• Polymer(Korea)
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• v.35 no.2
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• pp.171-175
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• 2011

Isophorone diisocyanate(IPDI), polytetramethylene glycol 1000 (PTMG1000), and N-methyl diethanol amine (MDEA) were applied to prepare cationic polyurethane water dispersions (PUD). Various neutralizers and chain extenders were introduced in order to investigate property changes, such as particle size, viscosity, $T_g$, tensile strength, and water swellability, depending on chemical structure of those chemicals. While the PUDs neutralized by acetic acid showed a typical elastomeric behavior, the others used with hydrochloride presented crystalline behavior. Among chain extenders isophorone diamine (IPDA) provided the best mechanical property. The particle size of the PUD neutralized with HCl was smaller than that with acetic acid. It is believed that this is attributed to the size difference of counter ions. The PUD chain-extended with hydrazine had the smallest particle size.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.28 no.3
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• pp.273-282
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• 2018

Objectives: Dustiness of nanomaterials is considered as exposure index of essential material. Research on dustiness of nanomaterial is needed to control exposure in workplaces. Method: Dustiness measurement using vortex shaker were installed in the laboratory. Nanomaterials, 1 g, was put in the glass test tube and shaked using vortex shaker. Aerosol dispersed was measured using scanning mobility particle sizer(SMPS) and optical particle counter(OPC). Mass concentration using PVC filter and cassette was measured and TEM grid sampling was conducted. Total particle concentration and size distribution were calculated. Image and chemical composition of particles in the air were observed using transmission electron microscopy and energy dispersive X-ray spectrometer. Eleven different test nanomaterials were used in the study. Results: Rank of mass concentration and particle number concentration were coincided in most cases. Rank of nanomateirals with low concentration were not coincided. Two types of fumed silica had the highest mass concentration and particle number concentration. Indium tin oxide, a mixture of indium oxide and tin oxide, had high mass concentration and particle number concentration. Indium oxide had very low mass concentration and particle number concentration. Agglomeration of nanoparticles in the air were observed in TEM analysis and size distribution. In this study, mass concentration and particle number concentration were coincided and two index can be used together. The range of dustiness in particle number concentration were too wide to measure in one method. Conclusion: Particle number concentration ranged from low concentration to high concentration depend on type of nanomaterial, and varied by preparation and amount of nanomaterial used. Further study is needed to measure dustiness of all nanomaterial as one reference method.

• Korea-Australia Rheology Journal
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• v.18 no.3
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• pp.153-160
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• 2006

We analyzed the non-Newtonian and non-isothermal flow with Carreau-Yasuda viscosity model in co-rotating and counter-rotating twin screw extruder systems. The mixing performances with respect to the screw speed, the screw pitch, and the rotating direction have been investigated. The dynamics of mixing was studied numerically by tracking the motions of particles. The extent of mixing was characterized in terms of the deformation rate, the residence time distribution, and the average strain. The results showed that the high screw speed decreases the residence time but increases the deformation rate. Small screw pitch increases the residence time. It is concluded that the high screw speed increases the dispersive mixing performance, while the small screw pitch increases the distributive mixing performance. Co-rotating screw extruder has the better conveying performance and the distributive mixing performance than counter-rotating screw extruder with the same screw speed and pitch. Co-rotating screw extruder developed faster transport velocity and it is advantageous the flow characteristics to the mixing that transfers polymer melt from one barrel to the other barrel.

• Tribology and Lubricants
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• v.24 no.2
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• pp.96-103
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• 2008

PTFE is generally utilized as the form of composites with adding various fillers. The purpose of this paper lies on clarifying the friction and wear properties of the PTFE coating layer on steel. Especially, the effects of PTFE powder size for coating and surface roughness of the counter material on the properties are investigated. Sliding friction and wear tests are conducted at several sliding speeds by employing two types of PTFE coating layer using different powder sizes. One type of coating layer is composed of uniform fine powder, whereas the other type is made up of mixture powder of different sizes. As results, it is found that PTFE coating layer are effective to improve the wear resistance and to reduce the friction coefficient. It is clear that PTFE coating layers are abrasively removed by asperities of the counter material during sliding contact. However, PTFE coating layer with uniform fine powder shows somewhat better wear resistance than that with mixture powder of different sizes in low sliding speed region. It can be seen that the wear of the coating layer are drastically reduced because wear fragment from counter material are transferred to the coating layer. On the other hand, friction coefficient is shown not to be directly related with PTFE powder size in coating layer.

• Mass Spectrometry Letters
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• v.7 no.3
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• pp.64-68
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• 2016

Scanning electron microscopy combined with thermal ionization mass spectrometry (SEM-TIMS) was used to determine the precise isotope ratios of ultra-trace levels of uranium contained in individual microparticles. An advanced multiple ion counter system consisting of three secondary ion multipliers and two compact discrete dynodes was used for complete simultaneous ion detection. For verification purposes, using TIMS with complete simultaneous measurement, isotopes were analyzed in 5 pg of uranium of a certified reference material. A microprobe in the SEM was used to transfer individual particles from a NUSIMEP-7 sample to TIMS filaments, which were then subjected to SEM-TIMS and complete simultaneous measurement. The excellent agreement in the resulting uranium isotope ratios with the certified NUSIMEP-7 values shows the validity of SEM-TIMS with complete simultaneous measurement for the analysis of uranium isotopes in individual particles. Further experimental study required for investigation of simultaneous measurement using the advanced multiple ion counter system is presented.

• Transactions of the Korean Society of Automotive Engineers
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• v.6 no.6
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• pp.202-209
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• 1998

For development of SDI(Spark-ignited Direct Injection) engine, stratified mixture formation with adequate strength at spark plug was required in wide range of engine operating conditions. So, spray structure under high ambient pressure and spray distribution after impingement on piston bowl in motoring engine was visualized by using laser equipments. Also, incylinder bulk flow structure was measured by using PIV (Paiticle Image Velocimetry) system. Counter-rotating tumble port and bowl piston was found effective to conserve bulk motion directed to spark plug in compression stroke. In addition, mask attached near valve seat in intake port was proposed to attenuate conventional tumble component and enhance counter-rotating tumble component.

• 한국가시화정보학회:학술대회논문집
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• 2007.11a
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• pp.116-118
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• 2007

Three-dimensional (3D) velocity field information of a laminar flow in a curved micro tube of circular cross-section has been measured using a digital micro holographic particle tracking velocimetry (HPTV). The temporal evolution of instantaneous velocity field of a water flow in a curved micro tube of $100\;{\mu}\;m$ and $300\;{\mu}\;m$ in inner diameter was obtained. The 3D mean velocity field distribution was obtained quantitatively by statistical-averaging of instantaneous velocity fields. At low Dean number (De), a secondary flow was not generated in the curved tube. With increasing Dean number, the secondary flow constituted of two large-scale counter-rotating vortices was formed due to enhanced centrifugal force. To reveal the flow characteristics of high Dean numbers, trajectories of fluid particles were evaluated experimentally from the 3D velocity fields data measured by the HPTV technique. The present experimental results, especially the 3D particle trajectories, would be helpful to design and to understand the mixing phenomena in 3D curved passages of various curved micro-tubes or micro-channels.

• Journal of ILASS-Korea
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• v.19 no.4
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• pp.182-187
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• 2014

As the regulations for Particulate Matter (PM) and Particle Number (PN) emissions from Gasoline Direct Injection (GDI) Vehicle stringent recently, a lot of studies have been made on the emission characteristics of PM and PN. In this study, PM and PN emission characteristics were compared to GDI and Multi Port Injection (MPI) Vehicles using the Condensation Particle Counter (CPC) measurement equipment. And driving mode is divided into normal driving mode (CVS-75, NEDC, NIER 6, NIER 9) and a constant speed driving mode (10 km/h, 35 km/h, 80 km/h, 110 km/h) to evaluate the characteristics in the various operating conditions. In the results, most of the driving mode, PM and PN were emitted from GDI Vehicle more than MPI Vehicle. However, in the constant speed mode of 110 km/h, PM and PN from MPI Vehicle were also a lot of emission. It is determined to cause a difficulty in the fuel injection control of the MPI Vehicle.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.3
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• pp.326-333
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• 2003

In the measurement using DMA and CPC in series, there is some time delay for particles classified in DMA to detect in CPC. During this time, the DMA time-response changes due to the velocity profile of sampling tube and the diffusion of particles in the volume that exists between the DMA exit and the detector of ultra-fine CPC. This is called mixing effect. In the accelerated measurement methods like the TSI -SMPS, the size distribution is obtained from the correlation between the time-varying electrical potential of the DMA and the corresponding particle concentrations sampled in DMA. If the DMA time -response changes during this delay time, this can cause the error of a size distribution measured by this accelerated technique. The kernel function considering this mixing effect using the residence time distribution is proposed by Russell et al. In this study, we obtained a size distribution using this kernel to compare to the result obtained by the commercial accelerated measurement system, TSI -SMPS for verification and considered the errors that result from the mixing effect with the geometric mean diameters of originally sampled particles, using virtually calculated responses obtained with this kernel as input data.

• Journal of ILASS-Korea
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• v.14 no.4
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• pp.184-189
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• 2009

Recently, ultrafine particles emitted from internal combustion engine is main concern because of its well known adverse health effects. So Europe decided to start the regulation about diesel engine particle number emissions. The nanoparticles smaller than 50nm in diameter have the ability to penetrate deep into interstitial tissue of luge, where they may cause severe respiratory inflammation and acute pulmonary toxicity. Recent studies have showed that spark ignition engines emit particles number concentration comparable to those from diesel engines with DPF under high load and rich mixture conditions, including cold starts and acceleration. So this study investigated emission characteristics of ultrafine particles according to fuel injection type in gasoline vehicles and LPG vehicles. The test vehicles were tested on CVS-75 and NEDC vehicle test mode using the chassis dynamometer, CPC system applied as a particle measuring instrument at the end of dilution tunnel. As a result, the correlation between fuel injection type and particulate emission was determined. GDI vehicle emitted 10 times higher particles than PFI vehicles, and compared to Mixer and LPGI type LPG vehicle, LPLI vehicle emitted particles high.