phenomena using modified 1-dimensional sectional method. In this model, we solve simultaneously particle volume and surface area conservation sectional equations which consider particles' irregularities. From the correlation between two conserved properties of sections, we can predict the evolution of the aggregates' morphology. We compared this model with a simple monodisperse-assumed model and more rigorous two dimensional sectional model. For the comparison, we simulated silica and titania particle formation and growth in a constant temperature reactor environment. This new model shows a good agreement with the detailed two dimensional sectional model in total number concentration, primary particle size. The present model can also successfully predict particle size distribution and morphology without costing very heavy computation load and memory needed for the analysis of two dimensional aerosol dynamics.

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An Experimental Study on the Characteristics of Generated Particle using Homogeneous Condensation Particle Generator (응축입자 발생기에서의 입자 발생특성에 관한 실험적 연구)

  • Kim, J.H.;Kim, S.S.
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.392-397
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    • 2000
  • Mono-disperse particles generated by a condensation particle generator are widely used to meet the experimental and industrial needs. The characteristics of particles generated by homogeneous nucleation have been studied experimentally using a laminar flow condensation particle generator. Dry nitrogen gas saturated with oleic acid vapor was cooled well below the saturation temperature causing the highly supersaturated vapor to nucleate. The dependence of GSD(Geometric Standard Deviation), GMD(Geometric Mean Diameter), and the mass concentration of particles on the temperature at the evaporator, flow rate and the temperature condition at condenser was studied. The experimental results show that the mass concentration of particles is affected by the radial temperature profile at condenser. Nucleation at the center of the condenser causes the mass concentration of particles to increase. The experimental results also show that the suppression of additional nucleation by a constant temperature condition at the condenser increases the mean diameter of particle.

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In-situ Particle Characterization of Cu Nanopowder using Scanning Mobility Particle Sizer in Pulsed Wire Evaporation Method (전기폭발법에서 SMPS를 이용한 Cu 나노분말의 실시간 입자특성평가)

  • 이창우;맹덕영;박중학;유지훈;이재훈;이창규;김흥회
    • Journal of Powder Materials
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    • v.10 no.4
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    • pp.275-280
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    • 2003
  • Synthesis and characteristics of Cu nanopowder were considered by in-situ characterization method using SMPS in pulsed wire evaporation process. With increasing pressure in chamber, particle size and degree of agglomeration increased by increase of collision frequency. Also, it was found from the XRD analyses and BET measurements that crystallite size and particle size decreased with elevating applied voltage. However, SMPS measurements and TEM observation revealed the increase of particle size and degree of agglomeration with increase of applied voltage. These results suggested that particle growth and agglomeration depend on overheating factor in chamber at the early stage and thermal coagulation in filtering system during powder formation until collection.

Particle Emission Characteristics of Heavy-duty Diesel Engine using Aftertreatment Systems (후처리장치 부착에 따른 대형디젤엔진의 입자 배출특성)

  • Kwon, Sangil;Park, Yonghee
    • Journal of ILASS-Korea
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    • v.17 no.3
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    • pp.146-151
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    • 2012
  • This study was primarily focused on the experimental comparison of the particle emission characteristics for heavy duty engine. PM and particle number from various heavy duty engines and DPF type were analyzed with a golden particle measurement system recommended by the Particle Measurement Program. And the repeatability and reproducibility between test mode was analyzed. This study was conducted for the experimental comparison on particulate emission characteristics between the European and World-Harmonized test cycles for a heavy-duty diesel engine. To verify the particulate mass and particle number concentrations from various operating modes, ETC/ESC and WHTC/WHSC, both of which will be enacted in Euro VI emission legislation, were evaluated. Real-time particle formation of the transient cycles ETC and WHTC were strongly correlated with engine operating conditions and after-treatment device temperature. A higher particle number concentration during the ESC mode was ascribed to passive DPF regeneration and the thermal release of low volatile particles at high exhaust temperature conditions.